JP2000169461A - Insecticide and microbicide composition and its production - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain the subject composition high in a pest-controlling activity, long persistent in controlling effect on Pyricularia oryzae and laborsaving in such a controlling operation by including a specific thiadiazole derivative and insecticidal activity-containing compound. SOLUTION: This composition is obtained by including, as an active ingredient, (A) an 1,2,3-thiadiazole derivative of the formula [R1 is e.g. H or an 1-6C alkyl; and R2 is e.g. a group of CO-Y-R3 (R3 is e.g. H or an 1-20C alkyl; and Y is e.g. O or S)] or its salt and (B) one or more kinds of compounds (e.g. carbamate-based insecticide) selected from insecticidal compounds. A formulation ratio of the composition is 0.1 to 100 pts.wt. of component B based on 1 pts.wt. of component A, and the formulation ratio of the total active ingredient to the composition is (1 to 50) to 100. The usage of the composition is pref. 1 to 50 g are as the active ingredient.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

The present invention relates to a 1,2,3-thiadiazole derivative represented by the general formula (I) useful as an agent for controlling undesirable pests and insect pests on crops, and a compound having insecticidal activity. The present invention relates to a pesticidal fungicide composition containing one or more pesticidal compounds and a method for using the same.

[0002]

2. Description of the Related Art The 1,2,3-thiadiazole derivative represented by the general formula (I) partially contains a novel 1,2,3-thiadiazole derivative, but most of them are disclosed in JP-A-8-325.
It is a known compound described in, for example, Japanese Patent Publication No. 110 and described as being useful as a plant disease controlling agent, and the other component, a compound having insecticidal activity, is described in, for example, Agricultural Chemicals Handbook 1997- Association) and the like. Conventionally, in order to control various pests, various insecticides and fungicides are used in nursery boxes in paddy rice cultivation and after transplantation in Honda, seedling boxes and upland in upland cultivation, orchards in orchard cultivation, seeds for various cultivation, etc. Has been applied.

[0003]

In recent years, the employment of the farming population has been decreasing and the population is aging, and there has been a strong demand for labor saving in farming work against the background of low-cost agriculture. Especially in paddy rice cultivation, the work load is heavy, so in order to reduce the labor and shorten the time required for spraying pesticides and fungicides for controlling pests of paddy rice, a broad spectrum pesticide It has been desired to develop an insecticidal fungicide which is effective against a plurality of pests without losing the characteristics of each compound. However, if you spray the drug,
It is necessary to adjust the time of use in accordance with the pest occurrence pattern, and the time of occurrence of the pest does not always coincide with the time of occurrence of the pest, so it has been difficult to achieve a sufficient control effect with a simple combination of drugs. In addition, when a conventional drug having a sufficient control effect on rice blast is applied to, for example, a rice nursery box, the effect is generally insufficient in persistence, so it was necessary to spray the drug again. . The same applies to the treatment of seeds or seedlings in upland cultivation, fruit tree cultivation, and the like.

[0004]

The present invention provides a compound of the general formula (I)

Embedded image Wherein R ¹ is a hydrogen atom, a (C _1-6 ) alkyl group or (C _3-7 )
R ² represents CO-YR ³ (wherein R ³ represents a cycloalkyl group)
Is a hydrogen atom, a (C _1-20 ) alkyl group, a halo (C _1-20 ) alkyl group, a (C _2-20 ) alkenyl group, a halo (C _2-20 ) alkenyl group, a (C _2-20 ) alkynyl group , Halo (C _2-20 ) alkynyl group, (C _3-12 ) cycloalkyl group, (C _1-6 ) alkoxy (C
_1-6 ) alkyl group, (C _1-6 ) alkoxy (C _1-6 ) alkoxy (C
_1-6 ) alkyl group, carboxy (C _1-6 ) alkyl group,
(C _1-20 ) alkoxycarbonyl (C _1-6 ) alkyl group, carbamoyl (C _1-6 ) alkyl group, which may be the same or different,
A (C _1-6 ) alkyl group, a phenyl group or one or more halogen atoms which may be the same or different or one or two substituents selected from a phenyl group substituted by a (C _1-6 ) alkyl group; Having a substituted carbamoyl (C _1-6 ) alkyl group, cyano (C _1-6 )
Alkyl group, (C _1-6 ) alkylcarbonyloxy (C _1-6 ) alkyl group, (C _1-6 ) alkylcarbonylamino (C _1-6 ) alkyl group, phenyl group, which may be the same or different, halogen Atom, hydroxyl group, cyano group, nitro group, (C _1-6 ) alkyl group, halo (C _1-6 ) alkyl group, (C _1-6 ) alkoxy group, halo
(C _1-6 ) alkoxy group, carboxyl group, (C _1-12 ) alkoxycarbonyl group, carbamoyl group or same or different, halogen atom, (C _1-12 ) alkyl group, phenyl group or 1-5 May be the same or different (C _1-6 )
A substituted phenyl group having 1 to 5 substituents selected from a carbamoyl group having 1 to 2 substituents selected from a phenyl group substituted by an alkyl group,

A phenyl (C _1-6 ) alkyl group, which may be the same or different, a halogen atom, a hydroxyl group, a cyano group, a nitro group, a (C _1-6 ) alkyl group, a halo (C _1-6 ) alkyl group, (C _1-6 )
An alkoxy group, a halo (C _1-6 ) alkoxy group, a carboxyl group, a (C _1-12 ) alkoxycarbonyl group, a carbamoyl group or may be the same or different, a halogen atom, (C _1-
12 ) selected from an alkyl group, a phenyl group or a carbamoyl group having 1 to 2 substituents selected from a phenyl group substituted by 1 to 5 identical or different (C _1-6 ) alkyl groups; A phenyl (C _1-6 ) alkyl group having 1 to 5 substituents on a ring, phenylcarbonyloxy
(C _1-6) alkyl group, which may be identical or different, a halogen atom, a hydroxyl group, a cyano group, a nitro group, (C _1-6) alkyl groups, halo (C _{1- 6)} alkyl, (C _{1- 6} ) alkoxy group, halo
(C _1-6 ) alkoxy group, carboxyl group, (C _1-12 ) alkoxycarbonyl group, carbamoyl group or same or different, halogen atom, (C _1-12 ) alkyl group, phenyl group or 1-5 May be the same or different (C _1-6 )
Substituted phenylcarbonyloxy (C _1-6 ) alkyl having 1 to 5 substituents on a ring selected from carbamoyl groups having 1 to 2 substituents selected from a phenyl group substituted by an alkyl group Group,

