JP2000279130A - Magnesium agent - Google Patents
Magnesium agentInfo
- Publication number
- JP2000279130A JP2000279130A JP11090907A JP9090799A JP2000279130A JP 2000279130 A JP2000279130 A JP 2000279130A JP 11090907 A JP11090907 A JP 11090907A JP 9090799 A JP9090799 A JP 9090799A JP 2000279130 A JP2000279130 A JP 2000279130A
- Authority
- JP
- Japan
- Prior art keywords
- magnesium
- coral
- dolomite
- baked
- calcined
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011777 magnesium Substances 0.000 title claims abstract description 117
- 229910052749 magnesium Inorganic materials 0.000 title claims abstract description 117
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title claims abstract description 116
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 20
- 235000014653 Carica parviflora Nutrition 0.000 claims abstract description 47
- 239000010459 dolomite Substances 0.000 claims abstract description 42
- 229910000514 dolomite Inorganic materials 0.000 claims abstract description 42
- 235000013305 food Nutrition 0.000 claims abstract description 15
- 235000013336 milk Nutrition 0.000 claims abstract description 9
- 239000008267 milk Substances 0.000 claims abstract description 9
- 210000004080 milk Anatomy 0.000 claims abstract description 9
- 241000243321 Cnidaria Species 0.000 claims abstract 7
- 235000014106 fortified food Nutrition 0.000 claims description 8
- 239000004480 active ingredient Substances 0.000 claims description 3
- 235000013365 dairy product Nutrition 0.000 claims description 3
- 235000019640 taste Nutrition 0.000 abstract description 7
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract description 4
- 239000011707 mineral Substances 0.000 abstract description 4
- 238000002156 mixing Methods 0.000 abstract description 4
- 239000002245 particle Substances 0.000 abstract description 4
- 208000001132 Osteoporosis Diseases 0.000 abstract description 3
- 206010012601 diabetes mellitus Diseases 0.000 abstract description 3
- 230000002265 prevention Effects 0.000 abstract description 3
- 201000010099 disease Diseases 0.000 abstract description 2
- 208000035475 disorder Diseases 0.000 abstract description 2
- 150000002680 magnesium Chemical class 0.000 abstract 1
- 210000000056 organ Anatomy 0.000 abstract 1
- 238000010298 pulverizing process Methods 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 244000132059 Carica parviflora Species 0.000 description 40
- 238000010521 absorption reaction Methods 0.000 description 11
- 239000000203 mixture Substances 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- 235000018102 proteins Nutrition 0.000 description 7
- 102000004169 proteins and genes Human genes 0.000 description 7
- 108090000623 proteins and genes Proteins 0.000 description 7
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 6
- 238000001354 calcination Methods 0.000 description 6
- 239000011575 calcium Substances 0.000 description 6
- 229910052791 calcium Inorganic materials 0.000 description 6
- 235000013351 cheese Nutrition 0.000 description 6
- 238000010304 firing Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 108010058846 Ovalbumin Proteins 0.000 description 5
- 235000015895 biscuits Nutrition 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 5
- 102000014171 Milk Proteins Human genes 0.000 description 4
- 108010011756 Milk Proteins Proteins 0.000 description 4
- 235000013361 beverage Nutrition 0.000 description 4
- 235000015110 jellies Nutrition 0.000 description 4
- 239000008274 jelly Substances 0.000 description 4
- 235000021239 milk protein Nutrition 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 102220547770 Inducible T-cell costimulator_A23L_mutation Human genes 0.000 description 3
- 229930006000 Sucrose Natural products 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 235000019606 astringent taste Nutrition 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 238000004945 emulsification Methods 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 235000010755 mineral Nutrition 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 239000005720 sucrose Substances 0.000 description 3
- -1 sucrose fatty acid ester Chemical class 0.000 description 3
- 235000013618 yogurt Nutrition 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 208000024172 Cardiovascular disease Diseases 0.000 description 2
- 206010010305 Confusional state Diseases 0.000 description 2
- 206010020772 Hypertension Diseases 0.000 description 2
- 240000001046 Lactobacillus acidophilus Species 0.000 description 2
- 235000013956 Lactobacillus acidophilus Nutrition 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 208000026980 Renal tubular disease Diseases 0.000 description 2
- 235000015197 apple juice Nutrition 0.000 description 2
- 210000000988 bone and bone Anatomy 0.000 description 2
- 230000003913 calcium metabolism Effects 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 238000009616 inductively coupled plasma Methods 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 229940039695 lactobacillus acidophilus Drugs 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 235000020124 milk-based beverage Nutrition 0.000 description 2
- 230000003472 neutralizing effect Effects 0.000 description 2
- 235000014059 processed cheese Nutrition 0.000 description 2
