JP2005213270A - Method for suppressing generation of spotted paddy rice caused by stink bug - Google Patents

Method for suppressing generation of spotted paddy rice caused by stink bug Download PDF

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JP2005213270A
JP2005213270A JP2005110204A JP2005110204A JP2005213270A JP 2005213270 A JP2005213270 A JP 2005213270A JP 2005110204 A JP2005110204 A JP 2005110204A JP 2005110204 A JP2005110204 A JP 2005110204A JP 2005213270 A JP2005213270 A JP 2005213270A
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stink bugs
rice
spotted
methyl
compound
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JP2005213270A5 (en
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Hidekazu Yamada
英一 山田
Yukio Kiritani
幸生 桐谷
Nobuyuki Kawahara
信行 河原
Takashi Watanabe
渡辺  孝
Oma Oe
桜麻 大江
Atsuko Kawahara
敦子 河原
Masahiko Nakamura
雅彦 中村
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Mitsui Chemicals Inc
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Mitsui Chemicals Inc
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for suppressing the generation of spotted paddy rice caused by stink bugs, capable of preventing a worker from being exposed to chemical agents and reducing chemical load to the environment and excellent in workability. <P>SOLUTION: This method for suppressing the generation of spotted paddy rice caused by stink bugs comprises applying to the water surface of a paddy field a composition containing at least one compound having penetrating and migrating properties and expressing an inhibitory effect on sapping of stink bugs. In the method, the compound is a nitromethylene-based insecticide, a nitroimino-based insecticide, a cyanoimino-based insecticide or an insecticide having phenylpyrazole skeleton. The nitromethylene-based insecticide is nitenpyram, the nitroimino-based insecticide is imidacloprid, dinotefuran, thiamethoxam or clothianidin, the cyanoimino-based insecticide is thiacloprid, the nitrocyano-based insecticide is acetamiprid and the phenylpyrazole skeleton-having insecticide is fipronyl, ethiprole or acetoprole. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、カメムシ類による水稲斑点米の生成を抑制する方法に関する。詳しくはカメムシ類の水稲の穂への加害を防止し、水稲斑点米の生成を抑制する方法に関する。   The present invention relates to a method for inhibiting the production of spotted rice by stink bugs. More specifically, the present invention relates to a method for preventing the occurrence of stink bugs on the ears of paddy rice and suppressing the production of spotted rice.

水稲に対する多くの害虫のうち、米の収穫や品質に重大な影響を及ぼす害虫として、ウンカ類やカメムシ類などの半翅目害虫がある。その中で、カメムシ類は近年、水稲の穂を加害し、収穫した米の品質を低下させる害虫として問題となり、難防除害虫となっている。ウンカ類の水稲に及ぼす影響とカメムシ類の水稲に及ぼす影響を比較すると、両者の水稲に及ぼす影響は大きく異なる。すなわち、ウンカ類はある程度の発生密度に達しないと水稲に対する被害が顕在化しない。それに対して、カメムシ類は非常に少ない発生密度でも、収穫した米の品質に対して、重大な被害が出る。一般に米1000粒中、2個以上の米粒にカメムシ類による吸汁痕があると、斑点米として、米の等級が下がる。また、1アール当たりに2、3頭のカメムシ類の存在が確認されると、そのカメムシが水稲の穂を吸汁し、その結果、収穫した米の品質に重大な被害が出る。そのため、カメムシ類の防除はウンカ類の防除と比べて、極めて高い防除効果を要求される。   Among the many insect pests on rice, there are hemipods such as planthoppers and stink bugs that have a significant effect on the harvest and quality of rice. Among them, stink bugs have recently become a problem as a pest that damages the ears of paddy rice and degrades the quality of the harvested rice, making it difficult to control. Comparing the effects of planthoppers on paddy rice and the effects of stink bugs on paddy rice, the effects of both on paddy rice are very different. In other words, the damage to paddy rice does not become obvious unless the planthoppers reach a certain density. On the other hand, stink bugs cause serious damage to the quality of harvested rice even at very low density. In general, if two or more rice grains in 1000 rice grains have a sucking trace due to stink bugs, the grade of the rice is lowered as spotted rice. In addition, if a few stink bugs are confirmed per are, the stink bug sucks the ears of paddy rice, resulting in serious damage to the quality of the harvested rice. Therefore, the control of stink bugs is required to have a very high control effect compared to the control of planthoppers.

これらのカメムシ類は、歩行或いは飛び込みにより水田に入り込み、増殖を繰り返して稲の穂、また、ある種のカメムシ類は茎部を加害する。一般的には、水稲の開花から収穫期に被害が発生する。   These stink bugs enter the paddy field by walking or jumping in and repeat the multiplication, and the ears of rice and certain stink bugs injure the stem. Generally, damage occurs from the flowering of paddy rice to the harvesting season.

