JP2000119946A - Nonwoven fabric of high elongation and its production - Google Patents

Nonwoven fabric of high elongation and its production

Info

Publication number
JP2000119946A
JP2000119946A JP10294350A JP29435098A JP2000119946A JP 2000119946 A JP2000119946 A JP 2000119946A JP 10294350 A JP10294350 A JP 10294350A JP 29435098 A JP29435098 A JP 29435098A JP 2000119946 A JP2000119946 A JP 2000119946A
Authority
JP
Japan
Prior art keywords
nonwoven fabric
elongation
web
area
fiber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP10294350A
Other languages
Japanese (ja)
Inventor
Takeshi Konishi
武四 小西
Narikazu Takeuchi
成和 竹内
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kuraray Co Ltd
Original Assignee
Kuraray Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kuraray Co Ltd filed Critical Kuraray Co Ltd
Priority to JP10294350A priority Critical patent/JP2000119946A/en
Publication of JP2000119946A publication Critical patent/JP2000119946A/en
Pending legal-status Critical Current

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Landscapes

  • Absorbent Articles And Supports Therefor (AREA)
  • Multicomponent Fibers (AREA)
  • Nonwoven Fabrics (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide high-elongation nonwoven fabric that is suitable as a simple nonwoven fabric by showing high elongation, particularly in the transverse direction, as a composite nonwoven fabric in combination with a stretchable material and as a back sheet for absorbing articles such as paper diaper and its production. SOLUTION: This nonwoven fabric is prepared by fuse-bonding the curd web comprising thermoplastic synthetic fibers having a filament elongation at break of >=200% so that the fusing units of 2-10 mm2 may distribute separately from each other and the total of the fuse-bonded areas may becomes 5-18% of the web area and the unit weight is 10-50 g/m2 and the elongation at break is >=150% in the transverse direction. Further, this nonwoven fabric is produced so that the orientation of the fibers constituting the web may be >=3 at a ratio of the longitudinal direction to the transverse direction, the unit weight may be 10-50 g/m2, and the fusing units of 2-10 mm2 area may distribute separately from each other and the total fusing area may become 5-18% of the web area.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業用の利用分野】本発明はオムツなどの吸収性物品
のバックシート等の利用に好適な高伸度不織布とその製
造方法に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a high elongation nonwoven fabric suitable for use as a back sheet for absorbent articles such as diapers, and a method for producing the same.

【0002】[0002]

【従来の技術】吸収性物品のバックシートなどに用いら
れる伸縮性の素材と合わせて用いられる不織布は、一般
に使用時の応力に対応した素材の伸びに追従した変形、
即ち伸びが要求されるが、従来のスパンボンドや乾式不
織布は必要な伸度が不足し、依って伸縮性素材の動きを
止めてしまう欠点があり、結果的に製品に望ましい機能
を付与し得ないという重大な欠陥を示していた。
2. Description of the Related Art A nonwoven fabric used in combination with an elastic material used for a back sheet of an absorbent article generally has a deformation following the elongation of the material corresponding to a stress during use,
In other words, although elongation is required, conventional spunbond and dry nonwoven fabrics have a drawback in that the required elongation is insufficient, and thus the movement of the elastic material is stopped, and as a result, the desired function can be imparted to the product. Not showing any serious flaws.

【0003】[0003]

【発明が解決しようとする課題】本発明は前記のような
問題を解決しようとするものであり、特に横方向に高度
な伸度を示すことによって、それ単独の不織布として、
または、併用する伸縮性素材との複合不織布として、そ
の伸縮度を損なうことなく、動きに容易に追従し得る不
織布を提供することを目的とするものである。
DISCLOSURE OF THE INVENTION The present invention is intended to solve the above-mentioned problems, and in particular, by exhibiting a high degree of elongation in the transverse direction, as a single nonwoven fabric,
Alternatively, it is another object of the present invention to provide a nonwoven fabric that can easily follow a movement as a composite nonwoven fabric with a stretchable material to be used in combination without impairing the degree of expansion and contraction.

【0004】[0004]

【課題を解決するための手段】本発明者は上記の課題を
種々検討した結果、特定の特性を有する熱可塑性合成繊
維の短繊維から成るカードウエブに、一定の条件下でエ
ンボスカレンダー等の熱融着結合を施すことにより、上
記課題が解決できることを見出し、本発明を完成するに
至った。
As a result of various studies on the above problems, the present inventor has found that a card web made of short fibers of thermoplastic synthetic fiber having specific characteristics is heat-treated under a certain condition, such as an embossed calender. It has been found that the above problem can be solved by performing fusion bonding, and the present invention has been completed.