A phenylcarbonylamino (C ₁ -C ₆ ) alkyl group, which may be the same or different, is a halogen atom, a hydroxyl group, a cyano group, a nitro group, a (C _1-6 ) alkyl group, a halo (C
_1-6) alkyl groups, (C _1-6) alkoxy groups, halo (C _1-6) alkoxy group, a carboxyl group, (C _1-12) alkoxycarbonyl group, carbamoyl group or the same or different and may, halogen 1 to 2 substituents selected from an atom, a (C _1-12 ) alkyl group, a phenyl group or a phenyl group substituted by 1 to 5 identical or different (C _1-6 ) alkyl groups Substituted phenylcarbonylamino having 1 to 5 substituents selected from a carbamoyl group having
(C _1-6 ) alkyl group, an oxygen atom, a 5- to 6-membered heterocyclic ring having one or more hetero atoms which may be the same or different and selected from an oxygen atom or a sulfur atom, which may be the same or different,
Halogen atom, hydroxyl group, cyano group, nitro group, (C _1-6 ) alkyl group, halo (C _1-6 ) alkyl group, (C _1-6 ) alkoxy group, halo (C _1-6 ) alkoxy group, carboxyl Group,
(C _1-12 ) alkoxycarbonyl group, carbamoyl group or may be the same or different, a halogen atom, (C _1-12 )
Selected from an alkyl group, a phenyl group or a carbamoyl group having 1 to 2 substituents selected from a phenyl group substituted by 1 to 5 same or different (C _1-6 ) alkyl groups. Substitution 5 to 6 having 1 to 5 substituents
5- or 6-membered heterocyclic (C _1-6 ) alkyl group having at least one hetero atom which may be the same or different and selected from an oxygen atom, a sulfur atom or a nitrogen atom, may be the same or different , Halogen atom, hydroxyl group, cyano group, nitro group,
(C _1-6) alkyl groups, halo (C _1-6) alkyl, (C _1-6) alkoxy groups, halo (C _1-6) alkoxy group, a carboxyl group,
(C _1-12 ) alkoxycarbonyl group, carbamoyl group or may be the same or different, a halogen atom, (C _1-12 )
Selected from an alkyl group, a phenyl group or a carbamoyl group having 1 to 2 substituents selected from a phenyl group substituted by 1 to 5 same or different (C _1-6 ) alkyl groups. A substituted 5-6 membered heterocyclic (C _1-6 ) alkyl group having 1 to 5 substituents on the ring,

A 5- to 6-membered heterocyclic carbonyloxy (C _1-6 ) alkyl group having one or more hetero atoms which may be the same or different and selected from an oxygen atom, a sulfur atom or a nitrogen atom. Well, halogen atom, hydroxyl group,
Cyano group, nitro group, (C _1-6 ) alkyl group, halo (C _1-6 ) alkyl group, (C _1-6 ) alkoxy group, halo (C _1-6 ) alkoxy group, carboxyl group, (C _{1 -12} ) alkoxycarbonyl group, carbamoyl group or may be the same or different,
Halogen atom, (C _1-12 ) alkyl group, phenyl group or 1
1 to 5 substituents selected from a carbamoyl group having 1 to 2 substituents selected from a phenyl group substituted by up to 5 same or different (C _1-6 ) alkyl groups A substituted 5- to 6-membered heterocyclic carbonyloxy (C _1-6 ) alkyl group having on the ring

[0008] Select from oxygen, sulfur or nitrogen atoms
With one or more heteroatoms which may be the same or different
5 to 6-membered heterocyclic carbonylamino (C_1-6) Alkyl
Groups, which may be the same or different, a halogen atom, a hydroxyl group,
Cyano group, nitro group, (C_1-6) Alkyl group, halo (C_1-6A)
Alkyl group, (C_1-6) Alkoxy group, halo (C_1-6) Alkoxy
Group, carboxyl group, (C_1-12) Alkoxycarbonyl
Group, carbamoyl group or may be the same or different,
Halogen atom, (C_1-12) Alkyl, phenyl or 1
Up to 5 identical or different (C_1-6) By alkyl group
1 to 2 substituents selected from substituted phenyl groups
1 to 5 positions selected from a carbamoyl group having a group
Substituted 5- or 6-membered heterocyclic carbonylamido having a substituent on the ring
No (C_1-6) Alkyl group or -N = C (R^Five) R⁶(Where R^FiveAnd R
⁶May be the same or different and represent a hydrogen atom, (C_1-6) Archi
Group, halo (C_1-6) Alkyl group, (C_3-6) Cycloalkyl
Group, a phenyl group or the same or different, a halo
Gen atom, (C_1-6) Alkyl group or (C _1-6) Alkoxy group
A phenyl group having a substituent selected from^Fiveas well as
R⁶Together form O, S or NR^Four(Where R^FourIs
Hydrogen atom or (C_1-6) Represents an alkyl group. Interrupted by
(C_2-6) Alkylene groups can also be indicated. )
Y represents O, S or NR^Four(Where R^FourIs the same as above
Same. ). ) Or

[0009]

Embedded image (Wherein X may be the same or different, and a halogen atom,
Hydroxyl group, cyano group, nitro group, (C _1-6 ) alkyl group, halo
(C _1-6 ) alkyl group, (C _1-6 ) alkoxy group, halo (C _1-6 ) alkoxy group, (C _1-6 ) alkylcarbonyl group, carboxyl group, (C _1-12 ) alkoxycarbonyl group A carbamoyl group or the same or different, a halogen atom, (C
_1-12 ) a carbamoyl group having 1 to 2 substituents selected from an alkyl group, a phenyl group, and a phenyl group substituted by 1 to 5 identical or different (C _1-6 ) alkyl groups And n represents an integer of 0 to 4. And a method for using the same, which comprises one or more compounds selected from the 1,2,3-thiadiazole derivatives or salts thereof and compounds having insecticidal activity represented by the following formula: Things.

The insecticidal fungicidal composition of the present invention shows high pest control activity when applied to a rice nursery box or to the surface of Honda. In particular, when applied to a rice nursery box, it has a long-lasting effect on rice blast. The effect is exhibited over a long period of time in one treatment compared with the above-mentioned medicine, so that the number of times of application is smaller than that of ordinary medicine application, and labor-saving control has become possible. In addition, in the normal application of chemicals, it is necessary to adjust the time of use in accordance with the occurrence pattern of pests, for example, in the case of rice nursery box application, it is not affected by the occurrence pattern of pests, a stable effect can be obtained is there. 1, one of the active ingredient compounds of the present invention represented by the general formula (I)
Representative compounds of 2,3-thiadiazole derivatives or salts thereof are shown in Tables 1 and 3, but the present invention is not limited thereto. General formula (I-1)

Embedded image

[0011]

[0012]

[0013]

[0014]

[0015]

[0016]

In Table 1, "Ph" represents a phenyl group,
“C−” represents an alicyclic hydrocarbon group, and Q ¹ and Q ² represent the following groups.

Embedded image Table 2 shows the NMR values of the compounds having the physical properties of the paste in Table 1.

[0018]

Formula (I-2)

Embedded image

[0020]

In the following, 1,2,3- represented by the general formula (I)
Representative examples of compounds having insecticidal activity (hereinafter referred to as compound group I) used in combination with a thiadiazole derivative or a salt thereof are shown, but the present invention is not limited thereto. Examples of the compound having insecticidal activity include carbamate-based insecticides (for example, compounds (1), (2), (3), (4), (5), (6),
(7), (8), etc.), neonicotinoid insecticides (for example, compounds (9), (10), (11), (12), (1)
3), (14), etc.), organophosphorus insecticides (for example, compounds (15), (16), (17), (18), (19), (2)
0), (21), (22), (23), (24), (25), (2
6), (27), (28), etc.), nereistoxin insecticides (for example, compounds (29), (30), (31) and the like described below), pyrethroid insecticides (for example, compound (32) below) , (3
3), (34), (35), (36), etc.) and IGR for other classifications
(Insect growth regulator) based compounds (for example, compounds (37), (38), (39), (40), (41), (42),
(43) etc.), nematicides (for example, compound (44) described below),
(45), (46) and the like, and various insecticides such as acaricides (for example, compounds (47) and (48) described below). For use in the field of rice cultivation, compounds (1), (2),
(3), (4), (9), (10), (11), (15),
(16), (17), (29), (30), (32), (33),
(34), (35), (37), (48) and the like are preferable.

