WO2010058830A1 - Method for controlling agricultural and horticultural plant disease - Google Patents
Method for controlling agricultural and horticultural plant disease Download PDFInfo
- Publication number
- WO2010058830A1 WO2010058830A1 PCT/JP2009/069679 JP2009069679W WO2010058830A1 WO 2010058830 A1 WO2010058830 A1 WO 2010058830A1 JP 2009069679 W JP2009069679 W JP 2009069679W WO 2010058830 A1 WO2010058830 A1 WO 2010058830A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- group
- agricultural
- horticultural
- plant
- diseases
- Prior art date
Links
- 201000010099 disease Diseases 0.000 title claims abstract description 154
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 title claims abstract description 154
- 238000000034 method Methods 0.000 title claims abstract description 107
- 241000196324 Embryophyta Species 0.000 claims abstract description 157
- 208000035240 Disease Resistance Diseases 0.000 claims abstract description 49
- 239000000411 inducer Substances 0.000 claims abstract description 49
- 238000009331 sowing Methods 0.000 claims abstract description 30
- 239000002689 soil Substances 0.000 claims abstract description 23
- 241000209140 Triticum Species 0.000 claims description 49
- 235000021307 Triticum Nutrition 0.000 claims description 49
- 239000000417 fungicide Substances 0.000 claims description 41
- 238000005507 spraying Methods 0.000 claims description 35
- 239000004480 active ingredient Substances 0.000 claims description 23
- 125000005843 halogen group Chemical group 0.000 claims description 23
- 230000000855 fungicidal effect Effects 0.000 claims description 22
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 17
- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 claims description 11
- 240000005979 Hordeum vulgare Species 0.000 claims description 11
- 235000007340 Hordeum vulgare Nutrition 0.000 claims description 11
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 11
- UGUHFDPGDQDVGX-UHFFFAOYSA-N 1,2,3-thiadiazole Chemical class C1=CSN=N1 UGUHFDPGDQDVGX-UHFFFAOYSA-N 0.000 claims description 10
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 claims description 8
- 235000013339 cereals Nutrition 0.000 claims description 8
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 8
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 7
- WHHIPMZEDGBUCC-UHFFFAOYSA-N probenazole Chemical compound C1=CC=C2C(OCC=C)=NS(=O)(=O)C2=C1 WHHIPMZEDGBUCC-UHFFFAOYSA-N 0.000 claims description 7
- 125000004305 thiazinyl group Chemical group S1NC(=CC=C1)* 0.000 claims description 7
- 125000004454 (C1-C6) alkoxycarbonyl group Chemical group 0.000 claims description 5
- 238000012545 processing Methods 0.000 claims description 5
- 125000003545 alkoxy group Chemical group 0.000 claims description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 4
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 4
- 125000001424 substituent group Chemical group 0.000 claims description 4
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 125000004434 sulfur atom Chemical group 0.000 claims description 3
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims description 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 2
- 230000012010 growth Effects 0.000 abstract description 28
- 230000002070 germicidal effect Effects 0.000 abstract description 3
- 238000011282 treatment Methods 0.000 description 65
- 150000001875 compounds Chemical class 0.000 description 42
- 230000001276 controlling effect Effects 0.000 description 33
- 238000012360 testing method Methods 0.000 description 30
- 239000003795 chemical substances by application Substances 0.000 description 24
- -1 difluorotyl group Chemical group 0.000 description 24
- 230000000694 effects Effects 0.000 description 23
- 239000000843 powder Substances 0.000 description 21
- 239000003814 drug Substances 0.000 description 15
- 238000010899 nucleation Methods 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 239000004563 wettable powder Substances 0.000 description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 12
- 230000000844 anti-bacterial effect Effects 0.000 description 12
- 229940079593 drug Drugs 0.000 description 12
- 239000008187 granular material Substances 0.000 description 12
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 12
- 239000000203 mixture Substances 0.000 description 12
- 241000221785 Erysiphales Species 0.000 description 11
- 239000002917 insecticide Substances 0.000 description 11
- 239000007921 spray Substances 0.000 description 11
- 239000007788 liquid Substances 0.000 description 10
- 240000007594 Oryza sativa Species 0.000 description 9
- 235000007164 Oryza sativa Nutrition 0.000 description 9
- 235000009566 rice Nutrition 0.000 description 9
- UHPMCKVQTMMPCG-UHFFFAOYSA-N 5,8-dihydroxy-2-methoxy-6-methyl-7-(2-oxopropyl)naphthalene-1,4-dione Chemical compound CC1=C(CC(C)=O)C(O)=C2C(=O)C(OC)=CC(=O)C2=C1O UHPMCKVQTMMPCG-UHFFFAOYSA-N 0.000 description 8
- 241000223218 Fusarium Species 0.000 description 8
- 239000002671 adjuvant Substances 0.000 description 8
- 239000003899 bactericide agent Substances 0.000 description 8
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 7
- 239000003112 inhibitor Substances 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 241001123569 Puccinia recondita Species 0.000 description 5
- 239000003905 agrochemical Substances 0.000 description 5
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 5
- 238000011161 development Methods 0.000 description 5
- 230000000749 insecticidal effect Effects 0.000 description 5
- 230000003902 lesion Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 241001480061 Blumeria graminis Species 0.000 description 4
- 240000008067 Cucumis sativus Species 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- 241001533598 Septoria Species 0.000 description 4
- 239000012752 auxiliary agent Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 230000018109 developmental process Effects 0.000 description 4
- 235000013399 edible fruits Nutrition 0.000 description 4
- 238000003898 horticulture Methods 0.000 description 4
- LVTJOONKWUXEFR-FZRMHRINSA-N protoneodioscin Natural products O(C[C@@H](CC[C@]1(O)[C@H](C)[C@@H]2[C@]3(C)[C@H]([C@H]4[C@@H]([C@]5(C)C(=CC4)C[C@@H](O[C@@H]4[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@@H](O)[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@H](CO)O4)CC5)CC3)C[C@@H]2O1)C)[C@H]1[C@H](O)[C@H](O)[C@H](O)[C@@H](CO)O1 LVTJOONKWUXEFR-FZRMHRINSA-N 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- 230000009897 systematic effect Effects 0.000 description 4
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- 208000035143 Bacterial infection Diseases 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 241000233866 Fungi Species 0.000 description 3
- 235000010469 Glycine max Nutrition 0.000 description 3
- 244000068988 Glycine max Species 0.000 description 3
- 239000005909 Kieselgur Substances 0.000 description 3
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 3
- 244000070406 Malus silvestris Species 0.000 description 3
- 206010027146 Melanoderma Diseases 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 3
- 244000061176 Nicotiana tabacum Species 0.000 description 3
- 241000233679 Peronosporaceae Species 0.000 description 3
- 241000221300 Puccinia Species 0.000 description 3
- 240000003768 Solanum lycopersicum Species 0.000 description 3
- 241000607479 Yersinia pestis Species 0.000 description 3
- 240000008042 Zea mays Species 0.000 description 3
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 3
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000000440 bentonite Substances 0.000 description 3
- 229910000278 bentonite Inorganic materials 0.000 description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 235000005822 corn Nutrition 0.000 description 3
- 239000000645 desinfectant Substances 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 230000008686 ergosterol biosynthesis Effects 0.000 description 3
- 238000003973 irrigation Methods 0.000 description 3
- 230000002262 irrigation Effects 0.000 description 3
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 3
- 230000011890 leaf development Effects 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 239000000575 pesticide Substances 0.000 description 3
- 239000005871 repellent Substances 0.000 description 3
- 230000002940 repellent Effects 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 3
- 229960002447 thiram Drugs 0.000 description 3
- 235000013311 vegetables Nutrition 0.000 description 3
- PPDBOQMNKNNODG-NTEUORMPSA-N (5E)-5-(4-chlorobenzylidene)-2,2-dimethyl-1-(1,2,4-triazol-1-ylmethyl)cyclopentanol Chemical compound C1=NC=NN1CC1(O)C(C)(C)CC\C1=C/C1=CC=C(Cl)C=C1 PPDBOQMNKNNODG-NTEUORMPSA-N 0.000 description 2
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 241000223600 Alternaria Species 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 244000105624 Arachis hypogaea Species 0.000 description 2
- 235000016068 Berberis vulgaris Nutrition 0.000 description 2
- 241000335053 Beta vulgaris Species 0.000 description 2
- 240000002791 Brassica napus Species 0.000 description 2
- 240000007124 Brassica oleracea Species 0.000 description 2
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 2
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 2
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 235000002566 Capsicum Nutrition 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 208000035473 Communicable disease Diseases 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 241000588698 Erwinia Species 0.000 description 2
- 239000005781 Fludioxonil Substances 0.000 description 2
- 239000005785 Fluquinconazole Substances 0.000 description 2
- 240000009088 Fragaria x ananassa Species 0.000 description 2
- 244000299507 Gossypium hirsutum Species 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 229920001732 Lignosulfonate Polymers 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- 208000031888 Mycoses Diseases 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 241001668536 Oculimacula yallundae Species 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 206010035148 Plague Diseases 0.000 description 2
- 240000005809 Prunus persica Species 0.000 description 2
- 235000006040 Prunus persica var persica Nutrition 0.000 description 2
- 241000221301 Puccinia graminis Species 0.000 description 2
- 241000228453 Pyrenophora Species 0.000 description 2
- 241000220324 Pyrus Species 0.000 description 2
- 241000813090 Rhizoctonia solani Species 0.000 description 2
- 206010039509 Scab Diseases 0.000 description 2
- 235000003434 Sesamum indicum Nutrition 0.000 description 2
- 244000040738 Sesamum orientale Species 0.000 description 2
- 235000002597 Solanum melongena Nutrition 0.000 description 2
- 244000061458 Solanum melongena Species 0.000 description 2
- 235000002595 Solanum tuberosum Nutrition 0.000 description 2
- 244000061456 Solanum tuberosum Species 0.000 description 2
- 229930182692 Strobilurin Natural products 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 241000723873 Tobacco mosaic virus Species 0.000 description 2
- 239000005859 Triticonazole Substances 0.000 description 2
- 241000700605 Viruses Species 0.000 description 2
- 241000589634 Xanthomonas Species 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 241001360088 Zymoseptoria tritici Species 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 235000020971 citrus fruits Nutrition 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 208000032625 disorder of ear Diseases 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000012990 dithiocarbamate Substances 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- DFBKLUNHFCTMDC-GKRDHZSOSA-N endrin Chemical compound C([C@@H]1[C@H]2[C@@]3(Cl)C(Cl)=C([C@]([C@H]22)(Cl)C3(Cl)Cl)Cl)[C@@H]2[C@H]2[C@@H]1O2 DFBKLUNHFCTMDC-GKRDHZSOSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 239000003337 fertilizer Substances 0.000 description 2
- 244000037666 field crops Species 0.000 description 2
- MUJOIMFVNIBMKC-UHFFFAOYSA-N fludioxonil Chemical compound C=12OC(F)(F)OC2=CC=CC=1C1=CNC=C1C#N MUJOIMFVNIBMKC-UHFFFAOYSA-N 0.000 description 2
- IJJVMEJXYNJXOJ-UHFFFAOYSA-N fluquinconazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1N1C(=O)C2=CC(F)=CC=C2N=C1N1C=NC=N1 IJJVMEJXYNJXOJ-UHFFFAOYSA-N 0.000 description 2
- 230000035784 germination Effects 0.000 description 2
- 238000003306 harvesting Methods 0.000 description 2
- 239000004009 herbicide Substances 0.000 description 2
- RONFGUROBZGJKP-UHFFFAOYSA-N iminoctadine Chemical compound NC(N)=NCCCCCCCCNCCCCCCCCN=C(N)N RONFGUROBZGJKP-UHFFFAOYSA-N 0.000 description 2
- 230000001939 inductive effect Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000011081 inoculation Methods 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- WLPCAERCXQSYLQ-UHFFFAOYSA-N isotianil Chemical compound ClC1=NSC(C(=O)NC=2C(=CC=CC=2)C#N)=C1Cl WLPCAERCXQSYLQ-UHFFFAOYSA-N 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 230000006651 lactation Effects 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 description 2
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 235000020232 peanut Nutrition 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 230000008635 plant growth Effects 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000003672 processing method Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000008262 pumice Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 230000005070 ripening Effects 0.000 description 2
- 230000034655 secondary growth Effects 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 239000012265 solid product Substances 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- RUVINXPYWBROJD-ONEGZZNKSA-N trans-anethole Chemical compound COC1=CC=C(\C=C\C)C=C1 RUVINXPYWBROJD-ONEGZZNKSA-N 0.000 description 2
- 238000002054 transplantation Methods 0.000 description 2
- 230000003612 virological effect Effects 0.000 description 2
- 235000020234 walnut Nutrition 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 1
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 1
- ZMYFCFLJBGAQRS-IAGOWNOFSA-N (2S,3R)-epoxiconazole Chemical compound C1=CC(F)=CC=C1[C@]1(CN2N=CN=C2)[C@@H](C=2C(=CC=CC=2)Cl)O1 ZMYFCFLJBGAQRS-IAGOWNOFSA-N 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- GRRIYLZJLGTQJX-UHFFFAOYSA-N 1,2-dibenzoylhydrazine Chemical compound C=1C=CC=CC=1C(=O)NNC(=O)C1=CC=CC=C1 GRRIYLZJLGTQJX-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- ZRKMQKLGEQPLNS-UHFFFAOYSA-N 1-Pentanethiol Chemical compound CCCCCS ZRKMQKLGEQPLNS-UHFFFAOYSA-N 0.000 description 1
- 125000006083 1-bromoethyl group Chemical group 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- 238000005160 1H NMR spectroscopy Methods 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- 125000004793 2,2,2-trifluoroethoxy group Chemical group FC(CO*)(F)F 0.000 description 1
- VBKWYZHROJJFSM-UHFFFAOYSA-N 2,3,4,5,6-pentachlorophenol;n-phenylaniline Chemical compound OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl.C=1C=CC=CC=1NC1=CC=CC=C1 VBKWYZHROJJFSM-UHFFFAOYSA-N 0.000 description 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- PTTPXKJBFFKCEK-UHFFFAOYSA-N 2-Methyl-4-heptanone Chemical compound CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 description 1
- PZBPHYLKIMOZPR-FIYGWYQWSA-K 2-[4-[2-[[(2r)-1-[[(4r,7s,10s,13r,16s,19r)-10-(4-aminobutyl)-4-[[(2r,3r)-1,3-dihydroxybutan-2-yl]carbamoyl]-7-[(1r)-1-hydroxyethyl]-16-[(4-hydroxyphenyl)methyl]-13-(1h-indol-3-ylmethyl)-6,9,12,15,18-pentaoxo-1,2-dithia-5,8,11,14,17-pentazacycloicos-19-yl] Chemical compound [68Ga+3].C([C@H](C(=O)N[C@H]1CSSC[C@H](NC(=O)[C@H]([C@@H](C)O)NC(=O)[C@H](CCCCN)NC(=O)[C@@H](CC=2C3=CC=CC=C3NC=2)NC(=O)[C@H](CC=2C=CC(O)=CC=2)NC1=O)C(=O)N[C@H](CO)[C@H](O)C)NC(=O)CN1CCN(CC([O-])=O)CCN(CC([O-])=O)CCN(CC([O-])=O)CC1)C1=CC=CC=C1 PZBPHYLKIMOZPR-FIYGWYQWSA-K 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- YOQUZCNSUOJWQS-UHFFFAOYSA-N 3-chloro-4-methylaniline;hydron;chloride Chemical compound Cl.CC1=CC=C(N)C=C1Cl YOQUZCNSUOJWQS-UHFFFAOYSA-N 0.000 description 1
- 125000006283 4-chlorobenzyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1Cl)C([H])([H])* 0.000 description 1
- OEDUIFSDODUDRK-UHFFFAOYSA-N 5-phenyl-1h-pyrazole Chemical compound N1N=CC=C1C1=CC=CC=C1 OEDUIFSDODUDRK-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 208000032484 Accidental exposure to product Diseases 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 241000743339 Agrostis Species 0.000 description 1
- 235000005254 Allium ampeloprasum Nutrition 0.000 description 1
- 240000006108 Allium ampeloprasum Species 0.000 description 1
- 244000291564 Allium cepa Species 0.000 description 1
- 235000002732 Allium cepa var. cepa Nutrition 0.000 description 1
- 241000352690 Alternaria kikuchiana Species 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- 244000144725 Amygdalus communis Species 0.000 description 1
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- 235000007319 Avena orientalis Nutrition 0.000 description 1
- 244000075850 Avena orientalis Species 0.000 description 1
- 241000271566 Aves Species 0.000 description 1
- 235000000832 Ayote Nutrition 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 description 1
- 241001480060 Blumeria Species 0.000 description 1
- 241001465180 Botrytis Species 0.000 description 1
- 241000123650 Botrytis cinerea Species 0.000 description 1
- 241000167854 Bourreria succulenta Species 0.000 description 1
- 235000011293 Brassica napus Nutrition 0.000 description 1
- 240000000385 Brassica napus var. napus Species 0.000 description 1
- 235000011299 Brassica oleracea var botrytis Nutrition 0.000 description 1
- 235000017647 Brassica oleracea var italica Nutrition 0.000 description 1
- 240000003259 Brassica oleracea var. botrytis Species 0.000 description 1
- 235000000540 Brassica rapa subsp rapa Nutrition 0.000 description 1
- 235000004977 Brassica sinapistrum Nutrition 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 241000589638 Burkholderia glumae Species 0.000 description 1
- MNUHVNVGEQMMNR-UHFFFAOYSA-N CCC(C(C)C)(C(C)C)OC(=O)C1=CC=CC=C1C(=O)O Chemical compound CCC(C(C)C)(C(C)C)OC(=O)C1=CC=CC=C1C(=O)O MNUHVNVGEQMMNR-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 239000005746 Carboxin Substances 0.000 description 1
- 241001157813 Cercospora Species 0.000 description 1
- 241000530549 Cercospora beticola Species 0.000 description 1
- 239000005747 Chlorothalonil Substances 0.000 description 1
- 235000007516 Chrysanthemum Nutrition 0.000 description 1
- 244000189548 Chrysanthemum x morifolium Species 0.000 description 1
- 244000241235 Citrullus lanatus Species 0.000 description 1
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 235000019499 Citrus oil Nutrition 0.000 description 1
- 241000228437 Cochliobolus Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 240000007154 Coffea arabica Species 0.000 description 1
- 229940126062 Compound A Drugs 0.000 description 1
- 241001529717 Corticium <basidiomycota> Species 0.000 description 1
- 241000219112 Cucumis Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 235000009849 Cucumis sativus Nutrition 0.000 description 1
- 240000004244 Cucurbita moschata Species 0.000 description 1
- 235000009854 Cucurbita moschata Nutrition 0.000 description 1
- 235000009804 Cucurbita pepo subsp pepo Nutrition 0.000 description 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 1
- 240000004585 Dactylis glomerata Species 0.000 description 1
- 235000002767 Daucus carota Nutrition 0.000 description 1
- 244000000626 Daucus carota Species 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- 241001645342 Diaporthe citri Species 0.000 description 1
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical class CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 1
- 241000237537 Ensis Species 0.000 description 1
- 241000221787 Erysiphe Species 0.000 description 1
- PNVJTZOFSHSLTO-UHFFFAOYSA-N Fenthion Chemical compound COP(=S)(OC)OC1=CC=C(SC)C(C)=C1 PNVJTZOFSHSLTO-UHFFFAOYSA-N 0.000 description 1
- 235000016623 Fragaria vesca Nutrition 0.000 description 1
- 235000011363 Fragaria x ananassa Nutrition 0.000 description 1
- 239000005791 Fuberidazole Substances 0.000 description 1
- 241000122692 Fusarium avenaceum Species 0.000 description 1
- 241000221778 Fusarium fujikuroi Species 0.000 description 1
- 241000223195 Fusarium graminearum Species 0.000 description 1
- 241000221779 Fusarium sambucinum Species 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 241000223247 Gloeocercospora Species 0.000 description 1
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 1
- 235000008694 Humulus lupulus Nutrition 0.000 description 1
- 244000025221 Humulus lupulus Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000005906 Imidacloprid Substances 0.000 description 1
- 244000017020 Ipomoea batatas Species 0.000 description 1
- 235000002678 Ipomoea batatas Nutrition 0.000 description 1
- 241000758791 Juglandaceae Species 0.000 description 1
- 240000007049 Juglans regia Species 0.000 description 1
- 235000009496 Juglans regia Nutrition 0.000 description 1
- 235000003228 Lactuca sativa Nutrition 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 244000165082 Lavanda vera Species 0.000 description 1
- 235000010663 Lavandula angustifolia Nutrition 0.000 description 1
- WLLGXSLBOPFWQV-UHFFFAOYSA-N MGK 264 Chemical compound C1=CC2CC1C1C2C(=O)N(CC(CC)CCCC)C1=O WLLGXSLBOPFWQV-UHFFFAOYSA-N 0.000 description 1
- 241001330975 Magnaporthe oryzae Species 0.000 description 1
- 229940127408 Melanin Synthesis Inhibitors Drugs 0.000 description 1
- 239000005951 Methiocarb Substances 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 241001518729 Monilinia Species 0.000 description 1
- 235000008708 Morus alba Nutrition 0.000 description 1
- 240000000249 Morus alba Species 0.000 description 1
- 241001558145 Mucor sp. Species 0.000 description 1
- 101100113998 Mus musculus Cnbd2 gene Proteins 0.000 description 1
- 240000005561 Musa balbisiana Species 0.000 description 1
- 241000131448 Mycosphaerella Species 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- SUAKHGWARZSWIH-UHFFFAOYSA-N N,N‐diethylformamide Chemical compound CCN(CC)C=O SUAKHGWARZSWIH-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- HRYILSDLIGTCOP-UHFFFAOYSA-N N-benzoylurea Chemical compound NC(=O)NC(=O)C1=CC=CC=C1 HRYILSDLIGTCOP-UHFFFAOYSA-N 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- QMGVPVSNSZLJIA-UHFFFAOYSA-N Nux Vomica Natural products C1C2C3C4N(C=5C6=CC=CC=5)C(=O)CC3OCC=C2CN2C1C46CC2 QMGVPVSNSZLJIA-UHFFFAOYSA-N 0.000 description 1
- 241000207836 Olea <angiosperm> Species 0.000 description 1
- 241000233855 Orchidaceae Species 0.000 description 1
- 241000736122 Parastagonospora nodorum Species 0.000 description 1
- 241000315044 Passalora arachidicola Species 0.000 description 1
- 239000006002 Pepper Substances 0.000 description 1
- 244000062780 Petroselinum sativum Species 0.000 description 1
- 241000440444 Phakopsora Species 0.000 description 1
- 241000682645 Phakopsora pachyrhizi Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 241001503951 Phoma Species 0.000 description 1
- 241000233622 Phytophthora infestans Species 0.000 description 1
- 231100000674 Phytotoxicity Toxicity 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 235000016761 Piper aduncum Nutrition 0.000 description 1
- 240000003889 Piper guineense Species 0.000 description 1
- 235000017804 Piper guineense Nutrition 0.000 description 1
- 235000008184 Piper nigrum Nutrition 0.000 description 1
- 241000758706 Piperaceae Species 0.000 description 1
- 235000010582 Pisum sativum Nutrition 0.000 description 1
- 240000004713 Pisum sativum Species 0.000 description 1
- 241001281803 Plasmopara viticola Species 0.000 description 1
- 229920001213 Polysorbate 20 Polymers 0.000 description 1
- 235000009827 Prunus armeniaca Nutrition 0.000 description 1
- 244000018633 Prunus armeniaca Species 0.000 description 1
- 241000682843 Pseudocercosporella Species 0.000 description 1
- 241000589516 Pseudomonas Species 0.000 description 1
- 241001281802 Pseudoperonospora Species 0.000 description 1
- 241000520648 Pyrenophora teres Species 0.000 description 1
- 241000231139 Pyricularia Species 0.000 description 1
- 235000014443 Pyrus communis Nutrition 0.000 description 1
- 244000088415 Raphanus sativus Species 0.000 description 1
- 235000006140 Raphanus sativus var sativus Nutrition 0.000 description 1
- 241001515786 Rhynchosporium Species 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 244000178231 Rosmarinus officinalis Species 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- 241000221662 Sclerotinia Species 0.000 description 1
- 241001518640 Sclerotinia homoeocarpa Species 0.000 description 1
- 241000221696 Sclerotinia sclerotiorum Species 0.000 description 1
- 241000209056 Secale Species 0.000 description 1
- 235000007238 Secale cereale Nutrition 0.000 description 1
- 240000003829 Sorghum propinquum Species 0.000 description 1
- 235000011684 Sorghum saccharatum Nutrition 0.000 description 1
- 241000592344 Spermatophyta Species 0.000 description 1
- 235000009337 Spinacia oleracea Nutrition 0.000 description 1
