JP2000072457A - Forming of float sheet glass and its formation apparatus - Google Patents

Forming of float sheet glass and its formation apparatus

Info

Publication number
JP2000072457A
JP2000072457A JP10248382A JP24838298A JP2000072457A JP 2000072457 A JP2000072457 A JP 2000072457A JP 10248382 A JP10248382 A JP 10248382A JP 24838298 A JP24838298 A JP 24838298A JP 2000072457 A JP2000072457 A JP 2000072457A
Authority
JP
Japan
Prior art keywords
glass
glass strip
float
forming
cooling
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP10248382A
Other languages
Japanese (ja)
Inventor
Akira Yuasa
章 湯浅
Hiroshi Tsuchiya
洋 土屋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Central Glass Co Ltd
Original Assignee
Central Glass Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Central Glass Co Ltd filed Critical Central Glass Co Ltd
Priority to JP10248382A priority Critical patent/JP2000072457A/en
Publication of JP2000072457A publication Critical patent/JP2000072457A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B18/00Shaping glass in contact with the surface of a liquid
    • C03B18/02Forming sheets
    • C03B18/04Changing or regulating the dimensions of the molten glass ribbon
    • C03B18/06Changing or regulating the dimensions of the molten glass ribbon using mechanical means, e.g. restrictor bars, edge rollers
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B18/00Shaping glass in contact with the surface of a liquid
    • C03B18/02Forming sheets
    • C03B18/04Changing or regulating the dimensions of the molten glass ribbon
    • C03B18/08Changing or regulating the dimensions of the molten glass ribbon using gas
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B25/00Annealing glass products
    • C03B25/04Annealing glass products in a continuous way
    • C03B25/06Annealing glass products in a continuous way with horizontal displacement of the glass products
    • C03B25/08Annealing glass products in a continuous way with horizontal displacement of the glass products of glass sheets

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)

Abstract

PROBLEM TO BE SOLVED: To suppress the occurrence of a defect arising from rolls by forcibly cooling both selvages of a glass strip near the inlet of a float bath or in the upstream area of a slow cooling kiln to form a cross-sectionally arch shape crowing in a central part in the axial direction of the glass strip to keep the glass strip contactless with the transporting rolls. SOLUTION: Selvages 4 of a glass strip 3 are forcibly cooled near the inlet of a float bath or in the inlet of a slow cooling kiln, by which the cross- sectionally arch shape crowing in the central part of the glass strip is formed. More specifically, blowing means 9 for a cooling medium to the selvages 4 of the glass strip 3 are disposed between the outlet of the float bath or the inlet of the slow cooling kiln, by which these potions are cooled. Air or gaseous nitrogen below ordinary temp. is used as the cooling medium. A central part 5 of the glass strip 3 in such a state does not came into contact with the transporting rolls and, therefore, the trouble by the contact with the rolls is eliminated.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、フロート板ガラス
の形成方法および形成装置に関する。
The present invention relates to a method and an apparatus for forming a float glass sheet.

【0002】[0002]

【従来技術および解決すべき課題】フロート板ガラス製
造に際し、ガラス帯が未だ固化しない状態において搬送
ロールと接触することにより、ロール傷や、ロールに沈
着した酸化錫の付着等の欠陥がしばしばずる。
2. Description of the Related Art In the manufacture of float glass sheets, defects such as roll flaws and adhesion of tin oxide deposited on the rolls often occur due to contact with a conveying roll in a state where the glass strip has not yet solidified.

【0003】これを防ぐ方法としては、ガラス表面に亜
硫酸ガスを接触させ、ガラス表面に芒硝の保護被覆を形
成する方法があるが、環境の清浄化が叫ばれる今日にお
いては、亜硫酸ガス量を極力抑える状況にあり、近い将
来においてはこの方法は採用されない方向にある。
As a method for preventing this, there is a method in which sulfur dioxide gas is brought into contact with the glass surface to form a protective coating of sodium sulfate on the glass surface. In the near future, this method will not be adopted in the near future.

【0004】特開昭53−75212 号公報には、ガラス帯が
フロートバスから引出された後、下方からのガスクッシ
ョンで支持する際に、ガスの供給、放出を調整すること
により、ガラス帯が断面アーチ状となるようにし、前記
欠陥を排除することが開示されている。しかしガスクッ
ションを形成するうえで、その設備規模は大がかりとな
り、またガス調整も容易ではない。
Japanese Patent Application Laid-Open No. 53-75212 discloses that, when a glass strip is drawn out of a float bath and supported by a gas cushion from below, the supply and discharge of gas are adjusted to reduce the glass strip. It is disclosed that the cross section has an arch shape and the defect is eliminated. However, in forming the gas cushion, the equipment scale becomes large and gas adjustment is not easy.