- 235000020185 raw untreated milk Nutrition 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 210000004872 soft tissue Anatomy 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 235000000346 sugar Nutrition 0.000 description 2
- 230000009967 tasteless effect Effects 0.000 description 2
- XWMKELOZYZOSKN-UHFFFAOYSA-N 1-[1-butyl-2-oxo-4-[3-(pyridin-3-ylmethoxy)phenyl]-1,8-naphthyridin-3-yl]-3-[2,6-di(propan-2-yl)phenyl]urea Chemical compound CC(C)C=1C=CC=C(C(C)C)C=1NC(=O)NC=1C(=O)N(CCCC)C2=NC=CC=C2C=1C(C=1)=CC=CC=1OCC1=CC=CN=C1 XWMKELOZYZOSKN-UHFFFAOYSA-N 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 206010003210 Arteriosclerosis Diseases 0.000 description 1
- 208000020401 Depressive disease Diseases 0.000 description 1
- 206010013911 Dysgeusia Diseases 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 208000000913 Kidney Calculi Diseases 0.000 description 1
- 240000002129 Malva sylvestris Species 0.000 description 1
- 235000006770 Malva sylvestris Nutrition 0.000 description 1
- 206010029148 Nephrolithiasis Diseases 0.000 description 1
- 101710121003 Oxygen-evolving enhancer protein 3, chloroplastic Proteins 0.000 description 1
- 241000700159 Rattus Species 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 241000194020 Streptococcus thermophilus Species 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 208000011775 arteriosclerosis disease Diseases 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 235000019658 bitter taste Nutrition 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 235000013353 coffee beverage Nutrition 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 235000014510 cooky Nutrition 0.000 description 1
- 235000015140 cultured milk Nutrition 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 235000013611 frozen food Nutrition 0.000 description 1
- 235000015203 fruit juice Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000021552 granulated sugar Nutrition 0.000 description 1
- 235000019674 grape juice Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000031891 intestinal absorption Effects 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 235000001055 magnesium Nutrition 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 230000003340 mental effect Effects 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 210000003205 muscle Anatomy 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 208000020016 psychiatric disease Diseases 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 235000020183 skimmed milk Nutrition 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 235000014214 soft drink Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 230000036325 urinary excretion Effects 0.000 description 1
- 235000012431 wafers Nutrition 0.000 description 1
Landscapes
- Non-Alcoholic Beverages (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
- Dairy Products (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
- Jellies, Jams, And Syrups (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、マグネシウム含量
が高く、呈味性が良好で、さらにマグネシウムの吸収性
に優れたマグネシウム剤に関する。また、本発明はマグ
ネシウム含量が高く、呈味性も良好で、さらにマグネシ
ウムの吸収性に優れたマグネシウム強化食品に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a magnesium agent having a high magnesium content, good taste, and excellent magnesium absorption. The present invention also relates to a magnesium-enriched food having a high magnesium content, good taste, and excellent magnesium absorption.
【0002】[0002]
【従来の技術】近年、健康維持や成人病の予防等に関し
てマグネシウムの役割が重要視され始めている。マグネ
シウムは生体内においてその60%は骨に、残りは筋肉や
その他の軟組織に存在し、酵素の調節作用、エネルギー
産生作用、タンパク質合成調節作用等を有しており、マ
グネシウムの摂取が不足すると臓器において重大な症候
性の変化が生じることが示唆されている。我が国におい
ても、出納試験の結果等から、1989年の「第4次改定
日本人の栄養所要量」からは、成人のマグネシウム摂取
目標量が 300mg/日と設定された。しかし、日本人成人
の実際のマグネシウム摂取量は 250mg/日程度であると
いわれており、マグネシウムの摂取量が不足していると
考えられる。また、アルコールや精神的なストレスによ
ってマグネシウムの尿中排泄量が増大することが知られ
ており、現代のストレス社会におけるマグネシウムの損
失が危惧されている。2. Description of the Related Art In recent years, the role of magnesium has become important in maintaining health and preventing adult diseases. Magnesium is found in bones, 60% in the body, and the rest in muscles and other soft tissues. Have been suggested to cause significant symptomatic changes. In Japan, based on the results of the balance test, etc., the "Fourth revision in 1989"
From the “Japanese nutritional requirements”, the target intake of magnesium for adults was set at 300 mg / day. However, the actual intake of magnesium in Japanese adults is said to be around 250 mg / day, indicating that the intake of magnesium is deficient. In addition, it is known that urinary excretion of magnesium is increased by alcohol and mental stress, and there is a fear that magnesium is lost in a modern stressed society.
【0003】また、マグネシウム代謝はカルシウム代謝
と密接な関係を有することが知られている。マグネシウ
ムが不足するとカルシウム代謝のバランスが崩れ、カル
シウムが軟組織に沈着し動脈硬化症や腎臓結石につなが
る。また、カルシウムの摂取量が増大するとマグネシウ
ムの腸管吸収が抑制され、体内のマグネシウム濃度を維
持するために骨中に貯蔵されていたマグネシウムが遊離
する。It is known that magnesium metabolism is closely related to calcium metabolism. Insufficient magnesium can disrupt the balance of calcium metabolism, depositing calcium in soft tissue, leading to arteriosclerosis and kidney stones. In addition, when the intake of calcium increases, the intestinal absorption of magnesium is suppressed, and the magnesium stored in the bone to maintain the magnesium concentration in the body is released.