Representative examples of the compounds having an insecticidal activity used as the compound group I in the present invention are shown below, but the present invention is not limited thereto. (1) Ethyl N- & 2,3-dihydro-2-, dimethylbenzofuran-7-yloxycarbonylmethylaminothio] -N-isopropyl-β-alaninate (generic name: benfracarb), (2). -Dihydro-2,2
-Dimethyl-7-benzo [b] furanyl N-dibutylaminothio] -N-methylcarbamate (generic name: carbosulfan); (3) .2-isopropoxyphenyl-N
-Methyl carbamate (generic name: PHC), (4) .butyl 2,3-dihydro-2,2-dimethylbenzofuran-
7-yl N, N'-dimethyl-thiodicarbamate (general name: furatiocarb), (5). S-methyl N-
(Methylcarbamoyloxy) thioacetimidate (generic name: mesomil), (6) .1-Naphthyl methyl carbamate (generic name: NAC, carbaryl), (7) .2,3
-Isopropylidenedioxyphenyl methyl carbamate (generic name: bendiocarb), (8) .ethyl
(Z) -N-benzyl-N-[[methyl (1-methylthioethylideneamino-oxycarbonyl) amino] thio] -β-alaninate (generic name: alanicarb)

(9). 1- (6-Chloro-3-pyridylmethyl) -N-nitroimidazolidin-2-indeneamine (generic name: imidacloprid); (10). (E) -N-
(6-chloro-3-pyridylmethyl) -N-ethyl-N
-Methyl-2-nitrovinylidenediamine (generic name: nitenpyram), (11). (E) -N-((6-chloro-3
-Pyridyl) methyl) -N-cyano-N-methylacetamidine (generic name: acetamiprid), (12).
Thiamethoxam (code: CG-216), (13).
Generic name: clothianidin (code name: TI-43)
5), (14). Generic name: Nidinotefuran (code name: M
TI-446), (15). 4- (Methylthio) phenyl
Dipropyl phosphate (generic name: propaphos), (1
6). O, O-diethyl-S-2- (ethylthio) ethyl phosphorodithioate (generic name: ethylthiomethone),
(17). O, O-diethyl O-2-isopropyl-6-
Methylpyrimidin-4-yl phosphothioate (generic name: diazinon), (18) dimethyl 2,2,2-trichloro-1-hydroxyethyl phosphate (generic name: trichlorfon, DEP),

(19). O, O-dimethyl O-4-methylthio-m-tolyl phosphorothioate (generic name: MP
P, phenthion), (20). O, S-dimethylacetylphosphoamidothioate (generic name: acephate),
(21). O, O-dimethyl O-5-phenylisoxazol-3-yl phosphorothioate (generic name: isoxathion), (22). O-ethyl O-2-isopropoxycarbonylphenyl N-isopropylphosphoramide Thioate (generic name: isofenphos), (23).
O-dimethyl O-3,5,6-trichloro-2-pyridyl phosphorothioate (generic name: chlorpyrifos.
Methyl), (24). 2-chloro-1- (2,4-dichlorophenyl) vinyl diethyl phosphate (generic name:
Chlorfenvinphos), (25). O, O-dimethyl S
-Methylcarbamoylmethyl phosphorodithioate (generic name: dimethoate),

(26). O-ethyl S-phenyl (R
S) -ethylphosphonodithioate (generic name: honophos), (27). O- (1,6-dihydro-6-oxo-1)
-Phenylpyridazin-3-yl) O, O-diethyl phosphorothioate (generic name: pyridafenthion),
(28). Dimethyl (E) -1-methyl-2- (methylcarbamoyl) vinyl phosphate (generic name: alphate), (29). S, S ′-(2-dimethylaminotrimethylene) bis (thiocarbamate) (Generic name: cartap), (30). N, N-dimethyl-1,2,3-trithian-5-ylamine (generic name: thiocyclam), (31).
S, S'-2-dimethylaminotrimethylene di (benzenethiosulfonate) (generic name: bensultap),
(32). (RS) -α-cyano-3-phenoxybenzyl (RS) -2,2-dichloro-1- (4-ethoxyphenyl) cyclopropanecarboxylate (generic name: cycloprotoline),

(33). 3-phenoxybenzyl (1RS,
3RS; 1RS, 3SR) -3- (2,2-dichlorovinyl-2,2-dimethylcyclopropanecarboxylate (generic name: permethrin), (34). 2- (4-ethoxyphenyl) -2-methylpropyl 3-phenoxybenzyl ether (generic name: etofenprox), (3
5). (4-ethoxyphenyl) (3- (4-fluoro-
3-phenoxyphenyl) propyl) (dimethyl) silane (generic name: silafluofen), (36).
6-tetrafluoro-4-methylbenzyl (Z)-
(1RS, 3RS) -3- (2-chloro-3,3,3-
(Trifluoroprop-1-enyl) -2,2-dimethylcyclopropanecarboxylate (generic name: tefluthrin), (37). 2-t-butylamino-3-isopropyl-5-phenyl-1,3,5- Thiadiazin-4-one (generic name: buprofezin),

(38). 1- (4- (2-chloro-α, α,
α-trifluoro-p-tolyloxy) -2-fluorophenyl) -3- (2,6-difluorobenzoyl) urea (generic name: flufenoxuron), (39). N-cyclopropyl-1,3,5 -Triazine-2,4,6-triamine (generic name: cyromazine), (40). (RS) -1
-[2,5-dichloro-4- (1,1,2,3,3,3
-Hexafluoropropoxy) phenyl] -3- (2,
6-difluorobenzoyl) urea (generic name: lufenuron), (41). Nt-butyl-N- (4-ethylbenzoyl) -3,5-dimethylbenzohydrazide (generic name: tebufenozide), (42). Nt-butyl-N-
(3-methoxy-4-methylbenzoyl) -3,5-dimethylbenzohydrazide (generic name: methoxyfenozide), (43). Chromafenozide (generic name, development code A)
NS-118),

(44). N, N-dimethyl-2-methylcarbamoyloxyimino-2- (methylthio) acetamide (generic name: oxamyl), (45). (RS)-[O-1-
(4-Chlorophenyl) -1H-pyrazol-4-yl] O-ethyl S-propyl phosphorothioate (generic name: pyraclofos), (46). (RS) -S-secondary-butyl O-ethyl 2-oxo-1, 3-thiazolidine-3-ylphosphonothioate (generic name: phosthiazate), (47). T-butyl (E) -α- (1,
3-dimethyl-5-phenoxypyrazol-4-ylmethyleneaminooxy) -p-toluate (generic name: fenpyroximate), (48). (+,-)-5-amino-
1- (2,6-dichloro-α, α, α-trifluoro-
(p-tolyl) -4-trifluoromethylsulfenylpyrazole-3-carbonitrile (generic name: fipronil), (49). (1,4,5,6,7,7-hexachloro-8,9,10- Norborn-5-ene-2,3-ylenebismethylene) sulfite (generic name: endosulfan),

