JP2000087117A - Method for joining valve shaft of solenoid valve to sintered movable iron core - Google Patents

Method for joining valve shaft of solenoid valve to sintered movable iron core

Info

Publication number
JP2000087117A
JP2000087117A JP26186698A JP26186698A JP2000087117A JP 2000087117 A JP2000087117 A JP 2000087117A JP 26186698 A JP26186698 A JP 26186698A JP 26186698 A JP26186698 A JP 26186698A JP 2000087117 A JP2000087117 A JP 2000087117A
Authority
JP
Japan
Prior art keywords
valve shaft
iron core
movable iron
green compact
alloy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP26186698A
Other languages
Japanese (ja)
Inventor
Kazuo Asaka
一夫 浅香
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Resonac Corp
Original Assignee
Hitachi Powdered Metals Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Powdered Metals Co Ltd filed Critical Hitachi Powdered Metals Co Ltd
Priority to JP26186698A priority Critical patent/JP2000087117A/en
Publication of JP2000087117A publication Critical patent/JP2000087117A/en
Pending legal-status Critical Current

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  • Magnetically Actuated Valves (AREA)
  • Powder Metallurgy (AREA)

Abstract

PROBLEM TO BE SOLVED: To perform the sintering of a green compact and its joining to a valve shaft by a single process, to reduce the size and weight of a movable iron core, and to improve the responsiveness of a solenoid valve by compacting a powder of ferromagnetic material excellent in soft magnetic properties or a powder mixture of equivalent composition into the required shape and size of a movable iron core, fitting the resultant green compact in the prescribed position of a valve shaft, and carrying out sintering. SOLUTION: It is preferable that the material of a sintered movable iron core is composed of any of pure iron, Fe-P-alloy, Fe-Si alloy, Fe-Si-P alloy, Permalloy (R) alloy, Permendur (R) alloy, and electrical stainless steel materials, and further, as for a fit tolerance between the inside diameter of a green compact and the valve shaft, running fit of <=5 μm clearance or close fit of <=60 μm interference is preferred. Moreover, the valve shaft is composed preferably of a non-magnetic material of <=100 magnetic permeability. Because no allowance for machining is necessary for attachment to the valve shaft in this method, the movable iron core can be reduced in size and weight. Further, the amount of expansion of the green compact, in the high temperature region where sintering proceeds, is smaller than that of the valve shaft composed of melted material, and the valve shaft can be held tight by the green compact.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】この発明は油圧ポンプ、自動
車エンジンの燃料噴射装置その他流体の制御用に広く用
いられているソレノイドで作動する電磁弁に関し、特に
電磁弁のシャフトに焼結合金の可動鉄心を一体に接合す
る方法に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a solenoid valve which is operated by a solenoid widely used for controlling a hydraulic pump, a fuel injection device of an automobile engine and other fluids, and more particularly to a movable iron core of a sintered alloy on a shaft of the solenoid valve. And a method for joining them together.

【0002】[0002]

【従来の技術】電磁弁のシャフト(弁軸)は例えばステ
ンレス鋼SUS304などの非磁性材が用いられ、その
一端に弁座と離接する弁体を、他方の端部ないしその手
前に通常円筒状の可動鉄心を備え、ソレノイドコイルに
電気パルスが印加されると可動鉄心が移動して弁を開く
形式が一般的である。なお組み立ての都合その他から弁
軸を弁体と可動鉄心の中間で分割し、弁体側の弁軸を可
動鉄心側の弁軸が押して動かす形式もあるが、この明細
書における弁軸は両方の場合を含んでいる。
2. Description of the Related Art A non-magnetic material such as stainless steel SUS304 is used for a shaft (valve shaft) of an electromagnetic valve. In general, a movable iron core is provided, and when an electric pulse is applied to a solenoid coil, the movable iron core moves to open a valve. For convenience of assembly and other reasons, there is also a type in which the valve shaft is divided between the valve body and the movable core, and the valve shaft on the valve body side is pushed and moved by the valve shaft on the movable core side, but the valve shaft in this specification is in both cases Contains.

