JP2000082211A - Production of substrate for information recording medium and information recording medium - Google Patents

Abstract

PROBLEM TO BE SOLVED: To continuously carry out uniform treatment for inhibiting the leaching of glass components from a glass-base substrate for a long time while maintaining the effect of the treatment by bringing the substrate into contact with a molten salt contg. at least a hydrogensulfate and/or a pyrosulfate and inhibiting the crystallization of the molten salt. SOLUTION: The pyrosulfate is a salt of pyrosulfuric acid (H2S2O7) and the hydrogensulfate is that of an alkali metal, an alkaline earth metal, ammonium or the like. A substrate for an information recording medium is immersed in the molten salt or only one face of the substrate is brought into contact with the molten salt. The temp. of the molten salt is preferably the melting temp. or liq. phase temp. to 500 deg.C and below the sublimation temp. of the molten salt. The crystallization of the molten salt is inhibited by feeding water to the molten salt or replenishing the water lost from the molten salt. The degeneration of the glass surface and the occurrence of foreign matter due to the migration of alkali metal ions to the surface are prevented.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

The present invention relates to a method for manufacturing a substrate for an information recording medium, an information recording medium, and the like.

[0002]

2. Description of the Related Art In recent years, as substrates for information recording media, glass substrates and ceramic substrates which are more excellent in various characteristics than other materials have been receiving attention. In detail, aluminum substrates were often used as substrates for magnetic disks.However, with the demand for smaller and thinner magnetic disks and lower flying height of magnetic heads, smaller and thinner aluminum substrates have been used. Since the magnetic head is easy, has high flatness, and is easy to lower the flying height of the magnetic head, the ratio of using a glass substrate or a ceramic substrate is increasing.

When a glass substrate is used as a substrate for an information recording medium, the surface of the glass substrate is subjected to a chemical strengthening treatment for the purpose of improving the shock resistance and vibration resistance and preventing the substrate from being damaged by the shock or vibration. In many cases, the strength is improved. As the chemical strengthening treatment, for example, alkali ions in the glass are replaced with alkali ions having a larger ionic radius, and a strong compressive stress is generated in the glass surface layer by increasing the volume of the ion exchange part, thereby strengthening the glass surface. Method (ion exchange method) or the like in many cases. When chemical strengthening is performed using an ion exchange method, it is necessary to use a glass substrate containing alkali ions in principle. In addition, among glass substrates for information recording media containing alkali ions, there are glass types (for example, high-valent glass and the like) having a predetermined strength even without being subjected to a chemical strengthening treatment.

When a ceramic (for example, crystallized glass) substrate is used as a substrate for an information recording medium, the crystallization improves the shock resistance and vibration resistance, so that chemical strengthening is not usually required.

When a glass or ceramic substrate is used as a substrate for an information recording medium, the elution of alkali contained in the glass or ceramic substrate often poses a problem, and it is desirable to minimize the elution of alkali. Elution of alkali also becomes a problem for the glass substrate after the ion exchange treatment.

[0006]

As described above, when a glass or ceramic substrate is used as a substrate for an information recording medium, the elution of alkali becomes a problem. However, a technique for suppressing the elution of alkali at a high level is known. Hardly developed.

The present invention has been made under the above-mentioned background, and it is possible to suppress the elution of alkali and other components from a glass substrate at a high level, and to continue the treatment effect for a long period of time. An object of the present invention is to provide a method for manufacturing a substrate for an information recording medium that can be uniformly processed.

[0008]

Means for Solving the Problems The applicant of the present invention is an alkali
The glass substrate for the information recording medium containing ions is
By immersing in molten salt such as elementary salt and treating,
Already filed for finding that elution can be suppressed significantly
(Japanese Patent Application No. 9-365326). here,
Treatment by immersing glass substrate in molten salt such as hydrogen sulfate
Elution of alkali from glass and glass substrates at a high level
The possible reason (mechanism) lies in the outermost layer of glass
From the non-crosslinked state of Si-O-Na, contained in hydrogen sulfate
Hydronium Ion and Si-ON
Na of a⁺Undergoes ion exchange with a silanol group (Si-O
-H), after which the silanol groups are dehydrated by heating
And cross-linking of Si-O-Si is performed on the glass surface
It is thought that it is. The present inventors have further studied
As a result of the superposition, hydrogen sulfate (for example, KHSO_Four) Etc.
As the treatment continues with salt, water evaporates and pyrosulfate
(Eg K_TwoS_TwoO₇) Crystals are precipitated, and the treatment effect is low.
(For example, 2KHSO _Four→ K_TwoS_Two
O₇+ H_TwoO ↑ reaction occurs and KHSO_FourIs K_TwoS_TwoO₇Nana
). Then, the processing solution is supplemented with water to provide
Process for a long period of time while maintaining the effect of
This led to the completion of the present invention. Also these
The effect of irrespective of the type of glass or ceramic, for example,
It has also been found that crystallized glass is effective. Sa
Besides, not only alkali but also alkaline earth, Si, Pb
And other elution components can be suppressed.
I found that. Elution suppression effect of alkaline earth, Si etc.
Tables 1 and 2 show specific data regarding the above. Table 1 and
Table 2 shows that the pyrosulfate salt and bisulfate salt
It turns out that the treatment with the molten salt is effective. In addition,
The outflow test was performed by placing the glass substrate in ultrapure water heated to 80 ° C.
Immerse for 4 hours and determine elution components by ion chromatography
Of alkali metal ions per glass substrate
(Μmol / Disk).

[0009]

[Table 1]

[0010]

[Table 2]

The alkali of the glass component causes not only the glass substrate for the information recording medium but also the burnt of the optical glass and the glass tableware. Therefore, the optical lens, the prism, the optical filter, the optical waveguide, the optical module, the optical element, etc. And optical components, display glass, solar cell substrate glass,
The treatment with a molten salt such as hydrogen sulfate of the present invention is effective in obtaining a glass product having good weather resistance, such as a substrate glass for a semiconductor, a substrate glass for an image sensor, an electronic component, a transfer mask, and a glass tableware.