(50). Methaldehyde (common name), (51).
Emamectin benzoate (generic name), (52). (2R, 3
aS, 5aR, 5bS, 9S, 13S, 14R, 16a
S, 16bR) -2- (6-deoxy-2,3,4-
Tri-O-methyl-α-L-mannopyranosiloxy)-
13- (4-Dimethylamino-2,3,4,6-tetradeoxy-β-D-erythopyranosiloxy) -9-ethyl-2,3,3a, 5a, 6,7,9,10,11 ,
12,13,14,15,16a, 16b-hexadecahydro-14-methyl-1H-8-oxacyclododeca (b) -as-indacene-7,15-dione and (2
R, 3aR, 5aS, 5bS, 9S, 13S, 14R,
16aS, 16bR) -2- (6-deoxy-2,
3,, 4-tri-O-methyl-α-L-mannopyranosiloxy) -13- (4-dimethylamino-2,3,4
6-tetradeoxy-β-D-erythropyranosiloxy) -9-ethyl-2,3,3a, 5a, 6,7,9,
10, 11, 12, 13, 14, 15, 16a, 16b
-Hexadecahydro-4,14-dimethyl-1H-8
-Oxacyclododeca (b) -as-indacene-7,
15-dione mixture (generic name: Spinosad),

(53). 4-Bromo-2- (4-chlorophenyl) -1-ethoxymethyl-5-trifluoromethylpyrrole-3-carbonitrile (generic name: chlorfenapyr), (54). (RS)- Methyl 7-chloro-2,
3,4a, 5-tetrahydro-2- (methoxycarbonyl (4-trifluoromethoxyphenyl) carbamoyl) indeno (1,2, e) (1,3,4) oxadiazine-4a-carboxylate (generic name: indoxa) Known compounds having a pesticidal activity, such as carb), and these can be used alone or in combination of two or more.

The insecticidal fungicide of the present invention comprising a combination of a 1,2,3-thiadiazole derivative represented by the general formula (I) or a salt thereof and one or more compounds selected from compounds having insecticidal activity. Compositions include, for example, rice blast (Pyricul
In addition to aria oryzae), the following plant diseases can be exemplified as the target of use. Broadly speaking, it includes fungal diseases, bacterial diseases, and viral diseases.
For example, incomplete fungi (eg, Botrytis)
Diseases of the genus, Helminthosporium Diseases of the genus, Fusarium, Septoria
toria), Sarcospora (Cercospora), Pyricularia (Pyricularia), Alternaria (Alteraria)
naria), basidiomycetes (eg, Hemilia)
eia) genus disease, Rhizoctonia genus disease, Puccinia genus disease, etc., Ascomycetes (eg, Venturia genus disease, Podosphae
ra) Disease of the genus, Erysiphe disease, monilinia
(Monilinia) disease, Unsinula disease, etc., and other fungi (eg, Ascochyt
a) Disease of the genus, Phoma Disease of the genus, Pythium
Genus diseases, genus Corticium genus diseases, Pyrenophora genus diseases, etc.), for example, Pseudomonas genus diseases, Xanthomonas genus diseases, Erwinia genus diseases. Or diseases caused by viruses (for example, tobacco mosaic virus).

Examples of individual diseases include rice blast (Pyricularia oryzae) and rice sheath blight (Rhizoctonia sol)
ani), rice sesame leaf blight (Cochiobolus miyabeanus), rice seedling blight (Rhizopus chinensis, Pythium graminico
la, Fusarium graminicola, Fusarium roseum, Mucor s
p., Phoma sp., Tricoderma sp.), rice stupid disease (Gibbe
rella fujikuroi), powdery mildew such as barley and wheat
(Erysiphe graminis) or powdery mildew such as cucumber (Spha
erotheca fuliginea) and other powdery mildews of host plants,
Eye spot disease of barley and wheat (Pseudocercosporella h)
erpotrichoides) and smut of wheat (Urocystis triti
ci), snow rot of barley and wheat, etc.
e, Pythium iwayamai, Typhla ishikariensis, Sclerot
inia borealis), oat crown rust (Puccinia corona)
ta) and rust of other plants, gray rot of cucumber, strawberry, etc. (Botrytis cinerea), sclerotium of tomato, cabbage, etc. Plague of the
Downy mildew of cucumber (Pseudoperonospora cubensis), downy mildew of grapevine (Plasmopara viticola)

[0033] Apple scab (Venturia inaequalis), apple spot leaf rot (Alternaria mali), pear black spot (Alter
naria kikuchiana), citrus black spot (Diaporthe citr)
i), citrus scab (Elsinoe fawcetti), sugar beet brown spot (Cercospora beticola), peanut brown spot (Cer
cospora arachidicola), peanut black rot (Cercospor
apersonata), wheat leaf blight (Septoria tritici), wheat blight (Septoria nodorum), barley cloud disease (Rhync
hosporium secalis) and wheat lintel smut (Tilletia
caries),

[0034] Shiva leaf rot (Rhizoctonia solani), Shiva dollar spot disease (Sclerotinia homoeocarpa), Psue
genus domonas, such as cucumber spot bacterial disease (Pseudomonas s
yringae pv. lachrymans), tomato bacterial wilt (Pseudomonas
solanacearum) and rice seed blight (Pseudomonas gluma)
e), genus Xanthomonas, such as cabbage black rot (Xanthomon
as campestris), rice leaf blight (Xanthomonas oryzae) and citrus canker (Xanthomonas citri), Erwinia
It has a remarkable control effect on genus, for example, bacterial diseases such as cabbage soft rot (Erwinia carotovora) and viral diseases such as tobacco mosaic virus.

Suitable for controlling various agriculture and forestry, horticulture, storage pests, sanitary pests, nematodes, and other pests and pests that injure paddy rice, fruit trees, vegetables, other crops and flowers. Adoxophyes orana fasciat
a), Anopheles sp., Adelaphyes sp., Graphholita inopinata, Nashihimesinpa (Grapholita molesta), Leguminda (Legu)
minivora glycinivorella), Kuwahamaki (Olethreute)
s mori) Chanohosoga (Caloptilia thevivora), Apple hosoga (Caloptilia zachrysa), Kimmonhosoga (Phyllonorycterringoniella), Nashihosoga (Spulerr)
ina astaurota, cabbage butterfly (Piers rapae cruci)
vora), Helicoverpa armys (Heliothis sp.), Codling moth (Laspey resia pomonella), Japanese moth (Plutella x
ylostella, apple turtle (Argyresthia conj)
ugella), peach sink moth (Carposina niponensis),