- 244000300264 Spinacia oleracea Species 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 235000021536 Sugar beet Nutrition 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 239000005941 Thiamethoxam Substances 0.000 description 1
- 239000005843 Thiram Substances 0.000 description 1
- 235000007303 Thymus vulgaris Nutrition 0.000 description 1
- 240000002657 Thymus vulgaris Species 0.000 description 1
- 241000722093 Tilletia caries Species 0.000 description 1
- 239000005846 Triadimenol Substances 0.000 description 1
- GCTFWCDSFPMHHS-UHFFFAOYSA-M Tributyltin chloride Chemical compound CCCC[Sn](Cl)(CCCC)CCCC GCTFWCDSFPMHHS-UHFFFAOYSA-M 0.000 description 1
- 241000219793 Trifolium Species 0.000 description 1
- 241000959260 Typhula Species 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 241000083901 Urocystis agropyri Species 0.000 description 1
- 241000221566 Ustilago Species 0.000 description 1
- 241000317942 Venturia <ichneumonid wasp> Species 0.000 description 1
- 241000228452 Venturia inaequalis Species 0.000 description 1
- 235000010749 Vicia faba Nutrition 0.000 description 1
- 240000006677 Vicia faba Species 0.000 description 1
- 235000002098 Vicia faba var. major Nutrition 0.000 description 1
- 235000011453 Vigna umbellata Nutrition 0.000 description 1
- 240000001417 Vigna umbellata Species 0.000 description 1
- 241000219094 Vitaceae Species 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 241000589636 Xanthomonas campestris Species 0.000 description 1
- 241000589652 Xanthomonas oryzae Species 0.000 description 1
- 235000006886 Zingiber officinale Nutrition 0.000 description 1
- 244000273928 Zingiber officinale Species 0.000 description 1
- 239000005870 Ziram Substances 0.000 description 1
- 241000981595 Zoysia japonica Species 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 235000020224 almond Nutrition 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 229940072049 amyl acetate Drugs 0.000 description 1
- 229940011037 anethole Drugs 0.000 description 1
- PGMYKACGEOXYJE-UHFFFAOYSA-N anhydrous amyl acetate Natural products CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 235000021016 apples Nutrition 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- FMTFZYKYVZBISL-HUVRVWIJSA-N azacosterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H](N(C)CCCN(C)C)[C@@]1(C)CC2 FMTFZYKYVZBISL-HUVRVWIJSA-N 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 235000021015 bananas Nutrition 0.000 description 1
- 235000012216 bentonite Nutrition 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 230000000443 biocontrol Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 125000005997 bromomethyl group Chemical group 0.000 description 1
- 125000004744 butyloxycarbonyl group Chemical group 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 239000000073 carbamate insecticide Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- GYSSRZJIHXQEHQ-UHFFFAOYSA-N carboxin Chemical compound S1CCOC(C)=C1C(=O)NC1=CC=CC=C1 GYSSRZJIHXQEHQ-UHFFFAOYSA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 235000019693 cherries Nutrition 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 1
- CRQQGFGUEAVUIL-UHFFFAOYSA-N chlorothalonil Chemical compound ClC1=C(Cl)C(C#N)=C(Cl)C(C#N)=C1Cl CRQQGFGUEAVUIL-UHFFFAOYSA-N 0.000 description 1
- 239000010500 citrus oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 239000002361 compost Substances 0.000 description 1
- JNGZXGGOCLZBFB-IVCQMTBJSA-N compound E Chemical compound N([C@@H](C)C(=O)N[C@@H]1C(N(C)C2=CC=CC=C2C(C=2C=CC=CC=2)=N1)=O)C(=O)CC1=CC(F)=CC(F)=C1 JNGZXGGOCLZBFB-IVCQMTBJSA-N 0.000 description 1
- QYCVHILLJSYYBD-UHFFFAOYSA-L copper;oxalate Chemical compound [Cu+2].[O-]C(=O)C([O-])=O QYCVHILLJSYYBD-UHFFFAOYSA-L 0.000 description 1
- 150000001896 cresols Chemical class 0.000 description 1
- 238000012272 crop production Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 125000001995 cyclobutyl group Chemical group [H]C1([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 125000004786 difluoromethoxy group Chemical group [H]C(F)(F)O* 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 1
- 230000005059 dormancy Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 125000003754 ethoxycarbonyl group Chemical group C(=O)(OCC)* 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000002871 fertility agent Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 230000037406 food intake Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- ZEYJIQLVKGBLEM-UHFFFAOYSA-N fuberidazole Chemical compound C1=COC(C=2N=C3[CH]C=CC=C3N=2)=C1 ZEYJIQLVKGBLEM-UHFFFAOYSA-N 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 235000019717 geranium oil Nutrition 0.000 description 1
- 239000010648 geranium oil Substances 0.000 description 1
- 235000008397 ginger Nutrition 0.000 description 1
- FVIZARNDLVOMSU-UHFFFAOYSA-N ginsenoside K Natural products C1CC(C2(CCC3C(C)(C)C(O)CCC3(C)C2CC2O)C)(C)C2C1C(C)(CCC=C(C)C)OC1OC(CO)C(O)C(O)C1O FVIZARNDLVOMSU-UHFFFAOYSA-N 0.000 description 1
- 239000011491 glass wool Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- OCDGBSUVYYVKQZ-UHFFFAOYSA-N gramine Chemical compound C1=CC=C2C(CN(C)C)=CNC2=C1 OCDGBSUVYYVKQZ-UHFFFAOYSA-N 0.000 description 1
- 235000021021 grapes Nutrition 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- MNWFXJYAOYHMED-UHFFFAOYSA-M heptanoate Chemical compound CCCCCCC([O-])=O MNWFXJYAOYHMED-UHFFFAOYSA-M 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000003707 hexyloxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])O* 0.000 description 1
- 235000012907 honey Nutrition 0.000 description 1
- 239000003501 hydroponics Substances 0.000 description 1
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 1
- 229940056881 imidacloprid Drugs 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000028993 immune response Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 125000005921 isopentoxy group Chemical group 0.000 description 1
- 125000003253 isopropoxy group Chemical group [H]C([H])([H])C([H])(O*)C([H])([H])[H] 0.000 description 1
- 125000005928 isopropyloxycarbonyl group Chemical group [H]C([H])([H])C([H])(OC(*)=O)C([H])([H])[H] 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 description 1
- 239000001102 lavandula vera Substances 0.000 description 1
- 235000018219 lavender Nutrition 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 239000003120 macrolide antibiotic agent Substances 0.000 description 1
- 229940041616 menthol Drugs 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- YFBPRJGDJKVWAH-UHFFFAOYSA-N methiocarb Chemical compound CNC(=O)OC1=CC(C)=C(SC)C(C)=C1 YFBPRJGDJKVWAH-UHFFFAOYSA-N 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 229960001047 methyl salicylate Drugs 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000011490 mineral wool Substances 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- 239000005645 nematicide Substances 0.000 description 1
- 125000005484 neopentoxy group Chemical group 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229960002715 nicotine Drugs 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- RUVINXPYWBROJD-UHFFFAOYSA-N para-methoxyphenyl Natural products COC1=CC=C(C=CC)C=C1 RUVINXPYWBROJD-UHFFFAOYSA-N 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 230000007170 pathology Effects 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- 125000004115 pentoxy group Chemical group [*]OC([H])([H])C([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 235000011197 perejil Nutrition 0.000 description 1
- 125000005004 perfluoroethyl group Chemical group FC(F)(F)C(F)(F)* 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010665 pine oil Substances 0.000 description 1
- 239000005962 plant activator Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 239000005648 plant growth regulator Substances 0.000 description 1
- 244000000003 plant pathogen Species 0.000 description 1
- 235000021018 plums Nutrition 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 235000012015 potatoes Nutrition 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 125000004742 propyloxycarbonyl group Chemical group 0.000 description 1
- 235000015136 pumpkin Nutrition 0.000 description 1
- DNXIASIHZYFFRO-UHFFFAOYSA-N pyrazoline Chemical compound C1CN=NC1 DNXIASIHZYFFRO-UHFFFAOYSA-N 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 229910052903 pyrophyllite Inorganic materials 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000241 respiratory effect Effects 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 230000005082 stem growth Effects 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 235000021012 strawberries Nutrition 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- RUPAXCPQAAOIPB-UHFFFAOYSA-N tert-butyl formate Chemical group CC(C)(C)OC=O RUPAXCPQAAOIPB-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- NWWZPOKUUAIXIW-FLIBITNWSA-N thiamethoxam Chemical compound [O-][N+](=O)\N=C/1N(C)COCN\1CC1=CN=C(Cl)S1 NWWZPOKUUAIXIW-FLIBITNWSA-N 0.000 description 1
- 239000001585 thymus vulgaris Substances 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 238000013519 translation Methods 0.000 description 1
- 230000014616 translation Effects 0.000 description 1
- BAZVSMNPJJMILC-UHFFFAOYSA-N triadimenol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC1=CC=C(Cl)C=C1 BAZVSMNPJJMILC-UHFFFAOYSA-N 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 125000000876 trifluoromethoxy group Chemical group FC(F)(F)O* 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- 230000009105 vegetative growth Effects 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
Definitions
- the spraying treatment of the plant disease control agent for agricultural and horticultural use normally performed on the BBCH 31 to 39 in the growth stage is T1 treatment
- the spraying treatment of the plant disease control agent for agricultural and horticultural treatment performed on the BBCH 40 to 59 is T2 treatment, BBCH60 or later
- T3 treatment for example, see Non-Patent Document 4
- the present invention [1] Seeds of target plant, cultivation carrier for sowing seed of target plant, soil for sowing seed of target plant, or soil for transplanting target plant grown on cultivation carrier with disease resistance inducer A method for controlling diseases of agricultural and horticultural plants, characterized in that the agricultural and horticultural fungicides are then sprayed at least once in the period after BBCH40, [2] The method for controlling diseases of agricultural and horticultural plants according to [1], wherein the period after BBCH 40 is BBCH 40 to 59; [3] The method for controlling diseases of agricultural and horticultural plants according to [1], wherein the time after BBCH40 is after BBCH60, [4] The method for controlling diseases of agricultural and horticultural plants according to any one of [1] to [3], wherein the target plants are cereals or crops for processing; [5] The method for controlling diseases of agricultural and horticultural plants according to any one of [1] to [3], wherein the target plant is wheat or barley; [6] The active ingredient of the
- R 1 , R 2 , R 3 , R 4 and R 5 may be the same or different and each represents a hydrogen atom; a halogen atom or a (C 1 -C 3 ) alkyl group.
- R 6 is a hydrogen atom; (C 1 -C 8 ) alkyl group; (C 3 -C 6 ) cycloalkyl group; phenyl (C 1 -C 6 ) alkyl group; halogen atom, cyano group, (C 1 -C 6 ) Alkyl group, halo (C 1 -C 6 ) alkyl group, (C 3 -C 6 ) cycloalkyl group, halo (C 3 -C 6 ) cycloalkyl group, (C 1 -C 6 ) alkoxy group, halo ( A substituted phenyl having one or more substituents which may be the same or different, selected from the group consisting of a C 1 -C 6 ) alk
- the control method can omit the spraying process performed before the BBCH 40 in each growth stage that is normally performed, improves the working environment of agricultural workers, and is based on the foliage spraying process. It is possible to prevent the scattering of agricultural chemicals and reduce the total amount of agricultural chemicals used in the system control method, and consequently reduce the environmental load. This is an excellent performance compared to the prior art, and not only shows excellent safety for the target plant and excellent control effect against plant diseases, but also has a long-lasting effect, so that The present invention provides a method for controlling diseases of horticultural plants.
- (C 3 -C 6 ) cycloalkyl group means, for example, 3 to 6 carbon atoms such as cyclopropyl group, cyclobutyl group, cyclopentyl group, cyclohexyl group, 2-methylcyclopropyl group, 2-methylcyclopentyl group, etc. Represents an alicyclic alkyl group.
- the plant diseases to which the disease control method for agricultural and horticultural plants of the present invention is applied are not limited to these, but the following plant diseases can be exemplified.
- Plant diseases are broadly classified into filamentous fungal diseases, bacterial diseases, and viral diseases.
- fungal diseases include, for example, diseases of the genus Botrytis, diseases of the genus Helmintosporium, diseases of the genus Fusarium, diseases of the genus Septoria, diseases of the genus Sarcospora, Diseases of the genus (Pseudocercosporella), diseases of the genus Rhynchosporium, diseases of the genus Pyricularia, diseases of the genus Alternaria; diseases of the genus Hemilelia, Diseases of the genus Ustilago, diseases of the genus Typhula, Pucchinia Diseases of the genus Puccinia, basidiomycetous diseases such as the disease of the genus Phakopsora;
- halogenated hydrocarbons eg, dichloroethane, chloroform, carbon tetrachloride, chlorinated benzene, etc.
- esters eg, ethyl acetate, diisopropylpropyl
- the disease resistance inducer used in the method for controlling diseases of agricultural and horticultural plants of the present invention can be mixed or used in combination with other components as necessary.
- animals such as birds can be used for seed treatment.
- repellents and other ingredients can be included.
- the active ingredient compound may be appropriately selected from the range of about 0.1 g to about 1000 g per are, and preferably in the range of about 1 to about 100 g.
- the seed treatment agent may be appropriately selected from the range of about 0.1 to about 1000 g as an active ingredient compound per 100 kg of dry seed weight, and preferably about 1 to about 300 g.
- the disease resistance inducer used in the method for controlling diseases of agricultural and horticultural plants of the present invention is not limited to single use, but various compounds, for example, plant disease control agents for agricultural and horticultural diseases having the bactericidal activity or insecticidal activity shown below. It can also be used in combination with it, and can also be used in combination.
- Test Example 2 Wheat red rust control effect test by mixed seed treatment (greenhouse test) Similar to the method described in Test Example 1, 0.1 g of water is applied to 10 g of wheat (variety: Chihoku wheat) dry seeds, and the amount of wettable powder described in the table is uniformly applied to the water-treated seeds. It processed so that it might adhere to. The treated seeds were air-dried and then sown in a plastic pot having a diameter of 10 cm and cultivated in a greenhouse. When the wheat grew at the 6-leaf stage / dividing stage (about 70 days after sowing), the wheat was spray-inoculated with a spore suspension of Puccinia recondita. Seven days after the inoculation, the disease index and the control value (%) of the developed leaves were calculated according to the criteria of Test 1. The results are shown in Table 4.
- the disease resistance inducer exhibits an effect superior to that of the control compound by the method for controlling diseases of the agricultural and horticultural plant of the present invention, and the dispersal treatment of the agricultural and horticultural fungicide (T2) performed at a time after BBCH40 in the growth stage. It has been proved that there is a possibility that the processing, T3 processing) can be reduced or reduced.
- the control compound J + K as a foliage spray was also sprayed during the internode elongation period (BBCH31-32) of wheat.
- BBCH31-32 internode elongation period
- Test 1 the incidence index of the naturally occurring Septoria tritici (Septoria tritici) disease was investigated and controlled for the next and stationary leaves at the time of wheat heading (around BBCH 75-83, 210-230 days after sowing). The value (%) was calculated. The results are shown in Table 8.
- the disease controlling effect of the present invention was maintained until the next year when wheat emerged (around BBCH 51-59, about 270 days after sowing). From this result, the disease resistance inducer used in the present invention showed a remarkable sustained effect over the control compound. Further, from the comparative example, the method for controlling diseases of agricultural and horticultural plants according to the present invention is applied to the horticultural horticultural fungicide spraying treatment (T1 treatment) performed on the BBCH 31 to 39 in the growth stage by system treatment and the BBCH 40 to 59 in the growth stage. It has been proved that there is a possibility that the spraying treatment (T2 treatment) of the agricultural and horticultural fungicide performed can be reduced.
- T1 treatment horticultural horticultural fungicide spraying treatment
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Provided is a method for controlling an agricultural and horticultural plant disease which comprises treating seeds of the subject plant or a cultivation carrier for sowing the subject plant with a disease resistance inducer to thereby reduce the application frequency of an agricultural and horticultural germicide against a disease occurring from the sowing time to the peak or later growth stage. A method for controlling an agricultural and horticultural plant disease characterized by comprising treating seeds of the subject plant, a cultivation carrier for sowing the seeds of the subject plant, soil for sowing the seeds of the subject plant or soil for transplanting plant seedlings having been raised in a cultivation carrier with a disease resistance inducer and then applying an agricultural and horticultural germicide at least once after BBCH growth stage 40.
Description
本発明は病害抵抗性誘導剤を用いた農園芸用植物の病害防除方法に関する。更に詳しくは、当該病害抵抗性誘導剤で防除処理対象植物の種子又は対象植物を播種する栽培担体又は対象植物の種子を播種する土壌等に処理する農園芸用植物の病害防除方法に関する。
The present invention relates to a disease control method for agricultural and horticultural plants using a disease resistance inducer. More specifically, the present invention relates to a method for controlling diseases of agricultural and horticultural plants that are treated with seeds of plants to be controlled with the disease resistance inducer, cultivation carriers for seeding the target plants, or soil for seeding the seeds of the target plants.
農業及び園芸等の作物生産は病害等による被害が今なお大きく、長期使用による既存剤に対する菌類の薬剤抵抗性菌株の報告もあり、新規作用性を有する農園芸用植物病害防除剤の開発の要望は高い。そこで、近年いわゆる病害抵抗性誘導物質(プラントアクチベーター)が次世代の農薬として注目されている。この病害抵抗性誘導物質は病害に対して直接的な殺菌効果を示さないが、植物自身が本来有している病害に対する抵抗性を誘導することにより病害を防除する。加えてその効果は比較的に長期に維持され、また、病原菌特異性がないため、広範囲の病害に対して防除効果を示すうえ、薬剤耐性株が出現することも殆どない(例えば、非特許文献1参照。)。
Agricultural and horticultural crop production is still severely damaged by diseases, etc., and there are reports of fungal drug-resistant strains against existing agents due to long-term use, and requests for the development of agricultural and horticultural plant disease control agents with new activities Is expensive. In recent years, so-called disease resistance inducers (plant activators) have attracted attention as next-generation agricultural chemicals. Although this disease resistance inducer does not show a direct bactericidal effect on the disease, the disease is controlled by inducing resistance to the disease inherent to the plant itself. In addition, the effect is maintained for a relatively long period of time, and since there is no pathogen-specificity, it exhibits a control effect against a wide range of diseases, and drug-resistant strains rarely appear (for example, non-patent literature) 1).
一方、近年就農者の老齢化等により各種の省力的な使用方法の開発や地球環境保全の目的から使用薬量の低減が求められており、これらに適した使用方法及び農園芸用植物病害防除剤の創出が強く求められている。従来の農園芸用植物の病害防除方法の一つとしては、例えば、農園芸用殺菌剤を対象植物の種子、対象植物を播種する栽培担体又は対象植物の種子を播種する土壌へ施用する方法が知られている。この使用方法は薬剤を対象植物の種子、対象植物を播種する栽培担体又は対象植物の種子を播種する土壌にしか存在させないから、使用薬量の低減につながり地球環境への負荷が軽減され、さらに作業者と薬剤との接触を減らせることにより作業者の安全性を高め、作業の省力化にも繋がるという特長を有する。
On the other hand, in recent years, due to the aging of farmers, the development of various labor-saving usage methods and the reduction of the amount of drugs to be used are required for the purpose of global environmental conservation. Usage methods suitable for these and control of plant diseases for agriculture and horticulture There is a strong demand for the creation of drugs. As one of conventional methods for controlling diseases of agricultural and horticultural plants, for example, there is a method of applying an agricultural and horticultural fungicide to the seed of the target plant, a cultivation carrier for seeding the target plant, or a soil for seeding the seed of the target plant. Are known. In this method of use, since the drug is present only in the seed of the target plant, the cultivation carrier for seeding the target plant, or the soil for seeding the seed of the target plant, the amount of drug used is reduced and the burden on the global environment is reduced. By reducing the contact between the worker and the medicine, the safety of the worker is increased, and the labor is saved.
作物栽培にかかわる農作業で、作物の生育を正確に把握することは、各作業適期の把握や気象災害予防の為に極めて重要である。特に除草剤や殺菌剤は、薬効、薬害の面から使用基準に示されている処理適期をはずすことは好ましくない。しかし同じ作物でも場面や地域で、生育時期の表現が異なるため、一般には理解しにくい。そのため植物の生育段階を数値化又は記号化し、農作業者などが作物の生育段階を簡単に理解できる表記法のBBCH法が浸透しつつある。
このBBCH法は、植物すべての生育段階を二桁の数字で表す方法で、2桁目(左側の数字)に植物の一時的生育段階を0~9(0:発芽期、1:葉の展開期、2:分げつ形成期、3:茎葉伸長期、4:収穫部の生長期、5:出穂又は花芽形成期、6:開花期、7:乳熟期、8:登熟期、9:枯死期、)の10段階に分類して表記し、1桁目(右側の数字)に植物の二次的生育段階の詳細を0~9段階に分類して表記する方法である。これにより、植物の生育段階を00~99の十進法「2桁コード」で表記できることになる。例えば、穀類では、BBCH00~29は、乾燥種子から分げつが終了する時期までを言い、BBCH31~39は茎葉伸長開始期から止葉展開終了期、BBCH41~59は止葉の伸長開始期から出穂終了期、BBCH60~89、99は第1花開花期から果実の落下が始まる時期、休眠期を表す(例えば、非特許文献2、3参照)。 Accurately grasping the growth of crops in agricultural work related to crop cultivation is extremely important for grasping the appropriate time for each work and preventing weather disasters. In particular, it is not preferable for herbicides and fungicides to be removed from the appropriate treatment period indicated in the usage standards in terms of medicinal efficacy and phytotoxicity. However, it is generally difficult to understand because the expression of the growing season varies depending on the scene and region even for the same crop. For this reason, the BBCH method, which is a notation method that makes it possible for farmers to easily understand the growth stage of crops by digitizing or symbolizing the growth stage of plants, is becoming popular.
In this BBCH method, the growth stage of all plants is represented by a two-digit number, and the temporary growth stage of the plant is 0 to 9 (0: germination stage, 1: leaf development) in the second digit (number on the left side). Period 2: tillering period 3: stem growth period 4: harvesting period 5: heading or flower bud formation period 6: flowering period 7: lactation period 8: ripening period 9 : The dead stage)), and the details of the secondary growth stage of the plant are classified into 0 to 9 stages in the first digit (number on the right side). As a result, the growth stage of the plant can be expressed by a decimal “two-digit code” of 00 to 99. For example, in cereals, BBCH 00-29 refers to the period from the dry seed to the end of tillering, BBCH 31-39 is from the start of stem and leaf elongation to the end of leaf development, and BBCH 41 to 59 is heading from the beginning of leaf extension. The end period, BBCH 60 to 89, 99 represents the period when the fruit starts to fall from the first flowering period, and the dormant period (see, for example,Non-Patent Documents 2 and 3).
このBBCH法は、植物すべての生育段階を二桁の数字で表す方法で、2桁目(左側の数字)に植物の一時的生育段階を0~9(0:発芽期、1:葉の展開期、2:分げつ形成期、3:茎葉伸長期、4:収穫部の生長期、5:出穂又は花芽形成期、6:開花期、7:乳熟期、8:登熟期、9:枯死期、)の10段階に分類して表記し、1桁目(右側の数字)に植物の二次的生育段階の詳細を0~9段階に分類して表記する方法である。これにより、植物の生育段階を00~99の十進法「2桁コード」で表記できることになる。例えば、穀類では、BBCH00~29は、乾燥種子から分げつが終了する時期までを言い、BBCH31~39は茎葉伸長開始期から止葉展開終了期、BBCH41~59は止葉の伸長開始期から出穂終了期、BBCH60~89、99は第1花開花期から果実の落下が始まる時期、休眠期を表す(例えば、非特許文献2、3参照)。 Accurately grasping the growth of crops in agricultural work related to crop cultivation is extremely important for grasping the appropriate time for each work and preventing weather disasters. In particular, it is not preferable for herbicides and fungicides to be removed from the appropriate treatment period indicated in the usage standards in terms of medicinal efficacy and phytotoxicity. However, it is generally difficult to understand because the expression of the growing season varies depending on the scene and region even for the same crop. For this reason, the BBCH method, which is a notation method that makes it possible for farmers to easily understand the growth stage of crops by digitizing or symbolizing the growth stage of plants, is becoming popular.