Incidentally, the published patent publication (Japanese Patent Application Laid-Open No. Hei 11-503)
No. 403) discloses a technique for removing alkali from a substrate surface in the presence of AlCl _{3 by} a wet method or by sublimation of a sulfate such as (NH ₄ ) ₂ SO ₄ . However, when AlCl ₃ is used, the processing temperature is 100
Since the temperature is as low as ° C., the processing time becomes as long as 24 hours as in the example. On the other hand, when the alkali is removed by sublimation of the sulfate, the sulfate must be converted into a gas, so that a high temperature of 450 to 580 ° C. is required as in the embodiment. On the other hand, in the present invention, the sulfate is contacted as a molten salt at a temperature at which the sulfate itself melts to carry out the dealkalization treatment.
And processing in a short time of about 5 minutes is possible. Therefore, there is an advantage that glass having a wide Tg range, such as glass having a low Tg temperature, can be processed, or the glass substrate is not deformed due to low-temperature processing. Specifically, in the present invention, the glass substrate has a Tg of 400.
Applicable up to around ° C. Since the distance between the glass substrate for the information recording medium and the magnetic head is 40 to 50 nm, a problem such as a crash occurs when the glass substrate is deformed. Therefore, the deformation of the glass in the glass substrate for the information recording medium is a serious problem. In addition, Tokio Table 1
In Japanese Patent Laid-Open No. 1-503403, glass chemically strengthened at 500 ° C. is subjected to dealkalization treatment at 500 ° C. with (NH ₄ ) ₂ SO _4. This causes a decrease in the strength of the glass substrate, resulting in a decrease in the strength of the glass substrate for the information recording medium. On the other hand, in the present invention, the dealkalization treatment is performed at a temperature lower by 80 to 130 ° C. than the chemical strengthening treatment, and the treatment time is as short as 5 minutes, so that stress relaxation hardly occurs. In addition, since the sulfate sublimation becomes a gas, it must be treated in a sealed state, and continuous operation is difficult, but the present invention does not need to be sealed for a liquid,
Continuous operation is easy, and a treatment for suppressing crystallization of the molten salt during dealkalization is performed. Therefore, even if continuous operation is performed, it is possible to obtain a sustained effect of dealkalization.

The present invention has the following configuration.

(Structure 1) A process for suppressing the elution of glass components by bringing a substrate mainly composed of glass for an information recording medium into contact with a molten salt containing at least hydrogen sulfate and / or pyrosulfate. A method for producing a substrate for an information recording medium, which comprises performing a process for suppressing crystallization of a molten salt when performing the process.

(Structure 2) The treatment for suppressing the elution of the glass component by contacting with the molten salt and the treatment for suppressing the crystallization of the molten salt are performed after the chemical strengthening treatment of the glass substrate, and the treatment with the molten salt is performed. At least 5 above the chemical strengthening temperature
The method for producing a substrate for an information recording medium according to Configuration 1, wherein the method is performed at a temperature lower by 0 ° C.

(Structure 3) The information recording medium substrate according to Structure 1 or 2, wherein the treatment of contacting the molten salt to suppress the elution of the glass component is performed at a temperature lower than the sublimation temperature of the molten salt. Production method.

(Structure 4) The glass component that suppresses elution is
4. The method for manufacturing a substrate for an information recording medium according to any one of Configurations 1 to 3, wherein the substrate is an alkali ion.

(Structure 5) The method for manufacturing a substrate for an information recording medium according to any one of structures 1 to 4, wherein the treatment for suppressing crystallization of the molten salt is a treatment for supplying water to the molten salt. Method.

(Structure 6) The information recording medium substrate according to any one of Structures 1 to 5, wherein the treatment for suppressing crystallization of the molten salt is a treatment for compensating for water lost from the molten salt. Production method.

(Structure 7) The information recording according to any one of Structures 1 to 6, wherein the molten salt containing hydrogen sulfate and / or pyrosulfate is a molten salt obtained by further adding sulfuric acid. A method for manufacturing a medium substrate.

(Structure 8) The method for manufacturing a substrate for an information recording medium according to Structure 5 or 6, wherein the method of supplying or supplementing the moisture is a method of introducing steam into the molten salt.

(Structure 9) The method for manufacturing a substrate for an information recording medium according to Structure 5 or 6, wherein the method of supplying or supplementing the moisture is a method of placing a molten salt in a steam atmosphere.

(Structure 10) The method for manufacturing a substrate for an information recording medium according to Structure 5 or 6, wherein the method of supplying or supplementing the water is a method of adding hydrogen sulfate to the molten salt.

(Structure 11) The structure according to any one of structures 1 to 10, wherein the temperature of the molten salt is from the melting temperature or the liquidus temperature to 500 ° C. and lower than the sublimation temperature of the molten salt. A method for manufacturing a substrate for an information recording medium.

(Structure 12) According to the method for manufacturing an information recording medium substrate according to any one of Structures 1 to 11, the glass surface is changed from the non-crosslinked state of Si—O—Na to Si—O—Na.
Na ^{+ of} O—Na is ion-exchanged with hydronium ions to be in a hydrated state, and thereafter, a silanol group is formed by heating and dehydration, and the silanol group is dehydrated, and cross-linking of Si—O—Si occurs on the glass surface. A method for manufacturing a substrate for an information recording medium, wherein

(Structure 13) According to the method for manufacturing an information recording medium substrate according to any one of Structures 1 to 11, the surface of the glass substrate is changed from the non-crosslinked state of Si—O—Na to S
A method for producing a substrate for an information recording medium, wherein i-O-Si is crosslinked.

(Structure 14) The method for manufacturing an information recording medium substrate according to any one of Structures 1 to 13, wherein the information recording medium substrate is a glass substrate subjected to a chemical strengthening treatment.

(Structure 15) The method for manufacturing an information recording medium substrate according to any one of structures 1 to 13, wherein the information recording medium substrate is a crystallized glass substrate.

(Structure 16) The information recording medium substrate according to any one of structures 1 to 15, wherein the information recording medium substrate is a substrate used for a magnetic disk reproduced by a magnetoresistive head. Substrate manufacturing method.

(Structure 17) At least a recording layer is formed on an information recording medium substrate obtained by using the method for manufacturing an information recording medium substrate according to any one of Structures 1 to 16. Information recording medium.

(Constitution 18) When a product containing glass as a main component is brought into contact with a molten salt containing at least hydrogen sulfate and / or pyrosulfate to suppress the elution of glass components, A method for producing a glass product, which comprises performing a treatment for suppressing crystallization of a salt.

(Structure 19) The method for manufacturing a glass product according to Structure 18, wherein the treatment of contacting the molten salt to suppress the elution of the glass component is performed at a temperature lower than the sublimation temperature of the molten salt.

[0033]

According to the present invention, the elution of alkali can be remarkably suppressed by immersing the substrate for an information recording medium in a molten salt such as hydrogen sulfate and treating. Therefore, it is possible to remarkably suppress the deterioration (burn, etc.) and the generation of foreign substances on the glass surface due to the movement of the alkali metal ions to the surface. In particular, in the present invention, by supplementing the processing solution with water, the water does not evaporate and the crystals of pyrosulfate do not precipitate and the effect of the treatment does not decrease. Can be processed. Further, elution of other elution components such as alkaline earth, Si, and Pb can be suppressed. As a result,
Improvements in water resistance, acid resistance, and the like can be achieved.