[0036] Japanese syrup (Chilo suppressalis), Japanese cypress (Cnaphalocrocis medinalis), Japanese cypress (Ephestia elutella), and Japanese cypress (Glyphode)
s pyloalis, Sankameiga (Scirpophaga incertula)
s), scorpion parsley (Parnara guttata), armyworm (Pseudaletia separata), rice armyworm (Sesamia)
inferens), Spodoptera litura (Spodoptera litura),
Lepidopteran pests, such as the armyworm (Spodoptera exigua), the leafhopper (Macrosteles fascifron)
s), leafhopper (Nephotettix cincticeps),
Brown planthopper (Nilaparvata lugens), white-spotted planthopper (Sogatella furcifera), orange lice (Diaphori)
na citri, whitefly (Aleurolobus taonaba)
e), whiteflies (Bemisia tabaci), whiteflies (Trialeurodes vaporariorum), flies (Lipaphis erysimi), peach aphids (Myzus persicae), hornworms (Ceroplastes)
ceriferus), Peanut (Pulvinaria a)
urantii), Citrus Insect (Pseudaonidia d)
uplex), pear beetle (Comstockaspis pern)
iciosa), Unaspis yanonensis
Hemiptera pests, such as Himakogane (Anomala rufocupre)
a), Bean beetle (Popillia japonica), Douganebuui (Anomala cuprea), Tobacco beetle (Lasiod)
erma serricorne, Flycatcher beetle (Lyctus brunn)
eus), Ladybird (Epilachna vigintio)
topunctata), adzuki beetle (Callosobruchus chine)
nsis) and the weevil (Listroderes costirostri)
s), weevil (Sitophilus zeamais), cotton weevil (Anthonomus gradis gradis), rice weevil (Lissorhoptrus oryzophilus),
cophora femoralis), Tency beetle (Chaetocn)
ema concinna, beetle beetle (Psyllioides angust)
icollis), rice beetle (Oulema oryzae),

The flea beetle (Phyllotreta striolat)
a), pine bark beetle (Tomicus piniperda), Colorado potato beetle (Leptinotarsa decemlineata),
Mexican beetle (Epilachna varivestis),
Coleoptera pests such as corn rootworms (Diabrotica sp.) And click beetles (Agriotes spp., Melanotus spp.); ), Onion fly (Deli
a antiqua), scallop (Delia platura), onion fly (Delia antiqua), sugar beet fly (Pego)
mya cunicularia), potato peach fly (Pego
mya dulcamarae, soybean flies (Asphondylia)
sp.), houseflies (Musca domestica), and house mosquitoes (Culex pipiens pipiens) such as dipteran pests,

The nematode (Pratylenchus s)
p.), southern nematode (Pratylenchus coffe)
ae), potato cyst nematode (Globodera rostoc)
hiensis), root-knot nematode (Meloidogyne sp.),
Tangerine nematode (Tylenchulussemipenetrans),
Pests of the order Nematodes, such as Aphelenchus avenae and Aphelenchoides ritzemabosi, Onychiurus spp.
, Millipede (Dilopoda spp.), Slugs (Mollusca
), And an excellent control effect against spider mites (Rhizoglyphus spp.) And the like.

[0039]

BEST MODE FOR CARRYING OUT THE INVENTION Plants to which the insecticidal fungicide composition of the present invention can be used are not particularly limited, and examples thereof include the following plants. Cereals (eg, rice, barley, wheat, rye, oats, corn, high oats, etc.), beans (soybeans, red beans, broad beans, peas, peanuts, etc.), fruit trees and fruits (apples, citrus fruits, pears, grapes,
Peach, plum, yellow peach, walnut, almond, banana, strawberry, etc.), vegetables (cabbage, tomato, spinach, broccoli, lettuce, onion, leek, green pepper, etc.), root vegetables (carrot, potato, sweet potato, radish, lotus root) , Turnips, etc.), crops for processing (cotton, hemp, mulberry, mitsumata, rapeseed, beet, hops, sugarcane, sugar beet, olives, rubber, coffee, tobacco, tea, etc.), melons (pumpkin, cucumber, watermelon, melon) ), Grasses (orchard grass, sorghum, timothy, clover, alfalfa, etc.), turf (Korai turf, bentgrass, etc.), crops for fragrances etc. (lavender, rosemary, thyme, parsley, pepper, ginger, etc.), Flowers (chrysanthemums, roses, orchids, etc.)
Etc. can be used for plants.

The pesticidal fungicidal composition of the present invention is expected to have an effective amount for controlling pests, as it is, or as it is appropriately diluted or suspended in water or the like, for controlling various pests. It may be used by applying it to plants or places where generation is not preferred. For example, for the purpose of controlling pests and pests on paddy rice, the method can be used by applying to the surface of the water to Honda, applying a lateral line, applying a rice seedling box, applying a seed dressing or the like, or applying a seed disinfection method. Fruit trees, cereals, vegetables and other diseases that occur in upland crops, besides spraying on the foliage, immersing the seeds in chemicals, treating seeds such as seed dressing, treating the soil etc. to absorb from the roots Can also be used. It may be treated with a hydroponic solution in hydroponics.

Examples of the method of seed treatment include a method in which a liquid or solid preparation is diluted or undiluted, and the seed is immersed in a liquid state to penetrate the drug, or a solid or liquid preparation is mixed with the seed. A method of coating the seed by adhering it to the surface of the seed by, for example, dressing, a method of mixing the resin with an adhesive carrier such as a resin and a polymer, and a method of spraying the seed near the seed simultaneously with planting. it can. The `` seed '' to be subjected to the seed treatment means a plant in the early stage of cultivation used for breeding of a plant, and other than the so-called seeds, bulbs, tubers, seed potatoes, baskets, bulbs, or stems for cutting cultivation. It contains plants for vegetative propagation. The `` soil '' to plant the target plant in the case of application or `` cultivation carrier '' described below is a support for cultivating the plant, particularly a support for growing roots, the material is not particularly limited, Any material capable of growing plants may be used, for example, so-called various soils, nursery mats, water, etc. Specific materials include, for example, sand, vermiculite, cotton, paper,
Diatomaceous earth, agar, gel-like substances, high-molecular substances, rock wool, glass wool, wood chips, bark, pumice stone and the like may be used.

As a method of spraying on the foliage, a liquid preparation such as an emulsion or a flowable or a solid preparation such as a wettable powder or a wettable powder is appropriately diluted with water and sprayed on the foliage or a powder. A method of spraying and the like can be mentioned. Examples of the method of application to soil include, for example, a method in which a liquid formulation is diluted or diluted with water and applied to a plant base or a nursery bed for raising seedlings, or a method in which granules are sprayed to the base or a nursery bed. Before sowing or transplanting, dust, wettable powder, wettable granules, spraying granules, etc. and mixing with the whole soil, before sowing or before planting plant holes, crops, etc. Examples of the method include a method of spraying a wetting agent, a water dispersible granule, a granule, and the like.

As a method of applying paddy rice to a nursery box, the dosage form may vary depending on the application time, for example, application at the time of sowing, application at the greening stage, application at the time of transplantation, etc. And the like. It can also be applied by mixing with cultivation soil, and can be mixed with cultivation soil and dust, wettable granules or granules, for example, mixing with floor soil, covering soil, mixing with the whole cultivation soil, and the like. Simply, the soil and the various preparations may be applied alternately in layers. The time of application at the time of sowing may be before, simultaneously with, or after sowing, or may be applied after covering the soil.

The method of application to paddy fields includes jumbo agents,
Solid preparations such as packs, granules and wettable powders, and liquid preparations such as flowables and emulsions are usually sprayed on flooded paddy fields. In addition, at the time of rice planting, the appropriate formulation as it is, or mixed with fertilizer and sprayed on the surface water or soil,
It can also be injected. (Side treatment) In addition, by applying chemicals such as emulsions, wettable powders, and flowables to the inflow source of water into paddy fields such as water outlets and irrigation devices, the water can be applied labor-saving with the supply of water to the paddy fields. You can also.