【0003】[0003]

【発明が解決しようとする課題】従来、弁軸への可動鉄
心の取り付けには圧入、かしめ、あるいは何等かの塑性
加工手段が用いられている。従って可動鉄心はその材質
が塑性変形可能なものに限定されること,内径の仕上げ
に高い寸法精度を必要としコスト高になること,塑性加
工を施す上である程度の大きさの加工代を要するため小
形軽量化に限界があることなど、鉄心の材質、形状、製
造工程などに種々の制約があった。そこでこの発明の目
的は、可動鉄心の材質その他の制約を受けずに、可動鉄
心を弁軸に一体接合するための安価で量産に適する方法
を提供することにある。
Heretofore, press-fitting, caulking, or some form of plastic working has been used for attaching the movable iron core to the valve shaft. Therefore, the material of the movable iron core is limited to a material that can be plastically deformed, high dimensional accuracy is required for finishing the inner diameter, cost is high, and a certain amount of machining allowance is required for plastic working. There were various restrictions on the material, shape, manufacturing process, and the like of the iron core, such as the limitations on miniaturization and weight reduction. SUMMARY OF THE INVENTION An object of the present invention is to provide an inexpensive method suitable for mass production for integrally joining a movable core to a valve shaft without being restricted by the material of the movable core and other restrictions.

【0004】[0004]

【課題を解決するための手段】この発明は、軟質磁気特
性が良好で可動鉄心に適する強磁性材料の粉末またはそ
の組成の混合粉を可動鉄心の所要の形状寸法に圧縮成形
し、この圧粉体を弁軸の所定の位置に嵌め込んで焼結す
ることにより、圧粉体の焼結と弁軸への接合を1工程で
完了することを骨子とするものである。この場合用途に
適う強磁性材料としては純鉄、Fe−P系,Fe−Si
系,Fe−Si−P系,パーマロイ系,パーメンジュー
ル系合金、および例えばSUS410などの電磁ステン
レス材料がある。また弁軸の材料はその透磁率が100
以下であることが好ましい。この方法では弁軸への取り
付けに加工代を要しないので、その分可動鉄心を小形軽
量化することができる。
SUMMARY OF THE INVENTION According to the present invention, a powder of a ferromagnetic material or a mixed powder of the composition thereof having good soft magnetic properties and suitable for a movable core is compression-molded into a required shape and size of the movable core. The essence is to complete the sintering of the green compact and joining to the valve shaft in one step by fitting the body into a predetermined position of the valve shaft and sintering. In this case, ferromagnetic materials suitable for use include pure iron, Fe-P, and Fe-Si.
System, Fe-Si-P system, permalloy system, permendur system alloy, and electromagnetic stainless material such as SUS410. The material of the valve shaft has a magnetic permeability of 100.
The following is preferred. In this method, no machining margin is required for attachment to the valve shaft, so that the movable iron core can be reduced in size and weight.

【0005】弁軸に可動鉄心(圧粉体)を嵌め合わせて
焼結接合する場合、得られる部品が高い接合強度を持つ
ためには単なる機械的な焼き嵌めだけでなく、両部材の
接合面が十分に密着した状態での焼結によって合金成分
の固相拡散による接合を図る必要がある。そしてこの点
については、純鉄以下の前記の材料は全て、後に説明す
るように焼結が進行する高温域(鉄系焼結合金では略8
00℃以上)における寸法変化量(膨脹量)が溶製材の
弁軸よりも小さく、圧粉体が弁軸を締め付けた状態で焼
結が進行するので極めて好都合である。
[0005] When a movable iron core (compact powder) is fitted to a valve shaft and sintered and joined, not only a simple mechanical shrink fitting but also a joining surface of both members is required to obtain high joining strength. It is necessary to achieve bonding by solid-phase diffusion of alloy components by sintering in a state where they are sufficiently adhered. Regarding this point, all of the above-mentioned materials below pure iron are in a high temperature range where sintering proceeds as described later (about 8 in the case of iron-based sintered alloys).
This is extremely convenient because the dimensional change (expansion) at (at least 00 ° C.) is smaller than that of the valve shaft of the ingot material, and sintering proceeds with the compact compacting the valve shaft.