Further, according to the information recording medium of the present invention, since a glass substrate in which the elution of alkali and other components is remarkably suppressed is used, an information recording medium having excellent weather resistance and life and high reliability is provided. Can be manufactured.

Furthermore, according to the glass product of the present invention and the method for producing the same, it is possible to obtain a product in which the elution of alkalis and other components is significantly suppressed, so that a glass product excellent in weather resistance and life and having high reliability is obtained. Can be

[0036]

BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail.

In the method of manufacturing a substrate for an information recording medium according to the present invention, a substrate mainly composed of glass for an information recording medium is brought into contact with a molten salt containing at least hydrogen sulfate and / or pyrosulfate. When performing the treatment for suppressing the elution of the glass component, a treatment for suppressing crystallization of the molten salt is performed.

As a treatment for suppressing crystallization of the molten salt, any method may be employed. For example, a method of supplying water to the molten salt (for example, a method of supplying water to the molten salt, Irrespective of the case where water is actively supplied), or a method of compensating for water lost from the molten salt. The treatment for suppressing the crystallization of the molten salt includes:
As a method other than the method of supplying or supplementing moisture, there are a method of preventing evaporation of moisture by vapor pressure or pressure, a method of sealing a treatment tank, and the like. If a method is used in which the periphery of the treatment tank is covered with a closed space, and the enclosed space is humidified to supply water and suppress evaporation from the molten salt, a large amount of cost is required to seal the periphery of the treatment tank. It takes
Care must be taken because it is necessary to exhaust SO _x generated from the molten salt.

The treatment for suppressing the crystallization of the molten salt may be carried out before or during the contact between the substrate and the molten salt. Further, a system in which the processing solution is circulated from the processing tank to the outside to suppress crystallization of the molten salt from the outside and a processing solution into which the crystallization is prevented flows into the processing tank may be employed. .

As a method for supplying water to the molten salt or a method for compensating for water lost from the molten salt, more specifically, the following methods can be mentioned.

First, there is a method of introducing steam into the molten salt. In this case, for example, a steam blowing nozzle may be inserted into the molten salt, and steam generated from the nozzle by a known method may be bubbled to supply or supplement moisture. More specifically, for example, as shown in FIG. 1, water 2 contained in a closed container 1 is heated to, for example, about 100 ° C., and air is supplied from the air supply pipe 3 to the water in the closed container to make the container 2 wet. The air may be heated through the steam pipe 4 to generate steam at, for example, about 280 ° C., and steam may be supplied into the molten salt 6 in the treatment tank 5 from the nozzle at the tip of the steam pipe 4 to supply or supplement moisture. The temperature of the steam is preferably around the temperature of the molten salt from the viewpoint of preventing the temperature of the molten salt from decreasing and crystallizing.

Second, there is a method of placing the molten salt under a steam atmosphere. In this case, for example, as shown in FIG. 2, steam may be injected toward the molten salt 6 from a nozzle at the tip of the steam pipe 4 disposed above the molten salt 6 to supply or supplement moisture.

Third, there is a method in which crystallization of the molten salt is prevented by adding a hydrogen sulfate or a hydrate of the hydrogen sulfate to the molten salt. In this case, the capacity of the molten salt increases.

As another method, there is a method of directly supplying water to the molten salt. In this case, if water is introduced into a high-temperature molten salt, a steam explosion occurs. After adding water, the mixture is allowed to react slowly, and then it is necessary to raise the temperature to the processing temperature again.

In the present invention, the pyrosulfate is a salt of pyrosulfuric acid (H ₂ S ₂ O ₇ ), which is disulfuric acid (S ₂ O ₇ ) and an alkali metal, an alkaline earth metal, other metals, ammonium, etc. And the compound When one mole of water is removed from two moles of hydrogen sulfate, it becomes pyrosulfate. When bisulfate is melted to form a molten salt, it loses water and becomes pyrosulfate.
In this case, water evaporates, but water slightly remaining in the molten salt contributes to the mechanism of preventing alkali elution.

Examples of the pyrosulfate include alkali metals, alkaline earth metals, ammonium, zinc, thallium (I),
Salts such as lead (II), iron (II), uranyl and the like can be mentioned. Potassium pyrosulfate, sodium pyrosulfate, and the like are preferable from the viewpoints of safety, environmental protection, economy, and handleability. As the hydrogen sulfate, alkali metals (Li,
Na, K, Rb, Cs), alkaline earth metals (Mg, C
a, Sr, Ba), ammonium, thallium, lead, vanadium, bismuth, rhodium and the like. From the viewpoint of safety and the like, potassium hydrogen sulfate, sodium hydrogen sulfate and the like are preferable.

The hydrogen sulfate and / or pyrosulfate can be used alone or in a mixture of hydrogen sulfate and pyrosulfate. The hydrogen sulfate and / or pyrosulfate can be used by mixing two or more different salts. In this case, the mixing ratio can be appropriately adjusted. Further, other components can be added to the molten salt as long as the effects of the present invention are not impaired.

Since pyrosulfate can be obtained by adding sulfuric acid to sulfate, pyrosulfate may be prepared by adding sulfuric acid to sulfate. When the treatment with a salt such as hydrogen sulfate is carried out for a long period of time, the crystals of the sulfate precipitate in the molten salt due to the alkali removed from the glass, but the crystals of the sulfate are added to the hydrogen sulfate and / or Alternatively, it can be returned to pyrosulfate. Since sulfuric acid does not hinder the treatment of the molten salt with hydrogen sulfate or the like, the treatment may be performed by adding it to the molten salt before the crystals of the sulfate are precipitated.

The term "contact" with the molten salt includes not only the case where the information recording medium substrate is immersed in the molten salt but also the case where only one surface of the information recording medium substrate is brought into contact with the molten salt.

The temperature of the molten salt may be higher than the melting temperature or liquidus temperature of the salt, and may be lower than the sublimation temperature of the salt. In terms of the effect of suppressing the alkali elution, the temperature does not depend so much on the temperature. However, it is preferable to set the temperature to 250 to 300 ° C. or higher because the alkali elution becomes zero or close to zero. On the other hand, the surface hardness and the like are reduced due to blue burn on the glass surface, which causes a problem in long-term reliability when the recording layer is formed and used as an information recording medium.
The temperature is preferably set to 350 ° C. to 500 ° C. or lower. 500
The reason why the upper limit is set to ℃ is that when the temperature exceeds 500 ℃, decomposition of the molten salt is likely to occur. In consideration of the fact that the chemically strengthened layer of glass chemically strengthened by ion exchange disappears and the strength decreases, in the case of chemically strengthened glass, 300
It is preferable that the temperature is set to be lower than or equal to 350C. From the above viewpoint, the temperature of the molten salt is from the melting temperature or the liquidus temperature to 5
The temperature is preferably 00 ° C. and less than the sublimation temperature of the molten salt (more preferably, the melting temperature or the liquidus temperature to 350 ° C.).
The temperature is more preferably 50 ° C. (more preferably 270 ° C. to 350 ° C.).
50 ° C to 300 ° C (more preferably 270 ° C to 300 ° C)
C). Although the melting point of potassium pyrosulfate is 325 ° C. (literature value), it is generally in the range of 210 to 300 ° C. because a part of it absorbs moisture and becomes hydrogen sulfate.
But it is in a molten state. Thus, the actual melting temperature may be different from the melting point. The melting point of potassium hydrogen sulfate is 21
0 ° C. Sodium bisulfate has a melting point of 185.7 ° C
It is.