【0005】即ち本発明の第一は、単繊維切断伸度が2
00%以上の熱可塑性合成繊維から成るカードウエブ
に、面積2〜10mm2の融着単位が互いに離間した分
布状態にあるように、かつその総計の融着結合面積が該
ウエブ面積の5〜18%となる様に熱融着結合を施して
なり、目付が10〜50g/m2で横方向の切断伸度が
150%以上であることを特徴とする不織布であり、ま
たその第二は、単繊維切断伸度が200%以上の熱可塑
性合成繊維から成り、ウエブを構成する繊維の配向度が
タテ/ヨコ比で3以上である、目付が10〜50g/m
2のカードウエブに、面積2〜10mm2の融着単位が互
いに離間した分布状態にあるように、かつその総計の融
着結合面積が該ウエブ面積の5〜18%となる様に熱融
着結合を施すことを特徴とする、横方向の切断伸度が1
50%以上である不織布の製造方法である。
That is, the first of the present invention is that the single fiber cut elongation is 2
On a card web made of thermoplastic synthetic fibers of 00% or more, the fused units having an area of 2 to 10 mm 2 are distributed so as to be separated from each other, and the total fused bonding area is 5 to 18% of the web area. %, A non-woven fabric characterized by having a basis weight of 10 to 50 g / m 2 and an elongation at break of 150% or more in the transverse direction. The fiber comprises a thermoplastic synthetic fiber having a single fiber cutting elongation of 200% or more, and the degree of orientation of the fiber constituting the web is 3 or more in a length / width ratio, and the basis weight is 10 to 50 g / m.
2. The heat fusion is performed so that the fusion units having an area of 2 to 10 mm 2 are distributed on the card web of 2 in a spaced apart manner, and the total fusion bonding area is 5 to 18% of the web area. Characterized by joining, having a transverse elongation of 1
This is a method for producing a nonwoven fabric of 50% or more.

【0006】以下、本発明を具体的に説明する。 求め
られる最終商品の特性から考えて、本発明に用いられる
単繊維の切断伸度は200%以上であることが必要であ
り、好ましくは300%以上である。このような高伸長
性の単繊維を用いることに依り高い伸度の不織布を得る
ことが出来る。
Hereinafter, the present invention will be described specifically. Considering the required properties of the final product, the cut elongation of the single fiber used in the present invention needs to be 200% or more, and preferably 300% or more. By using such a high-stretch single fiber, a nonwoven fabric having a high elongation can be obtained.

【0007】また本発明に用いられる上記高伸長性単繊
維としては、熱エンボスや高周波融着等熱融着特性に優
れた熱可塑性繊維であることが必要で、そのような繊維
としては、ポリオレフィン系或いはポリエステル系など
の複合繊維が好ましい。特にポリプロピレン等のオレフ
ィン系繊維は比較的高い伸度を示す点から好ましい。ま
た前記複合繊維に限定されず、高伸度と易熱融着性を満
足かるポリプロピレン等の単一成分繊維であってもよ
い。
[0007] The high-extensibility single fiber used in the present invention must be a thermoplastic fiber having excellent heat-sealing properties such as hot embossing and high-frequency welding. Composite fibers such as those based on polyester or polyester are preferred. In particular, olefin fibers such as polypropylene are preferable because they exhibit relatively high elongation. Further, the fiber is not limited to the conjugate fiber, and may be a single-component fiber such as polypropylene which satisfies high elongation and heat fusing property.

【0008】上記のような単繊維を用いてカードウエブ
を作成するに当たり、繊維の配列状態が一方向性、セミ
ランダム、ランダム或はクロスレイ等が考えられるが、
特に横方向に高い伸度を発現するには一方向性、セミラ
ンダムの配列が望ましい。例えば一方向性カードウエブ
では繊維の配向度がタテ/ヨコ比で90/10程度、セ
ミランダムウエブでは75/25程度であり、横方向へ
の変形の自由度がより大きいことが望ましい。尚、ここ
でいう配向度とは、ウエブをその状態のままで樹脂含浸
して固定し、タテ、ヨコの強度を測定してその数値の比
率で表したものである。
In producing a card web using the above-described single fibers, the arrangement state of the fibers may be unidirectional, semi-random, random or cross-lay.
In particular, a unidirectional, semi-random arrangement is desirable for expressing high elongation in the lateral direction. For example, in the case of a unidirectional card web, the degree of fiber orientation is about 90/10 in a length / width ratio, and in the case of a semi-random web, it is about 75/25, and it is desirable that the degree of freedom in deformation in the horizontal direction is greater. The degree of orientation referred to here is a value obtained by measuring the strength of a warp or a weft by fixing the web in that state by impregnating the resin with the resin, and expressing the result by the numerical value ratio.