【0006】また両部材を嵌め合わせる際の嵌め合い寸
法差(圧粉体の孔の内径寸法と弁軸の外径寸法との差)
も重要であって、弁軸の方を太め(締まり嵌め)に設定
して圧粉体の孔に圧入するのが好ましく、締め代は大き
いほど、両者の密着度が高くなる。但し強度が低い圧粉
体の引っ張り応力による破損を避けるため、締め代を好
ましくは30μm以内,多くとも60μm以内に止める
必要がある。通り嵌めを選ぶ場合でも、隙間は小さいほ
どよく、5μm以下に止めるべきである。
[0006] Further, a fitting dimensional difference in fitting the two members (difference between the inner diameter of the hole of the green compact and the outer diameter of the valve shaft).
It is also important that the valve shaft is set to be thicker (tight fit) and press-fitted into the hole of the green compact. The larger the interference, the higher the degree of adhesion between the two. However, in order to avoid breakage of the low-strength green compact due to tensile stress, it is necessary to stop the interference within 30 μm, preferably at most 60 μm. Even in the case of choosing a straight fit, the smaller the gap, the better, and should be kept below 5 μm.

【0007】[0007]

【発明の実施の形態】先ず弁軸材にステンレス鋼(SU
S304)を、可動鉄心材にFe−0.6Pの圧粉体
(圧粉密度7.0g/cm3 )を用いる場合について、
それぞれの加熱による熱膨張の状態を説明する。測定条
件はSUS304は真空中で,圧粉体は窒素ガス中で、
それぞれ毎分10℃の速度で1130℃まで昇温させ、
20分間保持したのち、同じ速度で降温させている。な
おこの明細書中の組成等に関する%は、特に断らない限
り重量%である。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS First, stainless steel (SU
S304) is based on the case where a green compact of Fe-0.6P (green compact density: 7.0 g / cm 3 ) is used for the movable core material.
The state of thermal expansion due to each heating will be described. The measurement conditions were as follows: SUS304 in vacuum, green compact in nitrogen gas,
Each was heated to 1130 ° C at a rate of 10 ° C per minute,
After holding for 20 minutes, the temperature is lowered at the same rate. In addition, the percentages related to the composition and the like in this specification are% by weight unless otherwise specified.

【0008】SUS304は室温で既にオーステナイト
相を呈しているので、加熱・冷却に伴う同素変態は生じ
ない。単なる熱による寸法変化であって温度の昇降につ
れて一様な膨脹・収縮を示し、室温に戻れば、寸法も元
の寸法に戻る。これに対してFe−0.6P圧粉体の場
合は、昇温過程で同素変態(α−γ変態に伴う収縮)お
よび熱による寸法変化を示すことは溶製材の場合と同様
であるが、焼結合金に特有の現象として圧粉体からの焼
結過程で粉末粒子の隙間の気孔化〜気孔の消失による緻
密化(収縮)を生じ、これらの収縮が熱による膨脹量を
減殺する。この結果、拡散接合が進行する略800℃以
上の高温域における圧粉体の熱膨張量はSUS304よ
り遥かに小さくなり、従って両者を嵌め合わせて焼結し
た場合、可動鉄心を弁軸に密着させた状態での焼結が確
実に行なわれる。
[0008] Since SUS304 already exhibits an austenite phase at room temperature, no allotropic transformation occurs upon heating and cooling. It is merely a dimensional change due to heat and shows uniform expansion and contraction as the temperature rises and falls. When the temperature returns to room temperature, the dimensions return to the original dimensions. On the other hand, in the case of the Fe-0.6P green compact, the allotrope transformation (shrinkage due to the α-γ transformation) and the dimensional change due to heat during the heating process are the same as in the case of the ingot material. As a phenomenon peculiar to a sintered alloy, pores in powder particles are densified (shrinkage) due to disappearance of pores in a process of sintering from a green compact, and these shrinkages reduce the amount of expansion due to heat. As a result, the thermal expansion of the green compact in the high temperature region of about 800 ° C. or higher where diffusion bonding proceeds is much smaller than that of SUS304. Therefore, when both are fitted and sintered, the movable iron core is brought into close contact with the valve shaft. The sintering in the pressed state is reliably performed.