The treatment time with the molten salt does not depend much on the treatment time in terms of the effect of suppressing the elution of alkali. For example, if the treatment time is longer than about 5 minutes, there is no significant difference in the effect of suppressing alkali elution even if the treatment time is increased.
Thus, the treatment time with the molten salt is 1 to 3
It is preferably about 0 minutes, and more preferably about 5 to 10 minutes in consideration of processing efficiency and productivity.

The treatment with a molten salt such as hydrogen sulfate does not damage the information recording medium substrate. Further, the treatment with a molten salt such as pyrosulfate has an effect of removing contaminants such as iron powder, and also has an effect of removing a deposited molten salt accompanying the chemical strengthening treatment.

In the present invention, a substrate mainly composed of glass (a product composed mainly of glass) is made of glass, amorphous glass, glass ceramic, crystallized glass, or a composite material of glass and ceramic. Point. As the glass substrate, glass having SiO ₂ as a skeleton is generally used, and there are a glass substrate containing alkali ions and a glass substrate containing no alkali ions. Crystallized glass often contains alkali ions when used as a substrate for an information recording medium. However, some crystallized glass does not contain alkali ions. The size, thickness, shape, and the like of the information recording medium substrate are not particularly limited.

Examples of the glass substrate containing alkali ions include aluminosilicate glass, silicate glass (high Young's modulus glass) containing high valence metal ions (eg, Ti, Y, etc.), soda lime glass, soda aluminosilicate glass , Aluminoborosilicate glass, borosilicate glass, chain silicate glass and the like. Preferably, the aluminosilicate glass or the like is chemically strengthened in order to improve impact resistance and vibration resistance. However, in the case of a glass substrate containing an alkali ion that does not require chemical strengthening, chemical strengthening is unnecessary.

As the aluminosilicate glass, Si
O_Two: 62 to 75% by weight, Al_TwoO_Three: 5 to 15% by weight,
Li_TwoO: 4 to 10% by weight, Na_TwoO: 4 to 12% by weight,
ZrO_Two: Containing 5.5 to 15% by weight as a main component
With Na_TwoO / ZrO_TwoIs 0.5 to 2.
0, Al_TwoO_Three/ ZrO_TwoWeight ratio of 0.4 to 2.5
Glass for chemical strengthening or SiO_Two: 62-75
Wt%, Al_TwoO_Three: 5 to 15% by weight, B_TwoO_Three: 0.5 ~
5% by weight, Li_TwoO: 4 to 10% by weight, Na_TwoO: 4-1
2% by weight, MgO: 0.5 to 5% by weight, CaO: 0.5
~ 5% by weight, Sb _TwoO_Three: Mainly 0.01 to 1.0% by weight
Glass for chemical strengthening contained as a component is preferred. Ma
ZrO_TwoGlass substrate surface caused by undissolved material
In order to eliminate the protrusion of_Two5
7-74%, ZrO_TwoFrom 0 to 2.8%, Al_TwoO_Three3 to
15%, LiO_Two7-16%, Na_TwoContains 4 to 14% O
It is preferable to use glass or the like for chemical strengthening.
Aluminosilicate glass having such a composition is chemically strong.
Compressive stress, tensile stress, compressive stress layer
The depth of the three can be controlled in a well-balanced manner,
Excellent strength and heat resistance, such as Na even under high temperature environment
Preservation of flatness with little precipitation, and also Knoop hardness
Excellent.

Examples of the crystallized glass substrate include crystallized glass having lithium disilicate (Li ₂ O.2SiO ₂ ) and α quartz (SiO ₂ ) as a main crystal phase, and potassium fluororichterite (KNaCaMg) as a main crystal phase. ₅ S
i ₈ O ₂₂ F ₂ ) and potassium-cassanite (K ₃ Na ₃ Ca)
₅ Si ₁₂ O ₃₀ F ₄ ). As a specific composition, in the former case, SiO _2: sixty to eighty-six wt%, Li ₂ O: 8~18 wt%, K ₂ O: 0~10 wt%, MgO: 0 to 8 wt%, ZnO: 0-10% by weight,
Sb ₂ O _3: 0~2 wt%, P ₂ O _5: 0.1~10 wt%, in the latter case, SiO _2: 50 to 75 wt%, Ca
O: 4 to 15% by weight, MgO: 5 to 30% by weight, F: 3
8 wt%, Na ₂ O: 2~9 wt%, Li ₂ O: 0~3
Wt%, BaO: 0 to 2 wt%, Al ₂ O _3: 0~10 wt%, and the like.

In the present invention, the glass substrate which has been chemically strengthened by immersing the glass substrate in a heated chemical strengthening treatment solution and ion-exchanging the ions of the surface layer of the glass substrate with ions in the chemical strengthening treatment solution, if necessary, The treatment with the molten salt can be performed. When the glass substrate that has been subjected to the chemical strengthening treatment is treated with the molten salt, it is preferable that the glass substrate is treated at a temperature at least 50 ° C., preferably 60 ° C., and more preferably 80 ° C. lower than the temperature of the chemical strengthening treatment.

As the ion exchange method, a low-temperature ion exchange method, a high-temperature ion exchange method, a surface crystallization method and the like are known. From the viewpoint, it is preferable to use a low-temperature ion exchange method. In the low-temperature ion exchange method, alkali ions in the glass are replaced with alkali ions having a larger ionic radius in a temperature range equal to or lower than the glass transition temperature (Tg), and the volume of the ion exchange portion increases to form a glass surface layer. This is a method in which a strong compressive stress is generated to strengthen the glass surface.

As the chemical strengthening treatment liquid, a molten salt such as potassium nitrate (KNO ₃ ), sodium nitrate (NaNO ₃ ), potassium carbonate (K ₂ CO ₃ ), or a mixture of these salts (for example, KNO ₃ + NaNO ₃ , KNO ₃ + K ₂ C
O ₃ ) or these salts, or Cu, A
A molten salt of a mixture of salts of ions such as g, Rb, and Cs is exemplified.