【0004】従来より、マグネシウムを含む食品添加物
として、塩化マグネシウムや硫酸マグネシウム等の無機
塩が使用されている。しかし、無機のマグネシウム塩は
苦味を呈するため、マグネシウム補強剤としての利用上
は必ずしも好ましいものとはいえない。また、近年で
は、穀類果皮由来のマグネシウム(特開平7- 87930号公
報)、マグネシウム含有量を増加したミルクカゼイン
(特開平8- 84562号公報)、天然珊瑚ミネラルやドロマ
イト等の天然物由来のマグネシウムが開発されている
が、風味の点では改善が認められるものの、マグネシウ
ム含有量が低いため、マグネシウムの補給という点で必
ずしも充分とはいえない。さらに、マグネシウムの吸収
性についてはほとんど検討されていなかった。Heretofore, inorganic salts such as magnesium chloride and magnesium sulfate have been used as food additives containing magnesium. However, since inorganic magnesium salts exhibit bitterness, they cannot always be said to be preferable for use as magnesium reinforcing agents. In recent years, magnesium derived from cereal peel (JP-A-7-87930), milk casein having an increased magnesium content (JP-A-8-84562), and magnesium derived from natural products such as natural coral minerals and dolomite have been developed. Has been developed, but the flavor is improved, but the magnesium content is low, so that it is not always sufficient in terms of replenishing magnesium. Furthermore, the absorption of magnesium has hardly been studied.
【0005】[0005]
【発明が解決しようとする課題】したがって、本発明
は、マグネシウム含量が高く、呈味性が良好で、さらに
マグネシウムの吸収性に優れたマグネシウム剤を提供す
ること、及び、該マグネシウム剤を含有するマグネシウ
ム強化食品を提供することを課題とする。SUMMARY OF THE INVENTION Accordingly, the present invention is to provide a magnesium agent having a high magnesium content, good taste, and excellent magnesium absorption, and containing the magnesium agent. It is an object to provide a magnesium-enriched food.
【0006】[0006]
【課題を解決するための手段】本発明者らは、上記の問
題点に鑑み、マグネシウム含量が高く、呈味性が良好
で、しかも吸収性に優れたマグネシウム剤を得るべく検
討を重ねた結果、珊瑚又はドロマイトを焼成して得られ
る焼成珊瑚又は焼成ドロマイトが前記の目的に合致する
ことを見出し、本発明を完成するに至った。Means for Solving the Problems In view of the above problems, the present inventors have repeatedly studied to obtain a magnesium agent having a high magnesium content, good taste, and excellent absorbability. It has been found that calcined coral or dolomite obtained by calcining coral or dolomite meets the above-mentioned object, and the present invention has been completed.
【0007】未焼成の珊瑚又はドロマイトは食品添加用
マグネシウムとして既に市販されているが、マグネシウ
ム含量は10重量%前後と含量が低く、本発明の焼成珊瑚
又は焼成ドロマイトとは全く異なるものである。また、
珊瑚から飲食品添加用の酸化マグネシウムを調製する方
法(特開平8- 73213号公報)が開発されている。しか
し、その方法により得られた組成物はマグネシウム含量
が高いものの、その製造工程は、珊瑚を酸で溶解した
後、アルカリで中和し、珊瑚に含まれるカルシウムを除
去した後、さらに熱分解工程を経て酸化マグネシウムを
製造するという煩雑なものである。Unfired coral or dolomite is already commercially available as magnesium for food addition, but its magnesium content is as low as about 10% by weight, which is completely different from the fired coral or dolomite of the present invention. Also,
A method for preparing magnesium oxide for adding food and drink from coral (JP-A-8-73213) has been developed. However, although the composition obtained by this method has a high magnesium content, the manufacturing process involves dissolving the coral with an acid, neutralizing with an alkali, removing calcium contained in the coral, and further subjecting the composition to a thermal decomposition process. The production of magnesium oxide is complicated.
【0008】本発明では、珊瑚を酸溶解・中和の工程を
経ることなく焼成して製造される焼成珊瑚を、マグネシ
ウム剤として用いる。本発明の焼成珊瑚は、工程中でカ
ルシウムを除去していないため、カルシウムの補給の点
でも優れたものとなる。In the present invention, calcined coral produced by calcining coral without going through an acid dissolving / neutralizing step is used as a magnesium agent. Since the calcined coral of the present invention does not remove calcium in the process, it is excellent in replenishing calcium.
【0009】また、本発明では、ドロマイトを酸溶解・
中和の工程を経ることなく焼成して製造される焼成ドロ
マイトを、マグネシウム剤として用いる。なお、焼成ド
ロマイトは、ガラス、陶磁器等の原料、アスファルト充
填剤等、工業的な利用が広くなされているが、食品分野
での応用例はない。Further, in the present invention, dolomite is dissolved in an acid.
A calcined dolomite produced by calcining without going through a neutralization step is used as a magnesium agent. In addition, calcined dolomite is widely used in industrial applications such as raw materials for glass and ceramics, asphalt filler, and the like, but there is no application in the food field.
【0010】[0010]
【発明の実施の形態】前記の目的を達成するため、珊瑚
又はドロマイトを焼成して、焼成珊瑚又は焼成ドロマイ
ト中のマグネシウム含量が15重量%以上となるように調
製する。BEST MODE FOR CARRYING OUT THE INVENTION In order to achieve the above object, coral or dolomite is calcined so that the magnesium content in the calcined coral or calcined dolomite is 15% by weight or more.