【0009】カードウエブに熱エンボス等熱融着結合を
施す場合、不織布の強度を保持しつつ横方向の切断伸度
を最大限発現させるために結合面積及びエンボスパター
ンは極めて重要な要因である。エンボスパターンについ
て言えば一方向性あるいはセミランダムウエブの繊維軸
(タテ)に対し直角にその長軸を位置させた長方型、ダ
イヤモンド形、或は楕円形等のエンボスパターンを千鳥
状に配置した場合に一般的に優れた伸度効果が得られ
る。また、最大伸度を得るため、および得られる不織布
の柔軟性や手触り、強度等を勘案して、結合面積は18
%以下5%以上であることが適当であり、15%以下8
以上がより好ましい。融着結合面積が18%を越えたも
のとなると、必要な伸度が得られない点で好ましくなく
なる。また5%未満の融着結合面積では必要な強力が得
られなくなる点で好ましくなくなる。
[0009] When performing heat fusion bonding such as hot embossing to a card web, the bonding area and the emboss pattern are extremely important factors in order to maximize the transverse elongation while maintaining the strength of the nonwoven fabric. Speaking of embossed patterns, embossed patterns such as rectangular, diamond, or elliptical with their major axis positioned at one-way or at right angles to the fiber axis (vertical) of the semi-random web are arranged in a zigzag pattern. In general, an excellent elongation effect is obtained. Further, in order to obtain the maximum elongation and in consideration of the flexibility, touch, strength and the like of the obtained nonwoven fabric, the bonding area is 18
5% or less is appropriate, and 15% or less 8%.
The above is more preferable. If the fusion bonding area exceeds 18%, it is not preferable in that the required elongation cannot be obtained. On the other hand, if the fusion bonding area is less than 5%, the required strength cannot be obtained, which is not preferable.

【0010】熱融着結合は、熱エンボスローラーや高周
波融着等、通常この種結合に用いられる公知の熱融着手
段を用いればよいが、そのエンボス等の融着領域は、2
〜10mm2の融着単位が、互いに離間した分布状態で
存在することが望ましい。融着単位が2mm2より小さ
いものであっては必要な強力が得られなくなり好ましく
なく、また10mm2より大きいものとなると必要な伸
度が得られなくなり好ましくない。なおここでの融着単
位は、その形状を限定するものではない。
For the heat fusion bonding, known heat fusion means usually used for this kind of bonding, such as a hot emboss roller or high frequency fusion, may be used.
To 10 mm 2 fusion unit is desirably present in the distribution state of being spaced apart from each other. If the fusion unit is smaller than 2 mm 2 , the necessary strength cannot be obtained, which is not preferable. If it is larger than 10 mm 2 , the required elongation cannot be obtained, which is not preferable. Here, the fusion unit does not limit its shape.

【0011】不織布の目付は用途の面から10〜50
g/m2の範囲であれば良く、また横方向の切断伸度は
150%以上であれば、併用する伸縮性素材の動きを殆
んど妨げることなく作用し、最終商品の機能を充分に満
たし得るものとなる。
The basis weight of the nonwoven fabric is from 10 to 50 in view of the application.
g / m 2 , and if the transverse elongation at break is 150% or more, it acts almost without hindering the movement of the stretchable material used in combination, and sufficiently functions as a final product. It can be satisfied.

【0012】併用する伸縮性素材としては、そのコスト
をも含め不織布が対象となり、伸縮性不織布であればそ
の種類を問わないが、なかでも好適な不織布としてメル
トブローン不織布が挙げられる。この場合、本不織布と
併用伸縮性不織布素材との積層体の目付が50〜200
g/m2で横方向の切断伸度が100%以上の積層シー
トとすることができる。
The stretchable material to be used in combination is a nonwoven fabric including its cost, and any type of stretchable nonwoven fabric may be used. Among them, a melt-blown nonwoven fabric is preferred. In this case, the basis weight of the laminate of the present nonwoven fabric and the combined stretchable nonwoven fabric material is 50 to 200.
A laminated sheet having a transverse elongation of 100% or more at g / m 2 can be obtained.