【0009】次に、同じく可動鉄心に適するパーマロイ
(Fe−47Ni)の圧粉体(圧粉密度7.1g/cm
3 )について、真空中で毎分10℃の速度で1200℃
まで昇温させ、20分間保持したのち同じ速度で常温に
戻した場合の熱膨張の状態をSUS304と比較して説
明する。
[0009] Next, a compact of permalloy (Fe-47Ni) (also having a compact density of 7.1 g / cm) which is also suitable for a movable iron core
About 3 ), 1200 ° C at a rate of 10 ° C per minute in vacuum
The state of thermal expansion in the case where the temperature is raised to and maintained for 20 minutes and then returned to room temperature at the same speed will be described in comparison with SUS304.

【0010】パーマロイ圧粉体は昇温過程の550℃付
近までは緩やかに膨脹し、その後は膨脹の勾配が幾分大
きくなるが、SUS304よりは膨脹量が常に小さい。
温度が1170℃以上では、焼結による収縮が観測さ
れ、この収縮は焼結温度の保持段階でも続く。そして室
温に戻った段階では、SUS304は寸法も元の寸法に
戻るのに対して、パーマロイ焼結体はFe−0.6Pの
場合と同じく、加熱前の圧粉体よりも収縮している。
[0010] The permalloy green compact expands slowly up to around 550 ° C during the heating process, and thereafter the gradient of expansion becomes somewhat larger, but the expansion amount is always smaller than that of SUS304.
At a temperature of 1170 ° C. or higher, shrinkage due to sintering is observed, and this shrinkage continues even during the step of maintaining the sintering temperature. When the temperature returns to room temperature, the size of SUS304 returns to the original size, whereas the permalloy sintered body shrinks more than the green compact before heating, as in the case of Fe-0.6P.

【0011】従って、粉末冶金法により前記適宜の強磁
性材料からなる可動鉄心を圧縮成形し、その圧粉体と非
磁性材の弁軸とを嵌め合わせて焼結すれば、圧粉体が弁
軸を締め付けた状態で焼結が進行し、両者を強固に一体
化することができる。
Therefore, if the movable core made of the appropriate ferromagnetic material is compression-molded by powder metallurgy and the green compact is fitted with a valve shaft made of a non-magnetic material and sintered, the green compact becomes a valve. Sintering proceeds while the shaft is tightened, and both can be firmly integrated.

【0012】(実施例1) 先ず可動鉄心用として、組
成がFe−0.6Pの円筒状圧粉体(内径4mm,外径
10mm,長さ12mm,圧粉密度7.0g/cm3
を、粉末潤滑剤にアクラワックス(商品名)0.5%を
用いて作製した。この円筒の外周には流体の通路として
縦方向に数条の溝が設けてあるが、そのことはこの発明
の要旨ではない。一方、弁軸には非磁性のステンレス鋼
SUS304を用い、直径4mmの弁軸を作製した。次
に圧粉体を締め代20μmの圧入により弁軸の所定の位
置まで嵌め込み、分解アンモニアガス雰囲気中1200
℃で60分間焼結して可動鉄心の焼結と弁軸への接合を
1工程で行なった。
(Example 1) First, for a movable iron core, a cylindrical green compact having a composition of Fe-0.6P (inner diameter 4 mm, outer diameter 10 mm, length 12 mm, green compact density 7.0 g / cm 3 )
Was prepared using 0.5% of Acurawax (trade name) as a powder lubricant. The outer periphery of the cylinder is provided with several grooves in the longitudinal direction as a fluid passage, but this is not the gist of the present invention. On the other hand, a non-magnetic stainless steel SUS304 was used for the valve stem to produce a valve stem having a diameter of 4 mm. Next, the green compact is fitted to a predetermined position of the valve shaft by press-fitting with a closing margin of 20 μm,
By sintering at 60 ° C. for 60 minutes, sintering of the movable iron core and joining to the valve shaft were performed in one step.