【0005】本発明は、前記不具合を解消し、容易な手
段でロール起因の欠陥の発生を抑制できるフロート板ガ
ラスの形成方法および形成装置を提供することを目的と
する。
An object of the present invention is to provide a method and an apparatus for forming a float glass sheet which can solve the above-mentioned problems and can suppress the occurrence of defects caused by rolls by simple means.

【0006】[0006]

【課題を解決するための手段】本発明は、フロート板ガ
ラス製造におけるフロートバス出口ないし徐冷窯上流域
において、ガラス帯の両耳部を強制冷却することによ
り、ガラス帯の幅方向における中央部が凸状の、横断面
アーチ型を形成して、搬送ロールとは非接触とするフロ
ート板ガラスの形成方法である。
According to the present invention, the center of the glass strip in the width direction is formed by forcibly cooling both ears of the glass strip at the float bath outlet or in the upstream area of the lehr in the manufacture of the float glass sheet. This is a method for forming a float glass sheet that forms a convex, cross-section arched shape and is not in contact with a transport roll.

【0007】また本発明は、フロートバス出口ないし徐
冷窯上流域の適宜箇所において、ガラス帯の両耳部への
冷却用媒体のブロウイング手段を配設し、またはガラス
帯の両耳部に冷却用媒体を導く配管を近接させた、前記
フロート板ガラスの形成方法に用いるフロート板ガラス
の形成装置を提供する。
Further, according to the present invention, there is provided a means for blowing a cooling medium to both ears of a glass strip at an appropriate position in a float bath outlet or an upstream area of an annealing furnace, or at both ears of a glass strip. Provided is an apparatus for forming a float glass sheet used in the method for forming a float glass sheet, wherein a pipe for guiding a cooling medium is brought close to the pipe.

【0008】[0008]

【発明の実施の形態】以下本発明の実施の形態を添付の
図面に基づき説明する。図1は、板ガラス製造における
フロートバスから徐冷窯にかけての、ガラス帯の移動状
況、ガラス帯両耳部の冷却手段の1例(ガラス帯両耳部
への冷却媒体の吹付けの例)を示す概略部分縦断面図、
図2Aは図1にかかるガラス帯両耳部の冷却状況を示す
概略部分斜視図、図2Bは図2Aの拡大部分斜視図であ
る。
Embodiments of the present invention will be described below with reference to the accompanying drawings. FIG. 1 shows an example of a moving state of a glass strip from a float bath to a slow cooling kiln in sheet glass production, and an example of cooling means for both ears of a glass strip (an example of spraying a cooling medium to both ears of a glass strip). Schematic partial longitudinal sectional view,
2A is a schematic partial perspective view showing a cooling state of the both ears of the glass strip according to FIG. 1, and FIG. 2B is an enlarged partial perspective view of FIG. 2A.

【0009】フロート板ガラス製造においては、ガラス
原料調合物はガラス溶融窯(図示せず)に投入され、溶
融ガラス化、均質化、脱泡清澄化されたうえで、フロー
トバス1の中の溶融金属錫浴2の上に流延され、該フロ
ートバス1(バス内雰囲気は金属錫が酸化されないよう
に、酸素を含まない窒素ガス、水素ガス、あるいはそれ
らの混合ガスとすることはフロート板ガラス成形におけ
る通常の技術手段である)において、周知のトップロー
ル等(図示せず)により、流延ガラスの上面側よりガラ
スの幅方向両側部を更に両サイドに引張り、所望のガラ
ス厚みに成形(製板)、調整される。
In the manufacture of a float glass sheet, a glass raw material mixture is charged into a glass melting furnace (not shown), melted, homogenized, defoamed and clarified, and then melted in a float bath 1. It is cast on a tin bath 2 and the float bath 1 (the atmosphere in the bath is a nitrogen gas containing no oxygen, a hydrogen gas, or a mixed gas thereof so as not to oxidize the metal tin is used for forming a float glass sheet. In conventional technical means), both sides in the width direction of the glass are further pulled to both sides from the upper surface side of the cast glass by a well-known top roll or the like (not shown), and formed into a desired glass thickness (plate making). ), Adjusted.