【0013】本不織布と併用する伸縮性素材との結合
は、熱融着によっても、またホットメルト接着剤等によ
ってもよいが、該両者の結合が前記不織布の高伸度を阻
害しないように実施することが肝要であり、後者ホット
メルト接着剤を用いての結合がより好ましい。
The bonding with the stretchable material used in combination with the present nonwoven fabric may be carried out by heat fusion or by using a hot melt adhesive or the like, but the bonding is carried out so that the high elongation of the nonwoven fabric is not hindered. It is important to perform bonding using the latter hot melt adhesive.

【0014】[0014]

【実施例】以下本発明をその実施例によってさらに詳細
に説明するが、本発明はそれによって限定されるもので
はない。 実施例1: ポリプロピレン−変性ポリプロピレンから
成る鞘芯型熱可塑性複合繊維(単繊維伸度410%)
の、2デニール38mmカットのステープルを用いてセ
ミランダム配向の目付25g/mm2のカードウエブを
作成した。このウエブの配向度はタテ、ヨコ比で79/
21であった。
EXAMPLES The present invention will be described in more detail with reference to the following Examples, but it should not be construed that the invention is limited thereto. Example 1: Sheath-core type thermoplastic composite fiber composed of polypropylene-modified polypropylene (elongation of single fiber: 410%)
Using a 2 denier 38 mm cut staple, a card web of 25 g / mm 2 in semi-random orientation was prepared. The degree of orientation of this web was 79 / vertical to horizontal ratio.
21.

【0015】次にこのカードウエブの流れ方向(タテ)
に対し、一辺が0.6mmの菱形の融着単位が千鳥状に
1cm2あたり融着単位が14ケに配置された、結合面
積が10%であるエンボスカレンダーを用いて、温度1
20℃、線圧30kg/cmでエンボス結合を施し不織
布を得た。得られた不織布の切断伸度はタテ64%、ヨ
コ220%であり、横方向に高い伸びを示した。
Next, the flow direction (vertical) of the card web
On the other hand, a diamond-shaped fusion unit having a side of 0.6 mm was staggered, and 14 fusion units were arranged in 1 cm 2 in a staggered manner.
Emboss bonding was performed at 20 ° C. and a linear pressure of 30 kg / cm to obtain a nonwoven fabric. The cut elongation of the obtained nonwoven fabric was 64% in length and 220% in width, and showed high elongation in the transverse direction.

【0016】上記不織布を、エチレン−オクテン共重合
体からなる伸縮性ポリオレフィンのメルトブローン不織
布とホットメルト接着剤を用いて貼り合わせ、パンツ型
紙オムツのバックシートとして用いたところ、メルトブ
ローン不織布の伸縮性が充分に発揮されフィット性に優
れたオムツが得られた。
When the above nonwoven fabric was bonded to an elastic polyolefin meltblown nonwoven fabric made of an ethylene-octene copolymer using a hot-melt adhesive and used as a back sheet for a pants-type paper diaper, the meltblown nonwoven fabric had sufficient elasticity. A diaper with excellent fit characteristics was obtained.

【0017】比較例1: ポリエステル−ポリプロピレ
ンから成る鞘芯型熱可塑性複合繊維(単繊維伸度57
%)の、2デニール38mmカットのステープルを用い
て、実施例1と全く同様の処理で不織布を得た。この不
織布の切断伸度はタテ51%、ヨコ92%であった。こ
の不織布を用いて実施例1と同じパンツ型紙オムツのバ
ックシートとして用いたところ、該紙オムツは、貼り合
わせた伸縮性メルトブローン不織布の伸度が規制された
フィット性に欠けるものであった。
Comparative Example 1: A sheath-core type thermoplastic composite fiber (polyfilament elongation 57) made of polyester-polypropylene
%) Of 2 denier 38 mm cut staples, and a nonwoven fabric was obtained in the same manner as in Example 1. The cut elongation of this nonwoven fabric was 51% in length and 92% in width. When this nonwoven fabric was used as a back sheet of a pants-type disposable diaper in the same manner as in Example 1, the disposable diaper lacked the fit in which the stretchability of the bonded stretchable meltblown nonwoven fabric was regulated.