カメムシ類の防除は、カメムシ類の発生が予期される時期に、散布器を用いた薬剤散布や或いは、航空機で薬剤を散布する方法で行なわれている。すなわち、出穂期、乳熟期或いは黄熟期にかけて粉剤、液剤等を2〜3回、散布することでカメムシ類の防除を行っている。この防除方法では、カメムシ類を完璧に防除するために、2〜3回の農薬散布を行う必要があり、人手や防除費用の面からも十分なものではなかった。また、散布器や航空機による薬剤散布は乳剤、水和剤、粉剤などをカメムシ類が存在する茎葉部に直接散布する方法であり、散布時における作業者の薬剤被爆、作業条件の困苦、水田以外の環境への拡散、散布効果維持の為に過剰量の薬剤の使用、降雨による防除効果の低下や防除適期の逸脱、作業効率が悪いなど、多くの解決すべき課題を抱えている。   Control of stink bugs is carried out by spraying drugs using a sprayer or by spraying drugs using an aircraft at the time when stink bugs are expected to occur. That is, stink bugs are controlled by spraying powder, liquid, etc. 2-3 times during heading, milk ripening or yellow ripening. In this control method, in order to completely control stink bugs, it was necessary to spray agricultural chemicals two to three times, which was not sufficient in terms of manpower and control costs. In addition, chemical spraying by sprayers and aircraft is a method in which emulsion, wettable powder, powder, etc. are sprayed directly on the foliage where stink bugs are present. The chemical exposure of workers during spraying, difficult working conditions, other than paddy fields There are many problems to be solved, such as the diffusion of the chemicals into the environment, the use of an excessive amount of chemicals to maintain the spraying effect, the deterioration of the control effect due to rainfall, the deviation from the appropriate control time, and the poor work efficiency.

最近、イミダクロプリド、ニテンピラム、チアメトキサム、チアクロプリド、クロチアニジン、アセアタミプリド、ジノテフランなどのニトロメチレン系殺虫剤、ニトロイミノ系殺虫剤、シアノイミノ系殺虫剤や、フィプロニル、エチプロール、アセトプロールなどのフェニルピラゾール骨格を有する殺虫剤など、浸透移行性を有する殺虫剤が水稲の害虫防除用殺虫剤として開発されている。(特開昭61−267575、特開平4−154741、特開平3−157308、特開平6−183918、特開平7−179448、特開昭63−316771、特開平6−271408、など。)
これらの殺虫剤は散布剤、水面施用剤の剤型で、ウンカ類などの水稲の害虫防除に使用できる。また、これらの殺虫剤の一部がカメムシ類に対して殺虫効果のあることも該公報などに記載されている。しかし、これら公報にはカメムシ類による水稲の穂の吸汁を防止することやそれによりカメムシ類による水稲斑点米の生成を防除することに関しては何も開示されていない。
Recently, nitromethylene insecticides such as imidacloprid, nitenpyram, thiamethoxam, thiacloprid, clothianidin, acetamiprid, dinotefuran, etc., insecticides having phenylpyrazole skeletons such as fipronil, ethiprole, acetoprole, etc. Insecticides having osmotic transfer properties have been developed as pest control insecticides for paddy rice. (Japanese Patent Laid-Open Nos. 61-267575, 4-154471, 3-157308, 6-183918, 7-179448, 63-316771, 6-271408, etc.)
These insecticides are in the form of spraying agent and water surface application agent, and can be used for pest control of paddy rice such as planthoppers. It is also described in the publication that some of these insecticides have an insecticidal effect against stink bugs. However, these publications do not disclose anything about preventing the sucking of paddy rice ears by stink bugs and thereby controlling the production of spotted rice by stink bugs.

特開昭61−267575号公報JP-A 61-267575 特開平04−154741号公報Japanese Patent Laid-Open No. 04-154741 特開平03−157308号公報JP 03-157308 A 特開平06−183918号公報Japanese Patent Laid-Open No. 06-183918 特開平07−179448号公報Japanese Unexamined Patent Publication No. 07-179448 特開昭63−316771号公報JP-A-63-316771 特開平06−271408号公報Japanese Patent Laid-Open No. 06-271408

本発明は従来の散布器を使用した殺虫剤散布方法によるカメムシ類の防除の問題点を解決し、作業者への薬剤被爆防止、作業条件の改善、環境への拡散防止、天候に左右されないなど、作業性に優れたカメムシ類による水稲斑点米の生成を抑制する方法を提供することを目的とし、更に本発明は、殺虫剤を水面に処理する方法によるカメムシ類の水稲の穂に対する吸汁を防止する方法、更にはカメムシ類が水稲の穂を吸汁することで引き起こされる、水稲斑点米の生成を抑制する方法を提供することを目的とする。   The present invention solves the problems of control of stink bugs by insecticide spraying methods using conventional sprayers, prevents chemical exposure to workers, improves working conditions, prevents diffusion to the environment, is not affected by the weather, etc. An object of the present invention is to provide a method for suppressing the production of spotted rice by stink bugs with excellent workability, and the present invention further prevents the stink bugs from sucking the ears of rice by the method of treating insecticide on the water surface. It is another object of the present invention to provide a method for suppressing the production of spotted rice caused by sucking rice ears by stink bugs.

本発明者らは、浸透移行性を有する化合物を含有する組成物の水面施用方法による、カメムシ類の水稲の穂に対する吸汁を防止する方法に関して鋭意検討した結果、浸透移行性を有する化合物を水面に処理すると、カメムシ類に対して吸汁阻害効果があること、及び、カメムシ類を完全に死に至らしめなくても、カメムシ類の水稲の穂に対する吸汁を十分に防止できること、更にその結果、水稲斑点米の生成を抑制できることを見い出し、本発明を完成させた。   As a result of earnestly examining the method for preventing the sucking of stink bugs on the ears of rice by the water surface application method of the composition containing the compound having osmotic transferability, the present inventors have found that the compound having osmotic transferability on the water surface. When treated, it has a sucking-inhibiting effect on stink bugs, and it can sufficiently prevent the stink bugs from sucking on the ears of rice without causing the stink bugs to die completely. The present invention has been completed by finding that the production of can be suppressed.

すなわち、本発明は、浸透移行性を有し、且つ、カメムシ類に吸汁阻害作用を示す、少なくとも1種類以上の化合物を含有する組成物を水田の水面に施用することを特徴とする、カメムシ類による水稲斑点米の生成を抑制する方法である。   That is, the present invention relates to a stink bug characterized by applying a composition containing at least one kind of compound having osmotic transfer properties and exhibiting a sucking inhibitory action to stink bugs to the water surface of a paddy field. This is a method for suppressing the production of spotted rice by paddy rice.