In this BBCH method, the growth stage of all plants is represented by a two-digit number, and the temporary growth stage of the plant is 0 to 9 (0: germination stage, 1: leaf development) in the second digit (number on the left side). Period 2: tillering period 3: stem growth period 4: harvesting period 5: heading or flower bud formation period 6: flowering period 7: lactation period 8: ripening period 9 : The dead stage)), and the details of the secondary growth stage of the plant are classified into 0 to 9 stages in the first digit (number on the right side). As a result, the growth stage of the plant can be expressed by a decimal “two-digit code” of 00 to 99. For example, in cereals, BBCH 00-29 refers to the period from the dry seed to the end of tillering, BBCH 31-39 is from the start of stem and leaf elongation to the end of leaf development, and BBCH 41 to 59 is heading from the beginning of leaf extension. The end period, BBCH 60 to 89, 99 represents the period when the fruit starts to fall from the first flowering period, and the dormant period (see, for example,
前期BBCH表記に従うと、コムギやオオムギ等の穀類に発生する病害に対する防除方法は、「その種子にトリアジメノール、ビテルタノール又はトリチコナゾール等のエルゴステロール生合成阻害剤又はチウラム等のジチオカーバメート剤等を種子処理することで、前記BBCH00~29の生育段階に発病する種子伝染性病害(裸黒穂病、なまぐさ黒穂病、麦角病など)及び土壌伝染性病害(立枯病、株腐病、眼紋病など)を防除し、BBCH31~99の生育段階で発病するうどんこ病、さび病、或いはセプトリアによる病害等を、防除効果を有するアゾール系殺菌剤、モルホリン系殺菌剤、ストロビルリン系殺菌剤等を2~3回茎葉散布することにより体系的に防除する。」と表される。このうち、通常、生育段階のBBCH31~39に行われる農園芸用植物病害防除剤の散布処理をT1処理、BBCH40~59に行われる農園芸用植物病害防除剤の散布処理をT2処理、BBCH60以降に行われる農園芸用植物病害防除剤の散布処理をT3処理と呼んでいる(例えば、非特許文献4参照)。
According to the BBCH notation in the previous term, the method for controlling diseases that occur in cereals such as wheat and barley is as follows: “Ergosterol biosynthesis inhibitors such as triazimenol, vitertanol or triticonazole, dithiocarbamate agents such as thiuram, etc. Seed infectious diseases (bare black ear disease, Namagusa black ear disease, ergot disease, etc.) and soil infectious diseases (withering disease, strain rot, eyeprint) that develop during the growth stage of BBCH00-29 Diseases such as powdery mildew, rust, or septoria that develops during the growth stage of BBCH 31-99, azole fungicides, morpholine fungicides, strobilurin fungicides etc. that have a controlling effect. It is controlled systematically by spraying the foliage 2-3 times. " Among these, the spraying treatment of the plant disease control agent for agricultural and horticultural use normally performed on the BBCH 31 to 39 in the growth stage is T1 treatment, the spraying treatment of the plant disease control agent for agricultural and horticultural treatment performed on the BBCH 40 to 59 is T2 treatment, BBCH60 or later The spraying treatment of the plant disease control agent for agricultural and horticultural use performed in the above is called T3 treatment (for example, see Non-Patent Document 4).
一方、チアジニル(一般名、例えば、非特許文献5参照。)、アシベンゾラル-S-メチル(一般名)、プロベナゾール(一般名)、NCI、INA、BIT及びイソチアニル(一般名)が病害抵抗性誘導剤として報告されている(例えば、非特許文献6又は7参照。)。その構造式を下記に示す。また特定の1,2,3-チアジアゾール誘導体を農園芸用植物病害防除剤として防除処理対象植物の種子又は対象植物を播種する栽培担体に処理する方法が知られている(例えば、特許文献1参照。)。
On the other hand, thiazinyl (generic name, for example, refer to Non-Patent Document 5), acibenzoral-S-methyl (generic name), probenazole (generic name), NCI, INA, BIT and isothianyl (generic name) are disease resistance inducers. (See, for example, Non-Patent Document 6 or 7). Its structural formula is shown below. Also known is a method of treating a specific 1,2,3-thiadiazole derivative as a plant disease control agent for agriculture and horticulture with a seed for the plant to be controlled or a cultivation carrier for seeding the plant (for example, see Patent Document 1). .)
前記のように、農園芸用殺菌剤を対象植物の種子又は対象植物を播種する栽培担体へ施用する方法が報告されているが、従来技術では殺菌スペクトラム、処理薬量、残効性、対象植物に対する安全性等において充分な性能が発揮できないという課題があった。また、当該方法は、対象植物の種子から生育初期までの期間(前記BBCH00~29)に発病する病害の防除を目的としていることから、生育盛期から後期(前記BBCH31以降)に発病する病害の防除には、別途、農園芸用殺菌剤等の散布による複数回の防除(T1処理、T2処理及びT3処理)が不可欠であった。そのため播種時から生育盛期あるいは後期に至るまでの間に発病する病害に対して長期の防除効果を有する農園芸用植物の病害防除方法、即ち、前記農園芸用殺菌剤等の散布による複数回の防除を低減することができる農園芸用植物の病害防除方法が求められていた。
As described above, a method of applying an agricultural and horticultural fungicide to the seed of a target plant or a cultivation carrier for seeding the target plant has been reported, but in the prior art, the sterilization spectrum, treatment dose, residual effect, target plant There has been a problem that sufficient performance cannot be exhibited in terms of safety and the like. In addition, since the method is intended to control diseases that develop during the period from the seed of the target plant to the early stage of growth (BBCH00 to 29), it is possible to prevent diseases that develop from the growing season to the late stage (after BBCH31). For the control, separately, a plurality of times of control (T1 treatment, T2 treatment and T3 treatment) by spraying agricultural and horticultural fungicides or the like were indispensable. Therefore, a disease control method for agricultural and horticultural plants having a long-term control effect against diseases that occur during the period from sowing to the growing season or later, that is, multiple times by spraying the agricultural and horticultural fungicides, etc. Therefore, there has been a demand for a method for controlling diseases of agricultural and horticultural plants that can reduce the control of the plant.
本発明者等は上記課題に対処すべく、鋭意研究を重ねた結果、病害抵抗性誘導剤を対象植物の種子、対象植物を播種する栽培担体又は対象植物の種子を播種する土壌へ施用する方法について鋭意検討し、当該病害抵抗性誘導剤が各種植物病害に対して優れた防除効果及び対象植物に対する優れた安全性を示すのみならず、従来技術では予想もつかない極めて長期間に亘る防除効果を有することを見い出し、本発明を完成させた。
As a result of intensive studies to address the above-mentioned problems, the inventors have applied a disease resistance inducer to the seed of the target plant, a cultivation carrier for seeding the target plant, or a soil for seeding the seed of the target plant. The disease resistance inducer not only exhibits excellent control effects against various plant diseases and excellent safety for target plants, but also has an extremely long-term control effect that is not expected in the prior art. The present invention has been completed.
即ち、本発明は
[1]対象植物の種子、対象植物の種子を播種するための栽培担体、対象植物の種子を播種する土壌、又は、栽培担体で育苗した対象植物を移植する土壌を、病害抵抗性誘導剤で処理し、次にBBCH40以降の時期に農園芸用殺菌剤を、少なくとも1回散布処理することを特徴とする農園芸用植物の病害防除方法、
[2]BBCH40以降の時期が、BBCH40~59である[1]に記載の農園芸用植物の病害防除方法、
[3]BBCH40以降の時期が、BBCH60以降である[1]に記載の農園芸用植物の病害防除方法、
[4]対象植物が穀類又は加工用作物類である[1]~[3]のいずれか1項に記載の農園芸用植物の病害防除方法、
[5]対象植物が小麦又は大麦である[1]~[3]のいずれか1項に記載の農園芸用植物の病害防除方法、
[6]病害抵抗性誘導剤の有効成分が、
一般式(I): That is, the present invention
[1] Seeds of target plant, cultivation carrier for sowing seed of target plant, soil for sowing seed of target plant, or soil for transplanting target plant grown on cultivation carrier with disease resistance inducer A method for controlling diseases of agricultural and horticultural plants, characterized in that the agricultural and horticultural fungicides are then sprayed at least once in the period after BBCH40,
[2] The method for controlling diseases of agricultural and horticultural plants according to [1], wherein the period after BBCH 40 is BBCH 40 to 59;
[3] The method for controlling diseases of agricultural and horticultural plants according to [1], wherein the time after BBCH40 is after BBCH60,
[4] The method for controlling diseases of agricultural and horticultural plants according to any one of [1] to [3], wherein the target plants are cereals or crops for processing;
[5] The method for controlling diseases of agricultural and horticultural plants according to any one of [1] to [3], wherein the target plant is wheat or barley;
[6] The active ingredient of the disease resistance inducer is
Formula (I):
[1]対象植物の種子、対象植物の種子を播種するための栽培担体、対象植物の種子を播種する土壌、又は、栽培担体で育苗した対象植物を移植する土壌を、病害抵抗性誘導剤で処理し、次にBBCH40以降の時期に農園芸用殺菌剤を、少なくとも1回散布処理することを特徴とする農園芸用植物の病害防除方法、
[2]BBCH40以降の時期が、BBCH40~59である[1]に記載の農園芸用植物の病害防除方法、
[3]BBCH40以降の時期が、BBCH60以降である[1]に記載の農園芸用植物の病害防除方法、
[4]対象植物が穀類又は加工用作物類である[1]~[3]のいずれか1項に記載の農園芸用植物の病害防除方法、
[5]対象植物が小麦又は大麦である[1]~[3]のいずれか1項に記載の農園芸用植物の病害防除方法、
[6]病害抵抗性誘導剤の有効成分が、
一般式(I): That is, the present invention
[1] Seeds of target plant, cultivation carrier for sowing seed of target plant, soil for sowing seed of target plant, or soil for transplanting target plant grown on cultivation carrier with disease resistance inducer A method for controlling diseases of agricultural and horticultural plants, characterized in that the agricultural and horticultural fungicides are then sprayed at least once in the period after BBCH40,
[2] The method for controlling diseases of agricultural and horticultural plants according to [1], wherein the period after BBCH 40 is BBCH 40 to 59;
[3] The method for controlling diseases of agricultural and horticultural plants according to [1], wherein the time after BBCH40 is after BBCH60,
[4] The method for controlling diseases of agricultural and horticultural plants according to any one of [1] to [3], wherein the target plants are cereals or crops for processing;
[5] The method for controlling diseases of agricultural and horticultural plants according to any one of [1] to [3], wherein the target plant is wheat or barley;
[6] The active ingredient of the disease resistance inducer is
Formula (I):
{式中、R1、R2、R3、R4及びR5はそれぞれ同一又は異なっても良く、水素原子;ハロゲン原子又は(C1-C3)アルキル基を示す。
R6は水素原子;(C1-C8)アルキル基;(C3-C6)シクロアルキル基;フェニル(C1-C6)アルキル基;ハロゲン原子、シアノ基、(C1-C6)アルキル基、ハロ(C1-C6)アルキル基、(C3-C6)シクロアルキル基、ハロ(C3-C6)シクロアルキル基、(C1-C6)アルコキシ基、ハロ(C1-C6)アルコキシ基、カルボキシル基及び(C1-C6)アルコキシカルボニル基からなる群より選択される1または同一もしくは異なっても良い2以上の置換基を有する置換フェニル(C1-C6)アルキル基;フェニル基;ハロゲン原子、シアノ基、(C1-C6)アルキル基、ハロ(C1-C6)アルキル基、(C3-C6)シクロアルキル基、ハロ(C3-C6)シクロアルキル基、(C1-C6)アルコキシ基、ハロ(C1-C6)アルコキシ基、カルボキシル基及び(C1-C6)アルコキシカルボニル基からなる群より選択される1または同一もしくは異なっても良い2以上の置換基を有する置換フェニル基を示す。
Yは酸素原子又は-N(R7)-(式中、R7は水素原子、(C1-C6)アルキル基、又は(C3-C6)シクロアルキル基を示す。)
Wは酸素原子又は硫黄原子を示す。}
で表される1,2,3-チアジアゾール誘導体若しくはその塩類である[1]~[5]のいずれか1項に記載の農園芸用植物の病害防除方法、
[7]病害抵抗性誘導剤の有効成分が、チアジニル、アシベンゾラル-S-メチル、プロベナゾール、NCI、INA、BIT及びイソチアニルである[1]~[6]のいずれか1項に記載の農園芸用植物の病害防除方法、
[8]病害抵抗性誘導剤の有効成分の有効量が対象植物の種子100重量部に対して0.0001~1重量部である[1]~[7]のいずれか1項に記載の農園芸用植物の病害防除方法、及び、
[9]病害抵抗性誘導剤が植物の病害に対する抵抗性を植物に付与する薬剤であることを特徴とする[1]に記載の農園芸用植物の防除方法、
に関する。 {Wherein R 1 , R 2 , R 3 , R 4 and R 5 may be the same or different and each represents a hydrogen atom; a halogen atom or a (C 1 -C 3 ) alkyl group.
R 6 is a hydrogen atom; (C 1 -C 8 ) alkyl group; (C 3 -C 6 ) cycloalkyl group; phenyl (C 1 -C 6 ) alkyl group; halogen atom, cyano group, (C 1 -C 6 ) Alkyl group, halo (C 1 -C 6 ) alkyl group, (C 3 -C 6 ) cycloalkyl group, halo (C 3 -C 6 ) cycloalkyl group, (C 1 -C 6 ) alkoxy group, halo ( A substituted phenyl having one or more substituents which may be the same or different, selected from the group consisting of a C 1 -C 6 ) alkoxy group, a carboxyl group and a (C 1 -C 6 ) alkoxycarbonyl group (C 1- C 6 ) alkyl group; phenyl group; halogen atom, cyano group, (C 1 -C 6 ) alkyl group, halo (C 1 -C 6 ) alkyl group, (C 3 -C 6 ) cycloalkyl group, halo (C 3 -C ) Cycloalkyl group, (C 1 -C 6) alkoxy groups, halo (C 1 -C 6) alkoxy groups, 1 or the same or is selected from the group consisting of carboxyl group and (C 1 -C 6) alkoxycarbonyl group A substituted phenyl group having two or more substituents which may be different is shown.
Y represents an oxygen atom or —N (R 7 ) — (wherein R 7 represents a hydrogen atom, a (C 1 -C 6 ) alkyl group, or a (C 3 -C 6 ) cycloalkyl group).
W represents an oxygen atom or a sulfur atom. }
The method for controlling diseases of agricultural and horticultural plants according to any one of [1] to [5], which is a 1,2,3-thiadiazole derivative represented by the formula:
[7] The agricultural and horticultural use according to any one of [1] to [6], wherein the active ingredient of the disease resistance inducer is thiazinyl, acibenzoral-S-methyl, probenazole, NCI, INA, BIT, and isothianyl. Plant disease control methods,
[8] The agriculture according to any one of [1] to [7], wherein the effective amount of the active ingredient of the disease resistance inducer is 0.0001 to 1 part by weight per 100 parts by weight of the seed of the target plant. Disease control method for horticultural plants, and
[9] The method for controlling agricultural and horticultural plants according to [1], wherein the disease resistance inducer is a drug that imparts resistance to plant diseases to plants.
About.
R6は水素原子;(C1-C8)アルキル基;(C3-C6)シクロアルキル基;フェニル(C1-C6)アルキル基;ハロゲン原子、シアノ基、(C1-C6)アルキル基、ハロ(C1-C6)アルキル基、(C3-C6)シクロアルキル基、ハロ(C3-C6)シクロアルキル基、(C1-C6)アルコキシ基、ハロ(C1-C6)アルコキシ基、カルボキシル基及び(C1-C6)アルコキシカルボニル基からなる群より選択される1または同一もしくは異なっても良い2以上の置換基を有する置換フェニル(C1-C6)アルキル基;フェニル基;ハロゲン原子、シアノ基、(C1-C6)アルキル基、ハロ(C1-C6)アルキル基、(C3-C6)シクロアルキル基、ハロ(C3-C6)シクロアルキル基、(C1-C6)アルコキシ基、ハロ(C1-C6)アルコキシ基、カルボキシル基及び(C1-C6)アルコキシカルボニル基からなる群より選択される1または同一もしくは異なっても良い2以上の置換基を有する置換フェニル基を示す。
Yは酸素原子又は-N(R7)-(式中、R7は水素原子、(C1-C6)アルキル基、又は(C3-C6)シクロアルキル基を示す。)
Wは酸素原子又は硫黄原子を示す。}
で表される1,2,3-チアジアゾール誘導体若しくはその塩類である[1]~[5]のいずれか1項に記載の農園芸用植物の病害防除方法、
[7]病害抵抗性誘導剤の有効成分が、チアジニル、アシベンゾラル-S-メチル、プロベナゾール、NCI、INA、BIT及びイソチアニルである[1]~[6]のいずれか1項に記載の農園芸用植物の病害防除方法、
[8]病害抵抗性誘導剤の有効成分の有効量が対象植物の種子100重量部に対して0.0001~1重量部である[1]~[7]のいずれか1項に記載の農園芸用植物の病害防除方法、及び、
[9]病害抵抗性誘導剤が植物の病害に対する抵抗性を植物に付与する薬剤であることを特徴とする[1]に記載の農園芸用植物の防除方法、
に関する。 {Wherein R 1 , R 2 , R 3 , R 4 and R 5 may be the same or different and each represents a hydrogen atom; a halogen atom or a (C 1 -C 3 ) alkyl group.
R 6 is a hydrogen atom; (C 1 -C 8 ) alkyl group; (C 3 -C 6 ) cycloalkyl group; phenyl (C 1 -C 6 ) alkyl group; halogen atom, cyano group, (C 1 -C 6 ) Alkyl group, halo (C 1 -C 6 ) alkyl group, (C 3 -C 6 ) cycloalkyl group, halo (C 3 -C 6 ) cycloalkyl group, (C 1 -C 6 ) alkoxy group, halo ( A substituted phenyl having one or more substituents which may be the same or different, selected from the group consisting of a C 1 -C 6 ) alkoxy group, a carboxyl group and a (C 1 -C 6 ) alkoxycarbonyl group (C 1- C 6 ) alkyl group; phenyl group; halogen atom, cyano group, (C 1 -C 6 ) alkyl group, halo (C 1 -C 6 ) alkyl group, (C 3 -C 6 ) cycloalkyl group, halo (C 3 -C ) Cycloalkyl group, (C 1 -C 6) alkoxy groups, halo (C 1 -C 6) alkoxy groups, 1 or the same or is selected from the group consisting of carboxyl group and (C 1 -C 6) alkoxycarbonyl group A substituted phenyl group having two or more substituents which may be different is shown.
Y represents an oxygen atom or —N (R 7 ) — (wherein R 7 represents a hydrogen atom, a (C 1 -C 6 ) alkyl group, or a (C 3 -C 6 ) cycloalkyl group).
W represents an oxygen atom or a sulfur atom. }
The method for controlling diseases of agricultural and horticultural plants according to any one of [1] to [5], which is a 1,2,3-thiadiazole derivative represented by the formula:
[7] The agricultural and horticultural use according to any one of [1] to [6], wherein the active ingredient of the disease resistance inducer is thiazinyl, acibenzoral-S-methyl, probenazole, NCI, INA, BIT, and isothianyl. Plant disease control methods,
[8] The agriculture according to any one of [1] to [7], wherein the effective amount of the active ingredient of the disease resistance inducer is 0.0001 to 1 part by weight per 100 parts by weight of the seed of the target plant. Disease control method for horticultural plants, and
[9] The method for controlling agricultural and horticultural plants according to [1], wherein the disease resistance inducer is a drug that imparts resistance to plant diseases to plants.
About.
本発明の農園芸用植物の病害防除方法によれば、病害抵抗性誘導剤によって植物の病害に対する抵抗性が増強されるので、従来、体系的防除方法において必須とされていた各生育段階での複数回の農園芸用殺菌剤の散布処理の回数を低減することができる。特に、本発明の農園芸用植物の病害防除方法は、播種後、出芽期から生育盛期ないし後期に至るまでの生育期間(前記BBCH31~59)に発病するうどんこ病、さび病、及びセプトリアによる病害等に対して病害防除効果を奏するものである。その結果、当該防除方法は、通常行われている各生育段階におけるBBCH40より前の時期に行われる散布処理を省略することが可能であり、農業作業者の労働環境を改善し、茎葉散布処理による農薬の飛散を防ぎ、かつ、体系防除方法で使用される農薬の全体量を低減せしめ、結果的に環境負荷を軽減させることができる。これは従来技術に比べて優れた性能であり、対象植物に対する優れた安全性及び植物病害に対する優れた防除効果を示すのみならず、極めて長期間に亘る効果持続性を有することから、新たな農園芸用植物の病害防除方法を提供するものである。
According to the disease control method for agricultural and horticultural plants of the present invention, since the resistance to plant diseases is enhanced by the disease resistance inducer, conventionally, in each growth stage that has been essential in the systematic control method. It is possible to reduce the number of times of spraying the agricultural and horticultural fungicides. In particular, the method for controlling diseases of agricultural and horticultural plants according to the present invention includes powdery mildew, rust, and septoria that develop during the growth period (BBCH 31 to 59) from the emergence stage to the growing season to the late stage after sowing. It exerts a disease control effect against diseases caused by. As a result, the control method can omit the spraying process performed before the BBCH 40 in each growth stage that is normally performed, improves the working environment of agricultural workers, and is based on the foliage spraying process. It is possible to prevent the scattering of agricultural chemicals and reduce the total amount of agricultural chemicals used in the system control method, and consequently reduce the environmental load. This is an excellent performance compared to the prior art, and not only shows excellent safety for the target plant and excellent control effect against plant diseases, but also has a long-lasting effect, so that The present invention provides a method for controlling diseases of horticultural plants.
本発明で規定する病害抵抗性誘導剤とは、動物の免疫反応に似た防除反応で、植物病原菌に対して直接的な殺菌効果を示さないが、病原菌の感染を受けると植物自身が有する病害抵抗性を誘導することによって病害を防除する化合物を有効成分とする組成物を言う。
本発明に好適に用いられる病害抵抗性誘導剤の有効成分としては、下記一般式(I)で表される1,2,3-チアジアゾール誘導体若しくはその塩類、チアジニル、アシベンゾラル-S-メチル、プロベナゾール、NCI、INA、BIT又はイソチアニル等が挙げられる。 The disease resistance inducer defined in the present invention is a control reaction similar to the immune response of animals, and does not show a direct bactericidal effect against plant pathogens, but is a disease possessed by the plant itself when it is infected with a pathogen. It refers to a composition comprising as an active ingredient a compound that controls disease by inducing resistance.
As an active ingredient of a disease resistance inducer suitably used in the present invention, 1,2,3-thiadiazole derivatives represented by the following general formula (I) or salts thereof, thiazinyl, acibenzoral-S-methyl, probenazole, NCI, INA, BIT, isotianil, etc. are mentioned.
本発明に好適に用いられる病害抵抗性誘導剤の有効成分としては、下記一般式(I)で表される1,2,3-チアジアゾール誘導体若しくはその塩類、チアジニル、アシベンゾラル-S-メチル、プロベナゾール、NCI、INA、BIT又はイソチアニル等が挙げられる。 The disease resistance inducer defined in the present invention is a control reaction similar to the immune response of animals, and does not show a direct bactericidal effect against plant pathogens, but is a disease possessed by the plant itself when it is infected with a pathogen. It refers to a composition comprising as an active ingredient a compound that controls disease by inducing resistance.
As an active ingredient of a disease resistance inducer suitably used in the present invention, 1,2,3-thiadiazole derivatives represented by the following general formula (I) or salts thereof, thiazinyl, acibenzoral-S-methyl, probenazole, NCI, INA, BIT, isotianil, etc. are mentioned.
上記一般式(I)の定義において、「ハロゲン原子」とは塩素原子、臭素原子、沃素原子又はフッ素原子を示す。「(C1-C6)アルキル基」とは、例えばメチル基、エチル基、ノルマルプロピル基、イソプロピル基、ノルマルブチル基、イソブチル基、セカンダリーブチル基、ターシャリーブチル基、ノルマルペンチル基、ネオペンチル基、ノルマルヘキシル基等の直鎖又は分鎖状の炭素原子数1~6個のアルキル基を示す。「ハロ(C1-C6)アルキル基」とは、同一又は異なっても良い1以上のハロゲン原子により置換された直鎖又は分岐鎖状の炭素原子数1~6個のアルキル基を示し、例えばトリフルオロメチル基、ジフルオロチル基、パーフルオロエチル基、パーフルオロイソプロピル基、クロロメチル基、ブロモメチル基、1-ブロモエチル基、2,3-ジブロモプロピル基等を示す。
In the definition of the general formula (I), the “halogen atom” refers to a chlorine atom, a bromine atom, an iodine atom or a fluorine atom. “(C 1 -C 6 ) alkyl group” means, for example, methyl group, ethyl group, normal propyl group, isopropyl group, normal butyl group, isobutyl group, secondary butyl group, tertiary butyl group, normal pentyl group, neopentyl group And a linear or branched alkyl group having 1 to 6 carbon atoms such as a normal hexyl group. The “halo (C 1 -C 6 ) alkyl group” refers to a linear or branched alkyl group having 1 to 6 carbon atoms substituted with one or more halogen atoms which may be the same or different, For example, trifluoromethyl group, difluorotyl group, perfluoroethyl group, perfluoroisopropyl group, chloromethyl group, bromomethyl group, 1-bromoethyl group, 2,3-dibromopropyl group and the like are shown.