In the case of field crops, such as wheat, from the time of sowing to the stage of raising seeds, treatment can be applied to cultivation carriers or the like that are close to seeds or plants. In plants sowing directly in the field,
In addition to the direct treatment of the seed, the treatment of the plant root of the plant being cultivated is suitable. Spraying treatment using granules or irrigation treatment of a drug diluted or not diluted with water in a liquid state can be performed. As the treatment of the cultivated plant to be transplanted at the time of sowing and raising the seedling, in addition to the direct treatment of the seed, the liquid irrigation treatment or the granule spraying treatment to the seedling bed for raising the seedling is preferable.
In addition, it is also preferable to apply a granule to the planting hole at the time of planting or to mix it with a cultivation carrier near the transplanting site.

The compounding ratio of the active ingredient in the insecticidal fungicide composition of the present invention is based on 1 part by weight of the 1,2,3-thiadiazole derivative represented by the general formula (I) or a salt thereof.
One or more compounds selected from the compound group I may be appropriately selected from the range of usually 0.01 to 1000 parts by weight, and preferably 0.1 to 100 parts by weight. The compounding ratio of the active ingredient compound in the insecticidal fungicide composition of the present invention may be appropriately selected from the range of 1 to 50 parts by weight based on 100 parts by weight of the composition.

The insecticidal fungicidal composition of the present invention has a usual dosage form,
For example, they may be formulated and applied in the form of emulsions, wettable powders, suspensions, liquids, granules, powders and the like, and the application rates are determined based on the compounding ratio of the active ingredient compound, weather conditions, formulation and timing of application. Although it depends on the method of application, the place of application, the disease to be controlled, the target crop, etc., it is usually 0.1 as an active ingredient compound per are.
The application may be appropriately selected from the range of 1 to 1000 g, and preferably 1 to 50 g. In the treatment of the seed, 0.1% of the active ingredient is compared with the seed weight.
It can be used in the range of 01% to 40%, preferably in the range of 0.1% to 10%. When the emulsions, wettable powders, suspensions, liquids and the like are diluted with water or the like and applied, the application concentration is 0.0001 to 0.1%, and the liquids when applied to granules, powders or seeds Etc. may be applied as it is without dilution.

Hereinafter, typical examples and test examples of the present invention will be illustrated, but the present invention is not limited thereto. In Examples, “parts” means “parts by weight”. Example 1 Compounds described in Table 1 or 3 10 parts One kind of compound group I 10 parts Calcined diatomaceous earth 63 parts Polyoxyethylene nonylphenyl ether 5 parts Naphthalenesulfonic acid formalin condensate 4 parts Hydrous silicic acid 8 parts Into a wettable powder.

Example 2 Compounds described in Table 1 or 3 10 parts One kind of compound group I 35 parts Calcined diatomaceous earth 28 parts Polyoxyethylene nonylphenyl ether 5 parts Naphthalenesulfonic acid formalin condensate 4 parts Hydrous silica 8 parts The above is uniformly mixed and pulverized to obtain a wettable powder. Example 3 Compounds listed in Table 1 or 3 40 parts One kind of Compound Group I 10 parts Calcined diatomaceous earth 33 parts Polyoxyethylene nonylphenyl ether 5 parts Naphthalenesulfonic acid formalin condensate 4 parts Hydrous silicic acid 8 parts Into a wettable powder.

Example 4 Compounds described in Table 1 or 3 5 parts One kind of Compound Group I 7 parts Synthetic hydrous silicon oxide 1 part lignin sulfonate 2 parts Bentonite 30 parts Kaolin clay 55 parts It is pulverized, kneaded by adding an appropriate amount of water, granulated and dried to obtain granules. Example 5 Compounds described in Table 1 or 3 20 parts One kind of Compound Group I 20 parts Sodium alkylnaphthalenesulfonate 3 parts Propylene glycol 5 parts Dimethylpolysiloxane 0.25 parts Parachlorometaxylenol 0.10 parts Xanthan gum 0.30 parts Water 51.35 parts The above is uniformly mixed and wet-pulverized to obtain a wettable powder or an aqueous suspension.

Example 6 Compounds described in Table 1 or 3 8 parts Benfracarb 6 parts Polyoxyethylene nonylphenyl ether 0.4 parts Polyvinyl alcohol 2 parts Synthetic hydrated silica 1 part Kaolin clay 82.6 parts The mixture is pulverized, kneaded by adding an appropriate amount of water, granulated and dried to obtain granules. Example 7 Compounds described in Table 1 or 3 8 parts Imidacloprid 2 parts Polyoxyethylene nonyl phenyl ether 0.4 parts Polyvinyl alcohol 2 parts Synthetic hydrous silicic acid 1 part Kaolin clay 86.6 parts Then, an appropriate amount of water is added and kneaded, granulated, and dried to obtain granules.

Example 8 Compounds described in Table 1 or 3 8 parts Pymetrozine 3 parts Polyoxyethylene nonylphenyl ether 0.4 parts Polyvinyl alcohol 2 parts Synthetic hydrous silicic acid 1 part Kaolin clay 85.6 parts The mixture is pulverized, kneaded by adding an appropriate amount of water, granulated and dried to obtain granules. Example 9 8 parts of the compounds described in Table 1 or 3 8 parts Propaphos 5 parts Polyoxyethylene nonylphenyl ether 0.4 parts Polyvinyl alcohol 2 parts Synthetic hydrous silicic acid 1 part Kaolin clay 83.6 parts Then, an appropriate amount of water is added and kneaded, granulated, and dried to obtain granules.

Example 10 Compounds described in Table 1 or 3 6 parts Cartap 4 parts Dioctyl sulfosuccinate 0.5 parts Sodium polycarboxylate 2 parts Bentonite 30 parts Sodium carbonate 56.5 parts Then, an appropriate amount of water is added and kneaded, granulated, and dried to obtain granules. Example 11 8 parts of the compounds described in Table 1 or 3 1 part of fipronil 1 part of polyoxyethylene nonyl phenyl ether 0.4 parts of polyvinyl alcohol 2 parts of synthetic hydrous silicic acid 1 part of kaolin clay 87.6 parts Then, an appropriate amount of water is added and kneaded, granulated, and dried to obtain granules.

Example 12 Compounds described in Table 1 or 3 6 parts Cycloprothrin 1.5 parts Dioctyl sulfosuccinate 0.5 parts Sodium polycarboxylate 2 parts Bentonite 30 parts Sodium carbonate 1 part Calcium carbonate 59 parts The above are uniformly mixed and pulverized, kneaded by adding an appropriate amount of water, granulated and dried to obtain granules. Example 13 Compounds described in Table 1 or 3 6 parts Buprofezin 2 parts Dioctyl sulfosuccinate 0.5 parts Sodium polycarboxylate 2 parts Bentonite 30 parts Sodium carbonate 1 part Calcium carbonate 58.5 parts It is pulverized, kneaded by adding an appropriate amount of water, granulated and dried to obtain granules.

Reference Example Compounds listed in Table 1 or 3 6 parts Dioctyl sulfosuccinate 0.5 parts Sodium polycarboxylate 2 parts Bentonite 30 parts Sodium carbonate 1 part Calcium carbonate 60.5 parts Then, an appropriate amount of water is added and kneaded, granulated, and dried to obtain granules.