本発明の方法はカメムシ類の水稲の穂に対する加害を防止し、その結果、斑点米の生成を効果的に抑制することができ、米の品質確保に貢献できる。
また、本発明の方法は薬剤を水面に施用するので、作業者への薬剤被爆防止、作業条件の改善、環境への拡散防止、天候に左右されないなど、従来のカメムシ類の防除方法の問題点を解決し、作業の簡便化、作業条件の改善などに寄与することができる。
更に、本発明の方法においてはカメムシを殺虫するための薬剤の施用量よりも少ない量でカメムシの水稲の穂の吸汁阻害が起こるため、従来の農薬の施用量よりも少ない薬剤量で十分な効果が得られ、防除コストの低減や土壌の環境汚染を防止できる。
The method of the present invention prevents the damage of stink bugs to the ears of paddy rice, and as a result, can effectively suppress the production of speckled rice and contribute to ensuring the quality of rice.
In addition, since the method of the present invention applies a chemical to the surface of the water, there are problems with conventional control methods for stink bugs, such as prevention of chemical exposure to workers, improvement of working conditions, prevention of diffusion to the environment, and independence from the weather. This can contribute to the simplification of work and the improvement of work conditions.
Furthermore, in the method of the present invention, the absorption of the ears of the ears of stink bug rice is inhibited in an amount smaller than the dose of the drug for killing stink bugs, so that a sufficient amount of the drug is less effective than the dose of the conventional agricultural chemical. Can be obtained, and control costs can be reduced and soil pollution can be prevented.

本発明で用いるカメムシ類に防除効果を示す化合物は、浸透移行性を有し、且つカメムシ類に対して吸汁阻害作用を示す化合物である。本発明で言う、浸透移行性を有する化合物は、活性化合物が植物の根や茎葉から吸収されて、植物の他の部位へ移行し、害虫が茎や葉を吸汁あるいは食することで、害虫を死に至らしめる作用を有する化合物である。本発明で言う、浸透移行性を有し、且つカメムシ類に対して吸汁阻害作用を示す化合物は、該化合物が植物体内を浸透移行し、その結果、カメムシ類を完全に死に至らしめなくても、カメムシ類の積極的な吸汁を阻止できる化合物を意味している。そのようなものは従来より殺虫性化合物として知られているものを含んでいる。本発明の方法に使用される化合物としては具体的に、イミダクロプリド、3-(2-クロロチアゾール-5-イルメチル)-5-メチル-1,3,5-オキサジアジナン-4-イリデン-N-(ニトロ)アミン(一般名チアメトキサム)、(RS)-1-メチル-2-ニトロ-3-[(3-テトラヒドロフリル)メチル]グアニジン(一般名ジノテフラン)、(E)-1-(2-クロロ-1,3-チアゾール-5-イルメチル)-3-メチル-2-ニトログアニジン(一般名クロチアニジン)などのニトロイミノ系殺虫剤、ニテンピラムなどのニトロメチレン系殺虫剤、アセタミプリド、N-[3-(6-クロロピリジン-3-イルメチル)チアゾリジン-2-イリデン]シアナミド(一般名チアクロプリド)などのシアノイミノ系殺虫剤やフィプロニル、5-アミノ-1-(2,6-ジクロル-α,α,α-トリフルオロ-p-トリル)-4-エチルスルフィニルピラゾール-3-カルボニトリル(一般名エチプロール)、1-[5-アミノ-1-(2,6-ジクロル-α,α,α-トリフルオロ-p-トリル)-4-メチルスルフィニルピラゾール-3-イル]エタノン(一般名アセトプロール)などのフェニルピラゾール骨格を有する殺虫剤があげられるが、浸透移行性を有し、且つカメムシ類に対して吸汁阻害作用を示す化合物であれば、これらに限定されるものではない。本発明の方法においては、これらの化合物を単独で、または2種以上を混合してカメムシ類に対して水面に施用する。   The compound showing the control effect on stink bugs used in the present invention is a compound having osmotic transfer properties and showing a sucking inhibitory action on stink bugs. According to the present invention, the compound having osmotic transfer property is that the active compound is absorbed from the roots and foliage of the plant and transferred to other parts of the plant, and the pests absorb the pests and leaves to eat or eat the pests. It is a compound that has the effect of causing death. According to the present invention, the compound having osmotic transfer properties and exhibiting a sucking inhibitory action against stink bugs, the compound permeates and transfers through the plant body, and as a result, the stink bugs do not completely die. , Meaning a compound that can prevent the positive sucking of stink bugs. Such include those conventionally known as insecticidal compounds. Specific examples of compounds used in the method of the present invention include imidacloprid, 3- (2-chlorothiazol-5-ylmethyl) -5-methyl-1,3,5-oxadiazinan-4-ylidene-N- (nitro ) Amine (generic name thiamethoxam), (RS) -1-methyl-2-nitro-3-[(3-tetrahydrofuryl) methyl] guanidine (generic name dinotefuran), (E) -1- (2-chloro-1) , 3-thiazol-5-ylmethyl) -3-methyl-2-nitroguanidine (generic name clothianidin) and other nitroimino insecticides, nitromethylene insecticides such as nitenpyram, acetamiprid, N- [3- (6-chloro Cyanoimino insecticides such as pyridin-3-ylmethyl) thiazolidine-2-ylidene] cyanamide (generic name thiacloprid) and fipronil, 5-amino-1- (2,6-dichloro-α, α, α-trifluoro-p -Tolyl) -4-ethylsulfinylpyrazole-3-carbonitrile ( (Generic name ethiprole), 1- [5-amino-1- (2,6-dichloro-α, α, α-trifluoro-p-tolyl) -4-methylsulfinylpyrazol-3-yl] ethanone (generic name aceto) Insecticides having a phenylpyrazole skeleton such as (Prolol) can be mentioned, but the compound is not limited to these as long as it is a compound having osmotic transfer properties and a sucking inhibitory action against stink bugs. In the method of the present invention, these compounds are applied to the surface of water against stink bugs alone or in admixture of two or more.