【0010】このように形成されたガラス帯3は、採板
可能な中央部5に対し、トップロール牽引跡部分を含む
幅方向両側周縁部、すなわち耳部4を併存しており、そ
のままフロートバス1より引出され、さらに徐冷窯6に
送入され、徐々に冷却される。なお徐冷窯6より移出さ
れたガラス帯3は、採板工程(図示せず)で前記両耳部
を切断除去したうえで採板される。
[0010] The glass strip 3 thus formed has both sides in the width direction including the top roll pulling traces, that is, the ears 4 coexisting with the central part 5 capable of sampling, and the float bath as it is. 1 and then sent to the slow cooling kiln 6 where it is gradually cooled. The glass strip 3 transferred from the annealing furnace 6 is sampled after cutting and removing the both ears in a sampling step (not shown).

【0011】フロートバス1より引出されたガラス帯3
の表面は、歪点(通常のソーダ石灰シリカ系ガラスにお
いて 520℃前後、なおソーダ石灰シリカ系ガラスにおい
て熱膨張係数は90×10ー7/℃前後である)を越えてお
り、またガラス帯の内部は更に温度の高い熱軟化状態に
あり、ガラス帯3が徐冷窯6の内において充分固化され
ないうちは、フロートバス1より引出される際のリフト
アウトロール7や、徐冷窯内の移送ロール8に、ガラス
帯の中央部5の下面が接触する際に、ロール跡、ロール
傷や、ロールに沈着した酸化錫の転写、転着等により、
商品価値を損なう欠陥がしばしば生ずる。
A glass strip 3 drawn from a float bath 1
Surface exceeds the strain point (about 520 ° C for ordinary soda-lime-silica glass, and the coefficient of thermal expansion is about 90 × 10-7 / ° C for soda-lime-silica glass). The inside is in a heat-softened state with a higher temperature. Until the glass strip 3 is sufficiently solidified in the annealing furnace 6, the lift-out roll 7 when it is drawn from the float bath 1 and the transfer in the annealing furnace 6 When the lower surface of the central portion 5 of the glass strip comes into contact with the roll 8, the roll marks, the roll scratches, and the transfer and transfer of tin oxide deposited on the roll,
Defects often detract from commercial value.

【0012】前記したように、ガラス表面に亜硫酸ガス
を接触させ、ガラス表面に芒硝被膜、すなわち保護被覆
を形成する方法もあるが、環境問題のうえから忌避され
る傾向にある。
As described above, there is also a method in which sulfur dioxide gas is brought into contact with the glass surface to form a mirabilite film, that is, a protective coating on the glass surface. However, this method tends to be avoided due to environmental problems.

【0013】本発明においては、フロートバス1の出口
ないし徐冷窯6の入口付近において、ガラス帯3の両耳
部4を強制冷却することにより、ガラス帯3の幅方向に
おける中央部5が凸状の、横断面アーチ型を形成させる
ものである。
In the present invention, the central portion 5 in the width direction of the glass strip 3 is protruded by forcibly cooling the both ears 4 of the glass strip 3 near the outlet of the float bath 1 or the inlet of the lehr 6. , A cross-section arch shape is formed.

【0014】具体的には一実施形態として、フロートバ
ス1の出口ないし徐冷窯6の入口の間の適宜箇所、好適
にはフロートバス1の出口近傍において、ガラス帯3の
両耳部4への冷却用媒体のブロウイング手段9を配設
し、該部を冷却するもので、冷却媒体としては常温(20
〜30℃)ないしそれ以下の温度の空気や窒素ガス、例え
ばガラスと反応せずガラスを変質するようなことのない
窒素ガスを、吹付け用スリットや、図示のごとく吹付け
用ノズル9よりブロウイングする。
More specifically, as one embodiment, at an appropriate place between the outlet of the float bath 1 and the inlet of the lehr 6, preferably near the outlet of the float bath 1, the both ends 4 of the glass strip 3 are connected. A cooling medium blowing means 9 is provided to cool the part.
Air or nitrogen gas having a temperature of 30 ° C. or lower, for example, nitrogen gas which does not react with the glass and does not deteriorate the glass, is blown through a blowing slit or a blowing nozzle 9 as shown in the drawing. Wing.