「(C3-C6)シクロアルキル基」とは、例えばシクロプロピル基、シクロブチル基、シクロペンチル基、シクロヘキシル基、2-メチルシクロプロピル基、2-メチルシクロペンチル基等の炭素原子数3~6個の脂環式アルキル基を示す。「(C1-C6)アルコキシ基」とは、例えばメトキシ基、エトキシ基、ノルマルプロポキシ基、イソプロポキシ基、ノルマルブトキシ基、セカンダリーブトキシ基、ターシャリーブトキシ基、ノルマルペンチルオキシ基、イソペンチルオキシ基、ネオペンチルオキシ基、ノルマルヘキシルオキシ基等の直鎖又は分岐鎖状の炭素原子数1~6個のアルコキシ基を示す。
The “(C 3 -C 6 ) cycloalkyl group” means, for example, 3 to 6 carbon atoms such as cyclopropyl group, cyclobutyl group, cyclopentyl group, cyclohexyl group, 2-methylcyclopropyl group, 2-methylcyclopentyl group, etc. Represents an alicyclic alkyl group. “(C 1 -C 6 ) alkoxy group” means, for example, methoxy group, ethoxy group, normal propoxy group, isopropoxy group, normal butoxy group, secondary butoxy group, tertiary butoxy group, normal pentyloxy group, isopentyloxy group A straight-chain or branched alkoxy group having 1 to 6 carbon atoms such as a group, a neopentyloxy group, and a normal hexyloxy group;
「ハロ(C1-C6)アルコキシ基」とは、同一又は異なっても良い1以上のハロゲン原子により置換された直鎖又は分岐鎖状の炭素原子数1~6個のアルコキシ基を示し、例えばジフルオロメトキシ基、トリフルオロメトキシ基、2,2,2-トリフルオロエトキシ基等を示す。「(C1-C6)アルコキシカルボニル基」とは、例えばメトキシカルボニル基、エトキシカルボニル基、ノルマルプロポキシカルボニル基、イソプロポキシカルボニル基、ノルマルブトキシカルボニル基、ターシャリーブトキシカルボニル基等の直鎖又は分岐鎖状の炭素原子数1~6個のアルコキシカルボニル基を示す。
The “halo (C 1 -C 6 ) alkoxy group” refers to a linear or branched alkoxy group having 1 to 6 carbon atoms substituted with one or more halogen atoms which may be the same or different, Examples thereof include a difluoromethoxy group, a trifluoromethoxy group, a 2,2,2-trifluoroethoxy group, and the like. “(C 1 -C 6 ) alkoxycarbonyl group” means, for example, linear or branched such as methoxycarbonyl group, ethoxycarbonyl group, normal propoxycarbonyl group, isopropoxycarbonyl group, normal butoxycarbonyl group, tertiary butoxycarbonyl group, etc. A chain-like alkoxycarbonyl group having 1 to 6 carbon atoms is shown.
一般式(I)で表される1,2,3-チアジアゾール誘導体は、その構造式中に1つ又は複数個の不斉中心を含む場合があり、2種以上の光学異性体及びジアステレオマーが存在する場合もあるが、本発明は各々の光学異性体及びそれらが任意の割合で含まれる混合物をも全て包含するものである。これらの誘導体は、特開2007-99749号公報に記載された方法で製造することができる。
The 1,2,3-thiadiazole derivative represented by the general formula (I) may contain one or more asymmetric centers in the structural formula, and two or more optical isomers and diastereomers However, the present invention includes all the optical isomers and the mixtures in which they are contained in an arbitrary ratio. These derivatives can be produced by the method described in Japanese Patent Application Laid-Open No. 2007-99749.
本発明の好ましい実施態様について述べる。R1、R2、R3、R4及びR5としては、 水素原子、(C1-C3)アルキル基が良く、好ましくは水素原子である。R6としては( 置換フェニル(C1-C6)アルキル基、置換フェニル基が良く、好ましくは4-クロロベンジル基、2、4-ジメトキシフェニル基、更に好ましくは2、4-ジメトキシフェニル基である。Yとしては酸素原子、-NH-が良く、好ましくは-NH-である。Wとしては酸素原子、硫黄原子が良く、好ましくは酸素原子である。
A preferred embodiment of the present invention will be described. R 1 , R 2 , R 3 , R 4 and R 5 are preferably a hydrogen atom or a (C 1 -C 3 ) alkyl group, preferably a hydrogen atom. R 6 is preferably a (substituted phenyl (C 1 -C 6 ) alkyl group or a substituted phenyl group, preferably a 4-chlorobenzyl group, a 2,4-dimethoxyphenyl group, more preferably a 2,4-dimethoxyphenyl group. Y is preferably an oxygen atom or —NH—, and preferably —NH—, and W is preferably an oxygen atom or a sulfur atom, preferably an oxygen atom.
本発明の病害防除方法に用いられる病害抵抗性誘導剤のうち、チアジニル、アシベンゾル-S-メチル、プロベナゾール及びBITを有効成分とするものは、それぞれ製品として市販されているので入手可能である。NCI(J.Pesticide Sci.15,413-417(1990))、INA(C.A.16877e(1956))、及びイソチアニル(特表2005-530847公報)は、それぞれ文献記載の方法に従って製造することができる。
Of the disease resistance inducers used in the disease control method of the present invention, those containing thiazinyl, acibenzol-S-methyl, probenazole and BIT as active ingredients are commercially available as products. NCI (J. Pesticide Sci. 15, 413-417 (1990)), INA (C.A. 16877e (1956)), and isotianil (Japanese translations of PCT publication No. 2005-530847) should each be manufactured according to the method described in the literature. Can do.
以下の第1表に、一般式(I)で表される1,2,3-チアジアゾール誘導体の具体例を列挙するが、これらに限定されるものではない。なお、第1表において、「Me」はメチル基を、「Et」はエチル基を、「Ph」はフェニル基を、「Bu」はブチル基を、「n-Pr」はノルマルプロピル基を、「i-Pr」はイソプロピル基を、「n-Bu」はノルマルブチル基を、「i-Bu」はイソブチル基を、「s-Bu」はセカンダリーブチル基を、「t-Bu」はターシャリーブチル基を表す。また「nD(℃)」は化合物の屈折率を示す。
Specific examples of the 1,2,3-thiadiazole derivatives represented by the general formula (I) are listed in Table 1 below, but are not limited thereto. In Table 1, “Me” represents a methyl group, “Et” represents an ethyl group, “Ph” represents a phenyl group, “Bu” represents a butyl group, “n-Pr” represents a normal propyl group, “I-Pr” is an isopropyl group, “n-Bu” is a normal butyl group, “i-Bu” is an isobutyl group, “s-Bu” is a secondary butyl group, and “t-Bu” is tertiary. Represents a butyl group. “N D (° C.)” represents the refractive index of the compound.
第1表に例示した1,2,3-チアジアゾール誘導体のうち、一部の化合物の1H-NMRデータを第2表に示す。第2表中の化合物番号は上記第1表に記載の番号を示す。
Among the 1,2,3-thiadiazole derivatives exemplified in Table 1, 1 H-NMR data of some compounds are shown in Table 2. The compound numbers in Table 2 indicate the numbers described in Table 1 above.
本発明の使用方法で用いる病害抵抗性誘導剤の有効成分は、長期に効果を有するものであればよく、その有効成分は、1,2,3-チアジアゾール誘導体若しくはその塩類、チアジニル、プロベナゾール、イソチアニル、アシベンゾラル-S-メチル、NCI、INA又はBITであるが、好ましくは1,2,3-チアジアゾール誘導体若しくはその塩類、チアジニル、プロベナゾール、イソチアニル、又はアシベンゾラル-S-メチルであり、特に好ましくは、1,2,3-チアジアゾール誘導体若しくはその塩類である。
The active ingredient of the disease resistance inducer used in the method of use of the present invention is not particularly limited as long as it has an effect over a long period of time, and the active ingredient is 1,2,3-thiadiazole derivative or a salt thereof, thiazinyl, probenazole, isothianyl , Acibenzoral-S-methyl, NCI, INA or BIT, preferably 1,2,3-thiadiazole derivatives or salts thereof, thiazinyl, probenazole, isothianyl, or acibenzoral-S-methyl, particularly preferably 1 2,3-thiadiazole derivatives or salts thereof.
本発明の農園芸用植物の病害防除方法の適用対象である植物病害としては、これらに限定されるものではないが、下記の植物病害を例示することができる。
植物病害は大きく分ければ、糸状菌類病害、細菌類病害、ウイルス病病害を含むものである。糸状菌類病害としては、例えば、ボトリチス(Botrytis)属病害、ヘルミントスポリウム(Helminthosporium)属病害、フザリウム(Fusarium)属病害、セプトリア(Septoria)属病害、サルコスポラ(Cercospora)属病害、シュードサルコスポレラ(Pseudocercosporella)属病害、リンコスポリウム(Rhynchosporium)属病害、ピリキュラリア(Pyricularia)属病害、アルタナリア(Alternaria)属病害等の不完全菌類病害;例えばヘミレリア(Hemilelia)属病害、リゾクトニア(Rhizoctonia)属病害、ウスティラゴ(Ustilago)属病害、ティフラ(Typhula)属病害、プッキニア(Puccinia)属病害、ファコプソラ(Phakopsora)属病害等の担子菌類病害;例えば、ベンチュリア(Venturia)属病害、ポドスフェラ(Podosphaera)属病害、レプトスファエリア(Leptosphaeria)属病害、ブルメリア(Blumeria)属病害、エリシフェ(Erysiphe)属病害、ミクロドキュウム(Microdochium)属病害、スクレロチニア(Sclerotinia)属病害、ゲウマノマイセス(Gaeumannomyces)属病害、モニリニア(Monilinia)属病害、ウンシヌラ(Unsinula)属病害等の子のう菌類病害;例えば、アスコクイタ(Ascochyta)属病害、フォマ(Phoma)属病害、ピシウム(Pythium)属病害、コルティシウム(Corticium)属病害、ピレノフォラ(Pyrenophora)属病害、ミコスファエラ属(Mycosphaerella)等のその他の菌類による病害が挙げられる。細菌類病害としては、例えば、シュードモナス(Pseudomonas)属病害、ザントモナス(Xanthomonas)属病害、エルヴィニア(Erwinia)属病害等の細菌類による病害が挙げられる。ウイルス病病害としては、例えば、タバコモザイクウイルス等のウイルス類よる病害等が挙げられる。 The plant diseases to which the disease control method for agricultural and horticultural plants of the present invention is applied are not limited to these, but the following plant diseases can be exemplified.
Plant diseases are broadly classified into filamentous fungal diseases, bacterial diseases, and viral diseases. Examples of fungal diseases include, for example, diseases of the genus Botrytis, diseases of the genus Helmintosporium, diseases of the genus Fusarium, diseases of the genus Septoria, diseases of the genus Sarcospora, Diseases of the genus (Pseudocercosporella), diseases of the genus Rhynchosporium, diseases of the genus Pyricularia, diseases of the genus Alternaria; diseases of the genus Hemilelia, Diseases of the genus Ustilago, diseases of the genus Typhula, Pucchinia Diseases of the genus Puccinia, basidiomycetous diseases such as the disease of the genus Phakopsora; for example, diseases of the genus Venturia; Diseases of the genus (Erysiphe), diseases of the genus Microdocium, diseases of the genus Sclerotinia, diseases of the genus Gaeumanomyces, diseases of the genus Monilinia, diseases of the genus Unsinula For example, Ascochita disease, Phoma disease, Pysiu ) Genus disease, Korutishiumu (Corticium) genus disease, Pyrenophora (Pyrenophora) spp diseases include diseases caused by other fungi such as Mikosufaera genus (Mycosphaerella). Examples of the bacterial diseases include diseases caused by bacteria such as Pseudomonas genus diseases, Xanthomonas genus diseases, and Erwinia genus diseases. Examples of virus diseases include diseases caused by viruses such as tobacco mosaic virus.
植物病害は大きく分ければ、糸状菌類病害、細菌類病害、ウイルス病病害を含むものである。糸状菌類病害としては、例えば、ボトリチス(Botrytis)属病害、ヘルミントスポリウム(Helminthosporium)属病害、フザリウム(Fusarium)属病害、セプトリア(Septoria)属病害、サルコスポラ(Cercospora)属病害、シュードサルコスポレラ(Pseudocercosporella)属病害、リンコスポリウム(Rhynchosporium)属病害、ピリキュラリア(Pyricularia)属病害、アルタナリア(Alternaria)属病害等の不完全菌類病害;例えばヘミレリア(Hemilelia)属病害、リゾクトニア(Rhizoctonia)属病害、ウスティラゴ(Ustilago)属病害、ティフラ(Typhula)属病害、プッキニア(Puccinia)属病害、ファコプソラ(Phakopsora)属病害等の担子菌類病害;例えば、ベンチュリア(Venturia)属病害、ポドスフェラ(Podosphaera)属病害、レプトスファエリア(Leptosphaeria)属病害、ブルメリア(Blumeria)属病害、エリシフェ(Erysiphe)属病害、ミクロドキュウム(Microdochium)属病害、スクレロチニア(Sclerotinia)属病害、ゲウマノマイセス(Gaeumannomyces)属病害、モニリニア(Monilinia)属病害、ウンシヌラ(Unsinula)属病害等の子のう菌類病害;例えば、アスコクイタ(Ascochyta)属病害、フォマ(Phoma)属病害、ピシウム(Pythium)属病害、コルティシウム(Corticium)属病害、ピレノフォラ(Pyrenophora)属病害、ミコスファエラ属(Mycosphaerella)等のその他の菌類による病害が挙げられる。細菌類病害としては、例えば、シュードモナス(Pseudomonas)属病害、ザントモナス(Xanthomonas)属病害、エルヴィニア(Erwinia)属病害等の細菌類による病害が挙げられる。ウイルス病病害としては、例えば、タバコモザイクウイルス等のウイルス類よる病害等が挙げられる。 The plant diseases to which the disease control method for agricultural and horticultural plants of the present invention is applied are not limited to these, but the following plant diseases can be exemplified.
Plant diseases are broadly classified into filamentous fungal diseases, bacterial diseases, and viral diseases. Examples of fungal diseases include, for example, diseases of the genus Botrytis, diseases of the genus Helmintosporium, diseases of the genus Fusarium, diseases of the genus Septoria, diseases of the genus Sarcospora, Diseases of the genus (Pseudocercosporella), diseases of the genus Rhynchosporium, diseases of the genus Pyricularia, diseases of the genus Alternaria; diseases of the genus Hemilelia, Diseases of the genus Ustilago, diseases of the genus Typhula, Pucchinia Diseases of the genus Puccinia, basidiomycetous diseases such as the disease of the genus Phakopsora; for example, diseases of the genus Venturia; Diseases of the genus (Erysiphe), diseases of the genus Microdocium, diseases of the genus Sclerotinia, diseases of the genus Gaeumanomyces, diseases of the genus Monilinia, diseases of the genus Unsinula For example, Ascochita disease, Phoma disease, Pysiu ) Genus disease, Korutishiumu (Corticium) genus disease, Pyrenophora (Pyrenophora) spp diseases include diseases caused by other fungi such as Mikosufaera genus (Mycosphaerella). Examples of the bacterial diseases include diseases caused by bacteria such as Pseudomonas genus diseases, Xanthomonas genus diseases, and Erwinia genus diseases. Examples of virus diseases include diseases caused by viruses such as tobacco mosaic virus.
個々の植物病害としては、例えば、イネいもち病(Pyricularia oryzae)、イネ紋枯病(Rhizoctonia solani)、イネごま葉枯病(Cochiobolus miyabeanus)、イネ苗立枯病(Rhizopus chinensis、Pythium graminicola、Fusarium graminicola、Fusarium roseum、Mucor sp.、Phoma sp.、Tricoderma sp.)、イネ馬鹿苗病(Gibberella fujikuroi)、オオムギ及びコムギ等のうどんこ病(Blumeria graminis)、キュウリ等のうどんこ病(Sphaerotheca fuliginea)、ナス等のうどんこ病(Erysiphe cichoracoarum)、他の植物のうどんこ病、オオムギ及びコムギ等の眼紋病(Pseudocercosporella herpotrichoides)、コムギ等の黒穂病(Urocystis tritici)、オオムギ及びコムギ等の雪腐病(Microdochium nivalis、Pythium iwayamai、Typhla ishikariensis、Typhla incarnata、Sclerotinia borealis)、オオムギ及びコムギ等の赤かび病(Fusarium graminearum、Fusarium avenaceum、Fusarium culmorum、Microdochium nivalis)、オオムギ及びコムギ等のさび病(Puccinia recondita、Puccinia striiformis、Puccinia graminis)、ダイズさび病(Phakopsora pachyrhizi)、他の植物のさび病、オオムギ及びコムギ等の立枯病(Gaeumannomyces graminis)、エンバクの冠さび病(Puccinia coronata)、他の植物の冠さび病、キュウリまたはイチゴ等の灰色かび病(Botrytis cinerea)、トマト及びキャベツ等の菌核病(Sclerotinia sclerotiorum)、ジャガイモ及びトマト等の疫病(Phytophthora infestans)、他の植物の疫病、キュウリべと病(Pseudoperonospora cubensis)、ブドウべと病(Plasmopara viticola)、種々の植物のべと病、トウモロコシごま葉枯病(Cochliobolus heterostrophus)、トウモロコシ Grey Leaf Spot病(Cercospora zeae-maydis)その他の植物の各種葉枯病等が挙げられる。
As individual plant diseases, for example, rice blast (Pyricularia oryzae), rice sheath blight (Rhizoctonia solani), rice sesame leaf blight (Cochiobulus miyabeanusus), rice seedling wilt (Rhizominuspisumisus) , Fusarium roseum, Mucor sp., Poma sp., Tricoderma sp.), Rice idiot seedlings (Gibberella fujikuroi), barley and wheat etc. powdery diseases (Blumeria gramin i), cucumbers, etc. Powdery mildew such as eggplant (E Ysiphe cichoracoarum), other plant powdery mildew, barley and wheat and other eye spot diseases (Pseudocercosporella herpotrichoides), wheat and other scab (Urocystis tritici), barley and wheat worms, and so on. Fusarium graminearum, Fusarium avenaceum, Fusarium cummorumum, Fusarium cummorumumum, Fusarium cumumumumumumumumum, Fusarium umbarumumumumumum, Fusarium umbarumumumumumumumum, Fusarium umbarumumumumumumum, Fusarium umbarumumumumumumumum, Fusariumumumumumumumumumu Rust (Puccinia recondita, Puccinia striformis, Puccinia graminis), soybean rust (Phakopsora pachyrhizi), other plant rust, barley and wheat, etc. , Crown rust of other plants, gray mold disease such as cucumber or strawberry (Botrytis cinerea), mycorrhizal diseases such as tomato and cabbage (Sclerotinia sclerotiorum), plagues such as potato and tomato (Phytophthora infestans), other plants Plague, cucumber downy mildew (Pseudoperonospora cu ensis), grape downy mildew (Plasmopara viticola), various plant downy mildews, corn sesame leaf blight (Cochliobolus heterotrophus), corn Grey Leaf Spot disease (Cercospora zeeae-maydis) and other plant diseases Is mentioned.
その他、リンゴ黒星病(Venturia inaequalis);リンゴ斑点落葉病(Alternaria mali)、ナシ黒斑病(Alternaria kikuchiana);カンキツ黒点病(Diaporthe citri);カンキツそうか病(Elsinoe fawcetti);テンサイ褐斑病(Cercospora beticola)、ラッカセイ褐斑病(Cercospora arachidicola)、odorum);オオムギ網斑病(Pyrenophora teres)、オオムギ斑葉病(Pyrenophora graminea);オオムギ雲形病(Rhynchosporium secalis);コムギ裸黒穂病(Ustilago nuda)、コムギなまぐさ黒穂病(Tilletia caries);シバの葉腐病(Rhizoctonia solani);シバのダラースポット病(Sclerotinia homoeocarpa);例えばキュウリ斑点細菌病(Pseudomonas syringae pv. lachrymans)、トマト青枯病(Pseudomonas solanacearum)、イネ籾枯細菌病(Pseudomonas glumae)等のPsuedomonas属による病害;例えばキャベツ黒腐病(Xanthomonas campestris)、イネ白葉枯病(Xanthomonas oryzae)、カンキツかいよう病(Xanthomonas citri)等のXanthomonas属による病害;例えばキャベツ軟腐病(Erwinia carotovora)等のErwinia属による細菌病、例えばタバコモザイク病(Tobacco mosaic virus)等のウイルス病等に対して顕著な防除効果を奏し、特にオオムギ及びコムギ等に発生するうどんこ病(Blumeria graminis)、眼紋病(Pseudocercosporella herpotrichoides)、雪腐病(Microdochium nivalis、Pythium iwayamai、Typhla ishikariensis、Typhla incarnata、Sclerotinia borealis)、赤かび病(Fusarium graminearum、Fusarium avenaceum、Fusarium culmorum、Microdochium nivalis)、さび病(Puccinia recondita、Puccinia striiformis、Puccinia graminis)、立枯病(Gaeumannomyces graminis)、コムギ等の黒穂病(Urocystis tritici)、コムギの葉枯病(Mycosphaerella graminicola)、コムギのふ枯病(Septoria nodorum)、コムギのTan Spot病(Drechslere tritici-repentis)等に有効である。
In addition, apple black spot (Venturia inaequalis); apple spotted leaf (Alternaria mary), pear black spot (Alternaria kikuchiana); citrus black spot (Diaporthe citri); Cercospora beticola, peanut brown spot (Cercospora arachidicola), odorum; barley net spot (Pyrenophora teres); Wheat lintel scab Tilletia caries); Shiba leaf rot (Rhizoctonia solani); Shiva dollar spot disease (Sclerotinia homoeocarpa); Diseases caused by the genus Psuedomonas such as Pseudomonas glumae; for example, cabbage black rot (Xanthomonas campestris), rice leaf blight (Xanthomonas oryzae), soft rot of the genus Xanthomonas It has a remarkable control effect against bacterial diseases caused by Erwinia genus such as rwinia carotovora, for example viral diseases such as tobacco mosaic disease (Tobacco mosaic virus), especially powdery mildew (Blumeria graminis) occurring in barley and wheat, etc. , Eyespot disease (Pseudocercosporella herpotrichoides), snow rot (Microdochium nivalis, Phythium iwayumumumiumumium, Typula isicarinum, Tyflaisumuminbain, Syphaimusum, Syphaimusum, Syphaimusum, Syphaimusum, Syphaimusum, Syphaimusum, Syphaimusum, Syphaimusum, Syphaimusum, Syphaimusum, Syphaimusum, Syphaimusum, Syphaimusum, Syphaimusum, Syphaimusum. Moromi, Microdocium nivalis), Rust (Puccinia recondita, Puccinia strifomis, Puccinia graminis), Bacterial leaf wilt (Gaeumnomyces graminis), Wheat cris It is effective against blight (Septoria nodorum), Tan's Spot disease of wheat (Drechsure tritici-repentis), and the like.
本発明の農園芸用植物の病害防除方法を適用できる農園芸用植物は特に限定されるものではないが、例えば以下に示した農園芸用植物が挙げられる。
穀類(例えば、稲、大麦、小麦、ライ麦、オート麦、トウモロコシ、高粱等)、豆類(例えば、大豆、小豆、そら豆、えんどう豆、落花生等)、果樹又は果実類(例えば、リンゴ、柑橘類、梨、ブドウ、桃、梅、桜桃、クルミ、アーモンド、バナナ、イチゴ等)、野菜類(例えば、キャベツ、トマト、ナス、ほうれん草、ブロッコリー、レタス、タマネギ、ネギ、ピーマン等)、根菜類(例えば、ニンジン、馬鈴薯、サツマイモ、大根、蓮根、かぶ等)、加工用作物類(例えば、綿、麻、コウゾ、ミツマタ、菜種、ビート、ホップ、サトウキビ、テンサイ、オリーブ、ゴム、コーヒー、タバコ、茶等)、瓜類(例えば、カボチャ、キュウリ、スイカ、メロン等)、牧草類(例えば、オーチャードグラス、ソルガム、チモシー、クローバー、アルファルファ等)、芝類(例えば、高麗芝、ベントグラス等)、香料等用作物類(例えば、ラベンダー、ローズマリー、タイム、パセリ、胡椒、しょうが等)、花卉類(例えば、キク、バラ、蘭等)等の植物に使用できるが、好ましくは穀類、より好ましくは大麦、小麦に適応される。 The agricultural and horticultural plants to which the disease control method for agricultural and horticultural plants of the present invention can be applied are not particularly limited, and examples thereof include the following agricultural and horticultural plants.