【0011】得られる焼成珊瑚のマグネシウム含量を15
重量%以上にするために、固形物中のマグネシウム含量
が8重量%以上である珊瑚を原料として焼成する。ま
た、ドロマイトのマグネシウム含量は一般的に10〜13重
量%であり、これを焼成することによって、マグネシウ
ム含量が15重量%以上の焼成ドロマイトを得ることがで
きる。The calcined coral obtained has a magnesium content of 15
In order to make the solid content higher than 8 wt%, calcining is performed using coral whose magnesium content in the solid is 8 wt% or more as a raw material. Further, the dolomite generally has a magnesium content of 10 to 13% by weight, and by calcining this, a calcined dolomite having a magnesium content of 15% by weight or more can be obtained.
【0012】得られる焼成珊瑚又は焼成ドロマイト中の
マグネシウム含量を高めるためには、炉内温度 800℃以
上で焼成することが望ましい。特に望ましくは、1000℃
付近で焼成すると、マグネシウム高含有で安定な焼成珊
瑚又は焼成ドロマイトを得ることができる。焼成時間に
は特に制限はないが、効率的に焼成するためには1時間
以上焼成することが望ましい。また、焼成に際しては、
珊瑚又はドロマイトを予め粉砕しておくと効率的に焼成
できる。また、既に粉砕済の市販珊瑚ミネラルや市販ド
ロマイトを焼成してもよい。このようにして得られた焼
成珊瑚又は焼成ドロマイトは、マグネシウム含量が高い
だけではなく、呈味性が良好であり、マグネシウムの吸
収性が非常に高いという特徴を有する。In order to increase the magnesium content in the resulting calcined coral or calcined dolomite, it is desirable to calcinate at a furnace temperature of 800 ° C. or higher. Particularly desirable is 1000 ° C
When calcined in the vicinity, stable calcined coral or calcined dolomite with a high magnesium content can be obtained. The firing time is not particularly limited, but it is preferable to perform firing for one hour or more for efficient firing. When firing,
If coral or dolomite is crushed in advance, it can be efficiently fired. Further, commercially available coral mineral or commercially available dolomite which has been pulverized may be fired. The calcined coral or the dolomite thus obtained has not only a high magnesium content, but also a good taste and a very high magnesium absorption.
【0013】このようにして製造された焼成珊瑚及び/
又は焼成ドロマイトを食品に添加することにより、本発
明のマグネシウム強化食品を得る。食品としては、コー
ヒー飲料、果汁飲料、清涼飲料等の各種飲料、ゼリー、
クッキー、ビスケット、ウエハース等の菓子、冷凍食品
等の食品、乳、乳飲料、発酵乳、粉乳、チーズ等の乳製
品等の各種飲食品を例示できる。特に、乳又は乳製品に
添加すると、マグネシウムの吸収性がさらに高くなるの
で望ましい。The calcined coral thus produced and / or
Alternatively, the magnesium-enriched food of the present invention is obtained by adding calcined dolomite to the food. Foods include coffee drinks, fruit juice drinks, various drinks such as soft drinks, jelly,
Examples of the foods include confectionery such as cookies, biscuits and wafers, foods such as frozen foods, milk and milk drinks, fermented milk, milk powder, and dairy products such as cheeses. In particular, when added to milk or dairy products, magnesium absorption is further enhanced, which is desirable.
【0014】焼成珊瑚及び/又は焼成ドロマイトを食品
に添加する方法には特に制限はなく、焼成して得られた
粉体をそのまま添加しても、粉砕機によって微粉末にし
た後に添加してもよい。なお、特に、焼成珊瑚及び/又
は焼成ドロマイトを飲料に添加する場合には、焼成した
後に粉砕し、乳化剤を混合してエマルジョン化したもの
を添加すると、本発明のマグネシウム剤の沈澱を防ぐこ
とが出来る。The method for adding the calcined coral and / or the calcined dolomite to the food is not particularly limited, and the powder obtained by calcining may be added as it is, or may be added after being pulverized into a fine powder by a pulverizer. Good. In particular, in the case where baked coral and / or baked dolomite are added to a beverage, if the baked crushed and crushed, and the emulsifier is mixed and emulsified to be added, precipitation of the magnesium agent of the present invention can be prevented. I can do it.
【0015】なお、本発明の焼成珊瑚及び/又は焼成ド
ロマイトを食品に配合するに際し、その配合量に制限は
特にないが、食品中のマグネシウム含量が、成人一人一
日当たりマグネシウムを10〜500mg 程度摂取できる含量
になるように、各種飲食品の形態に合わせて配合するこ
とが望ましい。The amount of the calcined coral and / or the calcined dolomite of the present invention is not particularly limited, but the amount of magnesium contained in the food may be about 10 to 500 mg of magnesium per day per adult. It is desirable to mix it according to the form of various foods and drinks so that the content can be obtained.