Test Example 1 Test for controlling water weevil and blast by applying a rice nursery box. Rice (cultivar: Kinnan style) cultivated in a nursery box was treated with 50 g of a granule prepared according to Example 1 per box, and then transplanted to Honda on the day (middle of May). At the same time, a diluent obtained by diluting the etofenprox emulsion 2,000-fold was sprayed at a rate of 100 L (10 liters) on 10 days and 17 days after transplantation. On the other hand, a granule prepared according to the Reference Example 17 days after transplantation was applied to another rice plant transplanted at the same time at a rate of 3 kg per 10 ares. The control effect on rice water weevil was determined by examining the number of adults per plant 25 days after transplantation, and the control effect on rice blast was determined by examining the lesion area rate 60 days after transplantation. The results are shown in Table 4.

[0057]

Test Example 2 Control test of rice planthopper and blast by application of rice nursery box. Rice (cultivar: Kinnan style) cultivated in nursery box is treated with 50 g of granules prepared according to Examples 2 and 3 per box, and then Honda is treated on the day. Transplanted (early June). At 35 days and 50 days after transplantation, a diluent obtained by diluting the etofenprox emulsion 2,000-fold was sprayed at a rate of 100 L per 10 ares on another rice transplanted at the same time. On the other hand, 20 days after transplanting, the granules prepared according to the reference example were applied to the surface of the other rice transplanted at a rate of 3 kg per 10 ares. 63 days after transplantation, the number of adults and larvae per plant was examined for the control effect on the brown planthopper, and the control effect on rice blast was determined by examining the lesion area ratio 50 days after the transplantation. The results are shown in Table 5.

[0059]

Test Example 3 Control test of rice dwarf beetle and blast by application of rice seedling box The rice (cultivar: Kinnan style) cultivated in the seedling box was treated with 50 g of the granules prepared according to Example 4 per box, and then transplanted to Honda on the day. (Early May). At the same time, a diluent obtained by diluting the etofenprox emulsion 2,000-fold was sprayed at a rate of 100 L per 10 ares on another transplanted rice 30 days and 40 days after the transplantation. Also, in another rice plant transplanted at the same time, 30 days after transplantation, 10 granules prepared according to the reference example were added.
The surface was applied at a rate of 3 kg per are. For the control effect on rice beetle, the number of adults per plant was examined 45 days after transplantation, and the control effect on rice blast was 68 days after transplantation.
After day, the lesion area ratio was investigated and determined. The results are shown in Table 6.

[0061]

Test Example 4 Test for controlling rice blast and rice blast by applying rice seedling box. Rice (cultivar: Kinnan style) cultivated in a nursery box was treated with 50 g of the granules prepared according to Examples 5 and 6 per box, and then transplanted to Honda on the day (early June). At 38 days and 45 days after transplantation, a diluent obtained by diluting the etofenprox emulsion 1000-fold was sprayed onto another rice plant that had been transplanted at a rate of 100 L per 10 ares. On the other hand, 20 days after transplanting, the granules prepared according to the reference example were applied to the surface of the other rice transplanted at a rate of 3 kg per 10 ares. The control effect on the corn beetle was determined by examining the rate of the foliage-affected leaves 60 days after transplantation, and the control effect on rice blast was determined by examining the lesion area ratio 50 days after transplantation. The results are shown in Table 7.

[0063]

Test Example 5 Test for controlling water weevil and blast by applying to the surface of Honda. Rice (variety: Kinnan style) was transplanted to a paddy field in mid-May, and one week later, granules prepared according to Example 7 were applied to the water surface at a rate of 3 kg per 10 ares. On the 10th and 17th days after the transplantation, a diluted solution of the etofenprox emulsion diluted 2000 times was sprayed at a rate of 100 L per 10 ares. The control effect on the rice weevil was determined by examining the number of adults per plant 20 days after transplantation, and the control effect on rice blast was determined by examining the lesion area rate 60 days after transplantation.
The results are shown in Table 8.

[0065]

Test Example 6 Test for controlling the leafhopper and the blast by applying to the surface of Honda. Rice (breed: Kinnan style) was transplanted to paddy in early June,
A day later, the granules prepared according to Example 8 were applied to the surface of the water at a rate of 3 kg per 10 ares. Further, 30 days and 37 days after the transplantation, a dilution of the etofenprox emulsion diluted 2000 times was sprayed at a rate of 100 L per 10 ares. The control effect on the leafhopper leafhopper was determined by examining the number of adults per plant 20 days after transplantation, and the control effect on rice blast was determined by examining the lesion area rate 60 days after transplantation.
The results are shown in Table 9.

[0067] In the reagent reagents in Tables 4 to 10, No. 55 used the compound No. 55 described in Table 1.

The insecticidal fungicidal composition of the present invention enables simultaneous control of pests and insects, and enables labor-saving crop cultivation. In particular, in a single treatment of seed or early-growth plant, nursery box application or water surface application, conventional single treatment with a fungicide once (water surface application) and insecticide twice (spraying a diluted solution of the drug) The same effect as in the case of treatment is obtained, and as a result, labor saving of pest control is achieved, and a stable effect can be obtained without being affected by the occurrence pattern of pests. The above effect is remarkable in paddy rice cultivation.

 ──────────────────────────────────────────────────続 き Continuation of the front page (72) Inventor Takayoshi Tajima 2-10-9, Nagai, Sumiyoshi-ku, Osaka, Osaka (72) Inventor Yoshinobu Yamamoto 1-40-1-625, Mikanodai, Kawachinagano, Osaka

Claims (2)