Cereals (eg, rice, barley, wheat, rye, oats, corn, coconut, etc.), beans (eg, soybeans, red beans, broad beans, peas, peanuts, etc.), fruit trees or fruits (eg, apples, citrus fruits, Pears, grapes, peaches, plums, cherry peaches, walnuts, almonds, bananas, strawberries, etc.), vegetables (e.g. cabbage, tomatoes, eggplant, spinach, broccoli, lettuce, onion, leek, peppers, etc.), root vegetables (e.g., Carrots, potatoes, sweet potatoes, radishes, lotus roots, turnips, etc.), crops for processing (eg cotton, hemp, mulberry, honey beet, rapeseed, beet, hops, sugar cane, sugar beet, olives, gum, coffee, tobacco, tea, etc.) Moss (eg, pumpkin, cucumber, watermelon, melon, etc.), pasture (eg, orchard grass, sorghum, timothy, clover, apricot Farfa, etc.), turf (eg, Korean turf, bentgrass, etc.), fragrance crops (eg, lavender, rosemary, thyme, parsley, pepper, ginger, etc.), flower (eg chrysanthemum, rose, orchid, etc.) ), But is preferably applied to cereals, more preferably barley and wheat.
穀類(例えば、稲、大麦、小麦、ライ麦、オート麦、トウモロコシ、高粱等)、豆類(例えば、大豆、小豆、そら豆、えんどう豆、落花生等)、果樹又は果実類(例えば、リンゴ、柑橘類、梨、ブドウ、桃、梅、桜桃、クルミ、アーモンド、バナナ、イチゴ等)、野菜類(例えば、キャベツ、トマト、ナス、ほうれん草、ブロッコリー、レタス、タマネギ、ネギ、ピーマン等)、根菜類(例えば、ニンジン、馬鈴薯、サツマイモ、大根、蓮根、かぶ等)、加工用作物類(例えば、綿、麻、コウゾ、ミツマタ、菜種、ビート、ホップ、サトウキビ、テンサイ、オリーブ、ゴム、コーヒー、タバコ、茶等)、瓜類(例えば、カボチャ、キュウリ、スイカ、メロン等)、牧草類(例えば、オーチャードグラス、ソルガム、チモシー、クローバー、アルファルファ等)、芝類(例えば、高麗芝、ベントグラス等)、香料等用作物類(例えば、ラベンダー、ローズマリー、タイム、パセリ、胡椒、しょうが等)、花卉類(例えば、キク、バラ、蘭等)等の植物に使用できるが、好ましくは穀類、より好ましくは大麦、小麦に適応される。 The agricultural and horticultural plants to which the disease control method for agricultural and horticultural plants of the present invention can be applied are not particularly limited, and examples thereof include the following agricultural and horticultural plants.
Cereals (eg, rice, barley, wheat, rye, oats, corn, coconut, etc.), beans (eg, soybeans, red beans, broad beans, peas, peanuts, etc.), fruit trees or fruits (eg, apples, citrus fruits, Pears, grapes, peaches, plums, cherry peaches, walnuts, almonds, bananas, strawberries, etc.), vegetables (e.g. cabbage, tomatoes, eggplant, spinach, broccoli, lettuce, onion, leek, peppers, etc.), root vegetables (e.g., Carrots, potatoes, sweet potatoes, radishes, lotus roots, turnips, etc.), crops for processing (eg cotton, hemp, mulberry, honey beet, rapeseed, beet, hops, sugar cane, sugar beet, olives, gum, coffee, tobacco, tea, etc.) Moss (eg, pumpkin, cucumber, watermelon, melon, etc.), pasture (eg, orchard grass, sorghum, timothy, clover, apricot Farfa, etc.), turf (eg, Korean turf, bentgrass, etc.), fragrance crops (eg, lavender, rosemary, thyme, parsley, pepper, ginger, etc.), flower (eg chrysanthemum, rose, orchid, etc.) ), But is preferably applied to cereals, more preferably barley and wheat.
本発明の農園芸用植物の病害防除方法で用いられる病害抵抗性誘導剤は、そのまま、又は水等で適宜希釈し、若しくは懸濁させた形で植物病害防除に有効な量を当該病害の発生が予測される対象植物の種子、播種するための栽培担体又は土壌等に処理すれば良く、例えば、稲育苗箱施用、種子粉衣等の施用方法、種子消毒法、植穴処理、株元処理、作条処理、土壌混和等の施用方法を好適に用いることができる。また、果樹、穀類、野菜等の畑作において発生する病害に対しては粉衣や浸漬等の種子処理、苗根の浸漬処理、播種時等の作条、育苗用の栽培容器や植え穴、株元等の育苗担体等への潅注、表面散布、混和処理等の後潅水して植物に吸収させる方法を好適に用いることができる。また、水耕栽培における水耕液を処理しても良い。好ましくは対象植物の種子に適用され、種子粉衣や種子消毒法の施用方法で処理される。いわゆる種子処理剤としての処理方法が特に適している。
The disease resistance inducer used in the method for controlling diseases of agricultural and horticultural plants according to the present invention is an occurrence of the disease in an amount effective for controlling plant diseases as it is, or appropriately diluted with water or suspended. The seeds of the target plant, for which seeding is expected, the cultivation carrier or the soil for sowing may be treated, for example, rice nursery box application, seed dressing application method, seed disinfection method, planting hole treatment, plant source treatment, etc. Application methods such as crop treatment and soil mixing can be suitably used. In addition, for diseases that occur in field crops such as fruit trees, cereals, and vegetables, seed treatment such as dressing and soaking, soaking treatment of seedling roots, cropping during sowing, cultivation containers and planting holes for seedlings, stocks A method of irrigating after the irrigation to the original seedling carrier, etc., surface spraying, mixing treatment, etc., and allowing it to be absorbed by the plant can be suitably used. Moreover, you may process the hydroponic liquid in hydroponics. Preferably, it is applied to the seeds of the target plant, and is treated by an application method such as seed dressing or seed disinfection. A treatment method as a so-called seed treatment agent is particularly suitable.
種子処理剤としての処理方法としては、例えば、液状又は固体状の病害抵抗性誘導剤を希釈又は希釈せずして液体状態にて種子を浸漬して薬剤を浸透させる方法、種子と混和、粉衣処理等して種子の表面に付着させる方法、樹脂、ポリマー等の付着性の高い担体と混和して種子に単層又は多層にコーティングする方法、植え付けと同時に種子の近辺に散布する方法等が挙げられる。
本明細書において「種子」には、種子植物が形成する種皮に覆われた種子だけではなく、球根、塊茎、種いも、鱗茎、あるいは挿し木栽培用の茎等の栄養繁殖用の植物体が含まれる。
本発明の農園芸用植物の病害防除方法を実施する場合の「土壌」又は「栽培担体」とは、植物を栽培するための支持体を示すものであり、材質は特に制限されないが、植物が生育しうる材質であれば良く、例えば、いわゆる各種土壌、育苗マット、水等を含むものであり、砂、バーミキュライト、綿、紙、珪藻土、寒天、ゲル状物質、高分子物質、ロックウール、グラスウール、木材チップ、バーク、軽石等を含むこともできる。 As a treatment method as a seed treatment agent, for example, a method of immersing seeds in a liquid state by diluting or undiluting a liquid or solid disease resistance inducer, mixing with the seed, powder There are a method of attaching to the surface of the seed by clothing treatment, a method of mixing with a highly adhesive carrier such as resin or polymer, a method of coating the seed in a single layer or a multilayer, a method of spraying around the seed simultaneously with planting, etc. Can be mentioned.
In this specification, “seed” includes not only seeds covered with seed coats formed by seed plants but also plants for vegetative propagation such as bulbs, tubers, seeds, bulbs, or stems for cutting cultivation. It is.
The “soil” or “cultivation carrier” in the case of carrying out the method for controlling diseases of agricultural and horticultural plants of the present invention refers to a support for cultivating plants, and the material is not particularly limited. It can be any material that can grow, and includes, for example, so-called various types of soil, seedling mats, water, etc., sand, vermiculite, cotton, paper, diatomaceous earth, agar, gel material, polymer material, rock wool, glass wool , Wood chips, bark, pumice and the like.
本明細書において「種子」には、種子植物が形成する種皮に覆われた種子だけではなく、球根、塊茎、種いも、鱗茎、あるいは挿し木栽培用の茎等の栄養繁殖用の植物体が含まれる。
本発明の農園芸用植物の病害防除方法を実施する場合の「土壌」又は「栽培担体」とは、植物を栽培するための支持体を示すものであり、材質は特に制限されないが、植物が生育しうる材質であれば良く、例えば、いわゆる各種土壌、育苗マット、水等を含むものであり、砂、バーミキュライト、綿、紙、珪藻土、寒天、ゲル状物質、高分子物質、ロックウール、グラスウール、木材チップ、バーク、軽石等を含むこともできる。 As a treatment method as a seed treatment agent, for example, a method of immersing seeds in a liquid state by diluting or undiluting a liquid or solid disease resistance inducer, mixing with the seed, powder There are a method of attaching to the surface of the seed by clothing treatment, a method of mixing with a highly adhesive carrier such as resin or polymer, a method of coating the seed in a single layer or a multilayer, a method of spraying around the seed simultaneously with planting, etc. Can be mentioned.
In this specification, “seed” includes not only seeds covered with seed coats formed by seed plants but also plants for vegetative propagation such as bulbs, tubers, seeds, bulbs, or stems for cutting cultivation. It is.
The “soil” or “cultivation carrier” in the case of carrying out the method for controlling diseases of agricultural and horticultural plants of the present invention refers to a support for cultivating plants, and the material is not particularly limited. It can be any material that can grow, and includes, for example, so-called various types of soil, seedling mats, water, etc., sand, vermiculite, cotton, paper, diatomaceous earth, agar, gel material, polymer material, rock wool, glass wool , Wood chips, bark, pumice and the like.
土壌への施用方法としては、例えば、液体又は固体製剤を水に希釈又は希釈せずして植物体の設置場所近辺又は育苗のための苗床等に施用する方法、粒剤を植物体の設置場所近辺又は苗床に散布する方法、播種前又は移植前に粉剤、水和剤、顆粒水和剤、粒剤等を散布し土壌全体と混和する方法、播種前又は植物体を植える前に植え穴、作条等に粉剤、水和剤、顆粒水和剤、粒剤等を散布する方法などが挙げられる。
水稲の育苗箱への施用方法としては、剤型は、播種時施用、緑化期施用、移植時施用など施用時期により異なる場合もあるが、例えば、粉剤、顆粒水和剤、粒剤等の剤型で施用すれば良い。培土との混和によっても施用することができ、培土と粉剤、顆粒水和剤又は粒剤等との混和、例えば、床土混和、覆土混和、培土全体への混和等することができる。単に、培土と各種製剤を交互に層状にして施用しても良い。播種時の施用の時期は播種の前、同時、播種後いずれでも良く、覆土後に施用しても良い。 Examples of application methods to the soil include, for example, a method in which a liquid or solid preparation is diluted or not diluted with water and applied to the vicinity of a plant installation place or a nursery bed for raising seedlings, etc. The method of spraying in the vicinity or nursery, the method of spraying powder, wettable powder, wettable granule powder, granule etc. before sowing or transplanting and mixing with the whole soil, the planting hole before sowing or before planting the plant, Examples include a method of spraying powder, wettable powder, wettable powder, granule, etc. on the strip.
As a method for applying paddy rice to a seedling box, the dosage form may differ depending on the application time, such as application at seeding, application at greening period, application at transplantation, etc., for example, agents such as powder, granule wettable powder, granule Apply with a mold. It can also be applied by mixing with soil, and it can be mixed with soil and powder, granulated wettable powder or granules, for example, mixed with ground soil, mixed with soil covering, mixed with the entire soil. Simply, the soil and various preparations may be applied alternately in layers. The time of application at the time of sowing may be before sowing, at the same time, after sowing, or after covering.
水稲の育苗箱への施用方法としては、剤型は、播種時施用、緑化期施用、移植時施用など施用時期により異なる場合もあるが、例えば、粉剤、顆粒水和剤、粒剤等の剤型で施用すれば良い。培土との混和によっても施用することができ、培土と粉剤、顆粒水和剤又は粒剤等との混和、例えば、床土混和、覆土混和、培土全体への混和等することができる。単に、培土と各種製剤を交互に層状にして施用しても良い。播種時の施用の時期は播種の前、同時、播種後いずれでも良く、覆土後に施用しても良い。 Examples of application methods to the soil include, for example, a method in which a liquid or solid preparation is diluted or not diluted with water and applied to the vicinity of a plant installation place or a nursery bed for raising seedlings, etc. The method of spraying in the vicinity or nursery, the method of spraying powder, wettable powder, wettable granule powder, granule etc. before sowing or transplanting and mixing with the whole soil, the planting hole before sowing or before planting the plant, Examples include a method of spraying powder, wettable powder, wettable powder, granule, etc. on the strip.
As a method for applying paddy rice to a seedling box, the dosage form may differ depending on the application time, such as application at seeding, application at greening period, application at transplantation, etc., for example, agents such as powder, granule wettable powder, granule Apply with a mold. It can also be applied by mixing with soil, and it can be mixed with soil and powder, granulated wettable powder or granules, for example, mixed with ground soil, mixed with soil covering, mixed with the entire soil. Simply, the soil and various preparations may be applied alternately in layers. The time of application at the time of sowing may be before sowing, at the same time, after sowing, or after covering.
畑作物、例えば麦等においては、播種から育苗期において、種子又は植物体に近接する栽培担体等への処理が好ましい。畑へ直接播種する植物においては、種子への直接の処理の他、栽培中の植物に近接する栽培担体等への処理が好適である。粒剤を用いて散布処理又は水に希釈又は希釈しない薬剤を液状にて潅注処理を行うこと等ができる。
移植を行う栽培植物の播種、育苗期の処理としては、種子への直接の処理の他、育苗用の苗床への液状とした薬剤の潅注処理又は粒剤の散布処理が好ましい。又、定植時に粒剤を植え穴に処理したり、移植場所近辺の栽培担体に混和することも好ましい態様である。
本発明の農園芸用植物の病害防除方法で用いられる病害抵抗性誘導剤の有効成分は、農薬製剤上の常法に従い、使用上都合の良い形状に製剤して使用するのが一般的である。即ち、病害抵抗性誘導剤の有効成分であり、一般式(I)で表される1,2,3-チアジアゾール誘導体若しくはその塩類は、これを適当な不活性担体に、又は必要に応じて補助剤と一緒に適当な割合に配合して溶解、分離、懸濁、混合、含浸、吸着若しくは付着させ、適宜の剤形、例えば懸濁剤、乳剤、液剤、水和剤、粒剤、粉剤、錠剤、種子コーティング等にあっては、噴霧、塗布、浸漬等の処理に適した懸濁液や液剤等に製剤して使用すれば良い。 In field crops such as wheat, treatment from a seed or a cultivating carrier in the vicinity of the plant body is preferable from the sowing to the seedling raising period. In plants that are sown directly in a field, in addition to direct treatment on seeds, treatment on a cultivation carrier in the vicinity of the plant being cultivated is suitable. It is possible to perform spraying treatment using a granule or irrigation treatment in a liquid of a drug diluted or not diluted in water.
As the seeding of the cultivated plant to be transplanted and the treatment at the seedling raising stage, in addition to the direct treatment to the seed, the irrigation treatment of the liquid drug or the granule spraying treatment to the nursery seedling bed is preferable. Moreover, it is also a preferable aspect that a granule is processed into a planting hole at the time of planting or is mixed with a cultivation carrier in the vicinity of the transplantation site.
The active ingredient of the disease resistance inducer used in the method for controlling diseases of agricultural and horticultural plants of the present invention is generally used in a form convenient for use according to conventional methods on agricultural chemical formulations. . That is, it is an active ingredient of a disease resistance inducer, and the 1,2,3-thiadiazole derivative represented by the general formula (I) or a salt thereof is supported by a suitable inert carrier or as needed. It is mixed with an agent in an appropriate ratio and dissolved, separated, suspended, mixed, impregnated, adsorbed or adhered, and an appropriate dosage form such as a suspension, emulsion, liquid, wettable powder, granule, powder, In the case of tablets, seed coatings, etc., they may be used by being formulated into suspensions or liquids suitable for treatment such as spraying, coating, and immersion.
移植を行う栽培植物の播種、育苗期の処理としては、種子への直接の処理の他、育苗用の苗床への液状とした薬剤の潅注処理又は粒剤の散布処理が好ましい。又、定植時に粒剤を植え穴に処理したり、移植場所近辺の栽培担体に混和することも好ましい態様である。
本発明の農園芸用植物の病害防除方法で用いられる病害抵抗性誘導剤の有効成分は、農薬製剤上の常法に従い、使用上都合の良い形状に製剤して使用するのが一般的である。即ち、病害抵抗性誘導剤の有効成分であり、一般式(I)で表される1,2,3-チアジアゾール誘導体若しくはその塩類は、これを適当な不活性担体に、又は必要に応じて補助剤と一緒に適当な割合に配合して溶解、分離、懸濁、混合、含浸、吸着若しくは付着させ、適宜の剤形、例えば懸濁剤、乳剤、液剤、水和剤、粒剤、粉剤、錠剤、種子コーティング等にあっては、噴霧、塗布、浸漬等の処理に適した懸濁液や液剤等に製剤して使用すれば良い。 In field crops such as wheat, treatment from a seed or a cultivating carrier in the vicinity of the plant body is preferable from the sowing to the seedling raising period. In plants that are sown directly in a field, in addition to direct treatment on seeds, treatment on a cultivation carrier in the vicinity of the plant being cultivated is suitable. It is possible to perform spraying treatment using a granule or irrigation treatment in a liquid of a drug diluted or not diluted in water.
As the seeding of the cultivated plant to be transplanted and the treatment at the seedling raising stage, in addition to the direct treatment to the seed, the irrigation treatment of the liquid drug or the granule spraying treatment to the nursery seedling bed is preferable. Moreover, it is also a preferable aspect that a granule is processed into a planting hole at the time of planting or is mixed with a cultivation carrier in the vicinity of the transplantation site.
The active ingredient of the disease resistance inducer used in the method for controlling diseases of agricultural and horticultural plants of the present invention is generally used in a form convenient for use according to conventional methods on agricultural chemical formulations. . That is, it is an active ingredient of a disease resistance inducer, and the 1,2,3-thiadiazole derivative represented by the general formula (I) or a salt thereof is supported by a suitable inert carrier or as needed. It is mixed with an agent in an appropriate ratio and dissolved, separated, suspended, mixed, impregnated, adsorbed or adhered, and an appropriate dosage form such as a suspension, emulsion, liquid, wettable powder, granule, powder, In the case of tablets, seed coatings, etc., they may be used by being formulated into suspensions or liquids suitable for treatment such as spraying, coating, and immersion.
本発明の農園芸用植物の病害防除方法で用いられる病害抵抗性誘導剤に使用できる不活性担体としては固体又は液体の何れであっても良く、固体の担体になりうる材料としては、例えばダイズ粉、穀物粉、木粉、樹皮粉、鋸粉、タバコ茎粉、クルミ殻粉、ふすま、繊維素粉末、植物エキス抽出後の残渣、粉砕合成樹脂等の合成重合体、粘土類(例えばカオリン、ベントナイト、酸性白土等)、タルク類(例えばタルク、ピロフィライト等)、シリカ類{例えば珪藻土、珪砂、雲母、ホワイトカーボン(含水微粉珪素、含水珪酸ともいわれる合成高分散珪酸で、製品により珪酸カルシウムを主成分として含むものもある。)}、活性炭、イオウ粉末、軽石、焼成珪藻土、レンガ粉砕物、フライアッシュ、砂、炭酸カルシウム、燐酸カルシウム等の無機鉱物性粉末、硫安、燐安、硝安、尿素、塩安等の化学肥料、堆肥等を挙げることができ、これらは単独で若しくは二種以上の混合物の形で使用される。
The inert carrier that can be used in the disease resistance inducer used in the method for controlling diseases of agricultural and horticultural plants of the present invention may be either solid or liquid. Examples of materials that can be used as a solid carrier include soybeans. Powder, cereal powder, wood powder, bark powder, saw powder, tobacco stem powder, walnut shell powder, bran, fiber powder, residues after extraction of plant extracts, synthetic polymers such as ground synthetic resin, clays (eg kaolin, Bentonite, acid clay, etc.), talc (eg, talc, pyrophyllite, etc.), silica (eg, diatomaceous earth, silica sand, mica, white carbon (hydrous finely divided silicon, hydrous silicic acid). Some are included as ingredients.)}, Activated carbon, sulfur powder, pumice, calcined diatomaceous earth, ground brick, fly ash, sand, calcium carbonate, calcium phosphate Inorganic mineral powders, ammonium sulfate, ammonium phosphate, ammonium nitrate, urea, fertilizer salts depreciation etc., can be exemplified compost or the like, which are used alone or in the form of a mixture of two or more.
液体の担体になりうる材料としては、それ自体溶媒能を有するものの他、溶媒能を有さずとも補助剤の助けにより有効成分化合物を分散させうることとなるものから選択され、例えば代表例として次に挙げる担体を例示できるが、これらは単独で若しくは2種以上の混合物の形で使用され、例えば水、アルコール類(例えばメタノール、エタノール、イソプロパノール、ブタノール、エチレングリコール等)、ケトン類(例えばアセトン、メチルエチルケトン、メチルイソブチルケトン、ジイソブチルケトン、シクロヘキサノン等)、エーテル類(例えばエチルエーテル、ジオキサン、セロソルブ、ジプロピルエ-テル、テトラヒドロフラン等)、脂肪族炭化水素類(例えばケロシン、鉱油等)、芳香族炭化水素類(例えばベンゼン、トルエン、キシレン、ソルベントナフサ、アルキルナフタレン等)、ハロゲン化炭化水素類(例えばジクロロエタン、クロロホルム、四塩化炭素、塩素化ベンゼン等)、エステル類(例えば酢酸エチル、ジイソプピルフタレ-ト、ジブチルフタレート、ジオクチルフタレート等)、アミド類(例えばジメチルホルムアミド、ジエチルホルムアミド、ジメチルアセトアミド等)、ニトリル類(例えばアセトニトリル等)、ジメチルスルホキシド類等を挙げることができる。
The material that can be used as a liquid carrier is selected from those having solvent ability itself and those capable of dispersing the active ingredient compound with the aid of an auxiliary agent without having solvent ability. The following carriers can be exemplified, but these are used alone or in the form of a mixture of two or more thereof, for example, water, alcohols (for example, methanol, ethanol, isopropanol, butanol, ethylene glycol, etc.), ketones (for example, acetone) , Methyl ethyl ketone, methyl isobutyl ketone, diisobutyl ketone, cyclohexanone, etc.), ethers (eg, ethyl ether, dioxane, cellosolve, dipropyl ether, tetrahydrofuran, etc.), aliphatic hydrocarbons (eg, kerosene, mineral oil, etc.), aromatic hydrocarbons (E.g. benzene, torr , Xylene, solvent naphtha, alkylnaphthalene, etc.), halogenated hydrocarbons (eg, dichloroethane, chloroform, carbon tetrachloride, chlorinated benzene, etc.), esters (eg, ethyl acetate, diisopropylpropyl phthalate, dibutyl phthalate) , Dioctyl phthalate, etc.), amides (eg, dimethylformamide, diethylformamide, dimethylacetamide, etc.), nitriles (eg, acetonitrile, etc.), dimethyl sulfoxides, and the like.
他の補助剤としては次に例示する代表的な補助剤をあげることができ、これらの補助剤は目的に応じて使用され、単独で、ある場合は二種以上の補助剤を併用し、又ある場合には全く補助剤を使用しないことも可能である。有効成分化合物の乳化、分散、可溶化及び/又は湿潤の目的のために界面活性剤が使用され、例えばポリオキシエチレンアルキルエーテル、ポリオキシエチレンアルキルアリールエーテル、ポリオキシエチレン高級脂肪酸エステル、ポリオキシエチレン樹脂酸エステル、ポリオキシエチレンソルビタンモノラウレート、ポリオキシエチレンソルビタンモノオレエート、アルキルアリ-ルスルホン酸塩、ナフタレンスルホン酸縮合物、リグニンスルホン酸塩、高級アルコール硫酸エステル等の界面活性剤を例示することができる。又、有効成分化合物の分散安定化、粘着及び/又は結合の目的のために、次に例示する補助剤を使用することもでき、例えばカゼイン、ゼラチン、澱粉、メチルセルロース、カルボキシメチルセルロース、アラビアゴム、ポリビニルアルコール、松根油、糠油、ベントナイト、リグニンスルホン酸塩等の補助剤を使用することもできる。
As other adjuvants, typical adjuvants exemplified below can be mentioned, and these adjuvants are used depending on the purpose, and singly, in some cases, two or more kinds of adjuvants are used together. In some cases it is possible to use no adjuvants at all. Surfactants are used for the purpose of emulsifying, dispersing, solubilizing and / or wetting of the active ingredient compound, such as polyoxyethylene alkyl ether, polyoxyethylene alkyl aryl ether, polyoxyethylene higher fatty acid ester, polyoxyethylene. Illustrative surfactants such as resin acid ester, polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan monooleate, alkyl aryl sulfonate, naphthalene sulfonic acid condensate, lignin sulfonate, higher alcohol sulfate be able to. In addition, for the purpose of stabilizing the dispersion of the active ingredient compound, adhesion and / or binding, the following auxiliary agents can be used, such as casein, gelatin, starch, methylcellulose, carboxymethylcellulose, gum arabic, polyvinyl Adjuvants such as alcohol, pine oil, coconut oil, bentonite, and lignin sulfonate can also be used.