【0016】このようにして得られる本発明のマグネシ
ウム剤及びマグネシウム強化食品は、マグネシウムの摂
取不足に伴う高血圧等の循環器疾患、抑鬱病、精神の錯
乱等の精神障害、腎尿細管機能障害、さらには糖尿病、
骨粗鬆症の予防又は治療のために使用することができ
る。The magnesium agent and the magnesium-enriched food of the present invention obtained as described above include cardiovascular diseases such as hypertension due to insufficient intake of magnesium, mental disorders such as depression and mental confusion, renal tubular dysfunction, Even diabetes,
It can be used for the prevention or treatment of osteoporosis.
【0017】以下、実施例及び試験例を示して本発明を
詳細に説明する。なお、実施例中、マグネシウム含量
は、誘導結合プラズマ発光分光器(ICP) (ST-3000、Leem
an Labs 社製) を用いて測定した。Hereinafter, the present invention will be described in detail with reference to examples and test examples. In the examples, the magnesium content was determined by an inductively coupled plasma emission spectrometer (ICP) (ST-3000, Leem
an Labs).
【0018】[0018]
【実施例1】市販の珊瑚ミネラル(商品名:SMP-500 、
マリーンバイオ社製)を、焼成炉内において約1000℃の
温度で1時間焼成して、焼成珊瑚を得た。なお、この焼
成珊瑚中のマグネシウム含量は18.8重量%であった。こ
の焼成珊瑚は、マグネシウム独特の収斂味が全くなく、
無味であった。Example 1 Commercially available coral mineral (trade name: SMP-500,
(Made by Marine Bio Inc.) was fired in a firing furnace at a temperature of about 1000 ° C. for 1 hour to obtain a fired coral. The magnesium content in the calcined coral was 18.8% by weight. This calcined coral has no astringent taste unique to magnesium,
It was tasteless.
【0019】[0019]
【実施例2】ドロマイトの原石を平均粒子径が10mm以下
になるまで粉砕機にて粉砕し、水洗いした後に焼成炉内
において約1100℃の温度で24時間焼成して、さらに平均
粒子径が0.15mm以下になるまで粉砕し、さらに高圧ホモ
ジナイザーにて平均粒子径が10μm 以下になるまで粉砕
し、微粉化した焼成ドロマイトを得た。なお、この焼成
ドロマイト中のマグネシウム含量は23.9重量%であっ
た。この焼成ドロマイトは、マグネシウム独特の収斂味
が全くなく、無味であった。Example 2 A dolomite rough was pulverized with a pulverizer until the average particle diameter became 10 mm or less, washed with water, fired in a firing furnace at a temperature of about 1100 ° C. for 24 hours, and further reduced to an average particle diameter of 0.15 mm. mm or less, and further pulverized with a high-pressure homogenizer until the average particle size becomes 10 μm or less, to obtain a finely powdered calcined dolomite. The magnesium content in the calcined dolomite was 23.9% by weight. This calcined dolomite had no astringent taste peculiar to magnesium and was tasteless.
【0020】[0020]
【試験例1】マグネシウム吸収試験を、10週齢のSD系雄
ラットを用いて行った。実験群は以下の6群とした。Test Example 1 A magnesium absorption test was performed using 10-week-old male SD rats. The experimental groups were the following six groups.
【0021】A群:市販の未焼成珊瑚粉末(商品名:SM
P-500 、マリーンバイオ社製、マグネシウム含量10.0重
量%)をマグネシウム源とし、タンパク質源として卵ア
ルブミンを用いた飼料群 B群:市販の未焼成ドロマイト(商品名:ドロマイト、
協和ハイフーズ社製、マグネシウム含量12.5重量%)を
マグネシウム源とし、タンパク質源として卵アルブミン
を用いた飼料群 C群:実施例1で得られた焼成珊瑚(マグネシウム含量
18.8重量%)をマグネシウム源とし、タンパク質源とし
て卵アルブミンを用いた飼料群 D群:実施例2で得られた焼成ドロマイト(マグネシウ
ム含量23.9重量%)をマグネシウム源とし、タンパク質
源として卵アルブミンを用いた飼料群 E群:実施例1で得られた焼成珊瑚(マグネシウム含量
18.8重量%)をマグネシウム源とし、タンパク質源とし
て乳タンパク質を用いた飼料群 F群:実施例2で得られた焼成ドロマイト(マグネシウ
ム含量23.9重量%)をマグネシウム源とし、タンパク質
源として乳タンパク質を用いた飼料群 なお、飼料の配合にあたっては、各飼料中のマグネシウ
ム含量が 0.1重量%となるように各マグネシウム剤を配
合し、さらに、炭酸カルシウムを用いて、各飼料中のカ
ルシウム含量が 0.5重量%となるように配合した。これ
らの飼料にて3週間飼育し、3週目に出納試験を行い、
見かけのマグネシウム吸収率を測定した。Group A: commercially available unfired coral powder (trade name: SM
P-500, manufactured by Marine Bio Inc., magnesium content 10.0% by weight) as a magnesium source, and a feed group using egg albumin as a protein source Group B: commercially available unfired dolomite (trade name: dolomite,
Feed group using Kyowa High Foods Co., Ltd., magnesium content of 12.5% by weight) as a magnesium source and egg albumin as a protein source Group C: baked coral (magnesium content) obtained in Example 1
18.8% by weight) as a magnesium source and a feed group using egg albumin as a protein source Group D: Using the calcined dolomite (magnesium content 23.9% by weight) obtained in Example 2 as a magnesium source and using egg albumin as a protein source Feed group E: baked coral obtained in Example 1 (magnesium content
18.8% by weight) as a magnesium source and a feed group using milk protein as a protein source Group F: Using the baked dolomite (magnesium content 23.9% by weight) obtained in Example 2 as a magnesium source and using milk protein as a protein source In addition, when mixing the feed, mix each magnesium agent so that the magnesium content in each feed is 0.1% by weight, and further use calcium carbonate to reduce the calcium content in each feed to 0.5% by weight. It was blended so that They were bred on these feeds for 3 weeks, and a cashier test was conducted on the 3rd week.