The heating temperature is 3 from the viewpoint of the glass transition point.
The temperature is preferably from 50 ° C to 650 ° C, particularly from 350 ° C to 500 ° C, more preferably from 350 ° C to 450 ° C. The immersion time is preferably about 1 to 20 hours from the viewpoint of the bending strength and the compressive stress layer. The thickness of the compressive stress layer formed on the surface of the glass substrate is preferably about 60 to 300 μm from the viewpoint of improving impact resistance and vibration resistance.

In the present invention, before the glass substrate is treated with a molten salt (a molten salt such as hydrogen sulfate, or a chemical strengthening treatment solution), the glass substrate is treated with a glass substrate of 200 to 350 to prevent cracking and cracking of the glass substrate. It is preferred to preheat to ° C.

In the treatment with a molten salt such as hydrogen sulfate or a chemical strengthening treatment liquid, it is preferable to carry out the treatment while holding the glass substrate at the end face. This is in order to avoid that if the glass substrate is held at a part of the surface, the part is not processed.

In the present invention, molten salts such as hydrogen sulfate and / or
Alternatively, it is preferable that after the treatment with the chemical strengthening treatment liquid, the glass substrate is pulled up from the molten salt and gradually cooled to a predetermined temperature so as to suppress generation of thermal distortion. By slow cooling in this way, damage due to thermal distortion can be avoided. The rate at which the glass substrate is gradually cooled is 2 ° C./min to 100 ° C.
/ Min, particularly preferably 5 ° C / min to 60 ° C / min, more preferably 10 ° C / min to 50 ° C / min.

In the present invention, after the above-mentioned slow cooling, it is preferable to rapidly cool the glass substrate, for example, at a rate at which crystallization of the molten salt deposited on the surface of the glass substrate is prevented. Thus, when the glass substrate is rapidly cooled, the molten salt that precipitates becomes fragile,
Removal of the molten salt is facilitated in a treatment step or a washing step using a molten salt such as hydrogen sulfate.

The speed of rapidly cooling the glass substrate is 1600 ° C.
/ Min to 200 ° C / min, especially 1200 ° C / min to 300 ° C /
Min, more preferably from 800 ° C / min to 400 ° C / min. The rapid cooling of the glass substrate is preferably performed at 100 ° C. to 0 ° C., more preferably 4 ° C., from the viewpoint of heat shock.
It is preferable to carry out the process by contacting with a refrigerant at 0 ° C to 10 ° C.
The time for bringing the glass substrate into contact with the cooling medium is preferably about 10 to 60 minutes from the viewpoint of the cleaning property of the deposited molten salt. As the refrigerant, liquid refrigerant such as water, hot water, solution,
In addition to gaseous refrigerants such as nitrogen gas, water vapor, and cooling air, air blowing and the like can be mentioned.

In the present invention, the surface of a glass substrate that has been subjected to a chemical strengthening treatment or a surface of a glass substrate that has not been subjected to a chemical strengthening treatment can be treated with a molten salt such as hydrogen sulfate, if necessary. When the glass substrate that has been subjected to the chemical strengthening treatment is treated with the molten salt, it is preferable that the glass substrate is treated at a temperature at least 50 ° C., preferably 60 ° C., and more preferably 80 ° C. lower than the temperature of the chemical strengthening treatment.

In the present invention, after any step in the manufacturing process, if necessary, washing with a commercially available detergent (neutral detergent, surfactant, alkaline detergent, etc.), scrub washing, pure water washing, solvent Known washing treatments such as washing, solvent vapor drying, and centrifugal drying can be performed. In each cleaning, heating or ultrasonic wave application may be performed.

The ultrasonic wave may be either a multi-frequency type that oscillates in a certain frequency range or a fixed-frequency type that oscillates at a constant frequency. The lower the frequency, the higher the cleaning effect, but the greater the damage to the glass substrate. Therefore, the frequency is determined in consideration of these factors.

In steam drying, since the drying speed is high, spots due to drying are hardly generated. Examples of the solvent used for steam drying include isopropyl alcohol, chlorofluorocarbon, acetone, methanol, and ethanol.

The method for manufacturing a substrate for an information recording medium of the present invention can be used as a method for manufacturing a glass substrate for a magnetic disk, a glass substrate for a magneto-optical disk, and a disk substrate for an electro-optical disk such as an optical memory disk. In particular, the information recording medium substrate of the present invention can be suitably used as a glass substrate used for a magnetic disk reproduced by a magnetoresistive head. More specifically, by using a glass substrate with a much better surface condition than in the past, when a magnetic disk for a magnetoresistive head or a large magnetoresistive head is used, the bed caused by foreign substances such as alkali elution and burns There is no occurrence of a crash, and there is no possibility that defects such as elution of alkali or burns are generated in a film such as a magnetic layer and cause an error.

Furthermore, the treatment method of the present invention can be widely used for applications in fields where it is necessary to prevent elution of constituents of glass and ceramics (alkali metal, alkaline earth metal, silicon, lead, etc.).

Next, the information recording medium of the present invention will be described. The information recording medium of the present invention is characterized in that at least a recording layer is formed on an information recording medium substrate obtained by using the above-described method of the present invention. Here, known recording layers and other layers can be used.

Since the information recording medium of the present invention uses the information recording medium substrate in which elution of alkali ions and the like is remarkably suppressed, an information recording medium having excellent weather resistance and long life and high reliability can be obtained.

Hereinafter, a magnetic recording medium will be described as an example of the information recording medium. A magnetic recording medium is usually manufactured by sequentially laminating a base layer, a magnetic layer, a concavo-convex forming layer, a protective layer, a lubricating layer, and the like on a magnetic disk substrate as necessary.

The underlayer in the magnetic recording medium is appropriately selected according to the magnetic layer. As the underlayer (including the seed layer), for example, Cr, Mo, Ta, Ti, W, V, B,
An underlayer made of at least one or more materials selected from nonmagnetic metals such as Al and Ni may be used. In the case of a magnetic layer containing Co as a main component, it is preferable to use Cr alone or a Cr alloy from the viewpoint of improving magnetic properties. Also,
The underlayer is not limited to a single layer, and may have a multilayer structure in which the same or different layers are stacked. For example, Cr / Cr,
Cr / CrMo, Cr / CrV, CrV / CrV, Al
/ Cr / CrMo, Al / Cr / Cr, NiAl / C
r, a multilayer base layer of NiAl / CrMo, NiAl / CrV, or the like.

The material of the magnetic layer is not particularly limited.

As the magnetic layer, specifically, for example, C
CoPt, CoCr, CoNi, Co mainly containing o
NiCr, CoCrTa, CoPtCr, CoNiP
t, CoNiCrPt, CoNiCrTa, CoCrP
Magnetic thin films such as tTa and CoCrPtSiO may be used. Further, the magnetic layer is formed of a nonmagnetic film (for example, Cr, CrM).
o, CrV, etc.) to reduce noise (for example, CoPtCr / CrMo / CoPtC)
r, CoCrTaPt / CrMo / CoCrTaPt).