本発明の農園芸用植物の病害防除方法で用いられる病害抵抗性誘導剤が固体製品の場合、固体製品の流動性改良のために次に挙げる補助剤を使用することもでき、例えばワックス、ステアリン酸塩、燐酸アルキルエステル等の補助剤を使用できる。懸濁性製品の解こう剤として、例えばナフタレンスルホン酸縮合物、縮合燐酸塩等の補助剤を使用することもできる。消泡剤としては、例えばシリコーン油等の補助剤を使用することもできる。
本発明の農園芸用植物の病害防除方法で用いられる病害抵抗性誘導剤には、更に防除対象病害虫、防除適期の拡大のため、或いは薬量の低減、相乗効果を図る目的で他の農園芸用殺虫剤、殺ダニ剤、殺線虫剤、殺菌剤、生物農薬等と混合して使用することも可能であり、又、使用場面に応じて除草剤、植物成長調節剤、肥料等と混合して使用することも可能である。 When the disease resistance inducer used in the method for controlling diseases of agricultural and horticultural plants of the present invention is a solid product, the following adjuvants may be used for improving the fluidity of the solid product, such as wax, stearin Adjuvants such as acid salts and alkyl phosphates can be used. As a peptizer for the suspension product, for example, auxiliary agents such as naphthalenesulfonic acid condensate and condensed phosphate can be used. As the antifoaming agent, for example, an auxiliary agent such as silicone oil can be used.
The disease resistance inducer used in the method for controlling diseases of agricultural and horticultural plants according to the present invention may further include pests to be controlled, other agricultural and horticultural purposes for the purpose of expanding the appropriate period of control, or reducing the dosage and synergistic effects. It can be mixed with insecticides, acaricides, nematicides, fungicides, biological pesticides, etc., and mixed with herbicides, plant growth regulators, fertilizers, etc. It is also possible to use it.
本発明の農園芸用植物の病害防除方法で用いられる病害抵抗性誘導剤には、更に防除対象病害虫、防除適期の拡大のため、或いは薬量の低減、相乗効果を図る目的で他の農園芸用殺虫剤、殺ダニ剤、殺線虫剤、殺菌剤、生物農薬等と混合して使用することも可能であり、又、使用場面に応じて除草剤、植物成長調節剤、肥料等と混合して使用することも可能である。 When the disease resistance inducer used in the method for controlling diseases of agricultural and horticultural plants of the present invention is a solid product, the following adjuvants may be used for improving the fluidity of the solid product, such as wax, stearin Adjuvants such as acid salts and alkyl phosphates can be used. As a peptizer for the suspension product, for example, auxiliary agents such as naphthalenesulfonic acid condensate and condensed phosphate can be used. As the antifoaming agent, for example, an auxiliary agent such as silicone oil can be used.
The disease resistance inducer used in the method for controlling diseases of agricultural and horticultural plants according to the present invention may further include pests to be controlled, other agricultural and horticultural purposes for the purpose of expanding the appropriate period of control, or reducing the dosage and synergistic effects. It can be mixed with insecticides, acaricides, nematicides, fungicides, biological pesticides, etc., and mixed with herbicides, plant growth regulators, fertilizers, etc. It is also possible to use it.
本発明の農園芸用植物の病害防除方法で用いられる病害抵抗性誘導剤には、必要に応じて他の成分を混合又は併用することができ、例えば種子処理に際して、鳥類をはじめとする動物類による摂取(誤飲を含む)を避けるために忌避剤や他の成分を含有せしめることもできる。忌避剤としては、例えばナフタレン化合物等の臭気性化合物、ひまし油、松脂、ポリブタン、ジフェニルアミンペンタクロロフェノール、キノン、酸化亜鉛、芳香族溶媒等の接触阻害剤、N-(トリクロロメチルチオ)-4-シクロヘキセン-1,2-カルボキシイミド、アントラキノン、蓚酸銅、テルペン油等の苦味物質類、パラジクロルベンゼン、アリールイソチオシアナート、酢酸アミル、アネトール、柑橘油、クレゾール類、ゼラニウム油又はラベンダー油等のハーブ油、メントール、サリチル酸メチル、ニコチン、ペンタンチオール、ピリジン類、塩化トリブチルスズ、チラム、ジラム、カーバメート系殺虫剤(例えばメチオカルブ等)、グアザチン、塩素化シクロジエン系殺虫剤(例えばエンドリン等)、有機リン系殺虫剤(例えばフェンチオン等)等を例示することができる。他の成分として、毒性物質又は増殖抑制物質(不妊化剤)としては、例えば3-クロロ-4-トルイジン塩酸塩、ストリキニーネ、20,25-ジアザコレステロール塩酸塩(コード名:SC-12937)等を例示することができる。
The disease resistance inducer used in the method for controlling diseases of agricultural and horticultural plants of the present invention can be mixed or used in combination with other components as necessary. For example, animals such as birds can be used for seed treatment. To avoid ingestion (including accidental ingestion), repellents and other ingredients can be included. Repellents include, for example, odorous compounds such as naphthalene compounds, contact inhibitors such as castor oil, pine resin, polybutane, diphenylamine pentachlorophenol, quinone, zinc oxide, aromatic solvents, N- (trichloromethylthio) -4-cyclohexene- Bitter substances such as 1,2-carboximide, anthraquinone, copper oxalate, terpene oil, paradichlorobenzene, aryl isothiocyanate, amyl acetate, anethole, citrus oil, cresols, geranium oil or lavender oil, Menthol, methyl salicylate, nicotine, pentanethiol, pyridines, tributyltin chloride, thiram, ziram, carbamate insecticides (such as methiocarb), guazatine, chlorinated cyclodiene insecticides (such as endrin), organophosphorus insecticides (such as endrin) Example If it is possible to illustrate the fenthion, etc.) and the like. As other components, toxic substances or growth inhibitory substances (fertility agents) include, for example, 3-chloro-4-toluidine hydrochloride, strychnine, 20,25-diazacholesterol hydrochloride (code name: SC-12937), etc. Can be illustrated.
本発明の農園芸用植物の病害防除方法で用いられる病害抵抗性誘導剤の有効成分の含有量としては、病害抵抗性誘導剤100質量部あたり、約0.01~約80質量部の範囲から適宜選択して使用すれば良く、例えば、農園芸分野で使用される各種製剤(乳剤、粉剤、水和剤、粒剤、顆粒水和剤、フロアブル剤等)とする場合は約0.01~約50質量部が適当であり、好ましくは、約1~約50質量部が良い。当該病害抵抗性誘導剤の施用量は、有効成分化合物の配合割合、気象条件、製剤形態、施用時期、施用方法、施用場所、防除対象病害、対象作物等により異なるが、通常の散布剤としては、有効成分化合物として1アール当たり約0.1g~約1000gの範囲から適宜選択して施用すれば良く、好ましくは約1~約100gの範囲が良い。種子処理剤としては、通常乾燥種子重量100kgあたり有効成分化合物として約0.1~約1000gの範囲から適宜選択して施用すれば良く、好ましくは約1~約300gの範囲が良い。
The content of the active ingredient of the disease resistance inducer used in the method for controlling diseases of agricultural and horticultural plants of the present invention ranges from about 0.01 to about 80 parts by mass per 100 parts by mass of the disease resistance inducer. For example, when various preparations used in the field of agriculture and horticulture (emulsion, powder, wettable powder, granule, wettable powder, flowable powder, etc.) are used, about 0.01 to About 50 parts by weight is suitable, preferably about 1 to about 50 parts by weight. The dosage of the disease resistance inducer varies depending on the compounding ratio of the active ingredient compound, weather conditions, formulation form, application timing, application method, application location, disease to be controlled, target crop, etc. The active ingredient compound may be appropriately selected from the range of about 0.1 g to about 1000 g per are, and preferably in the range of about 1 to about 100 g. The seed treatment agent may be appropriately selected from the range of about 0.1 to about 1000 g as an active ingredient compound per 100 kg of dry seed weight, and preferably about 1 to about 300 g.
本発明の農園芸用植物の病害防除方法で用いられる病害抵抗性誘導剤は、単独の使用ばかりでなく種々の化合物、例えば、以下に示す殺菌活性又は殺虫活性を有する農園芸用植物病害防除剤と混合して使用することもでき、又併用して使用することもできる。
殺菌活性を示す農園芸用植物病害防除剤としては、例えば、メラニン合成阻害剤、ストロビルリン系殺菌剤、エルゴステロール生合成阻害剤、酸アミド系殺菌剤、コハク酸合成酵素阻害系殺菌剤、アシルアラニン系殺菌剤、ジカルボキシイミド系殺菌剤、ベンゾイミダゾール系殺菌剤、ジチオカーバメート系殺菌剤、ピロール系殺菌剤、金属含有性殺菌剤又は抗生物質等の種々の殺菌剤が挙げられる。好ましくは、フルキンコナゾール等のエルゴステロール生合成阻害剤或いはフルジオキソニル等のピロール系殺菌剤が良い。
殺虫活性を示す農園芸用植物病害防除剤としては、例えば、ネオニコチノイド系殺虫剤、ベンゾイルウレア系殺虫剤、ジベンゾイルヒドラジン系殺虫剤、ピラゾリン系殺虫剤、フェニルピラゾール系殺虫剤、呼吸剤阻害剤、マクロライド系殺虫剤等の種々の殺虫剤が挙げられる。好ましくは、イミダクロプリド、チアメトキサム等のネオニコチノイド系殺虫剤が良い。 The disease resistance inducer used in the method for controlling diseases of agricultural and horticultural plants of the present invention is not limited to single use, but various compounds, for example, plant disease control agents for agricultural and horticultural diseases having the bactericidal activity or insecticidal activity shown below. It can also be used in combination with it, and can also be used in combination.
Examples of agricultural and horticultural plant disease control agents showing bactericidal activity include, for example, melanin synthesis inhibitors, strobilurin fungicides, ergosterol biosynthesis inhibitors, acid amide fungicides, succinic acid synthase inhibitor fungicides, acylalanine Examples include various bactericides such as a system bactericidal agent, a dicarboximide bactericidal agent, a benzimidazole bactericidal agent, a dithiocarbamate bactericidal agent, a pyrrole bactericidal agent, a metal-containing bactericidal agent or an antibiotic. An ergosterol biosynthesis inhibitor such as fluquinconazole or a pyrrole fungicide such as fludioxonil is preferable.
Examples of agricultural and horticultural plant disease control agents showing insecticidal activity include neonicotinoid insecticides, benzoylurea insecticides, dibenzoylhydrazine insecticides, pyrazoline insecticides, phenylpyrazole insecticides, respiratory inhibitor inhibitors And various insecticides such as a macrolide insecticide. Neonicotinoid insecticides such as imidacloprid and thiamethoxam are preferred.
殺菌活性を示す農園芸用植物病害防除剤としては、例えば、メラニン合成阻害剤、ストロビルリン系殺菌剤、エルゴステロール生合成阻害剤、酸アミド系殺菌剤、コハク酸合成酵素阻害系殺菌剤、アシルアラニン系殺菌剤、ジカルボキシイミド系殺菌剤、ベンゾイミダゾール系殺菌剤、ジチオカーバメート系殺菌剤、ピロール系殺菌剤、金属含有性殺菌剤又は抗生物質等の種々の殺菌剤が挙げられる。好ましくは、フルキンコナゾール等のエルゴステロール生合成阻害剤或いはフルジオキソニル等のピロール系殺菌剤が良い。
殺虫活性を示す農園芸用植物病害防除剤としては、例えば、ネオニコチノイド系殺虫剤、ベンゾイルウレア系殺虫剤、ジベンゾイルヒドラジン系殺虫剤、ピラゾリン系殺虫剤、フェニルピラゾール系殺虫剤、呼吸剤阻害剤、マクロライド系殺虫剤等の種々の殺虫剤が挙げられる。好ましくは、イミダクロプリド、チアメトキサム等のネオニコチノイド系殺虫剤が良い。 The disease resistance inducer used in the method for controlling diseases of agricultural and horticultural plants of the present invention is not limited to single use, but various compounds, for example, plant disease control agents for agricultural and horticultural diseases having the bactericidal activity or insecticidal activity shown below. It can also be used in combination with it, and can also be used in combination.
Examples of agricultural and horticultural plant disease control agents showing bactericidal activity include, for example, melanin synthesis inhibitors, strobilurin fungicides, ergosterol biosynthesis inhibitors, acid amide fungicides, succinic acid synthase inhibitor fungicides, acylalanine Examples include various bactericides such as a system bactericidal agent, a dicarboximide bactericidal agent, a benzimidazole bactericidal agent, a dithiocarbamate bactericidal agent, a pyrrole bactericidal agent, a metal-containing bactericidal agent or an antibiotic. An ergosterol biosynthesis inhibitor such as fluquinconazole or a pyrrole fungicide such as fludioxonil is preferable.
Examples of agricultural and horticultural plant disease control agents showing insecticidal activity include neonicotinoid insecticides, benzoylurea insecticides, dibenzoylhydrazine insecticides, pyrazoline insecticides, phenylpyrazole insecticides, respiratory inhibitor inhibitors And various insecticides such as a macrolide insecticide. Neonicotinoid insecticides such as imidacloprid and thiamethoxam are preferred.
当該病害抵抗性誘導剤と、殺菌活性若しくは殺虫活性を有する農園芸用植物病害防除剤を各々単独で製剤化したものまたはその希釈液を、使用の現場において処理時に混用して施用してもよく、更に、別々に同時期にこれらを用いて植物の茎葉部、種子、栽培担体等を処理してもよい。なお、各々単独で別々に施用する場合、同時に施用してもよく、約7日程度の間隔を設けてもよいが、いずれか一方の有効成分が植物又は栽培担体に残存している時期に他方の有効成分を施用することが好ましく、上記の「同時期」とは、そのように両者が処理されている時期の少なくとも一部が重複することを含む概念であり、必ずしも全く同時に施用作業を行う必要はない。当該病害抵抗性誘導剤と、殺菌活性を有する農園芸用植物病害防除剤の有効量としては、上述した農園芸用植物防除剤と同様である。
The disease resistance inducer and the agricultural or horticultural plant disease control agent having bactericidal activity or insecticidal activity, respectively, or a diluted solution thereof may be mixed and applied at the time of use at the time of treatment. Furthermore, the plant foliage, seeds, cultivation carrier and the like may be treated separately at the same time. In addition, when each is applied separately separately, it may be applied at the same time, and an interval of about 7 days may be provided, but at the time when any one of the active ingredients remains in the plant or the cultivation carrier, the other The above-mentioned “simultaneous period” is a concept including that at least a part of the period during which both are treated as described above, and the application work is not necessarily performed at the same time. There is no need. The effective amounts of the disease resistance inducer and the agricultural and horticultural plant disease control agent having bactericidal activity are the same as those described above for the agricultural and horticultural plant control agent.
本発明の農園芸用植物の病害防除方法において、当該病害抵抗性誘導剤と、殺菌活性を有する農園芸用植物病害防除剤との配合比は、当該病害抵抗性誘導剤1質量部に対して殺菌活性若しくは殺虫活性を有する農園芸用植物病害防除剤が約0.01~約1000質量部の範囲で配合され、好ましくは約0.05~約100質量部の範囲であり、より好ましくは約0.1~約50質量部の範囲である。
In the disease control method for agricultural and horticultural plants of the present invention, the compounding ratio of the disease resistance inducer to the agricultural and horticultural plant disease control agent having bactericidal activity is 1 part by mass of the disease resistance inducer. Agro-horticultural plant disease control agent having bactericidal or insecticidal activity is blended in the range of about 0.01 to about 1000 parts by weight, preferably in the range of about 0.05 to about 100 parts by weight, more preferably about The range is from 0.1 to about 50 parts by mass.
本発明の農園芸用植物の病害防除方法は、対象植物の種子等を病害抵抗性誘導剤で処理した後、BBCH39までの時期に農園芸用殺菌剤を散布することなく、BBCH40以降の時期に農園芸用殺菌剤を、少なくとも1回散布処理することを特徴としている。
In the method for controlling diseases of agricultural and horticultural plants according to the present invention, the seeds of the target plants are treated with a disease resistance inducer, and then the horticultural and horticultural fungicides are not sprayed until BBCH39, and after BBCH40. The agricultural and horticultural fungicide is sprayed at least once.
本発明でBBCH40以降の時期に少なくとも1回散布処理される農園芸用殺菌剤は、殺菌活性を有する化合物なら特に限定されない。例えば、病害抵抗性誘導剤と併用可能な殺菌活性を示す農園芸用植物病害防除剤として例示した各種農園芸用殺菌剤を好適に使用することができる。また、対象植物の種子処理等に用いた病害抵抗性誘導剤を用いてもよい。散布処理する農園芸用殺菌剤は1種類に限定されず、2種類以上の農園芸用殺菌剤を組み合わせて使用してもよい。
The agricultural and horticultural fungicide sprayed at least once in the period after BBCH 40 in the present invention is not particularly limited as long as it is a compound having bactericidal activity. For example, various agricultural and horticultural fungicides exemplified as an agricultural and horticultural plant disease control agent exhibiting bactericidal activity that can be used in combination with a disease resistance inducer can be suitably used. Moreover, you may use the disease resistance inducer used for the seed treatment of the object plant, etc. The agricultural and horticultural fungicide to be sprayed is not limited to one type, and two or more agricultural and horticultural fungicides may be used in combination.
本発明の農園芸用植物の病害防除方法は、病害抵抗性誘導剤で種子等を処理後、BBCH39以前の時期に行う農園芸用殺菌剤等の散布処理を省略することができる。BBCH40以降の時期においては、農園芸用殺菌剤の散布時期や散布回数は特に制限されず、農園芸用殺菌剤をどの時期に何回散布処理しても構わない。BBCH40以降の時期においては少なくとも1回農園芸用殺菌剤を散布処理すればよく、2回以上散布処理しても良い。中でも、BBCH40~59の時期に少なくとも1回農園芸用殺菌剤を散布処理すること、または、BBCH60以降の時期に少なくとも1回農園芸用殺菌剤を散布処理することが好ましい。
The method for controlling diseases of agricultural and horticultural plants according to the present invention can omit spraying treatment of agricultural and horticultural fungicides and the like performed before BBCH39 after treating seeds with a disease resistance inducer. In the period after BBCH 40, the spraying time and the number of spraying of the agricultural and horticultural fungicide are not particularly limited, and the agricultural and horticultural fungicide may be sprayed any number of times at any time. In the period after BBCH 40, the agricultural and horticultural fungicide may be sprayed at least once and may be sprayed twice or more. Among them, it is preferable to spray the agricultural and horticultural fungicide at least once in the period of BBCH 40 to 59, or spray the agricultural and horticultural fungicide at least once in the period after BBCH60.
本発明においてBBCH40以降の時期に行われる散布処理では、農園芸用殺菌剤の他に上述の忌避剤や殺虫活性を示す農園芸用植物病害防除剤を、必要に応じて混合又は併用することができる。
また、BBCH40以降の時期に行われる散布処理の処理方法は、適宜調製した農園芸用殺菌剤を対象の植物体に噴霧する等、通常の処理方法が用いられる。 In the spraying treatment performed in the present invention after BBCH40, in addition to the agricultural and horticultural fungicide, the above-mentioned repellent and agricultural and horticultural plant disease control agent exhibiting insecticidal activity may be mixed or used together as necessary. it can.
Moreover, the processing method of the dispersion | spreading process performed at the time after BBCH40 uses a normal processing method, such as spraying the target plant body with the agricultural / horticultural germicide prepared suitably.
また、BBCH40以降の時期に行われる散布処理の処理方法は、適宜調製した農園芸用殺菌剤を対象の植物体に噴霧する等、通常の処理方法が用いられる。 In the spraying treatment performed in the present invention after BBCH40, in addition to the agricultural and horticultural fungicide, the above-mentioned repellent and agricultural and horticultural plant disease control agent exhibiting insecticidal activity may be mixed or used together as necessary. it can.
Moreover, the processing method of the dispersion | spreading process performed at the time after BBCH40 uses a normal processing method, such as spraying the target plant body with the agricultural / horticultural germicide prepared suitably.
BBCH法は、植物すべての生育段階を二桁の数字で表す方法で、2桁目(左側の数字)に植物の一時的生育段階を0~9(0:発芽期、1:葉の展開期、2:分げつ形成期、3:茎葉伸長期、4:収穫部の生長期、5:出穂又は花芽形成期、6:開花期、7:乳熟期、8:登熟期、9:枯死期、)の10段階に分類して表記し、1桁目(右側の数字)に植物の二次的生育段階の詳細を0~9段階に分類して表記する方法である(例えば、非特許文献2、3参照)。植物の生育段階を数値化することにより、作物により、また地域により生育時期の表現が異なるという問題が解消され、作物の生育段階を簡単に理解することが可能となる。
The BBCH method is a method in which the growth stage of all plants is expressed by a two-digit number, and the temporary growth stage of the plant is 0 to 9 (0: germination stage, 1: leaf development stage) in the second digit (number on the left side). 2: tillering period, 3: foliage elongation period, 4: growing period of harvesting part, 5: heading or flower bud forming period, 6: flowering period, 7: lactation period, 8: ripening period, 9: This is a method of classifying and expressing the details of the secondary growth stage of the plant in 0 to 9 stages in the first digit (number on the right side) (for example, non-death). (See Patent Documents 2 and 3). By quantifying the growth stage of the plant, the problem that the expression of the growth time varies depending on the crop and by region, so that the growth stage of the crop can be easily understood.
BBCH法において、BBCH31~39とは植物の茎葉伸長期を意味し、茎葉長の直径が最終形態の約10~100%を形成する時期、又は第1~9節が確認可能な時期に該当し、BBCH40~59とは収穫する栄養成長部の成長期から出穂、花芽形成期に該当し、BBCH60以降とは開花形成から枯死、休眠期に該当する(図1参照)。
In the BBCH method, BBCH 31-39 means the plant's foliage elongation period, and corresponds to the time when the diameter of the foliage forms about 10-100% of the final form, or when the first to ninth sections can be confirmed. BBCH 40 to 59 correspond to the heading and flower bud formation period from the growth period of the vegetative growth part to be harvested, and BBCH 60 and later correspond to the flowering formation, withering and dormancy period (see FIG. 1).
従来の体系的防除方法においては、植物の各生育段階での複数回にわたる農園芸用殺菌剤の散布処理、具体的には、植物の生育段階のBBCH31~39に行われる農園芸用殺菌剤の散布処理(T1処理)、BBCH40~59に行われる農園芸用殺菌剤の散布処理(T2処理)、及びBBCH60以降に行われる農園芸用殺菌剤の散布処理(T3処理)が必須とされている。
本発明の農園芸用植物の病害防除方法によれば、対象植物の種子等を病害抵抗性誘導剤で処理した後は、止葉の展開が終了するBBCH39以前の時期に農園芸用殺菌剤等の病害防除剤で対象植物等を処理する必要がない。止葉とは出穂前に抽出する最後の葉を意味する。また、BBCH40以降の時期においては、通常の体系的防除方法で必要とされる複数回の農園芸用殺菌剤等での病害防除処理を少なくとも1回にするなど、省略または簡略することができる。したがって、本発明の農園芸用植物の病害防除方法は、少ない薬量で従来と同様の防除効果を示すため、就農者の作業を省力することができる。また、病原菌特異性がなく、広範囲の病害に対して防除効果を示すうえに、薬剤耐性菌株の出現を抑制することができる。 In the conventional systematic control method, a plurality of agricultural and horticultural fungicide spraying treatments at each growth stage of the plant, specifically, the agricultural and horticultural fungicide applied to theBBCH 31 to 39 in the plant growth stage. A spraying process (T1 process), an agricultural and horticultural fungicide spraying process (T2 process) performed on BBCH 40 to 59, and an agricultural and horticultural fungicide spraying process (T3 process) performed after BBCH60 are essential. .
According to the method for controlling diseases of agricultural and horticultural plants of the present invention, after treating the seeds of the target plant with a disease resistance inducer, the agricultural and horticultural fungicides and the like before BBCH39 when the development of the leaf stop is completed There is no need to treat the target plant with the disease control agent. Stop leaf means the last leaf extracted before heading. In addition, in the period after BBCH 40, it is possible to omit or simplify the disease control process with a plurality of agricultural and horticultural fungicides or the like required in a normal systematic control method. Therefore, since the disease control method for agricultural and horticultural plants of the present invention shows the same control effect as before with a small amount of medicine, the work of the farmer can be saved. Moreover, there is no pathogen-specificity, and the control effect is demonstrated with respect to a wide range of diseases, and the appearance of drug-resistant strains can be suppressed.