Apparent magnesium absorption was measured.
【0022】結果を表1に示す。The results are shown in Table 1.
【0023】[0023]
【表1】 [Table 1]
【0024】表1の結果より、本発明の焼成珊瑚又は焼
成ドロマイトをマグネシウム源とするC群、D群、E
群、F群は、マグネシウムの吸収性に優れていることが
確認された。また、中でも、タンパク質源として乳タン
パク質を使用したE群、F群は、卵アルブミンを使用し
たC群、D群と比較しても、さらにマグネシウムの吸収
性に優れていることが示された。From the results shown in Table 1, groups C, D, and E using the calcined coral or dolomite of the present invention as a magnesium source were obtained.
It was confirmed that the group and the F group were excellent in magnesium absorption. Further, among them, it was shown that the group E and the group F using milk protein as a protein source were more excellent in magnesium absorbability as compared with the group C and the group D using egg albumin.
【0025】[0025]
【実施例3】混合異性化糖15.0重量%、リンゴ果汁10.0
重量%、香料 0.1重量%、実施例1で得られた焼成珊瑚
0.3重量%、水74.6重量%を混合して、 100℃で30分間
殺菌し、マグネシウムを強化したリンゴ果汁飲料を得
た。得られた飲料中のマグネシウム含量は、飲料100gあ
たり55mgであった。[Example 3] Mixed isomerized sugar 15.0% by weight, apple juice 10.0
Wt%, fragrance 0.1 wt%, calcined coral obtained in Example 1
0.3% by weight and 74.6% by weight of water were mixed and sterilized at 100 ° C. for 30 minutes to obtain an apple juice beverage enriched with magnesium. The magnesium content in the obtained beverage was 55 mg per 100 g of the beverage.
【0026】[0026]
【実施例4】40℃の水58.4重量%に、ブドウ果汁20.0重
量%、グラニュー糖15.0重量%、水飴 5.0重量%、寒天
粉末 1.0重量%、実施例2で得られた焼成ドロマイト
0.5重量%及び香料 0.1重量%を混合してミックスとし
た。このミックスを 130℃で2秒間殺菌した後、充填機
により容器に充填し、さらに10℃まで冷却して、マグネ
シウムを強化したゼリーを得た。得られたゼリー中のマ
グネシウム含量は、ゼリー100gあたり 117mgであった。Example 4 58.4% by weight of water at 40 ° C., 20.0% by weight of grape juice, 15.0% by weight of granulated sugar, 5.0% by weight of starch syrup, 1.0% by weight of agar powder, calcined dolomite obtained in Example 2
A mixture was prepared by mixing 0.5% by weight and 0.1% by weight of flavor. After this mixture was sterilized at 130 ° C. for 2 seconds, it was filled into a container by a filling machine, and further cooled to 10 ° C. to obtain a jelly reinforced with magnesium. The magnesium content in the obtained jelly was 117 mg per 100 g of jelly.
【0027】[0027]
【実施例5】バター12.0重量%、砂糖24.0重量%、卵
6.0重量%、牛乳 7.0重量%、小麦粉48.3重量%、ベー
キングパウダー 0.5重量%、香料 0.2重量%、実施例2
で得られた焼成ドロマイト 2.0重量%を配合して常法に
よりビスケット用の生地を調製した。得られた生地を、
185℃、15分間加熱し、マグネシウムを強化したビスケ
ットを得た。得られたビスケット中のマグネシウム含量
は、ビスケット100gあたり 477mgであった。Example 5 12.0% by weight of butter, 24.0% by weight of sugar, egg
6.0% by weight, milk 7.0% by weight, flour 48.3% by weight, baking powder 0.5% by weight, fragrance 0.2% by weight, Example 2
The baked dolomite obtained in the above was mixed with 2.0% by weight to prepare biscuit dough by a conventional method. The obtained dough,
The mixture was heated at 185 ° C. for 15 minutes to obtain a biscuit reinforced with magnesium. The magnesium content in the obtained biscuit was 477 mg per 100 g of biscuit.