【0013】この製品について、可動鉄心を固定してお
いて弁軸を押し出す破壊試験をしたところ、接合面が破
壊する前に、負荷が350kgに達した時点で弁軸の変
形を生じた。これは、弁軸の圧縮降伏強さよりも両部材
の接合強度が優ったためで、電磁弁の部品として十分な
接合が達成されたと評価される。ちなみに従来は弁軸の
外周に設けた環状溝に可動鉄心をかしめ付けているが、
その際の規格が耐負荷180kgであるから、この発明
の方法は遥かに超えていることになる。
The product was subjected to a destructive test in which the movable core was fixed and the valve shaft was pushed out. As a result, the valve shaft was deformed when the load reached 350 kg before the joint surface was broken. This is because the joining strength of both members was superior to the compressive yield strength of the valve shaft, and it is evaluated that sufficient joining as a component of the solenoid valve was achieved. By the way, conventionally, the movable iron core is caulked to the annular groove provided on the outer circumference of the valve shaft,
Since the standard at that time is 180 kg of the withstand load, the method of the present invention is far beyond.

【0014】(実施例2) 弁軸は実施例1の場合と同
一で、可動鉄心用の圧粉体の材質をパーマロイ(Fe−
47Ni;圧粉密度7.1g/cm3 )に変更した。両
者を締め代20μmの圧入により嵌め合わせて真空中1
200℃で60分間焼結し、得られた製品の強度を実施
例1の場合と同様にして測定したところ、その結果は実
施例1の場合と同様であった。従ってこれも、電磁弁の
部品として十分な接合に達していると評価される。
(Embodiment 2) The valve shaft is the same as that of Embodiment 1, and the material of the compact for the movable core is permalloy (Fe-
47Ni; compact density was 7.1 g / cm 3 ). The two are fitted together by press-fitting with a 20 μm interference, and
After sintering at 200 ° C. for 60 minutes, the strength of the obtained product was measured in the same manner as in Example 1, and the result was the same as that in Example 1. Therefore, this is also evaluated as having reached sufficient bonding as a component of the solenoid valve.

【0015】[0015]

【発明の効果】以上に詳述したように、溶製材から形成
した可動鉄心を塑性加工などで弁軸に固定する従来の方
法とは異なり、焼結合金を用いるこの発明によれば可動
鉄心を従来より小形軽量化することができ、電磁弁の応
答性が改善される。さらに可動鉄心の焼結と弁軸への接
合が1工程で完了するので、経済的にも優れている。
As described above in detail, according to the present invention using a sintered alloy, unlike the conventional method in which the movable core formed from the ingot material is fixed to the valve shaft by plastic working or the like. The size and weight can be reduced as compared with the conventional case, and the responsiveness of the solenoid valve is improved. Furthermore, since the sintering of the movable core and the joining to the valve shaft are completed in one step, it is economically excellent.

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 軟質磁気特性の優れた強磁性材の粉末ま
たはその組成の混合粉を可動鉄心の所要の形状寸法に圧
縮成形し、この圧粉体を弁軸の所定の位置に嵌め込んで
焼結することにより圧粉体の焼結と弁軸への接合を一工
程で完了することを特徴とする、電磁弁における弁軸と
焼結可動鉄心の接合方法。
1. A powder of a ferromagnetic material having excellent soft magnetic properties or a mixed powder of the composition thereof is compression-molded into a required shape and size of a movable iron core, and the compact is fitted into a predetermined position of a valve shaft. A method for joining a valve shaft and a sintered movable iron core in an electromagnetic valve, wherein sintering of the green compact and joining to a valve shaft are completed in one step by sintering.
【請求項2】 焼結可動鉄心の材質が、純鉄,Fe−P
系合金,Fe−Si系合金,Fe−Si−P系合金,パ
ーマロイ系合金,パーメンジュール系合金,電磁ステン
レス材料の何れかである請求項1に記載の電磁弁におけ
る弁軸と焼結可動鉄心の接合方法。
2. The sintered movable iron core is made of pure iron, Fe-P
The valve shaft and the sintering movable of the solenoid valve according to claim 1, wherein the valve shaft is any one of a system alloy, a Fe-Si system alloy, a Fe-Si-P system alloy, a permalloy system alloy, a permendur system alloy, and an electromagnetic stainless steel material. Iron core joining method.
【請求項3】 圧粉体の内径と弁軸との嵌め合い寸法差
が隙間5μm以下の通り嵌めもしくは締め代60μm以
内の締まり嵌めである、請求項1または請求項2に記載
の電磁弁における弁軸と焼結可動鉄心の接合方法。
3. The solenoid valve according to claim 1, wherein the fitting dimension difference between the inner diameter of the green compact and the valve shaft is a fitting with a gap of 5 μm or less or a fitting with a fitting margin of 60 μm or less. A method of joining the valve shaft and the sintered movable iron core.
【請求項4】 弁軸が透磁率100以下の非磁性材であ
る、請求項1,請求項2または請求項3に記載の電磁弁
における弁軸と焼結可動鉄心の接合方法。
4. The method according to claim 1, wherein the valve shaft is made of a non-magnetic material having a magnetic permeability of 100 or less.
JP26186698A 1998-09-16 1998-09-16 Method for joining valve shaft of solenoid valve to sintered movable iron core Pending JP2000087117A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP26186698A JP2000087117A (en) 1998-09-16 1998-09-16 Method for joining valve shaft of solenoid valve to sintered movable iron core