As a magnetic layer corresponding to a magnetoresistive head (MR head) or a large magnetoresistive head (GMR head), Y, Si, rare earth elements, Hf, G
An impurity element selected from e, Sn, and Zn, or an element containing an oxide of these impurity elements is also included.

As the magnetic layer, in addition to the above, magnetic particles such as Fe, Co, FeCo, and CoNiPt are dispersed in a nonmagnetic film made of ferrite, iron-rare earth, SiO ₂ , BN, or the like. It may be a granular structure or the like. Further, the magnetic layer may have any of an inner surface type and a perpendicular type recording format.

The unevenness forming layer is provided for the purpose of controlling the unevenness of the medium surface. There is no particular limitation on the method of forming the unevenness forming layer, the material, and the like. Further, the formation position of the unevenness forming layer is not particularly limited.

In the case of a magnetic recording medium for a non-contact recording type magnetic disk device, the unevenness forming layer forms unevenness due to the unevenness of the unevenness forming layer on the medium surface. It is formed for the purpose of preventing attraction between the magnetic recording medium and the magnetic recording medium and improving CSS durability.

In the case of a magnetic recording medium for a contact recording type magnetic disk drive, the surface of the medium is preferably as flat as possible to avoid damage to the magnetic head and the magnetic recording medium. No need.

The surface roughness of the unevenness forming layer is Ra = 10 to 5
Preferably, it is 0 Å. A more preferred range is Ra = 10 to 30 angstroms.

When Ra is less than 10 angstroms,
Since the surface of the magnetic recording medium is nearly flat, the magnetic head and the magnetic recording medium are attracted to each other, and the magnetic head and the magnetic recording medium are damaged, or the head crashes due to the attracting, resulting in fatal damage. On the other hand, if Ra exceeds 50 angstroms, the glide height becomes large and the recording density is lowered, which is not preferable.

There are various known materials and methods for forming the concavo-convex forming layer, and there is no particular limitation. As the material of the unevenness forming layer, Al, Ti, Cr, Ag, Nb, Ta, Bi, S
i, Zr, Cu, Ce, Au, Sn, Pd, Sb, G
Metals such as e, Mg, In, W, and Pb and alloys thereof, or oxides, nitrides, and carbides of these metals and alloys can be used. From the viewpoint of easy formation, etc., A
l Simple substance, Al alloy, Al oxide (Al ₂ O ₃ etc.), A nitride
It is desirable to use a metal mainly containing Al, such as 1 (AlN or the like).

The unevenness forming layer may be a continuous texture film, or may be constituted by discretely distributed island-like projections. The height of the island-like projections is preferably 100 to 500 Å, and more preferably 100 to 300 Å.

The surface roughness and the height of the unevenness (projections) of the unevenness forming layer can be controlled by the material and composition of the unevenness forming layer, heat treatment conditions, and the like.

Examples of other methods for forming unevenness include texturing by mechanical polishing, texturing by chemical etching, texturing by energy beam irradiation, and the like, and these methods can be combined.

As the protective layer, for example, a Cr film, a Cr alloy film, a carbon film, a hydrogenated carbon film, a zirconia film,
A silica film is exemplified. These protective films are an underlayer,
It can be formed continuously with an in-line type or stationary facing type sputtering device together with a magnetic layer or the like. Further, these protective films may be a single layer, or may be a multilayer structure composed of the same or different films.

Another protective layer may be formed on the above protective layer or in place of the above protective layer. For example, instead of the above-mentioned protective layer, colloidal silica fine particles may be dispersed and applied while diluting tetraalkoxylan with an alcohol-based solvent, and then baked to form a silicon oxide (SiO ₂ ) film. . In this case, it functions as both the protective layer and the unevenness forming layer.

Although various proposals have been made for the lubricating layer, generally, a perfluoropolyether (PF) is generally used.
A liquid lubricant composed of PE) or the like is applied to the surface of the medium by a dipping method (immersion method), a spin coating method, a spray method, or the like, and is formed by performing a heat treatment as needed.

[0092]

EXAMPLES The present invention will be described below more specifically based on examples.

Embodiment 1

(1) Preparation of Glass Substrate A disc-shaped glass substrate (T.sub.g: 600.degree. C.) made of a silicate glass containing high valence metal ions (high Young's modulus glass) (Tg: 600.degree. Inch, inner diameter 0.
8 inches and a thickness of 0.25 inches). In addition, as a silicate glass containing a high valent metal ion, 43% of SiO ₂ , 5% of Al ₂ O ₃ , and Li ₂ O
8%, Na ₂ O 2%, MgO 6%, CaO 19
%, TiO ₂ 15%, and ZrO ₂ 2%.

(2) Chemical Strengthening Step Next, the glass substrate was washed and then chemically strengthened. For the chemical strengthening, a chemically strengthened treatment solution prepared by mixing potassium nitrate (60%) and sodium nitrate (40%) is prepared, and the chemically strengthened treatment solution is heated to 480 ° C., and the cleaned glass substrate preheated to 300 ° C. For about 4 hours. In this immersion, in order to chemically strengthen the entire surface of the glass substrate, the immersion was performed in a state where a plurality of glass substrates were housed in a holder so as to be held at end faces.

As described above, by performing the immersion treatment in the chemical strengthening treatment liquid, lithium ions and sodium ions in the surface layer of the glass substrate are replaced by sodium ions and potassium ions in the chemical strengthening treatment liquid, respectively, and the glass substrate is strengthened. . The thickness of the compressive stress layer formed on the surface layer of the glass substrate was about 100 to 200 μm.

(3) Cooling, acid treatment, and washing steps The glass substrate that has been chemically strengthened is gradually cooled in the first and second slow cooling chambers. First, the glass substrate is pulled up from the chemical strengthening treatment liquid, transferred to a first annealing room heated to 300 ° C., and held therein for about 10 minutes to gradually cool the glass substrate to 300 ° C. Next, the glass substrate was transferred from the first annealing room to the second annealing room heated to 200 ° C.
The glass substrate is gradually cooled to 200 ° C. By thus gradually cooling the glass substrate in two stages, the glass substrate can be released from damage due to thermal strain. Next, the glass substrate that has been slowly cooled is immersed in a 20 ° C.
Maintained for minutes. The glass substrate after the cooling step was sequentially immersed and washed in a washing tank of a neutral detergent, a neutral detergent, pure water, pure water, IPA (isopropyl alcohol), and IPA (steam drying). In addition, ultrasonic waves (frequency 4
0 kHz).