本発明の農園芸用植物の病害防除方法によれば、対象植物の種子等を病害抵抗性誘導剤で処理した後は、止葉の展開が終了するBBCH39以前の時期に農園芸用殺菌剤等の病害防除剤で対象植物等を処理する必要がない。止葉とは出穂前に抽出する最後の葉を意味する。また、BBCH40以降の時期においては、通常の体系的防除方法で必要とされる複数回の農園芸用殺菌剤等での病害防除処理を少なくとも1回にするなど、省略または簡略することができる。したがって、本発明の農園芸用植物の病害防除方法は、少ない薬量で従来と同様の防除効果を示すため、就農者の作業を省力することができる。また、病原菌特異性がなく、広範囲の病害に対して防除効果を示すうえに、薬剤耐性菌株の出現を抑制することができる。 In the conventional systematic control method, a plurality of agricultural and horticultural fungicide spraying treatments at each growth stage of the plant, specifically, the agricultural and horticultural fungicide applied to the
According to the method for controlling diseases of agricultural and horticultural plants of the present invention, after treating the seeds of the target plant with a disease resistance inducer, the agricultural and horticultural fungicides and the like before BBCH39 when the development of the leaf stop is completed There is no need to treat the target plant with the disease control agent. Stop leaf means the last leaf extracted before heading. In addition, in the period after BBCH 40, it is possible to omit or simplify the disease control process with a plurality of agricultural and horticultural fungicides or the like required in a normal systematic control method. Therefore, since the disease control method for agricultural and horticultural plants of the present invention shows the same control effect as before with a small amount of medicine, the work of the farmer can be saved. Moreover, there is no pathogen-specificity, and the control effect is demonstrated with respect to a wide range of diseases, and the appearance of drug-resistant strains can be suppressed.
以下に本発明の代表的な製剤例及び生物試験例を示すが、本発明はこれらに限定されるものではない。尚、製剤例中、「部」とあるのは「重量部」を示し、各化合物番号は第1表に記載の化合物番号を示す。
Hereinafter, typical preparation examples and biological test examples of the present invention are shown, but the present invention is not limited thereto. In the preparation examples, “parts” indicates “parts by weight”, and each compound number indicates a compound number described in Table 1.
[製剤例1]
化合物番号1-12 10部
キシレン 70部
N-メチルピロリドン 10部
ポリオキシエチレンノニルフェニルエーテルと
アルキルベンゼンスルホン酸カルシウムとの混合物 10部
以上を均一に混合溶解して乳剤とする。 [Formulation Example 1]
Compound No. 1-12 10 parts Xylene 70 parts N-methylpyrrolidone 10 parts A mixture of polyoxyethylene nonylphenyl ether and calcium alkylbenzenesulfonate 10 parts or more are uniformly mixed and dissolved to prepare an emulsion.
化合物番号1-12 10部
キシレン 70部
N-メチルピロリドン 10部
ポリオキシエチレンノニルフェニルエーテルと
アルキルベンゼンスルホン酸カルシウムとの混合物 10部
以上を均一に混合溶解して乳剤とする。 [Formulation Example 1]
Compound No. 1-12 10 parts Xylene 70 parts N-
[製剤例2]
化合物番号1-93 3部
クレー粉末 82部
珪藻土粉末 15部
以上を均一に混合粉砕して粉剤とする。 [Formulation Example 2]
Compound No. 1-93 3 parts Clay powder 82 parts Diatomaceous earth powder 15 parts or more are mixed and ground uniformly to form a powder.
化合物番号1-93 3部
クレー粉末 82部
珪藻土粉末 15部
以上を均一に混合粉砕して粉剤とする。 [Formulation Example 2]
Compound No. 1-93 3 parts Clay powder 82 parts Diatomaceous earth powder 15 parts or more are mixed and ground uniformly to form a powder.
[製剤例3]
化合物番号1-12 5部
ベントナイトとクレーの混合粉末 90部
リグニンスルホン酸カルシウム 5部
以上を均一に混合し、適量の水を加えて混練し、造粒、乾燥して粒剤とする。 [Formulation Example 3]
Compound No. 1-12 5 parts Bentonite / clay mixed powder 90 parts 5 parts or more of calcium lignin sulfonate are uniformly mixed, kneaded with an appropriate amount of water, granulated and dried to form granules.
化合物番号1-12 5部
ベントナイトとクレーの混合粉末 90部
リグニンスルホン酸カルシウム 5部
以上を均一に混合し、適量の水を加えて混練し、造粒、乾燥して粒剤とする。 [Formulation Example 3]
Compound No. 1-12 5 parts Bentonite / clay mixed powder 90 parts 5 parts or more of calcium lignin sulfonate are uniformly mixed, kneaded with an appropriate amount of water, granulated and dried to form granules.
[製剤例4]
化合物番号1-93 20部
カオリンと合成高分散珪酸 75部
ポリオキシエチレンノニルフェニルエーテルと
アルキルベンゼンスルホン酸カルシウムとの混合物 5部
以上を均一に混合粉砕して水和剤とする。 [Formulation Example 4]
Compound No. 1-93 20 parts Kaolin, synthetic highly dispersed silicic acid 75 parts Mixture of polyoxyethylene nonylphenyl ether and calcium alkylbenzenesulfonate 5 parts or more are uniformly mixed and ground to obtain a wettable powder.
化合物番号1-93 20部
カオリンと合成高分散珪酸 75部
ポリオキシエチレンノニルフェニルエーテルと
アルキルベンゼンスルホン酸カルシウムとの混合物 5部
以上を均一に混合粉砕して水和剤とする。 [Formulation Example 4]
Compound No. 1-93 20 parts Kaolin, synthetic highly dispersed silicic acid 75 parts Mixture of polyoxyethylene nonylphenyl ether and calcium alkylbenzenesulfonate 5 parts or more are uniformly mixed and ground to obtain a wettable powder.
試験例1.種子処理剤混用によるコムギうどんこ病防除効果試験(温室内試験)
10gのコムギ(品種:チホクコムギ)乾燥種子に0.1gの水を塗し、表中記載の処理薬量の水和剤を当該水処理した種子に均一に付着するように処理した。処理した種子を風乾後、直径10cmのプラスチックポットに播種し温室内で栽培した。コムギが6葉期/分けつ期に生育した時点(約70日後)で、そのコムギにうどんこ病菌(Blumeria graminis)の胞子をふりかけ接種した。接種7日後に、下記の基準に従って、展開葉の発病指数及び防除価(%)を算出した。このとき無処理区の発病指数は5.0であった。結果を第3表に示す。 Test Example 1 Wheat powdery mildew control effect test by mixing seed treatment agent (greenhouse test)
10 g of wheat (variety: chihoku wheat) dried seed was coated with 0.1 g of water, and treated with a treatment dosage amount of wettable powder as shown in the table so as to uniformly adhere to the water-treated seed. The treated seeds were air-dried and then sown in a plastic pot having a diameter of 10 cm and cultivated in a greenhouse. When the wheat grew at the 6th leaf / divided stage (about 70 days later), the wheat was inoculated with spores of powdery mildew (Blumeria graminis). Seven days after the inoculation, the disease index and the control value (%) of the developed leaves were calculated according to the following criteria. At this time, the disease index of the untreated section was 5.0. The results are shown in Table 3.
10gのコムギ(品種:チホクコムギ)乾燥種子に0.1gの水を塗し、表中記載の処理薬量の水和剤を当該水処理した種子に均一に付着するように処理した。処理した種子を風乾後、直径10cmのプラスチックポットに播種し温室内で栽培した。コムギが6葉期/分けつ期に生育した時点(約70日後)で、そのコムギにうどんこ病菌(Blumeria graminis)の胞子をふりかけ接種した。接種7日後に、下記の基準に従って、展開葉の発病指数及び防除価(%)を算出した。このとき無処理区の発病指数は5.0であった。結果を第3表に示す。 Test Example 1 Wheat powdery mildew control effect test by mixing seed treatment agent (greenhouse test)
10 g of wheat (variety: chihoku wheat) dried seed was coated with 0.1 g of water, and treated with a treatment dosage amount of wettable powder as shown in the table so as to uniformly adhere to the water-treated seed. The treated seeds were air-dried and then sown in a plastic pot having a diameter of 10 cm and cultivated in a greenhouse. When the wheat grew at the 6th leaf / divided stage (about 70 days later), the wheat was inoculated with spores of powdery mildew (Blumeria graminis). Seven days after the inoculation, the disease index and the control value (%) of the developed leaves were calculated according to the following criteria. At this time, the disease index of the untreated section was 5.0. The results are shown in Table 3.
[発病指数]
0 : 発病なし
0.5: 病斑面積率 10%未満
1 : 病斑面積率 10~20%未満
2 : 病斑面積率 20~30%未満
3 : 病斑面積率 30~40%未満
4 : 病斑面積率 40~50%未満
5 : 病斑面積率 50~60%未満
6 : 病斑面積率 60~70%未満
7 : 病斑面積率 70~80%未満
8 : 病斑面積率 80~90%未満
9 : 病斑面積率 90~100%未満
10 : 病斑面積率 100%
[式-1]
防除価(%)=(1-{処理区の発病指数÷無処理区の発病指数})×100 [Disease index]
0: No disease occurrence 0.5: Spot area ratio less than 10% 1: Spotlesion area ratio 10 to less than 20% 2: Spot lesion area ratio 20 to less than 30% 3: Spot lesion area ratio 30 to less than 40% 4: Spot area ratio 40 to less than 50% 5: Spot area ratio 50 to less than 60% 6: Spot area ratio 60 to less than 70% 7: Spot area ratio 70 to less than 80% 8: Spot area ratio 80 to Less than 90% 9: lesion area ratio 90 to less than 100% 10: lesion area ratio 100%
[Formula-1]
Control value (%) = (1− {onset index of treated area ÷ onset index of untreated area}) × 100
0 : 発病なし
0.5: 病斑面積率 10%未満
1 : 病斑面積率 10~20%未満
2 : 病斑面積率 20~30%未満
3 : 病斑面積率 30~40%未満
4 : 病斑面積率 40~50%未満
5 : 病斑面積率 50~60%未満
6 : 病斑面積率 60~70%未満
7 : 病斑面積率 70~80%未満
8 : 病斑面積率 80~90%未満
9 : 病斑面積率 90~100%未満
10 : 病斑面積率 100%
[式-1]
防除価(%)=(1-{処理区の発病指数÷無処理区の発病指数})×100 [Disease index]
0: No disease occurrence 0.5: Spot area ratio less than 10% 1: Spot
[Formula-1]
Control value (%) = (1− {onset index of treated area ÷ onset index of untreated area}) × 100
対照化合物は、以下の物質を用いた。
化合物A:ビテルタノール(bitertanol)
化合物B:フベリダゾール(fuberidazole)
化合物C:トリアジメノール(triadimenol)
化合物D:トリチコナゾール(triticonazole)
化合物E:グアザチン(guazatine)
化合物F:カルボキシン(carboxin)
化合物G:チウラム(thiram) The following substances were used as control compounds.
Compound A: bittertanol
Compound B: fuberidazole
Compound C: triadimenol
Compound D: triticonazole
Compound E: guazatine
Compound F: Carboxin
Compound G: thiuram
化合物A:ビテルタノール(bitertanol)
化合物B:フベリダゾール(fuberidazole)
化合物C:トリアジメノール(triadimenol)
化合物D:トリチコナゾール(triticonazole)
化合物E:グアザチン(guazatine)
化合物F:カルボキシン(carboxin)
化合物G:チウラム(thiram) The following substances were used as control compounds.
Compound A: bittertanol
Compound B: fuberidazole
Compound C: triadimenol
Compound D: triticonazole
Compound E: guazatine
Compound F: Carboxin
Compound G: thiuram
表中、「ga.i./100Kg種子」は種子100Kgあたりに使用した有効成分(Active Ingredient)の量(g)を意味する(以下、第4表~第6表も同意義)。
In the table, “ga.i./100 Kg seed” means the amount (g) of the active ingredient (Active Ingredient) used per 100 kg of seeds (hereinafter, Tables 4 to 6 have the same meaning).
本発明の農園芸用植物の病害防除方法で病害抵抗性誘導剤は対照薬剤に優る防除価を示した。
In the method for controlling diseases of agricultural and horticultural plants according to the present invention, the disease resistance inducer showed a control value superior to that of the control drug.
試験例2.種子処理剤混用によるコムギ赤さび病防除効果試験(温室内試験)
試験例1に記載の方法と同様に、10gのコムギ(品種:チホクコムギ)乾燥種子に0.1gの水を塗し、表中記載の処理薬量の水和剤を当該水処理した種子に均一に付着するように処理した。処理した種子を風乾後、直径10cmのプラスチックポットに播種し温室内で栽培した。コムギが6葉期/分けつ期に生育した時点(播種後約70日)で、そのコムギに赤さび病菌(Puccinia recondita)の胞子懸濁液を噴霧接種した。接種7日後に、試験1の基準に従って、展開葉の発病指数及び防除価(%)を算出した。結果を第4表に示す。 Test Example 2 Wheat red rust control effect test by mixed seed treatment (greenhouse test)
Similar to the method described in Test Example 1, 0.1 g of water is applied to 10 g of wheat (variety: Chihoku wheat) dry seeds, and the amount of wettable powder described in the table is uniformly applied to the water-treated seeds. It processed so that it might adhere to. The treated seeds were air-dried and then sown in a plastic pot having a diameter of 10 cm and cultivated in a greenhouse. When the wheat grew at the 6-leaf stage / dividing stage (about 70 days after sowing), the wheat was spray-inoculated with a spore suspension of Puccinia recondita. Seven days after the inoculation, the disease index and the control value (%) of the developed leaves were calculated according to the criteria ofTest 1. The results are shown in Table 4.
試験例1に記載の方法と同様に、10gのコムギ(品種:チホクコムギ)乾燥種子に0.1gの水を塗し、表中記載の処理薬量の水和剤を当該水処理した種子に均一に付着するように処理した。処理した種子を風乾後、直径10cmのプラスチックポットに播種し温室内で栽培した。コムギが6葉期/分けつ期に生育した時点(播種後約70日)で、そのコムギに赤さび病菌(Puccinia recondita)の胞子懸濁液を噴霧接種した。接種7日後に、試験1の基準に従って、展開葉の発病指数及び防除価(%)を算出した。結果を第4表に示す。 Test Example 2 Wheat red rust control effect test by mixed seed treatment (greenhouse test)
Similar to the method described in Test Example 1, 0.1 g of water is applied to 10 g of wheat (variety: Chihoku wheat) dry seeds, and the amount of wettable powder described in the table is uniformly applied to the water-treated seeds. It processed so that it might adhere to. The treated seeds were air-dried and then sown in a plastic pot having a diameter of 10 cm and cultivated in a greenhouse. When the wheat grew at the 6-leaf stage / dividing stage (about 70 days after sowing), the wheat was spray-inoculated with a spore suspension of Puccinia recondita. Seven days after the inoculation, the disease index and the control value (%) of the developed leaves were calculated according to the criteria of
温室内試験において、本発明の農園芸用植物の病害防除方法により病害抵抗性誘導剤は対照薬剤に優る防除価を示した。
In the greenhouse test, the disease resistance inducer showed a control value superior to that of the control drug by the method for controlling diseases of agricultural and horticultural plants of the present invention.
試験例3.種子処理によるコムギうどんこ病防除効果試験(圃場試験)
10gのコムギ(品種:チホクコムギ)乾燥種子に0.1gの水を塗し、表中記載の処理薬量の水和剤を当該水処理した種子に均一に付着するように処理した。処理翌日に、播種量を120kg/ha相当になるように、処理した種子を2m2(1m×2m)の区画内に条播した。翌年のコムギが出穂する時期(BBCH51-59頃、播種から約190日後)に、次葉及び止葉について、試験1の基準に従って、自然発生したうどんこ病菌(Blumeria graminis)の発病指数及び防除価(%)を算出した。結果を第5表に示す。 Test Example 3 Wheat powdery mildew control effect test by seed treatment (field test)
10 g of wheat (variety: chihoku wheat) dried seed was coated with 0.1 g of water, and treated with a treatment dosage amount of wettable powder as shown in the table so as to uniformly adhere to the water-treated seed. On the next day of the treatment, the treated seeds were sown in a 2 m 2 (1 m × 2 m) compartment so that the sowing amount would be 120 kg / ha. In the next year when wheat emerges (around BBCH 51-59, about 190 days after sowing), the occurrence index and control value of naturally occurring powdery mildew (Blumeria graminis) on the following leaves and flag leaves according to the criteria of Test 1 (%) Was calculated. The results are shown in Table 5.
10gのコムギ(品種:チホクコムギ)乾燥種子に0.1gの水を塗し、表中記載の処理薬量の水和剤を当該水処理した種子に均一に付着するように処理した。処理翌日に、播種量を120kg/ha相当になるように、処理した種子を2m2(1m×2m)の区画内に条播した。翌年のコムギが出穂する時期(BBCH51-59頃、播種から約190日後)に、次葉及び止葉について、試験1の基準に従って、自然発生したうどんこ病菌(Blumeria graminis)の発病指数及び防除価(%)を算出した。結果を第5表に示す。 Test Example 3 Wheat powdery mildew control effect test by seed treatment (field test)
10 g of wheat (variety: chihoku wheat) dried seed was coated with 0.1 g of water, and treated with a treatment dosage amount of wettable powder as shown in the table so as to uniformly adhere to the water-treated seed. On the next day of the treatment, the treated seeds were sown in a 2 m 2 (1 m × 2 m) compartment so that the sowing amount would be 120 kg / ha. In the next year when wheat emerges (around BBCH 51-59, about 190 days after sowing), the occurrence index and control value of naturally occurring powdery mildew (Blumeria graminis) on the following leaves and flag leaves according to the criteria of Test 1 (%) Was calculated. The results are shown in Table 5.
圃場試験において本発明の農園芸用植物の病害防除方法により、病害抵抗性誘導剤は対照化合物に優る効果を示し、生育段階のBBCH40以降の時期に行われる農園芸用殺菌剤の散布処理(T2処理、T3処理、)を低減又は削減できる可能性があることが証明された。
In the field test, the disease resistance inducer exhibits an effect superior to that of the control compound by the method for controlling diseases of the agricultural and horticultural plant of the present invention, and the dispersal treatment of the agricultural and horticultural fungicide (T2) performed at a time after BBCH40 in the growth stage. It has been proved that there is a possibility that the processing, T3 processing) can be reduced or reduced.
試験例4.種子処理によるコムギ赤さび病防除効果試験(圃場試験)
10gのコムギ(品種:チホクコムギ)乾燥種子に0.1gの水を塗し、表中記載の処理薬量の水和剤を当該水処理した種子に均一に付着するように処理した。処理翌日に、播種量を120kg/ha相当になるように、上記処理した種子を2m2(1m×2m)の区画内に条播した。翌年のコムギが出穂する時期(BBCH51-59頃、播種後約270日後)に、次葉及び止葉について、試験1の基準に従って、自然発生した赤さび病菌(Puccinia recondita)の発病指数及び防除価(%)を算出し、効果判定を行った。結果を第6表に示す。 Test Example 4 Wheat red rust control effect test by seed treatment (field test)
10 g of wheat (variety: chihoku wheat) dried seed was coated with 0.1 g of water, and treated with a treatment dosage amount of wettable powder as shown in the table so as to uniformly adhere to the water-treated seed. On the next day of the treatment, the treated seeds were sown in 2 m 2 (1 m × 2 m) sections so that the sowing amount would be 120 kg / ha. In the next year when the wheat emerges (around BBCH 51-59, about 270 days after sowing), the incidence index and control value of the naturally occurring red rust fungus (Puccinia recondita) according to the criteria ofTest 1 for the subsequent leaves and the stationary leaves ( %) Was calculated and the effect was judged. The results are shown in Table 6.
10gのコムギ(品種:チホクコムギ)乾燥種子に0.1gの水を塗し、表中記載の処理薬量の水和剤を当該水処理した種子に均一に付着するように処理した。処理翌日に、播種量を120kg/ha相当になるように、上記処理した種子を2m2(1m×2m)の区画内に条播した。翌年のコムギが出穂する時期(BBCH51-59頃、播種後約270日後)に、次葉及び止葉について、試験1の基準に従って、自然発生した赤さび病菌(Puccinia recondita)の発病指数及び防除価(%)を算出し、効果判定を行った。結果を第6表に示す。 Test Example 4 Wheat red rust control effect test by seed treatment (field test)
10 g of wheat (variety: chihoku wheat) dried seed was coated with 0.1 g of water, and treated with a treatment dosage amount of wettable powder as shown in the table so as to uniformly adhere to the water-treated seed. On the next day of the treatment, the treated seeds were sown in 2 m 2 (1 m × 2 m) sections so that the sowing amount would be 120 kg / ha. In the next year when the wheat emerges (around BBCH 51-59, about 270 days after sowing), the incidence index and control value of the naturally occurring red rust fungus (Puccinia recondita) according to the criteria of
比較例1.茎葉散布剤体系によるコムギうどんこ病防除効果試験(圃場試験)
種子消毒剤の対照化合物Iとの混用で、化合物1-93または対照化合物Hを、表中記載の処理薬量でコムギ(品種:Claire)乾燥種子に均一に付着するように処理した。処理後、播種量を180kg/ha相当で、上記処理した種子を20m2(2m×10m)の区画内に条播した。翌年に種子処理と茎葉散布の体系防除区では、コムギが止葉を抽出または完全展開する時期(BBCH43-55)に茎葉散布剤の対照化合物C+Dを体系的に散布した。なお、慣行防除区では、コムギの節間伸長時期(BBCH31-32)にも茎葉散布剤の対照化合物J+Kを散布した。コムギが出穂した時期(BBCH75~83頃、播種210~230日後)の次葉及び止葉について、試験例1の基準に従って、自然発生したうどんこ病菌(Blumeria graminis)の発病指数を調査し、防除価(%)を算出した。結果を第7表に示す。 Comparative Example 1 Wheat powdery mildew control effect test by foliar spray system (field test)
When the seed disinfectant was mixed with the control compound I, the compound 1-93 or the control compound H was treated so as to uniformly adhere to dry seeds of wheat (cultivar: Claire) at the treatment doses shown in the table. After the treatment, the sowing amount was equivalent to 180 kg / ha, and the treated seed was sown in a 20 m 2 (2 m × 10 m) section. In the following year, in the system control section for seed treatment and foliage spraying, the foliar spray control compound C + D was systematically sprayed at the time when the wheat leaves were extracted or fully developed (BBCH 43-55). In the conventional control zone, the control compound J + K as a foliage spray was also sprayed during the internode elongation period (BBCH31-32) of wheat. According to the criteria of Test Example 1, the incidence index of naturally occurring powdery mildew (Blumeria graminis) was investigated and controlled for the next and stationary leaves at the time of wheat heading (around BBCH 75-83, 210-230 days after sowing). The value (%) was calculated. The results are shown in Table 7.
種子消毒剤の対照化合物Iとの混用で、化合物1-93または対照化合物Hを、表中記載の処理薬量でコムギ(品種:Claire)乾燥種子に均一に付着するように処理した。処理後、播種量を180kg/ha相当で、上記処理した種子を20m2(2m×10m)の区画内に条播した。翌年に種子処理と茎葉散布の体系防除区では、コムギが止葉を抽出または完全展開する時期(BBCH43-55)に茎葉散布剤の対照化合物C+Dを体系的に散布した。なお、慣行防除区では、コムギの節間伸長時期(BBCH31-32)にも茎葉散布剤の対照化合物J+Kを散布した。コムギが出穂した時期(BBCH75~83頃、播種210~230日後)の次葉及び止葉について、試験例1の基準に従って、自然発生したうどんこ病菌(Blumeria graminis)の発病指数を調査し、防除価(%)を算出した。結果を第7表に示す。 Comparative Example 1 Wheat powdery mildew control effect test by foliar spray system (field test)
When the seed disinfectant was mixed with the control compound I, the compound 1-93 or the control compound H was treated so as to uniformly adhere to dry seeds of wheat (cultivar: Claire) at the treatment doses shown in the table. After the treatment, the sowing amount was equivalent to 180 kg / ha, and the treated seed was sown in a 20 m 2 (2 m × 10 m) section. In the following year, in the system control section for seed treatment and foliage spraying, the foliar spray control compound C + D was systematically sprayed at the time when the wheat leaves were extracted or fully developed (BBCH 43-55). In the conventional control zone, the control compound J + K as a foliage spray was also sprayed during the internode elongation period (BBCH31-32) of wheat. According to the criteria of Test Example 1, the incidence index of naturally occurring powdery mildew (Blumeria graminis) was investigated and controlled for the next and stationary leaves at the time of wheat heading (around BBCH 75-83, 210-230 days after sowing). The value (%) was calculated. The results are shown in Table 7.
対照化合物は、以下の物質を用いた。
化合物H:フルキンコナゾール(fluquinconazole)
化合物I:フルジオキソニル(fludioxonil)
化合物J:エポキシコナゾール(Epoxiconazole)
化合物K:クロロタロニル(Chlorothalonil) The following substances were used as control compounds.