【0018】比較例2: 実施例1と同じカードウエブ
を用い、このカードウエブにエンボス結合を施した。こ
の場合エンボスパターンは同じで、その配置も類似であ
るがパターン面積が全表面積の26%(即ち結合面積が
26%)のエンボスローラーを用いた。得られた不織布
の切断伸度はタテ38%、ヨコ68%で、柔軟性に著し
く欠けるものであった。このものを実施例と同様にして
パンツ型紙オムツに用いたところ、メルトブローン不織
布の伸縮性が著しく阻害されフィット性に乏しく肌ざわ
りの悪いオムツしか得られなかった。
Comparative Example 2 The same card web as in Example 1 was used, and the card web was embossed. In this case, an embossing roller having the same embossing pattern and similar arrangement but using a pattern area of 26% of the total surface area (that is, a bonding area of 26%) was used. The cut elongation of the obtained nonwoven fabric was 38% in length and 68% in width, and it was remarkably lacking in flexibility. When this was used for a pants-type paper diaper in the same manner as in the example, the elasticity of the melt blown nonwoven fabric was significantly inhibited, and only a diaper having poor fit and poor texture was obtained.

【0019】[0019]

【発明の効果】本発明の高伸度不織布は、特に一方向の
切断伸度が極めて高いためオムツなどの吸収性物品等に
用いられる伸縮性素材と併せて使用する場合、その高い
伸びに容易に追従し得るため最終商品に期待される機能
を充分に満足させることが出来る。
The high elongation non-woven fabric of the present invention has an extremely high elongation in one direction, and therefore, when used in combination with a stretchable material used for absorbent articles such as diapers, the high elongation is easily achieved. Therefore, the functions expected of the final product can be sufficiently satisfied.

フロントページの続き Fターム(参考) 3B029 BB02 BB07 BC02 BC07 4L041 AA07 BA02 BA05 BA09 BA21 BA49 BC04 BC20 BD03 BD07 BD11 BD20 CA38 DD01 DD05 4L047 AA14 AA27 AB02 AB03 AB10 BA08 CA05 CA12 CA19 CB01 CC04 Continued on the front page F term (reference) 3B029 BB02 BB07 BC02 BC07 4L041 AA07 BA02 BA05 BA09 BA21 BA49 BC04 BC20 BD03 BD07 BD11 BD20 CA38 DD01 DD05 4L047 AA14 AA27 AB02 AB03 AB10 BA08 CA05 CA12 CA19 CB01 CC04

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 単繊維切断伸度が200%以上の熱可塑
性合成繊維から成るカードウエブに、面積2〜10mm
2の融着単位が互いに離間した分布状態にあるように、
かつその総計の融着結合面積が該ウエブ面積の5〜18
%となる様に熱融着結合を施してなり、目付が10〜5
0g/m2で横方向の切断伸度が150%以上であるこ
とを特徴とする不織布。
1. A card web made of a thermoplastic synthetic fiber having a single fiber cut elongation of 200% or more is applied to an area of 2 to 10 mm.
As the two fused units are in a distributed state separated from each other,
And the total fusion bonding area is 5 to 18 of the web area.
% By heat fusion bonding, and the basis weight is 10 to 5%.
A nonwoven fabric characterized by having a transverse elongation at cut of 150% or more at 0 g / m 2 .
【請求項2】請求項1記載の不織布において、該不織布
を構成する単繊維切断伸度が200%以上の熱可塑性合
成繊維が、芯鞘型またはサイドバイサイド型複合繊維で
あって、その少なくとも表面側に位置する成分が他の成
分に対して低融点の、熱融着型複合繊維であることを特
徴とする不織布。
2. The nonwoven fabric according to claim 1, wherein the nonwoven fabric has a single-fiber cut elongation of at least 200% of a thermoplastic synthetic fiber which is a core-sheath type or a side-by-side type composite fiber, at least on the surface side thereof. A non-woven fabric characterized in that the component (1) is a heat-fusible conjugate fiber having a lower melting point than other components.
【請求項3】単繊維切断伸度が200%以上の熱可塑性
合成繊維から成り、ウエブを構成する繊維の配向度がタ
テ/ヨコ比で3以上である、目付が10〜50g/m2
のカードウエブに、面積2〜10mm2の融着単位が互
いに離間した分布状態にあるように、かつその総計の融
着結合面積が該ウエブ面積の5〜18%となる様に熱融
着結合を施すことを特徴とする、横方向の切断伸度が1
50%以上である不織布の製造方法。
3. A web comprising a thermoplastic synthetic fiber having a breaking elongation of a single fiber of 200% or more, a degree of orientation of a fiber constituting the web being 3 or more in a length / width ratio, and a basis weight of 10 to 50 g / m 2.
Thermal fusion bonding so that the fusion units having an area of 2 to 10 mm 2 are in a distribution state separated from each other on the card web, and the total fusion bonding area is 5 to 18% of the web area. A transverse elongation at break of 1
A method for producing a nonwoven fabric which is 50% or more.
JP10294350A 1998-10-16 1998-10-16 Nonwoven fabric of high elongation and its production Pending JP2000119946A (en)