(4) Treatment Step with Molten Salt Using a molten salt of potassium pyrosulfate as a special grade reagent, a glass substrate was immersed in the molten salt for treatment. At this time, as shown in Table 3, steam was added to the molten salt (air: 2000 cm ³ / min, steam: 1 g / min (calculated from the reduced amount of water / hour)).
(Steam temperature: 280 ° C.) was supplied for 2 hours or 4 hours, and then the treatment was performed (samples 1 and 2). For comparison,
Samples were also prepared when no steam was supplied to the molten salt (Comparative Sample 2) and when no treatment with potassium pyrosulfate was performed with the molten salt (Comparative Sample 1). The temperature of the molten salt was 300 ° C., and the immersion time was 5 minutes.

After cleaning the glass substrate after the above treatment, an elution test and an environmental test were performed. Table 3 shows the results.
Shown in Table 3 shows that the treatment with a molten salt of potassium pyrosulfate is effective.

[0100]

[Table 3]

In the elution test, the glass substrate was immersed in ultrapure water heated to 80 ° C. for 24 hours, the elution components were quantified by ion chromatography, and the elution amount of alkali metal ions per glass substrate (μmol / Disk) ) Asked. In the environmental test, the glass substrate was left for 1 week in a high-temperature and high-humidity environment at a temperature of 80 ° C. and a relative humidity of 80%, and the glass surface was observed under a microscope to observe the precipitation of alkali chloride and the like due to elution of the alkali. did.

Example 2 As a glass substrate, lithium disilicate (L
Crystallized glass having i ₂ O.2SiO ₂ ) and α quartz (SiO ₂ ) (SiO ₂ : 76.0% by weight, Li ₂ O:
9.7% by weight, Na ₂ O: 1.0% by weight, K ₂ O: 3.5
Wt%, MgO: 1.5 wt%, Al ₂ O _3: 3.5 wt%, P ₂ O _5: 3.0 wt%, TiO _2: 1.5 wt%,
As ₂ O ₃ : glass containing 0.3% by weight).
After heating at a temperature rising rate of 0 ° C./min and holding at this forming temperature for 1.5 hours, heating at a temperature rising rate of about 2.0 ° C./min.
What was kept at 5 ° C. for 2.5 hours was prepared. This glass substrate was subjected to a washing treatment, then treated with a molten salt of potassium pyrosulfate, and a dissolution test and an environmental test were performed in the same manner as in Example 1. For comparison, a sample not treated with potassium pyrosulfate was similarly tested. Table 4 shows the results.

[0103]

[Table 4]

Table 4 shows that the treatment with a molten salt of potassium pyrosulfate is also effective for ceramics containing alkali.

Example 3 As a glass substrate, a crystallized glass having potassium fluororichterite and potassium canasite as main crystal phases (SiO ₂ : 56.5% by weight, MgO: 11.8% by weight, CaO: 14) 0.1% by weight, glass containing 5.4% by weight of Na ₂ O, 8.7% by weight of K ₂ O, and 5.5% by weight of F) at a heating rate of about 4.0 ° C./min. And maintained at this forming temperature for 1.5 hours, and then heated at a rate of about 2.0 ° C./min and maintained at 840 ° C. for 2.5 hours to prepare. This glass substrate was subjected to a washing treatment, then treated with a molten salt of potassium pyrosulfate, and a dissolution test and an environmental test were performed in the same manner as in Example 1. Also,
For comparison, a sample not treated with potassium pyrosulfate was similarly tested. Table 5 shows the results.

[0106]

[Table 5]

Example 4 The relationship between the time for introducing steam and the time for crystal precipitation was examined for 110 kg of K ₂ S ₂ O ₇ molten salt at 320 ° C. Table 6 shows the results.

[0108]

[Table 6]

When no steam was introduced, crystals were precipitated in 120 hours. When steam was introduced for 3 hours, crystals were precipitated in 220 hours. When steam was continuously introduced, no crystals were precipitated.

Example 5 The difference due to the difference in the method of supplementing moisture was examined. Table 7 shows the results.

[0111]

[Table 7]

The time until the addition of water at the time of crystal precipitation and the subsequent precipitation of crystals is 72 hours after the addition of potassium hydrogen sulfate, and 1 hour when water vapor is introduced for 3 hours.
It was after 00 hours. In each case, the crystals immediately disappeared due to the addition of water.

Example 6 The same procedure as in Example 1 was carried out except that a molten salt of sodium pyrosulfate, a molten salt of potassium hydrogen sulfate, or a molten salt of sodium hydrogen sulfate was used in place of the molten salt of potassium pyrosulfate. Then, a dissolution test and an environmental test were performed.
Table 8 shows the results.

[0114]

[Table 8]

Example 7 A molten salt obtained by mixing potassium pyrosulfate as a special grade reagent and sodium pyrosulfate as a special grade reagent was used, or a molten salt obtained by mixing potassium bisulfate as a special grade reagent and sodium bisulfate as a special grade reagent was used. A dissolution test and an environmental test were carried out in the same manner as in Example 1 except for using. Table 9 shows the results.

[0116]

[Table 9]

Example 8 An elution test and an environmental test were carried out in the same manner as in Example 1 except that a molten salt obtained by adding sulfuric acid to potassium pyrosulfate at a weight ratio of 1: 1 was used. Table 10 shows the results.

[0118]

[Table 10]

Examples 9 to 11 Instead of high-valent metal ion-containing glass, an aluminosilicate glass (composition: SiO ₂
To 74%, a ZrO ₂ 0 to 2.8%, the Al ₂ O ₃ 3 to 1
5%, 7-16% of Li ₂ O, containing Na ₂ O as 4-14% main component, Tg: 500 ° C., the chemical strengthening treatment: 400
(C, 3 hours) (Example 9), soda lime glass (Example 10), soda aluminosilicate glass (Example 1)
1) An elution test and an environmental test were performed in the same manner as in Example 1 except that a borosilicate glass containing a heavy metal ion was used. As a result, the same effect as in Example 1 was recognized. Table 11 shows the results of Example 9 (aluminosilicate glass).

[0120]

[Table 11]

In the above Examples 1 to 11, Examples 1, 6, 7, and 8 in which the chemically strengthened substrate was treated with a molten salt.
Substantially no stress relaxation was observed on the substrates after the molten salt treatments 8 and 9.

Example 12 On both surfaces of the magnetic disk glass substrate obtained in Examples 1 to 11, Al (film thickness 50 Å) / Cr (1
000 angstroms) / CrMo (100 angstroms) underlayer, CoPtCr (120 angstroms) / CrMo (50 angstroms) /
A magnetic layer made of CoPtCr (120 angstroms) and a protective layer of Cr (50 angstroms) were formed by an in-line type sputtering apparatus.