【0028】[0028]
【実施例6】乳化剤としてショ糖脂肪酸エステル(商品
名:DKエステルF−160、第一工業製薬社製)を、
65℃の温水中に15分間保持して溶解し、6重量%となる
ように水溶液を調製した後、冷却した。次いで、実施例
1で得られた焼成珊瑚と、前記で調製したショ糖脂肪酸
エステル水溶液とを、分散液中の焼成珊瑚濃度が18重量
%、ショ糖脂肪酸エステル濃度が2重量%になるように
混合して、焼成珊瑚を含有する分散液を得た。次いで、
前記の操作で得られた焼成珊瑚を含有する分散液を、高
圧ホモジナイザーにより均質化した分散液を得た。な
お、高圧ホモジナイザーの圧力は450kgf/cm2となるよう
に調整した。この分散液を、マグネシウム含量が 50mg/
100gとなるように生乳に添加し、150kgf/cm2で均質処理
を行い、プレート殺菌機を用いて 130℃、2秒間殺菌
し、マグネシウム強化乳飲料を得た。Example 6 A sucrose fatty acid ester (trade name: DK ester F-160, manufactured by Daiichi Kogyo Seiyaku Co., Ltd.) was used as an emulsifier.
After dissolving in hot water of 65 ° C. for 15 minutes to dissolve the solution, an aqueous solution was prepared to be 6% by weight, and then cooled. Next, the fired coral obtained in Example 1 and the aqueous sucrose fatty acid ester solution prepared above were mixed so that the fired coral concentration in the dispersion was 18% by weight and the sucrose fatty acid ester concentration was 2% by weight. By mixing, a dispersion containing calcined coral was obtained. Then
The dispersion containing the calcined coral obtained by the above operation was homogenized with a high-pressure homogenizer to obtain a dispersion. The pressure of the high-pressure homogenizer was adjusted to 450 kgf / cm 2 . This dispersion is treated with a magnesium content of 50 mg /
100 g was added to the raw milk, homogenized at 150 kgf / cm 2 and sterilized at 130 ° C. for 2 seconds using a plate sterilizer to obtain a magnesium-enriched milk beverage.
【0029】[0029]
【実施例7】脱脂粉乳を固形率が12%となるように水に
溶解し、90℃で20分間加熱殺菌した後、25℃に冷却し、
この還元脱脂乳にラクトバチルス・アシドフィルス(Lac
tobacillus acidophilus) 及びストレプトコッカス・サ
ーモフィルス(Streptococcusthermophilus)を接種して
発酵させた。次に、乳酸酸度が 1.0%で、pHが 4.3にな
った時点で培養物を5℃に冷却し、スターターカルチャ
ーとした。このスターターカルチャーを脂肪分 3.5%の
殺菌した生乳に5%接種した後、実施例1で得られた焼
成珊瑚 0.5重量%を添加し、常法に従って醗酵させてマ
グネシウムを強化したヨーグルトを得た。得られたヨー
グルト中のマグネシウム含量は、ヨーグルト100gあたり
102mgであった。Example 7 Skim milk powder was dissolved in water to a solid content of 12%, sterilized by heating at 90 ° C for 20 minutes, and then cooled to 25 ° C.
Lactobacillus acidophilus (Lac
tobacillus acidophilus) and Streptococcus thermophilus and fermented. Next, when the lactic acid acidity reached 1.0% and the pH reached 4.3, the culture was cooled to 5 ° C. to obtain a starter culture. 5% of this starter culture was inoculated into sterilized raw milk having a fat content of 3.5%, to which 0.5% by weight of the calcined coral obtained in Example 1 was added, followed by fermentation according to a conventional method to obtain a yogurt enriched with magnesium. Magnesium content in the obtained yogurt, per 100g of yogurt
102 mg.
【0030】[0030]
【実施例8】原料チーズとして、ゴーダチーズとチェダ
ーチーズを1:1の割合で混合し、これに溶融塩として
クエン酸ナトリウムを原料チーズに対して2%添加し、
さらに、添加水10%及び実施例2で得られた焼成ドロマ
イト1%を添加して、乳化温度85℃で常法に従い乳化し
た。そして、乳化後、カルトンに充填し、二昼夜5℃で
冷却して、マグネシウムを強化したプロセスチーズを得
た。得られたプロセスチーズ中のマグネシウム含量は、
プロセスチーズ100gあたり 255mgであった。Example 8 As raw material cheese, Gouda cheese and cheddar cheese were mixed at a ratio of 1: 1. To this, 2% of sodium citrate was added as a molten salt to the raw material cheese.
Further, 10% of added water and 1% of the calcined dolomite obtained in Example 2 were added, and emulsification was carried out at an emulsification temperature of 85 ° C according to a conventional method. Then, after emulsification, the mixture was filled in a carton and cooled at 5 ° C. for two days and night to obtain a process cheese reinforced with magnesium. The magnesium content in the obtained processed cheese is
It was 255 mg per 100 g of processed cheese.
【0031】[0031]
【発明の効果】以上説明した通り、本発明により、マグ
ネシウムを15重量%以上含有する焼成珊瑚及び/又は焼
成ドロマイトを有効成分とするマグネシウム剤が提供さ
れる。また、本発明の焼成珊瑚及び/又は焼成ドロマイ
トをマグネシウム剤として含有する、マグネシウム強化
食品が提供される。As described above, the present invention provides a magnesium agent containing calcined coral and / or calcined dolomite containing 15% by weight or more of magnesium as an active ingredient. Further, there is provided a magnesium-enriched food containing the baked coral and / or baked dolomite of the present invention as a magnesium agent.