Compound H: fluquinconazole
Compound I: fludioxonil
Compound J: Epoxyconazole
Compound K: Chlorothalonil
化合物H:フルキンコナゾール(fluquinconazole)
化合物I:フルジオキソニル(fludioxonil)
化合物J:エポキシコナゾール(Epoxiconazole)
化合物K:クロロタロニル(Chlorothalonil) The following substances were used as control compounds.
Compound H: fluquinconazole
Compound I: fludioxonil
Compound J: Epoxyconazole
Compound K: Chlorothalonil
比較例2.茎葉散布剤体系によるコムギセプトリア葉枯病防除効果試験(圃場試験)
種子消毒剤の対照化合物Iとの混用で、化合物1-93または対照化合物Hを、表中記載の処理薬量でコムギ(品種:Riband)乾燥種子に均一に付着するように処理した。処理後、播種量を180kg/ha相当で、上記処理した種子を20m2(2m×10m)の区画内に条播した。翌年に種子処理と茎葉散布の体系防除区では、コムギが止葉を抽出または完全展開する時期(BBCH43-55)に茎葉散布剤の対照化合物C+Dを体系的に散布した。なお、慣行防除区では、コムギの節間伸長時期(BBCH31-32)にも茎葉散布剤の対照化合物J+Kを散布した。コムギが出穂した時期(BBCH75~83頃、播種210~230日後)の次葉及び止葉について、試験1の基準に従って、自然発生したセプトリア葉枯病菌(Septoria tritici)の発病指数を調査し、防除価(%)を算出した。結果を第8表に示す。 Comparative Example 2 Wheat Septoria leaf blight control effect test with foliar spray system (field test)
In the combined use of the seed disinfectant with the control compound I, the compound 1-93 or the control compound H was treated so as to uniformly adhere to the dried wheat (variety: Riband) seeds at the treatment doses shown in the table. After the treatment, the sowing amount was equivalent to 180 kg / ha, and the treated seed was sown in a 20 m 2 (2 m × 10 m) section. In the following year, in the system control section for seed treatment and foliage spraying, the foliar spray control compound C + D was systematically sprayed at the time when the wheat leaves were extracted or fully developed (BBCH 43-55). In the conventional control zone, the control compound J + K as a foliage spray was also sprayed during the internode elongation period (BBCH31-32) of wheat. According to the criteria ofTest 1, the incidence index of the naturally occurring Septoria tritici (Septoria tritici) disease was investigated and controlled for the next and stationary leaves at the time of wheat heading (around BBCH 75-83, 210-230 days after sowing). The value (%) was calculated. The results are shown in Table 8.
種子消毒剤の対照化合物Iとの混用で、化合物1-93または対照化合物Hを、表中記載の処理薬量でコムギ(品種:Riband)乾燥種子に均一に付着するように処理した。処理後、播種量を180kg/ha相当で、上記処理した種子を20m2(2m×10m)の区画内に条播した。翌年に種子処理と茎葉散布の体系防除区では、コムギが止葉を抽出または完全展開する時期(BBCH43-55)に茎葉散布剤の対照化合物C+Dを体系的に散布した。なお、慣行防除区では、コムギの節間伸長時期(BBCH31-32)にも茎葉散布剤の対照化合物J+Kを散布した。コムギが出穂した時期(BBCH75~83頃、播種210~230日後)の次葉及び止葉について、試験1の基準に従って、自然発生したセプトリア葉枯病菌(Septoria tritici)の発病指数を調査し、防除価(%)を算出した。結果を第8表に示す。 Comparative Example 2 Wheat Septoria leaf blight control effect test with foliar spray system (field test)
In the combined use of the seed disinfectant with the control compound I, the compound 1-93 or the control compound H was treated so as to uniformly adhere to the dried wheat (variety: Riband) seeds at the treatment doses shown in the table. After the treatment, the sowing amount was equivalent to 180 kg / ha, and the treated seed was sown in a 20 m 2 (2 m × 10 m) section. In the following year, in the system control section for seed treatment and foliage spraying, the foliar spray control compound C + D was systematically sprayed at the time when the wheat leaves were extracted or fully developed (BBCH 43-55). In the conventional control zone, the control compound J + K as a foliage spray was also sprayed during the internode elongation period (BBCH31-32) of wheat. According to the criteria of
比較例3.茎葉散布剤体系によるコムギ赤さび病防除効果試験(圃場試験)
種子消毒剤の対照化合物Iとの混用で、化合物1-93または対照化合物Hを、表中記載の処理薬量でコムギ(品種:Riband)乾燥種子に均一に付着するように処理した。処理後、播種量を180kg/ha相当で、上記処理した種子を20m2(2m×10m)の区画内に条播した。翌年に種子処理と茎葉散布の体系防除区では、コムギが止葉を抽出または完全展開する時期(BBCH43-55)に茎葉散布剤の対照化合物C+Dを体系的に散布した。なお、慣行防除区では、コムギの節間伸長時期(BBCH31-32)にも茎葉散布剤の対照化合物J+Kを散布した。コムギが出穂した時期(BBCH75~83頃、播種210~230日後)の次葉及び止葉について、試験1の基準に従って、自然発生した赤さび病菌(Puccinia recondita)の発病指数を調査し、防除価(%)を算出した。結果を第9表に示す。 Comparative Example 3 Wheat red rust control effect test with foliar spray system (field test)
In the combined use of the seed disinfectant with the control compound I, the compound 1-93 or the control compound H was treated so as to uniformly adhere to the dried wheat (variety: Riband) seeds at the treatment doses shown in the table. After the treatment, the sowing amount was equivalent to 180 kg / ha, and the treated seed was sown in a 20 m 2 (2 m × 10 m) section. In the following year, in the system control section for seed treatment and foliage spraying, the foliar spray control compound C + D was systematically sprayed at the time when the wheat leaves were extracted or fully developed (BBCH 43-55). In the conventional control zone, the control compound J + K as a foliage spray was also sprayed during the internode elongation period (BBCH31-32) of wheat. According to the criteria ofTest 1, the incidence index of naturally occurring red rust fungus (Puccinia recondita) was investigated according to the criteria of Test 1, and the control value (about BBCH 75-83, after 210-230 days after sowing) %) Was calculated. The results are shown in Table 9.
種子消毒剤の対照化合物Iとの混用で、化合物1-93または対照化合物Hを、表中記載の処理薬量でコムギ(品種:Riband)乾燥種子に均一に付着するように処理した。処理後、播種量を180kg/ha相当で、上記処理した種子を20m2(2m×10m)の区画内に条播した。翌年に種子処理と茎葉散布の体系防除区では、コムギが止葉を抽出または完全展開する時期(BBCH43-55)に茎葉散布剤の対照化合物C+Dを体系的に散布した。なお、慣行防除区では、コムギの節間伸長時期(BBCH31-32)にも茎葉散布剤の対照化合物J+Kを散布した。コムギが出穂した時期(BBCH75~83頃、播種210~230日後)の次葉及び止葉について、試験1の基準に従って、自然発生した赤さび病菌(Puccinia recondita)の発病指数を調査し、防除価(%)を算出した。結果を第9表に示す。 Comparative Example 3 Wheat red rust control effect test with foliar spray system (field test)
In the combined use of the seed disinfectant with the control compound I, the compound 1-93 or the control compound H was treated so as to uniformly adhere to the dried wheat (variety: Riband) seeds at the treatment doses shown in the table. After the treatment, the sowing amount was equivalent to 180 kg / ha, and the treated seed was sown in a 20 m 2 (2 m × 10 m) section. In the following year, in the system control section for seed treatment and foliage spraying, the foliar spray control compound C + D was systematically sprayed at the time when the wheat leaves were extracted or fully developed (BBCH 43-55). In the conventional control zone, the control compound J + K as a foliage spray was also sprayed during the internode elongation period (BBCH31-32) of wheat. According to the criteria of
圃場試験において本発明の農園芸用植物の病害防除方法により、翌年のコムギが出穂する時期(BBCH51~59頃、播種後約270日後)まで病害の防除効果が持続していることが分かった。この結果より、本発明で用いられる病害抵抗性誘導剤は対照化合物に優る顕著な持続効果を示した。また比較例より、本発明の農園芸用植物の病害防除方法は、体系処理による生育段階のBBCH31~39に行われる農園芸用殺菌剤の散布処理(T1処理)及び生育段階のBBCH40~59に行われる農園芸用殺菌剤の散布処理(T2処理)を削減できる可能性があることが証明された。
In the field test, it was found that the disease controlling effect of the present invention was maintained until the next year when wheat emerged (around BBCH 51-59, about 270 days after sowing). From this result, the disease resistance inducer used in the present invention showed a remarkable sustained effect over the control compound. Further, from the comparative example, the method for controlling diseases of agricultural and horticultural plants according to the present invention is applied to the horticultural horticultural fungicide spraying treatment (T1 treatment) performed on the BBCH 31 to 39 in the growth stage by system treatment and the BBCH 40 to 59 in the growth stage. It has been proved that there is a possibility that the spraying treatment (T2 treatment) of the agricultural and horticultural fungicide performed can be reduced.
本発明は従来技術とは異なり、対象作物の種子又は対象作物を播種する担体へ病害抵抗性誘導剤を施用することにより、対象作物の種子から生育後期に至るまでに発病する病害を農園芸用殺菌剤の併用をすることなく防除することが可能となる。この効果により農薬使用量の低減、作業者と薬剤との接触を低減させることにより作業者の安全性を高めることができる。
Unlike the prior art, the present invention applies a disease resistance inducer to seeds of a target crop or a carrier for seeding the target crop, so that diseases that develop from the seed of the target crop to the late stage of growth can be used for agriculture and horticulture. Control is possible without using a bactericide. By this effect, the safety of workers can be improved by reducing the amount of agricultural chemicals used and reducing the contact between the workers and the medicine.
本発明の農園芸用植物の病害防除方法は、従来、体系的防除方法において必須とされていた農園芸用殺菌剤の散布処理のうち、BBCH40より前の時期に行われる農園芸用殺菌剤の散布処理回数を省略することができ、BBCH40以降の時期に行われる農園芸用殺菌剤の散布処理回数を少なくとも1回とすることができる。
The method for controlling diseases of agricultural and horticultural plants according to the present invention is an agricultural and horticultural fungicide that is performed at a time prior to BBCH40 in the spraying treatment of agricultural and horticultural fungicides, which has been conventionally essential in systematic control methods. The number of spraying processes can be omitted, and the number of spraying processes of the agricultural and horticultural fungicide performed at the time after BBCH40 can be set to at least one.
Claims (8)
- 対象植物の種子、対象植物の種子を播種するための栽培担体、対象植物の種子を播種する土壌、又は、栽培担体で育苗した対象植物を移植する土壌を、病害抵抗性誘導剤で処理し、次にBBCH40以降の時期に農園芸用殺菌剤を、少なくとも1回散布処理することを特徴とする農園芸用植物の病害防除方法。 Treating the seed of the target plant, the cultivation carrier for sowing the seed of the target plant, the soil for sowing the seed of the target plant, or the soil for transplanting the target plant grown on the cultivation carrier with a disease resistance inducer, Next, a method for controlling diseases of agricultural and horticultural plants, comprising spraying at least one agricultural and horticultural fungicide at a time after BBCH40.
- BBCH40以降の時期が、BBCH40~59である請求項1に記載の農園芸用植物の病害防除方法。 The method for controlling diseases of agricultural and horticultural plants according to claim 1, wherein the period after BBCH 40 is BBCH 40 to 59.
- BBCH40以降の時期が、BBCH60以降である請求項1に記載の農園芸用植物の病害防除方法。 The method for controlling diseases of agricultural and horticultural plants according to claim 1, wherein the time after BBCH40 is after BBCH60.
- 対象植物が穀類又は加工用作物類である請求項1~3のいずれか1項に記載の農園芸用植物の病害防除方法。 The method for controlling diseases of agricultural and horticultural plants according to any one of claims 1 to 3, wherein the target plant is a cereal or a crop for processing.
- 対象植物が小麦又は大麦である請求項1~3のいずれか1項に記載の農園芸用植物の病害防除方法。 The method for controlling diseases of agricultural and horticultural plants according to any one of claims 1 to 3, wherein the target plant is wheat or barley.
- 病害抵抗性誘導剤の有効成分が、
一般式(I):
R6は水素原子;(C1-C8)アルキル基;(C3-C6)シクロアルキル基;フェニル(C1-C6)アルキル基;ハロゲン原子、シアノ基、(C1-C6)アルキル基、ハロ(C1-C6)アルキル基、(C3-C6)シクロアルキル基、ハロ(C3-C6)シクロアルキル基、(C1-C6)アルコキシ基、ハロ(C1-C6)アルコキシ基、カルボキシル基及び(C1-C6)アルコキシカルボニル基からなる群より選択される1または同一もしくは異なっても良い2以上の置換基を有する置換フェニル(C1-C6)アルキル基;フェニル基;ハロゲン原子、シアノ基、(C1-C6)アルキル基、ハロ(C1-C6)アルキル基、(C3-C6)シクロアルキル基、ハロ(C3-C6)シクロアルキル基、(C1-C6)アルコキシ基、ハロ(C1-C6)アルコキシ基、カルボキシル基及び(C1-C6)アルコキシカルボニル基からなる群より選択される1または同一もしくは異なっても良い2以上の置換基を有する置換フェニル基を示す。
Yは酸素原子又は-N(R7)-(式中、R7は水素原子、(C1-C6)アルキル基、又は(C3-C6)シクロアルキル基を示す。)
Wは酸素原子又は硫黄原子を示す。}
で表される1,2,3-チアジアゾール誘導体若しくはその塩類である請求項1~5のいずれか1項に記載の農園芸用植物の病害防除方法。 The active ingredient of the disease resistance inducer is
Formula (I):
R 6 is a hydrogen atom; (C 1 -C 8 ) alkyl group; (C 3 -C 6 ) cycloalkyl group; phenyl (C 1 -C 6 ) alkyl group; halogen atom, cyano group, (C 1 -C 6 ) Alkyl group, halo (C 1 -C 6 ) alkyl group, (C 3 -C 6 ) cycloalkyl group, halo (C 3 -C 6 ) cycloalkyl group, (C 1 -C 6 ) alkoxy group, halo ( A substituted phenyl having one or more substituents which may be the same or different, selected from the group consisting of a C 1 -C 6 ) alkoxy group, a carboxyl group and a (C 1 -C 6 ) alkoxycarbonyl group (C 1- C 6 ) alkyl group; phenyl group; halogen atom, cyano group, (C 1 -C 6 ) alkyl group, halo (C 1 -C 6 ) alkyl group, (C 3 -C 6 ) cycloalkyl group, halo (C 3 -C ) Cycloalkyl group, (C 1 -C 6) alkoxy groups, halo (C 1 -C 6) alkoxy groups, 1 or the same or is selected from the group consisting of carboxyl group and (C 1 -C 6) alkoxycarbonyl group A substituted phenyl group having two or more substituents which may be different is shown.
Y represents an oxygen atom or —N (R 7 ) — (wherein R 7 represents a hydrogen atom, a (C 1 -C 6 ) alkyl group, or a (C 3 -C 6 ) cycloalkyl group).
W represents an oxygen atom or a sulfur atom. }
The method for controlling diseases of agricultural and horticultural plants according to any one of claims 1 to 5, which is a 1,2,3-thiadiazole derivative represented by the formula: - 病害抵抗性誘導剤の有効成分が、チアジニル、アシベンゾラル-S-メチル、プロベナゾール、NCI、INA、BIT及びイソチアニルである請求項1~6のいずれか1項に記載の農園芸用植物の病害防除方法。 The method for controlling diseases of agricultural and horticultural plants according to any one of claims 1 to 6, wherein the active ingredient of the disease resistance inducer is thiazinyl, acibenzoral-S-methyl, probenazole, NCI, INA, BIT and isothianyl. .
- 病害抵抗性誘導剤の有効成分の有効量が対象植物の種子100重量部に対して0.0001~1重量部である請求項1~7のいずれか1項に記載の農園芸用植物の病害防除方法。 The disease of an agro-horticultural plant according to any one of claims 1 to 7, wherein the effective amount of the active ingredient of the disease resistance inducer is 0.0001 to 1 part by weight with respect to 100 parts by weight of the seed of the target plant. Control method.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2008297692 | 2008-11-21 | ||
JP2008-297692 | 2008-11-21 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2010058830A1 true WO2010058830A1 (en) | 2010-05-27 |
Family
ID=42198269
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2009/069679 WO2010058830A1 (en) | 2008-11-21 | 2009-11-20 | Method for controlling agricultural and horticultural plant disease |
Country Status (1)
Country | Link |
---|---|
WO (1) | WO2010058830A1 (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013107785A1 (en) * | 2012-01-21 | 2013-07-25 | Bayer Intellectual Property Gmbh | Use of host defense inducers for controlling bacterial harmful organisms in useful plants |
WO2014050773A1 (en) * | 2012-09-28 | 2014-04-03 | 住友化学株式会社 | Method for preventing/controlling rice diseases |
WO2018116073A1 (en) | 2016-12-21 | 2018-06-28 | Pi Industries Ltd. | 1, 2, 3-thiadiazole compounds and their use as crop protecting agent |
WO2020090603A1 (en) * | 2018-10-31 | 2020-05-07 | クミアイ化学工業株式会社 | Method for preventing diseases in wheat, wheat seed, and method for inhibiting lodging damage in wheat |
CN115885801A (en) * | 2022-12-23 | 2023-04-04 | 吉林省农业科学院 | Method for reducing harm of peanut net blotch |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11512405A (en) * | 1995-09-13 | 1999-10-26 | ビーエーエスエフ アクチェンゲゼルシャフト | Germicidal mixture |
JP2000501400A (en) * | 1995-12-07 | 2000-02-08 | バイエル・アクチエンゲゼルシヤフト | 1,2,3-thiadiazolecarboxylic acid (thio) esters and their use as pesticides or microbicides |
JP2000103710A (en) * | 1998-07-30 | 2000-04-11 | Nippon Nohyaku Co Ltd | Germicidal composition and its use |
JP2007099749A (en) * | 2005-02-24 | 2007-04-19 | Nippon Nohyaku Co Ltd | 4-cyclopropyl-1,2,3-thiadiazole derivative, agrohorticultural plant disease controlling agent, and method for using the same |
JP2007254317A (en) * | 2006-03-22 | 2007-10-04 | Nippon Nohyaku Co Ltd | Crop-increasing agent and method for using the same |
-
2009
- 2009-11-20 WO PCT/JP2009/069679 patent/WO2010058830A1/en active Application Filing
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11512405A (en) * | 1995-09-13 | 1999-10-26 | ビーエーエスエフ アクチェンゲゼルシャフト | Germicidal mixture |
JP2000501400A (en) * | 1995-12-07 | 2000-02-08 | バイエル・アクチエンゲゼルシヤフト | 1,2,3-thiadiazolecarboxylic acid (thio) esters and their use as pesticides or microbicides |
JP2000103710A (en) * | 1998-07-30 | 2000-04-11 | Nippon Nohyaku Co Ltd | Germicidal composition and its use |
JP2007099749A (en) * | 2005-02-24 | 2007-04-19 | Nippon Nohyaku Co Ltd | 4-cyclopropyl-1,2,3-thiadiazole derivative, agrohorticultural plant disease controlling agent, and method for using the same |
JP2007254317A (en) * | 2006-03-22 | 2007-10-04 | Nippon Nohyaku Co Ltd | Crop-increasing agent and method for using the same |
Non-Patent Citations (3)
Title |
---|
NOGYO GIJUTSU, vol. 60, no. 4, 2005, pages 145 - 149 * |
SHIN NOYAKU KAIHATSU NO SAIZENSEN -SEIBUTSU SEIGYO KAGAKU ENO TENKAI-, 1ST PRINT, 30 May 2003 (2003-05-30), pages 57 - 60 * |
SHOKUCHO, vol. 36, no. 2, 2002, pages 53 - 62 * |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2015504077A (en) * | 2012-01-21 | 2015-02-05 | バイエル・インテレクチユアル・プロパテイー・ゲー・エム・ベー・ハー | Use of host defense inducers to control bacterial harmful microorganisms in useful plants |
JP2017222661A (en) * | 2012-01-21 | 2017-12-21 | バイエル・インテレクチュアル・プロパティ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツングBayer Intellectual Property GmbH | Use of host defense inducers for controlling bacterial harmful organisms in useful plants |
WO2013107785A1 (en) * | 2012-01-21 | 2013-07-25 | Bayer Intellectual Property Gmbh | Use of host defense inducers for controlling bacterial harmful organisms in useful plants |
US20150011394A1 (en) * | 2012-01-21 | 2015-01-08 | Bayer Intellectual Property Gmbh | Use of host defense inducers for controlling bacterial harmful organisms in useful plants |
CN104661528B (en) * | 2012-09-28 | 2017-11-17 | 住友化学株式会社 | The method of control of rice disease |
CN104661528A (en) * | 2012-09-28 | 2015-05-27 | 住友化学株式会社 | Method for preventing/controlling rice diseases |
JP2014070033A (en) * | 2012-09-28 | 2014-04-21 | Sumitomo Chemical Co Ltd | Method for controlling rice diseases |
WO2014050773A1 (en) * | 2012-09-28 | 2014-04-03 | 住友化学株式会社 | Method for preventing/controlling rice diseases |
WO2018116073A1 (en) | 2016-12-21 | 2018-06-28 | Pi Industries Ltd. | 1, 2, 3-thiadiazole compounds and their use as crop protecting agent |
WO2020090603A1 (en) * | 2018-10-31 | 2020-05-07 | クミアイ化学工業株式会社 | Method for preventing diseases in wheat, wheat seed, and method for inhibiting lodging damage in wheat |
CN112955008A (en) * | 2018-10-31 | 2021-06-11 | 组合化学工业株式会社 | Method for preventing and treating wheat diseases, wheat seeds and method for suppressing lodging loss of wheat |
JPWO2020090603A1 (en) * | 2018-10-31 | 2021-09-30 | クミアイ化学工業株式会社 | Pest control method for wheat, seeds for wheat and lodging damage control method for wheat |
CN112955008B (en) * | 2018-10-31 | 2023-07-14 | 组合化学工业株式会社 | Prevention and control method for wheat diseases, wheat seeds and inhibition method for lodging loss of wheat |
JP7524067B2 (en) | 2018-10-31 | 2024-07-29 | クミアイ化学工業株式会社 | Method for controlling wheat and barley diseases, wheat and barley seeds, and method for suppressing lodging damage to wheat and barley |
CN115885801A (en) * | 2022-12-23 | 2023-04-04 | 吉林省农业科学院 | Method for reducing harm of peanut net blotch |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6359551B2 (en) | Three-way disinfectant mixture | |
JP5254957B2 (en) | Nematicide composition and method of use thereof | |
RU2165144C1 (en) | Fungicide composition, method of control of plant disease | |
DK2356905T3 (en) | Synergistic fungicidal combination of active | |
EA016506B1 (en) | Method of seed treatment for protecting plants after germination from the attack of foliar phytopathogenic fungi by use of arylcarboxylic acid biphenylamides | |
WO2015135421A1 (en) | Fungicidal composition | |
WO2010055909A1 (en) | Pest control agent composition for agricultural and horticultural use | |
WO2010058830A1 (en) | Method for controlling agricultural and horticultural plant disease | |
CN114223665A (en) | Application of bactericidal composition in preventing and treating plant pathogenic fungi | |
WO2015135422A1 (en) | Method for protecting plant against plant disease | |
JP2000103710A (en) | Germicidal composition and its use | |
JP2006282553A (en) | Agricultural and horticultural fungicide composition and use method thereof | |
JP2008143875A (en) | Agricultural and horticultural fungicidal composition, use thereof, agricultural and horticultural disease control method and use of inorganic copper compound therefor, | |
CN107593710B (en) | Bactericidal composition | |
JPWO2009069676A1 (en) | Agricultural and horticultural insecticide composition | |
JPS6368505A (en) | Agricultural, insecticidal and germicidal composition | |
CN106982851B (en) | Bactericidal composition | |
CN106982842B (en) | Bactericidal composition | |
JP2017078026A (en) | Pest control method and control agent | |
KR101795850B1 (en) | Acaricide and nematocide composition comprising 2-(1-undecyloxy)-1-ethanol | |
JP2019026616A (en) | Bactericide for agricultural and horticultural use containing benzoxazinone compound as active ingredient | |
CN107637601B (en) | Bactericidal composition | |
CN107593711B (en) | Bactericidal composition | |
JP2019026575A (en) | Novel compound and bactericide for agricultural and horticultural use containing the same as active ingredient | |
JPS60260572A (en) | Imidazole derivative and fungicide for agricultural and horticultural use |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 09827611 Country of ref document: EP Kind code of ref document: A1 |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 09827611 Country of ref document: EP Kind code of ref document: A1 |
|
NENP | Non-entry into the national phase |
Ref country code: JP |