カメムシ類の水稲の穂に対する吸汁を防止するために、浸透移行性を有し、且つカメムシ類に対して吸汁阻害作用を示す化合物は、カメムシ類の吸汁阻害効果が出る薬量以上を、水面に施用すればよい。具体的には、10アール当たり、1g以上の活性成分を水面に施用すれば、活性成分が水稲へ浸透移行して、カメムシ類に吸汁阻害効果が出る。活性成分を多く施用しても、カメムシ類の吸汁阻害効果の発現に影響はないが、経済的な観点から、100g以下の施用量で十分である。好ましくは、10アールあたり、10g以上70g以下の活性成分の施用量で十分である。浸透移行性を有し、且つカメムシ類に対して吸汁阻害作用を示す化合物が殺虫剤である場合には、これら施用量は該殺虫剤が殺虫効果を示す量よりも一般的に少ない量で十分である。   In order to prevent the stink bugs from sucking into the rice ears, compounds that have osmotic transfer properties and have a sucking inhibitory action against stink bugs can be used on the surface more than the dosage that produces the stink bug sucking inhibitory effect. What is necessary is just to apply. Specifically, if 1 g or more of active ingredient is applied to the water surface per 10 ares, the active ingredient permeates and transfers to paddy rice, and stink bugs have a sucking inhibitory effect. Even if a large amount of active ingredient is applied, it does not affect the expression of stink bug sucking inhibitory effect, but an application amount of 100 g or less is sufficient from an economical point of view. Preferably, an application amount of 10 g or more and 70 g or less of active ingredient per 10 ares is sufficient. If the compound that has osmotic transfer properties and exhibits a sucking inhibitory action against stink bugs is an insecticide, these doses are generally sufficient in amounts less than the amount that the insecticide exhibits an insecticidal effect. It is.

本発明の、浸透移行性を有し、且つ、カメムシ類に吸汁阻害作用を示す化合物を含有する組成物を水面に施用する時期は、水稲の生育期間内であれば、いつでもよいが、好ましくは、水稲の分けつ時期から黄熟期の間に該殺虫剤を水面に処理すれば、効果的にカメムシ類の水稲の穂に対する吸汁を防止することができる。更に好ましくは、水稲の出穂30日前から出穂20日後の期間に該殺虫剤を処理すればよい。本願の方法は通常、1回の処理で、十分にカメムシ類の水稲の穂に対する吸汁を防除することができるが、カメムシ類の発生状況に応じて、2回以上、水面に処理しても、何ら問題はない。   The timing of applying to the water surface the composition containing the compound having osmotic transfer properties and having a sucking inhibitory action on stink bugs of the present invention may be any time as long as it is within the growing period of paddy rice, preferably If the insecticide is treated on the surface of the water during the period from the time when the rice is divided to the time of yellow ripening, it is possible to effectively prevent stink bugs from sucking the rice. More preferably, the insecticide may be treated during a period from 30 days before heading of rice to 20 days after heading. The method of the present application is usually able to control the sucking of the ears of stink bugs in a single treatment, but depending on the occurrence of stink bugs, even if treated on the water surface, There is no problem.

本発明で言う、カメムシ類の水稲の穂に対する吸汁を防止する方法は、浸透移行性を有し、且つ、カメムシ類に吸汁阻害作用を示す化合物を含有する組成物を水面に施用する方法である。ここで言う、水面に施用する方法とは、該化合物を固体製剤、液体製剤等の組成物の形態で、水面に直接施用することを意味している。該化合物の固体製剤は直接水面に施用するか、あるいは、水に懸濁し、少量且つ高濃度状態の液体あるいは懸濁液の状態で水面に施用する。畦畔から手振り散布、パック等に粒剤を封入し、これを投与する方法、水口からの水の流入拡散を利用した水口処理等の方法が挙げられる。該化合物の液状製剤も固体製剤と同様に水面に処理する。水面への施用が可能な固体製剤は、粒剤、ジャンボ剤、水和剤、顆粒水和剤、顆粒水溶剤、粉剤等が挙げられる。また、これらをPVAなどの水溶性フィルム等でパックした剤型も使用できる。水面に施用が可能な液体製剤は、乳剤、液剤、油剤、フロアブル剤、エマルジョン剤,マイクロエマルジョン剤、サスポエマルジョン剤、マイクロカプセル剤等である。いかなる剤型においても、浸透移行性を有し、且つ、カメムシ類に吸汁阻害作用を示す殺虫剤を水面に施用すれば、該化合物が水稲植物内へ浸透移行し、カメムシ類の水稲の穂に対する吸汁を防止することができる。   According to the present invention, the method of preventing stink bugs from sucking rice ears is a method of applying to the water surface a composition containing a compound having osmotic transfer properties and a stink bug inhibiting action on stink bugs. . As used herein, the method of applying to the water surface means applying the compound directly to the water surface in the form of a composition such as a solid preparation or a liquid preparation. The solid preparation of the compound is applied directly to the water surface, or suspended in water and applied to the water surface in the form of a small amount of liquid or suspension in a high concentration state. Examples include a method of spraying a hand from the shore, a method of encapsulating a granule in a pack and the like, a method of administering this, and a method of water mouth treatment using inflow diffusion of water from the water mouth. The liquid preparation of the compound is treated on the water surface in the same manner as the solid preparation. Examples of solid preparations that can be applied to the water surface include granules, jumbo agents, wettable powders, granular wettable powders, granular water solvents, and powders. Moreover, the dosage form which packed these with water-soluble films, such as PVA, can also be used. Liquid preparations that can be applied to the water surface include emulsions, solutions, oils, flowables, emulsions, microemulsions, suspoemulsions, microcapsules and the like. In any dosage form, when an insecticide that has osmotic transfer properties and exhibits a sucking-inhibiting action on stink bugs is applied to the water surface, the compound permeates into the rice plant and the stink bugs against the ears of paddy rice Absorption can be prevented.