[Claims] [Claim 1] General formula (I):[Wherein, R¹Is a hydrogen atom, (C_1-6) Alkyl group or (C_3-7)
R represents a cycloalkyl group;^TwoIs CO-Y-R^Three(Where R^Three
Is a hydrogen atom, (C_1-20) Alkyl group, halo (C_1-20) Archi
Group, (C_2-20) Alkenyl group, halo (C_2-20) Alkenyl
Group, (C_2-20) Alkynyl group, halo (C_2-20) Alkynyl
Group, (C_3-12) Cycloalkyl group, (C_1-6) Alkoxy (C
_1-6) Alkyl group, (C_1-6) Alkoxy (C_1-6) Alkoxy (C
_1-6) Alkyl group, carboxy (C_1-6) Alkyl group,
(C_1-20) Alkoxycarbonyl (C_1-6) Alkyl group, cal
Bamoyl (C_1-6) An alkyl group, which may be the same or different,
(C_1-6) Alkyl, phenyl or one or more of the same or different
Halogen atom or (C_{1- 6}) From an alkyl group
1-2 substituents selected from substituted phenyl groups
Substituted carbamoyl (C_1-6) Alkyl group, cyano (C
_1-6) Alkyl group, (C_1-6) Alkylcarbonyloxy (C
_1-6) Alkyl group, (C_1-6) Alkylcarbonylamino (C_1-
6) Alkyl group, phenyl group, which may be the same or different,
Halogen atom, hydroxyl group, cyano group, nitro group, (C_1-6A)
Alkyl group, halo (C_1-6) Alkyl group, (C_1-6) Alkoxy
Group, halo (C_1-6) Alkoxy group, carboxyl group,
(C_1-12) Alkoxycarbonyl group, carbamoyl group or
May be the same or different, a halogen atom, (C_{1- 12})
Alkyl group, phenyl group or 1 to 5 identical or different
(C_1-6) Phenyl group substituted by alkyl group
Carbamoyl having 1 or 2 substituents selected from
Phenyl having 1 to 5 substituents selected from
Group, phenyl (C_1-6) Alkyl group, same or different
Well, halogen atom, hydroxyl group, cyano group, nitro group, (C
_1-6) Alkyl group, halo (C_1-6) Alkyl group, (C_1-6Arco
Xy group, halo (C_1-6) Alkoxy group, carboxyl group, (C
_1-12) An alkoxycarbonyl group, a carbamoyl group or
May be one or different, a halogen atom, (C_1-12A)
Alkyl group, phenyl group or 1 to 5 identical or different
Is also good (C_1-6) Is a phenyl group substituted by an alkyl group
A carbamoyl group having one or two substituents selected from
Substituted 1 to 5 substituents on the ring selected from
Henil (C_1-6) Alkyl group, phenylcarbonyloxy (C
_1-6) Alkyl group, which may be the same or different,
, Hydroxyl group, cyano group, nitro group, (C_1-6) Alkyl group,
Halo (C_1-6) Alkyl group, (C_1-6) Alkoxy group, halo (C
_1-6) Alkoxy group, carboxyl group, (C_1-12) Alkoki
Cicarbonyl group, carbamoyl group or the same or different
May be a halogen atom, (C_1-12) Alkyl group,
Nyl group or 1 to 5 identical or different (C_1-6A)
1 selected from a phenyl group substituted by an alkyl group
Selected from carbamoyl groups having up to 2 substituents
Substituted phenyl carbonyl having 1 to 5 substituents on the ring
Luoxy (C_1-6) Alkyl group, phenylcarbonylamino
(C_1-6) Alkyl groups, which may be the same or different and are halogen
Atom, hydroxyl, cyano, nitro, (C_1-6) Alkyl
Group, halo (C_1-6) Alkyl group, (C_1-6) Alkoxy group, halo
(C_1-6) Alkoxy group, carboxyl group, (C_1-12) Arco
Xycarbonyl group, carbamoyl group or the same or different
May be a halogen atom, (C_1-12) Alkyl group
Enyl group or 1 to 5 identical or different (C_1-6)
Selected from phenyl groups substituted by alkyl groups
Selected from carbamoyl groups having 1 to 2 substituents
Substituted phenylcarbo having 1 to 5 substituents on the ring
Nilamino (C_1-6) Alkyl group, oxygen atom, sulfur atom or
One or more which may be the same or different selected from nitrogen atoms
5 to 6-membered heterocyclic ring having a hetero atom of the same or different
Halogen, hydroxyl, cyano, nitro
Group, (C_1-6) Alkyl group, halo (C_1-6) Alkyl group, (C_1-6)
Alkoxy group, halo (C_1-6) Alkoxy group, carboxyl
Group, (C_1-12) Alkoxycarbonyl group, carbamoyl group
Or the same or different, a halogen atom, (C
_1-12) Alkyl, phenyl or 1-5 identical or
May be different (C_1-6) Fe substituted by an alkyl group
Carba having one or two substituents selected from nyl group
Substitution having 1 to 5 substituents selected from moyl groups
From a 5- to 6-membered heterocyclic ring, oxygen atom, sulfur atom or nitrogen atom
One or more heteroatoms selected, which may be the same or different
5 to 6-membered heterocyclic ring having _1-6) Alkyl group, same or different
May be halogen, hydroxyl, cyano, nitro
Group, (C_1-6) Alkyl group, halo (C_1-6) Alkyl group, (C
_1-6) Alkoxy group, halo (C_1-6) Alkoxy group, carboxy
A sil group, (C_1-12) Alkoxycarbonyl group, carbamoy
Or a halogen group,
(C_1-12) Alkyl, phenyl or 1-5 identical or
May be different (C_1-6) Alkyl group substituted
Having one or two substituents selected from phenyl
Having 1 to 5 substituents selected from a bamoyl group on the ring;
Substituted 5- to 6-membered heterocycle (C_1-6) Alkyl group, oxygen atom,
Same or different selected from sulfur atom or nitrogen atom
5- to 6-membered heterocyclic kar having one or more heteroatoms
Bonyloxy (C_1-6) Alkyl group, same or different
Halo, hydroxyl, cyano, nitro, (C
_1-6) Alkyl group, halo (C_1-6) Alkyl group, (C_1-6Arco
Xy group, halo (C_1-6) Alkoxy group, carboxyl group, (C
_1-12) An alkoxycarbonyl group, a carbamoyl group or
May be one or different, a halogen atom, (C_1-12A)
Alkyl group, phenyl group or 1 to 5 identical or different
Is also good (C_1-6) Is a phenyl group substituted by an alkyl group
A carbamoyl group having one or two substituents selected from
A substituent 5 having 1 to 5 substituents on the ring selected from
To 6-membered heterocyclic carbonyloxy (C _1-6) Alkyl group, oxygen
Same or different selected from atoms, sulfur atoms or nitrogen atoms
5- or 6-membered complex having one or more heteroatoms which may be
Ring carbonylamino (C_1-6) Alkyl group, same or different
Halogen, hydroxyl, cyano, nitro
Group, (C_1-6) Alkyl group, halo (C_1-6) Alkyl group, (C_1-6)
Alkoxy group, halo (C _1-6) Alkoxy group, carboxyl
Group, (C_1-12) Alkoxycarbonyl group, carbamoyl group
Or the same or different, a halogen atom, (C
_1-12) Alkyl, phenyl or 1-5 identical or
May be different (C_1-6) Fe substituted by an alkyl group
Carba having one or two substituents selected from nyl group
Having 1 to 5 substituents selected from moyl groups on the ring
Substituted 5- to 6-membered heterocyclic carbonylamino (C_1-6) Alkyl
Group or -N = C (R^Five) R⁶(Where R^FiveAnd R⁶Are the same or different
Hydrogen atom, (C_1-6) Alkyl group, halo (C_1-6)
Alkyl group, (C_3-6) Cycloalkyl, phenyl or
May be the same or different, a halogen atom, (C_1-6A)
Alkyl group or (C_1-6) A substituent selected from an alkoxy group
A phenyl group having^FiveAnd R⁶Are together
, O, S or NR^Four(Where R^FourIs a hydrogen atom or (C
_1-6) Represents an alkyl group. ) May be interrupted (C
_2-6) Alkylene groups can also be indicated. ), And Y is
O, S or NR^Four(Where R^FourIs the same as above. )
You. ) Or(Wherein X may be the same or different, and a halogen atom,
Hydroxyl group, cyano group, nitro group, (C_1-6) Alkyl group, halo
(C_1-6) Alkyl group, (C_1-6) Alkoxy group, halo (C_1-6A)
Alkoxy group, (C_1-6) Alkylcarbonyl group, carboxy
Group, (C_1-12) Alkoxycarbonyl group, carbamoyl
Group or the same or different, a halogen atom, (C
_1-12) Alkyl, phenyl or 1-5 identical or
May be different (C_1-6) Fe substituted by an alkyl group
Carba having one or two substituents selected from nyl group
Represents a moyl group, and n represents an integer of 0 to 4. ]
1,2,3-thiadiazole derivatives or salts thereof;
One or more selected from compounds having insecticidal activity
Characterized by containing the above compound as an active ingredient
Insecticidal fungicide composition. 2. A pesticidal fungicidal composition comprising applying an effective amount of the pesticidal fungicidal composition according to claim 1 to a target plant or soil in order to control undesirable pests against crops. how to use.