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Publication number Priority date Publication date Assignee Title
JP2002096413A (en) * 2000-09-21 2002-04-02 Toray Ind Inc Composite reinforced fiber base material and preform
WO2003052179A1 (en) * 2001-12-14 2003-06-26 The Procter & Gamble Company High elongation, low denier fibers using high extrusion rate spinning
JP2009535525A (en) * 2006-04-27 2009-10-01 インビスタ テクノロジーズ エス エイ アール エル Anisotropic and stretchable nonwoven fabric
US20130161057A1 (en) * 2011-02-08 2013-06-27 Hitachi Cable Fine-Tech, Ltd. Flexible flat cable

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JPS5430929A (en) * 1977-08-05 1979-03-07 Chisso Corp Heat fusible composite fibers and their production
JPS5443987A (en) * 1977-09-14 1979-04-06 Chisso Corp Manufacture of composite fiber
JPH03287818A (en) * 1990-04-03 1991-12-18 Chisso Corp Thermally bondable fiber and nonwoven fabric
JPH0770898A (en) * 1993-08-31 1995-03-14 Unitika Ltd Heat-bonded nonwoven cloth and its production
JPH07276573A (en) * 1994-04-12 1995-10-24 New Oji Paper Co Ltd Stretchable composite waterproof sheet
JPH0978436A (en) * 1995-07-03 1997-03-25 Mitsui Petrochem Ind Ltd Nonwoven fabric and its production
JPH09279453A (en) * 1996-02-14 1997-10-28 Idemitsu Petrochem Co Ltd Unidirection-stretchable nonwoven cloth and its production
JPH1088457A (en) * 1996-09-13 1998-04-07 Unitika Ltd Elastic polyester-based nonwoven fabric and its production

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JPS5430929A (en) * 1977-08-05 1979-03-07 Chisso Corp Heat fusible composite fibers and their production
JPS5443987A (en) * 1977-09-14 1979-04-06 Chisso Corp Manufacture of composite fiber
JPH03287818A (en) * 1990-04-03 1991-12-18 Chisso Corp Thermally bondable fiber and nonwoven fabric
JPH0770898A (en) * 1993-08-31 1995-03-14 Unitika Ltd Heat-bonded nonwoven cloth and its production
JPH07276573A (en) * 1994-04-12 1995-10-24 New Oji Paper Co Ltd Stretchable composite waterproof sheet
JPH0978436A (en) * 1995-07-03 1997-03-25 Mitsui Petrochem Ind Ltd Nonwoven fabric and its production
JPH09279453A (en) * 1996-02-14 1997-10-28 Idemitsu Petrochem Co Ltd Unidirection-stretchable nonwoven cloth and its production
JPH1088457A (en) * 1996-09-13 1998-04-07 Unitika Ltd Elastic polyester-based nonwoven fabric and its production

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002096413A (en) * 2000-09-21 2002-04-02 Toray Ind Inc Composite reinforced fiber base material and preform
JP4517483B2 (en) * 2000-09-21 2010-08-04 東レ株式会社 Composite reinforcing fiber substrate and preform
WO2003052179A1 (en) * 2001-12-14 2003-06-26 The Procter & Gamble Company High elongation, low denier fibers using high extrusion rate spinning
JP2009535525A (en) * 2006-04-27 2009-10-01 インビスタ テクノロジーズ エス エイ アール エル Anisotropic and stretchable nonwoven fabric
KR101497711B1 (en) * 2006-04-27 2015-03-03 인비스타 테크놀러지스 에스.에이 알.엘. Anisotropic extensible nonwovens
US20130161057A1 (en) * 2011-02-08 2013-06-27 Hitachi Cable Fine-Tech, Ltd. Flexible flat cable
US8927867B2 (en) * 2011-02-08 2015-01-06 Hitachi Metals, Ltd. Flexible flat cable

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