本発明の方法で、効果的に、且つ簡易にカメムシ類による水稲の穂に対する吸汁を防止できる。ここで言う、水稲の穂に対する吸汁を防止できるカメムシ類として、例えば、以下のものが挙げられる。ナカグロメクラガメ、ブチヒゲクロメクラガメ、アカホシメクラガメ、ハナグロミドリメクラガメ、マダラメクラガメ、マキバメクラガメ、アカスジメクラガメ、ムギメクラガメ、アカミャクメクラガメ、ナカムギメクラガメ、アカヒゲホソミドリメクラガメ等のメクラカメムシ科、メダカバガカメムシ等のメダカナガカメムシ科、ヒメヒラタナガカメムシ、モンシロナガカメムシ、ウスグロシロヘリナガカメムシ、シロヘリナガカメムシ、アムールシロヘリナガカメムシ、チャイロナガカメムシ、ヒメナガカメムシ、ミナミホソナガカメムシ、クロアシホソナガカメムシ、キベリヒョウタンナガカメムシ、ヒラタヒョウタンナガカメムシ、サビヒョウタンナガカメムシ、ヒゲナガカメムシ、ヨツボシヒョウタンナガカメムシ、マダラナガカメムシ、コバネヒョウタンナガカメムシ等のナガカメムシ科、フタモンホシカメムシ等のホシカメムシ科、アズキヘリカメムシ、ヒメハリカメムシ、ハリカメムシ、ホソハリカメムシ、ホシハラビロヘリカメムシ等のヘリカメムシ科、ヒメクモヘリカメムシ、クモヘリカメムシ、タイワンクモヘリカメムシ、ホソヘリカメムシ等のホソヘリカメムシ科、アカヒメヘリカメムシ、ケブカヒメヘリカメムシ、スカシヒメヘリカメムシ、ブチヒゲヘリカメムシ等のヒメヘリカメムシ科、チャイロカメムシ等のキンカメムシ科、エビイロカメムシ、ウズラカメムシ、トゲカメムシ、ムラサキカメムシ、ブチヒゲカメムシ、ハナダカカメムシ、ムラサキシラホシカメムシ、マルシラホシカメムシ、オオトゲシラホシカメムシ、トゲシラホシカメムシ、シラホシカメムシ、クサギカメムシイネカメムシ、ツマジロカメムシ、アオクサカメムシ、ミナミアオカメムシ、エゾアオカメムシ、イチモンジカメムシ、チャバネアオカメムシ、アカカメムシ、イネクロカメムシ、イワサキカメムシ等のカメムシ類が挙げられる。本発明の方法は、これらのカメムシ類のうち、特に水稲の穂を吸汁するカメムシ類に対して効果的に、その吸汁を防止することができる。   By the method of the present invention, it is possible to effectively and simply prevent the soup from sucking rice ears by stink bugs. Examples of the stink bugs that can prevent the soup from sucking rice ears include the following. The winged turtle, the horned winged turtle, the red winged turtle, the yellow winged turtle, the spotted turtle, the winged turtle, the red turtle, the turtle, the turtle, , Medaka, stag beetle, stag beetle, horned beetle, horned beetle, white-headed beetle, white-headed beetle , Hirata Leopardus longhorn bug, Sabi Leopardus longhorn bug, Giant longhorn beetle, Vulgaria lepidoptera, Red spotted bug Bark beetles such as worms, kobanhyotanagamekamushi, horned beetles such as phlegm beetle, azuki bean bug, beetle beetle, beetle beetle, beetle, beetle beetle such as beetle beetle, beetle beetle, beetle beetle Spider helicoptercidae, Thai spider helicoptercidae, Hosohelimemushi, etc., Hosohelikamushi, Akahhimeheramemushi, Kebukahimeheramemushi, Scashihimeheramemushi, Himeherikamemushi, etc. Chrysomelidae, shrimp bug, quail stink bug, bark beetle, spotted stink bug, spotted beetle, spotted beetle, spotted shrimp bug, marshirahoshimemushi, otogeshirahoshimemushi, togeshirahoshimushi Hoshikamemushi, brown marmorated stink bug rice bug, garnishing Giro bugs, order Hemiptera, southern green stink bug, Ezo stali, Piezodorus bug, Plautia crossota stali, red bugs, rice black bugs and bugs such as Iwasaki stink bug like. The method of the present invention can effectively prevent the sucking of these stink bugs, particularly the stink bugs that suck the ears of paddy rice.

本発明の方法により、カメムシ類を完全に死に至らしめることなく、カメムシ類の積極的な吸汁活動を防止することができる。更には、水稲の穂に対する吸汁活動を防止することができる。その結果、水稲の穂に対するカメムシ類の吸汁活動によって引き起こされる、水稲斑点米の生成を抑制することができる。   By the method of the present invention, the positive sucking activity of stink bugs can be prevented without causing the stink bugs to die completely. Furthermore, it is possible to prevent sucking activity on the ears of paddy rice. As a result, it is possible to suppress the production of rice spotted rice caused by the sucking activity of stink bugs on the ears of rice.