【0032】本発明のマグネシウム剤は、マグネシウム
の含量が高いだけではなく、収斂味がないため呈味性に
も優れ、さらにはマグネシウムの吸収性にも優れてい
る。また、本発明のマグネシウム剤を配合した本発明の
マグネシウム強化食品は、マグネシウムの補給のために
有効なものとなる。特に、乳タンパク質を含有する乳又
は乳製品に本発明のマグネシウム剤を配合したものは、
特にマグネシウムの吸収性に優れており、マグネシウム
の補給のために有効である。The magnesium agent of the present invention not only has a high magnesium content, but also has excellent taste due to lack of astringent taste, and also has excellent magnesium absorption. Further, the magnesium-enriched food of the present invention containing the magnesium agent of the present invention is effective for supplementing magnesium. In particular, those containing the magnesium agent of the present invention in milk or milk products containing milk protein,
In particular, it has excellent magnesium absorption, and is effective for replenishing magnesium.
【0033】そして、本発明のマグネシウム剤及びマグ
ネシウム強化食品は、マグネシウムの摂取不足に伴う高
血圧等の循環器疾患、抑鬱病、精神の錯乱等の精神障
害、腎尿細管機能障害、さらには糖尿病、骨粗鬆症の予
防又は治療に使用することができる。The magnesium agent and the magnesium-enriched food of the present invention are useful for treating cardiovascular diseases such as hypertension, depression, mental disorders such as mental confusion, renal tubular dysfunction, diabetes, It can be used for the prevention or treatment of osteoporosis.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) A23L 2/52 A23L 2/38 B 4C087 2/38 A61K 31/00 603B A61K 31/00 603 33/06 33/06 35/56 35/56 A23L 2/00 F Fターム(参考) 4B001 AC46 BC08 BC12 EC05 4B017 LC03 LG04 LK01 LP18 4B018 LB01 LB07 LB08 MD03 MD71 ME03 ME04 ME05 MF04 MF07 4B041 LC10 LD01 LH10 LK02 LP01 LP03 4C086 AA02 AA03 HA04 MA01 MA02 MA04 MA52 NA05 ZA12 ZA18 ZA36 ZA81 ZA97 ZC35 4C087 AA01 BB04 CA01 MA02 MA52 NA05 ZA12 ZA18 ZA36 ZA81 ZA97 ZC35 ──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) A23L 2/52 A23L 2/38 B 4C087 2/38 A61K 31/00 603B A61K 31/00 603 33/06 33 / 06 35/56 35/56 A23L 2/00 FF term (reference) 4B001 AC46 BC08 BC12 EC05 4B017 LC03 LG04 LK01 LP18 4B018 LB01 LB07 LB08 MD03 MD71 ME03 ME04 ME05 MF04 MF07 4B041 LC10 LD01 LH10 LK02 LP01 LP02 A04A04A MA01 MA02 MA04 MA52 NA05 ZA12 ZA18 ZA36 ZA81 ZA97 ZC35 4C087 AA01 BB04 CA01 MA02 MA52 NA05 ZA12 ZA18 ZA36 ZA81 ZA97 ZC35
Claims (4)
効成分とするマグネシウム剤。A magnesium agent comprising calcined coral and / or calcined dolomite as an active ingredient.
焼成珊瑚及び/又は焼成ドロマイトを有効成分とするマ
グネシウム剤。2. A magnesium agent comprising as an active ingredient calcined coral and / or calcined dolomite having a magnesium content of 15% by weight or more.
有することを特徴とするマグネシウム強化食品。3. A magnesium-enriched food containing calcined coral and / or calcined dolomite.
載のマグネシウム強化食品。4. The magnesium-fortified food according to claim 3, wherein the food is milk or a dairy product.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001158742A (en) * | 1999-12-02 | 2001-06-12 | Marine Bio Kk | Active oxygen scavenger, filter, health food, food, and drink |
JP2004043335A (en) * | 2002-07-10 | 2004-02-12 | Marine Bio Kk | Mineral-containing composition having blood sugar level-lowering function |
JP2009112222A (en) * | 2007-11-05 | 2009-05-28 | Snow Brand Milk Prod Co Ltd | Blue-veined natural cheese and method for producing the same |
-
1999
- 1999-03-31 JP JP09090799A patent/JP4046256B2/en not_active Expired - Fee Related
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001158742A (en) * | 1999-12-02 | 2001-06-12 | Marine Bio Kk | Active oxygen scavenger, filter, health food, food, and drink |
JP4611476B2 (en) * | 1999-12-02 | 2011-01-12 | マリーンバイオ株式会社 | filter |
JP2004043335A (en) * | 2002-07-10 | 2004-02-12 | Marine Bio Kk | Mineral-containing composition having blood sugar level-lowering function |
JP2009112222A (en) * | 2007-11-05 | 2009-05-28 | Snow Brand Milk Prod Co Ltd | Blue-veined natural cheese and method for producing the same |
Also Published As
Publication number | Publication date |
---|---|
JP4046256B2 (en) | 2008-02-13 |
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