The above substrate is immersed in an organic silicon compound solution (a mixed solution of water, IPA and tetraethoxysilane) in which fine silica particles (particle size: 100 Å) are dispersed,
A protective layer made of SiO ₂ is formed by firing, and a dip treatment is performed on the protective layer with a lubricant made of perfluoropolyether to form a lubricating layer.
A magnetic disk for an R head was obtained.

When a glide test was performed on the obtained magnetic disk, no deformation or deformation of the substrate and no hit or crash caused by foreign substances such as alkali elution or burnt were observed. It was also confirmed that no defect occurred in the film such as the magnetic layer.

Further, when the weather resistance and the life were examined, no deterioration or defect of the magnetic film or the like due to the deterioration of the surface of the glass substrate was found.

Example 13 On both surfaces of the magnetic disk glass substrate obtained in Examples 1 to 11, using an in-line type sputtering apparatus,
Cr underlayer, CrMo underlayer, CoPtCr magnetic layer, C
A protective layer was sequentially formed to obtain a magnetic disk. The same as in Example 12 was confirmed for the above magnetic disk.

Example 14 The underlayer was made of Al / Cr / Cr, and the magnetic layer was made of CoNiCr.
A magnetic disk for a thin film head was obtained in the same manner as in Example 13 except that Ta was used. The same as in Example 12 was confirmed for the above magnetic disk.

Although the present invention has been described with reference to the preferred embodiments, the present invention is not necessarily limited to the above embodiments.

For example, the heating temperature, type, immersion time and the like of the molten salt such as pyrosulfate are not limited to those in the examples, but can be changed appropriately according to the required quality level and the like. Further, after an arbitrary step in the manufacturing process, a washing step can be performed if necessary.

[0130]

As described above, according to the method of the present invention, the elution of alkali and the like can be remarkably suppressed by immersing the information recording medium substrate in a molten salt such as hydrogensulfate and treating it. At the same time, by supplying or supplementing water to the processing liquid, the water does not evaporate and crystals of pyrosulfate precipitate and the effect of the processing does not decrease. Can be processed.

Further, according to the information recording medium of the present invention, since the information recording medium substrate which can significantly suppress the elution of alkali and the like is used, an information recording medium having excellent weather resistance and long life and high reliability can be obtained. Can be manufactured.

Further, according to the glass product of the present invention and the method for producing the same, it is possible to obtain a product in which the elution of alkali and other components is significantly suppressed, so that a highly reliable glass product having excellent weather resistance and life can be obtained. Can be

[Brief description of the drawings]

FIG. 1 is a diagram illustrating one embodiment of a method for supplying steam.

FIG. 2 is a diagram for explaining another embodiment of a method for supplying steam.

[Explanation of symbols]

 DESCRIPTION OF SYMBOLS 1 Closed container 2 Water 3 Air supply pipe 4 Steam pipe 5 Processing tank 6 Molten salt

Claims (19)

[Claims] 1. A process for suppressing the elution of glass components by bringing a substrate mainly composed of glass for an information recording medium into contact with a molten salt containing at least hydrogen sulfate and / or pyrosulfate. A process for suppressing crystallization of the molten salt. 2. A process of contacting the molten salt to suppress the elution of glass components and a process of suppressing crystallization of the molten salt are performed after the chemical strengthening process of the glass substrate, and the process with the molten salt is chemically strengthened. 2. The method for manufacturing a substrate for an information recording medium according to claim 1, wherein the temperature is lower than the processing temperature by at least 50 ° C. 3. The production of a substrate for an information recording medium according to claim 1, wherein the treatment of contacting the molten salt to suppress the elution of glass components is performed at a temperature lower than the sublimation temperature of the molten salt. Method. 4. The method for producing a substrate for an information recording medium according to claim 1, wherein the glass component that suppresses elution is an alkali ion. 5. The method for manufacturing a substrate for an information recording medium according to claim 1, wherein the process of suppressing crystallization of the molten salt is a process of supplying water to the molten salt. . 6. The method for manufacturing a substrate for an information recording medium according to claim 1, wherein the treatment for suppressing crystallization of the molten salt is a treatment for compensating for water lost from the molten salt. Method. 7. The information recording medium according to claim 1, wherein the molten salt containing hydrogen sulfate and / or pyrosulfate is a molten salt obtained by further adding sulfuric acid. Of manufacturing substrates for 8. A method for supplying or supplementing moisture, the method comprising:
The method for producing a substrate for an information recording medium according to claim 5, wherein the method is a method of introducing steam into the molten salt. 9. A method for supplying or supplementing water,
7. The method according to claim 5, wherein the molten salt is placed in a steam atmosphere. 10. The method for manufacturing a substrate for an information recording medium according to claim 5, wherein the method of supplying water or the method of supplementing water is a method of adding hydrogen sulfate to a molten salt. 11. The information according to claim 1, wherein the temperature of the molten salt is from the melting temperature or the liquidus temperature to 500 ° C. and lower than the sublimation temperature of the molten salt. A method for manufacturing a recording medium substrate. 12. The method for manufacturing a substrate for an information recording medium according to claim 1, wherein the glass surface is changed from a non-crosslinked state of Si—O—Na to Si—O—N.
The Na ^{+ of a} is ion-exchanged with hydronium ions to be in a hydrated state, and thereafter, a silanol group is formed by heating and dehydration, and the silanol group is dehydrated. A method for manufacturing a substrate for an information recording medium, wherein the method is performed. 13. The method for manufacturing a substrate for an information recording medium according to claim 1, wherein the surface of the glass substrate is changed from a non-crosslinked state of Si—O—Na to Si—O.
-A method for producing a substrate for an information recording medium, wherein the substrate is brought into a state where Si is crosslinked. 14. The information recording medium substrate according to claim 1, wherein the substrate is a glass substrate subjected to a chemical strengthening treatment.
14. The method for manufacturing a substrate for an information recording medium according to any one of claims 13 to 13. 15. The method for manufacturing an information recording medium substrate according to claim 1, wherein the information recording medium substrate is a crystallized glass substrate. 16. The information recording medium substrate according to claim 1, wherein the information recording medium substrate is a substrate used for a magnetic disk reproduced by a magnetoresistive head. Manufacturing method. 17. An information recording medium comprising at least a recording layer formed on an information recording medium substrate obtained by using the method for manufacturing an information recording medium substrate according to claim 1. Description: recoding media. 18. A process for suppressing the elution of glass components by contacting a glass-based product with a molten salt containing at least hydrogen sulfate and / or pyrosulfate. A method for producing a glass product, comprising performing a treatment for suppressing crystallization. 19. The method for producing a glass product according to claim 18, wherein the treatment of contacting the molten salt to suppress the elution of the glass component is performed at a temperature lower than the sublimation temperature of the molten salt.