本発明の方法に使用される組成物を実際に施用するにあたって、組成物は、必要に応じて、他の活性化合物、例えば殺菌剤や肥料等と混用して使用してもよい。更に、その他の活性化合物を含む場合、これらの活性化合物は、浸透移行性を有するものが好ましい。その代表例として、イソプロチオラン、フルトラニル、アゾキシストロビン、プロベナゾール、フラメトピル、チフルザミド、バリダマイシン、ピロキロン、メトミノストロビン、IBP、フサライド、カスガマイシン、カルプロパミド、ジクロメジン、トリシクラゾール、バリダマイシン、ペンシクロン、ポリオキシン、メプロニル、EDDPなどを例示できる。   In actually applying the composition used in the method of the present invention, the composition may be used in combination with other active compounds, for example, bactericides and fertilizers, if necessary. Furthermore, when other active compounds are included, these active compounds preferably have osmotic transfer properties. Representative examples thereof include isoprothiolane, flutolanil, azoxystrobin, probenazole, furamethpyr, tifluzamide, validamycin, pyroxylone, metminostrobin, IBP, fusalide, kasugamycin, carpropamide, dichromedin, tricyclazole, validamycin, pencyclon, mepronil, EDDP, etc. Can be illustrated.

本発明の方法に使用される組成物の製剤化にあたっては、何らの特別の条件を必要とせず、一般農薬に準じて当業技術の熟知する方法によって、粒剤、水和剤、顆粒水和剤、顆粒水溶剤、粉剤、乳剤、液剤、油剤、フロアブル剤、エマルジョン剤、マイクロエマルジョン剤、サスポエマルジョン剤、マイクロカプセル剤等の任意の剤型に調製することができる。   The formulation of the composition used in the method of the present invention does not require any special conditions, and granule, wettable powder, granule hydration is performed by a method familiar to those skilled in the art according to general agricultural chemicals. It can be prepared in any dosage form such as an agent, a granular water solvent, a powder, an emulsion, a liquid, an oil, a flowable, an emulsion, a microemulsion, a suspoemulsion, and a microcapsule.

かくして、浸透移行性を有し、且つ、カメムシ類に吸汁阻害作用を示す、少なくとも1種類以上の化合物を含有する組成物を水面に施用すれば、カメムシ類による水稲斑点米の生成を効果的に抑制できる他、農作業の簡便化、農作業に従事する作業者への薬剤被爆、環境への拡散、天候の影響など、従来の散布器を使用した防除方法の問題点を全て解決することができる。   Thus, if a composition containing at least one kind of compound that has osmotic transfer properties and exhibits a sucking inhibitory action on stink bugs is applied to the water surface, the production of spotted rice by stink bugs can be effectively performed. In addition to being able to control, all the problems of the conventional control method using a sprayer such as simplification of farm work, chemical exposure to workers engaged in farm work, diffusion to the environment, and influence of weather can be solved.

以下に製剤例及び試験例により本発明を更に詳細に説明する。尚、製剤例中の部は重量部を示す。   Hereinafter, the present invention will be described in more detail with reference to formulation examples and test examples. In addition, the part in a formulation example shows a weight part.

製剤例1
ジノテフランを10部、ソルポール355S(東邦化学製、界面活性剤)10部、ソルベッソ150(エクソン製)80部、以上を均一に撹拌混合して乳剤を得た。
Formulation Example 1
An emulsion was obtained by uniformly stirring and mixing 10 parts of dinotefuran, 10 parts of Solpol 355S (manufactured by Toho Chemical Co., Ltd., surfactant) and 80 parts of Solvesso 150 (manufactured by Exxon).

製剤例2
ジノテフランを10部、アルキルナフタレンスルホン酸ナトリウム2部、リグニンスルホン酸ナトリウム1部、ホワイトカーボン5部、ケイソウ土82部、以上を均一に撹拌混合して水和剤100部を得た。
Formulation Example 2
10 parts of dinotefuran, 2 parts of sodium alkylnaphthalene sulfonate, 1 part of sodium lignin sulfonate, 5 parts of white carbon, 82 parts of diatomaceous earth were uniformly stirred and mixed to obtain 100 parts of wettable powder.

製剤例3
ジノテフランを10部、ポリビニルアルコールの20%水溶液5部を充分撹拌混合した後、キサンタンガムの0.8%水溶液65部を加えて再び撹拌混合してフロアブル剤100部を得た。
Formulation Example 3
After 10 parts of dinotefuran and 5 parts of a 20% aqueous solution of polyvinyl alcohol were sufficiently stirred and mixed, 65 parts of a 0.8% aqueous solution of xanthan gum was added and stirred again to obtain 100 parts of a flowable agent.

製剤例4
ジノテフランを20部、尿素90部を部を均一に十分攪拌混合して水溶剤100部を得た。
Formulation Example 4
20 parts of dinotefuran and 90 parts of urea were uniformly and thoroughly mixed to obtain 100 parts of an aqueous solvent.

製剤例5
ジノテフランを1部、ホワイトカーボン2部、リグニンスルホン酸ナトリウム2部、ベントナイト95部、以上を均一に粉砕混合後、水を加えて混練し、造粒乾燥して粒剤100部を得た。
Formulation Example 5
1 part of dinotefuran, 2 parts of white carbon, 2 parts of sodium lignin sulfonate, 95 parts of bentonite were uniformly ground and mixed, then kneaded with water, granulated and dried to obtain 100 parts of granules.