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP26186698A JP2000087117A (en) 1998-09-16 1998-09-16 Method for joining valve shaft of solenoid valve to sintered movable iron core

Publications (1)

Publication Number Publication Date
JP2000087117A true JP2000087117A (en) 2000-03-28

Family

ID=17367854

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EP1667177A1 (en) * 2003-09-17 2006-06-07 Hitachi Powdered Metals Co., Ltd. Sintered movable iron-core and method of manufacturing the same
DE102004034164B4 (en) * 2003-07-17 2007-07-19 Advics Co., Ltd., Kariya Movable core of a solenoid valve with valve stem and method for its production
CN107256752A (en) * 2017-07-05 2017-10-17 北京科技大学 A kind of preparation method for sintering iron powder base soft-magnetic composite material
JP2017214967A (en) * 2016-05-31 2017-12-07 愛三工業株式会社 Valve device and welding method of valve shaft and valve body of valve device
US20170365385A1 (en) * 2016-06-15 2017-12-21 Tdk Corporation Soft magnetic metal powder, soft magnetic metal fired body, and coil type electronic device

Cited By (13)

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Publication number Priority date Publication date Assignee Title
DE102004034164B4 (en) * 2003-07-17 2007-07-19 Advics Co., Ltd., Kariya Movable core of a solenoid valve with valve stem and method for its production
JPWO2005029515A1 (en) * 2003-09-17 2007-11-15 日立粉末冶金株式会社 Sintered movable iron core and manufacturing method thereof
EP1667177A4 (en) * 2003-09-17 2009-05-27 Hitachi Powdered Metals Sintered movable iron-core and method of manufacturing the same
US7541906B2 (en) 2003-09-17 2009-06-02 Hitachi Powdered Metals Co., Ltd. Sintered plunger and production method therefor
JP4702945B2 (en) * 2003-09-17 2011-06-15 日立粉末冶金株式会社 Sintered movable iron core and manufacturing method thereof
EP1667177A1 (en) * 2003-09-17 2006-06-07 Hitachi Powdered Metals Co., Ltd. Sintered movable iron-core and method of manufacturing the same
JP2017214967A (en) * 2016-05-31 2017-12-07 愛三工業株式会社 Valve device and welding method of valve shaft and valve body of valve device
CN107527701A (en) * 2016-06-15 2017-12-29 Tdk株式会社 Soft magnetic metal powder, soft magnetic metal sintered body and coil form electronic unit
US20170365385A1 (en) * 2016-06-15 2017-12-21 Tdk Corporation Soft magnetic metal powder, soft magnetic metal fired body, and coil type electronic device
US10607756B2 (en) * 2016-06-15 2020-03-31 Tdk Corporation Soft magnetic metal powder, soft magnetic metal fired body, and coil type electronic device
CN111430092A (en) * 2016-06-15 2020-07-17 Tdk株式会社 Soft magnetic metal powder, soft magnetic metal sintered body, and coil-type electronic component
CN107256752A (en) * 2017-07-05 2017-10-17 北京科技大学 A kind of preparation method for sintering iron powder base soft-magnetic composite material
CN107256752B (en) * 2017-07-05 2019-01-22 北京科技大学 A kind of preparation method being sintered iron powder base soft-magnetic composite material

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