製剤例6
チアクロプリドを1部、ホワイトカーボン2部、リグニンスルホン酸ナトリウム2部、ベントナイト95部、以上を均一に粉砕混合後、水を加えて混練し、造粒乾燥して粒剤100部を得た。
Formulation Example 6
1 part of thiacloprid, 2 parts of white carbon, 2 parts of sodium lignin sulfonate and 95 parts of bentonite were uniformly ground and mixed, then kneaded with water, granulated and dried to obtain 100 parts of granules.

製剤例7
チアメトキサムを1部、ホワイトカーボン2部、リグニンスルホン酸ナトリウム2部、ベントナイト95部、以上を均一に粉砕混合後、水を加えて混練し、造粒乾燥して粒剤100部を得た。
Formulation Example 7
1 part of thiamethoxam, 2 parts of white carbon, 2 parts of sodium lignin sulfonate and 95 parts of bentonite were uniformly ground and mixed, then kneaded with water, granulated and dried to obtain 100 parts of granules.

製剤例8
クロチアニジンを1部、ホワイトカーボン2部、リグニンスルホン酸ナトリウム2部、ベントナイト95部、以上を均一に粉砕混合後、水を加えて混練し、造粒乾燥して粒剤100部を得た。
Formulation Example 8
1 part of clothianidin, 2 parts of white carbon, 2 parts of sodium lignin sulfonate and 95 parts of bentonite were uniformly ground and mixed, then kneaded with water, granulated and dried to obtain 100 parts of granules.

製剤例9
エチプロールを1部、ホワイトカーボン2部、リグニンスルホン酸ナトリウム2部、ベントナイト95部、以上を均一に粉砕混合後、水を加えて混練し、造粒乾燥して粒剤100部を得た。
Formulation Example 9
1 part of Ethiprole, 2 parts of white carbon, 2 parts of sodium lignin sulfonate and 95 parts of bentonite were uniformly ground and mixed, then kneaded with water, granulated and dried to obtain 100 parts of granules.

製剤例10
アセトプロールを1部、ホワイトカーボン2部、リグニンスルホン酸ナトリウム2部、ベントナイト95部、以上を均一に粉砕混合後、水を加えて混練し、造粒乾燥して粒剤100部を得た。
Formulation Example 10
1 part of acetoprole, 2 parts of white carbon, 2 parts of sodium lignin sulfonate, 95 parts of bentonite, and the like were uniformly ground and mixed, then kneaded with water, granulated and dried to obtain 100 parts of granules.

試験例1 ポットでの出穂時処理におけるカメムシ類への効果
出穂時期のイネ(こしひかり:1/5000aポット:水深3cmで管理)に上記の製剤例5〜10で作成した粒剤、或いは市販品アドマイヤー1粒剤、ベストガード粒剤、モスピラン粒剤、プリンス粒剤を3kg/10a相当量散布した。処理7日後に穂の部分のみをゴースで覆い、ゴースの中にオオトゲシラホシカメムシを雄雌各5頭ずつ放飼した(1区3連制)。放飼6日後に生死判定を行った。更に収穫時、斑点米の調査を行った。試験の結果、死虫率が不十分でカメムシが死滅しなくても、十分な吸汁阻害作用を示す事がわかった。
Test Example 1 Effects on stink bugs in heading treatment in pots Grains prepared in Formulation Examples 5 to 10 above, or commercially available products in rice at the heading time (koshihikari: 1 / 5000a pot: managed at a water depth of 3 cm) One Meyer granule, Bestguard granule, Mospiran granule, and Prince granule were sprayed in an amount equivalent to 3 kg / 10a. Seven days after the treatment, only the ears were covered with goose, and 5 males and 5 females were released in the goose (1 ward, 3 continuous). Life or death was determined 6 days after release. In addition, spotted rice was investigated at the time of harvest. As a result of the test, it was found that even if the mortality rate was insufficient and the stink bug did not die, it exhibited a sufficient juice-inhibiting action.

Figure 2005213270
Figure 2005213270

試験例2 ポットでの出穂時処理におけるカメムシ類への効果
出穂10日前のイネ(こしひかり:1/5000aポット:水深3cmで管理)に製剤例5で作成した粒剤を3kg/10a相当量水面に処理した。また、製剤例3で調製したフロアブル剤を30gai./10a相当量水面し処理した。処理20日後に穂の部分のみをゴースで覆い、ゴースの中にオオトゲシラホシカメムシを雄雌各5頭ずつ放飼した(1区3連制)。放飼6日後に生死判定を行った。試験の結果、剤型に関わらず同じ処理量では同程度の吸汁阻害作用が見られた。
Test Example 2 Effect on stink bugs in heading treatment in pots Rice (Koshihikari: 1 / 5000a pot: managed at a water depth of 3 cm) 10 days before heading the granules prepared in Formulation Example 5 on the surface equivalent to 3 kg / 10a Processed. In addition, the flowable agent prepared in Formulation Example 3 was added to 30 gai. / 10a equivalent amount of water surface was processed. Twenty days after the treatment, only the ears were covered with goose, and 5 males and 5 females were released in the goose (1 ward, 3 continuous). Life or death was determined 6 days after release. As a result of the test, the same amount of sucking inhibition was observed at the same treatment amount regardless of the dosage form.

Figure 2005213270
Figure 2005213270

Claims (4)

(RS)-1-メチル-2-ニトロ-3-[(3-テトラヒドロフリル)メチル]グアニジン(一般名ジノテフラン)、(E)-1-(2-クロロ-1,3-チアゾール-5-イルメチル)-3-メチル-2-ニトログアニジン(一般名クロチアニジン)、N-[3-(6-クロロピリジン-3-イルメチル)チアゾリジン-2-イリデン]シアナミド(一般名チアクロプリド)、及び3-(2-クロロチアゾール-5-イルメチル)-5-メチル-1,3,5-オキサジアジナン-4-イリデン-N-(ニトロ)アミン(一般名チアメトキサム)から選ばれる少なくとも1種類以上の化合物を含有する組成物を水稲の出穂30日前から出穂20日後の期間に該化合物を粒剤、ジャンボ剤、顆粒水和剤、顆粒水溶剤、又はこれらを水溶性フィルム等でパックした剤型の形態で、水田の水面に直接施用することを特徴とする、カメムシ類による水稲斑点米の生成を抑制する方法。   (RS) -1-methyl-2-nitro-3-[(3-tetrahydrofuryl) methyl] guanidine (generic name dinotefuran), (E) -1- (2-chloro-1,3-thiazol-5-ylmethyl) ) -3-Methyl-2-nitroguanidine (generic name clothianidin), N- [3- (6-chloropyridin-3-ylmethyl) thiazolidine-2-ylidene] cyanamide (common name thiacloprid), and 3- (2- A composition containing at least one compound selected from chlorothiazol-5-ylmethyl) -5-methyl-1,3,5-oxadiazinan-4-ylidene-N- (nitro) amine (generic name: thiamethoxam) In the form from 30 days before heading of paddy rice to 20 days after heading, the compound is packed in the form of granules, jumbo, granule wettable powder, granule water solvent, or water-soluble film etc. Inhibits the production of spotted rice by stink bugs, characterized by direct application How. (RS)-1-メチル-2-ニトロ-3-[(3-テトラヒドロフリル)メチル]グアニジン(一般名ジノテフラン)、(E)-1-(2-クロロ-1,3-チアゾール-5-イルメチル)-3-メチル-2-ニトログアニジン(一般名クロチアニジン)、N-[3-(6-クロロピリジン-3-イルメチル)チアゾリジン-2-イリデン]シアナミド(一般名チアクロプリド)、及び3-(2-クロロチアゾール-5-イルメチル)-5-メチル-1,3,5-オキサジアジナン-4-イリデン-N-(ニトロ)アミン(一般名チアメトキサム)から選ばれる少なくとも1種類以上の化合物を含有する組成物を水稲の出穂30日前から出穂20日後の期間に該化合物を粒剤、ジャンボ剤、顆粒水和剤、顆粒水溶剤、又はこれらを水溶性フィルム等でパックした固体製剤の形態で、水田の水面に直接施用することを特徴とする、カメムシ類による水稲斑点米の生成を抑制する方法。   (RS) -1-methyl-2-nitro-3-[(3-tetrahydrofuryl) methyl] guanidine (generic name dinotefuran), (E) -1- (2-chloro-1,3-thiazol-5-ylmethyl) ) -3-Methyl-2-nitroguanidine (generic name clothianidin), N- [3- (6-chloropyridin-3-ylmethyl) thiazolidine-2-ylidene] cyanamide (common name thiacloprid), and 3- (2- A composition containing at least one compound selected from chlorothiazol-5-ylmethyl) -5-methyl-1,3,5-oxadiazinan-4-ylidene-N- (nitro) amine (generic name: thiamethoxam) During the period from 30 days before heading of paddy rice to 20 days after heading, the compound is in the form of a granule, jumbo agent, granule wettable powder, granule water solvent, or a solid preparation in which these are packed in a water-soluble film, etc. Production of spotted rice by stink bugs, characterized by direct application How to win. 10アール当たり、化合物を1g以上100g以下の量を水田の水面に施用することを特徴とする、請求項1又は2記載のカメムシ類による水稲斑点米の生成を抑制する方法。   3. A method for suppressing the production of spotted rice by stink bugs according to claim 1 or 2, wherein an amount of 1 g to 100 g of the compound per 10 ares is applied to the water surface of the paddy field. 10アール当たり、化合物を10g以上70g以下の量を水田の水面に施用することを特徴とする、請求項1又は2記載のカメムシ類による水稲斑点米の生成を抑制する方法。   3. A method for suppressing the production of spotted rice by stink bugs according to claim 1 or 2, wherein an amount of 10 g or more and 70 g or less of the compound per 10 ares is applied to the water surface of the paddy field.
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JP2008088058A (en) * 2006-09-05 2008-04-17 Sumitomo Chemical Co Ltd Method for controlling damage of paddy rice by paddy rice sap-sucking stinkbugs
JP2008133267A (en) * 2006-10-30 2008-06-12 Sumitomo Chemical Co Ltd Method for suppressing damage of paddy rice caused by paddy rice sap-sucking insect pest
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008088058A (en) * 2006-09-05 2008-04-17 Sumitomo Chemical Co Ltd Method for controlling damage of paddy rice by paddy rice sap-sucking stinkbugs
JP2008133267A (en) * 2006-10-30 2008-06-12 Sumitomo Chemical Co Ltd Method for suppressing damage of paddy rice caused by paddy rice sap-sucking insect pest
EP2008519A1 (en) * 2007-06-28 2008-12-31 Bayer CropScience AG Use of agent combinations with insecticidal properties for controlling animal pests from the stinkbug family
WO2009000443A3 (en) * 2007-06-28 2009-09-24 Bayer Cropscience Ag Use of active substance combinations having insecticidal properties for controlling animal pests from the stink bug family
WO2010149274A3 (en) * 2009-06-23 2011-07-21 Bayer Cropscience Aktiengesellschaft Use of active ingredient combinations having insecticidal properties for controlling pests from the family of stink bugs
JP2011252025A (en) * 2011-09-06 2011-12-15 Mitsui Chemicals Agro Inc Method for preventing sapping from ear of paddy rice by stink-bugs

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