【0015】一実施条件および結果を以下に示す。 フロートガラス帯の幅:3.3m フロートガラス移送速度:11m/分 窒素ガス(約30℃)吹付け量:片側5L/分(両側10L/
分) フロートガラス幅方向中央部の湾曲高さ:5cm(図2A
中zで示す)
[0015] One embodiment conditions and results are shown below. Float glass band width: 3.3 m Float glass transfer speed: 11 m / min Nitrogen gas (approximately 30 ° C.) spray amount: 5 L / min on one side (10 L / min on both sides)
Minute) Width of the center of the float glass in the width direction: 5 cm (Fig. 2A)
(Indicated by z)

【0016】別の例として、フロートバス1の出口近傍
から徐冷窯6の入口に到る間、ガラス帯の両耳部4の直
下(耳部との間隔10mm以下)に、冷却用の20℃程度の水
を通水した配管を近接したところ、前記同様の、ガラス
帯中央部5において上に凸のアーチ型が形成された。
As another example, while cooling from the vicinity of the outlet of the float bath 1 to the entrance of the annealing furnace 6, the cooling belt 20 is placed immediately below both ears 4 of the glass strip (at a distance of 10 mm or less from the ears). When a pipe through which water of about ° C. was passed was placed close to the pipe, an upwardly convex arch shape was formed in the center portion 5 of the glass band as described above.

【0017】前記局部(耳部)冷却による作用について
は充分解明されないが、図2Bに示すように、ガラス帯
の耳部4が冷却により矢印→←xのごとく収縮し、それ
に対しガラス帯中央部5はより高い温度に維持され、矢
印←→yのごとく拡張状態で弛緩された状態にあり、従
ってガラス帯中央部5は上下方に湾曲する余地がある
が、下方への湾曲は移送ロールにより規制され、また、
ガラス帯における下流域では、ガラス帯全体が均一冷
却、固化され平板化する結果として、該部のガラス帯中
央部5が凸状の、横断面アーチ型を形成するものと推測
される。
The effect of the local (ear) cooling is not fully understood, but as shown in FIG. 2B, the ear 4 of the glass band shrinks as shown by the arrow → ← x due to cooling, while the center of the glass band is contracted. 5 is maintained at a higher temperature and is in a state of being relaxed in an expanded state as shown by an arrow ← → y, so that the center portion 5 of the glass strip can be bent upward and downward, but the downward bending is performed by a transfer roll. Regulated and
It is presumed that in the downstream region of the glass strip, as a result of uniform cooling, solidification, and flattening of the entire glass strip, the glass strip central portion 5 of the part forms a convex, cross-sectional arch shape.

【0018】このような形態のガラス帯3は、その中央
部5がロール7、8と接触することがないので、ロール
7、8と接触することによる前記弊害を排除できる。な
お、ガラス帯の両耳部に冷却用媒体を導く配管を近接さ
せ、それを介して冷却させる手段において、前記配管と
して水冷管以外にも、風冷管、その他気化し易い液の通
管等がある。
In the glass strip 3 having such a configuration, the central portion 5 does not come into contact with the rolls 7 and 8, so that the above-mentioned adverse effects caused by contact with the rolls 7 and 8 can be eliminated. In addition, in a means for bringing a pipe for guiding a cooling medium close to both ears of the glass strip and cooling through the pipe, in addition to the water-cooled pipe, the pipe may be a wind-cooled pipe, or another pipe for easily vaporizing liquid. There is.

【0019】前記耳部の冷却により形成されたガラス帯
の断面アーチ型構造は、ガラス帯の幅方向全面が、徐冷
窯の下流域を経て、徐々に冷却される際に、前記強制冷
却の耳部とガラス帯中央部、およびガラス帯内部との温
度差が無くなることにより、ガラス帯自体平坦化され
て、採板に際してガラス板の平坦性が損なわれるような
ことがなく、平板ガラスとしての品質を維持できる。
The cross-section arch-shaped structure of the glass band formed by cooling the ear portion is characterized in that when the entire surface of the glass band in the width direction is gradually cooled through the downstream area of the slow cooling kiln, the forced cooling is performed. By eliminating the temperature difference between the ear part, the center part of the glass band, and the inside of the glass band, the glass band itself is flattened, and the flatness of the glass plate is not impaired at the time of sampling, and as a flat glass Quality can be maintained.

【0020】[0020]

【発明の効果】本発明によれば、フロート板ガラス製造
において、容易な手段でロール起因の欠陥の発生を抑制
できるという効果を奏する。
According to the present invention, there is an effect that in the production of a float plate glass, the occurrence of defects caused by rolls can be suppressed by an easy means.

【図面の簡単な説明】[Brief description of the drawings]

【図1】板ガラス製造におけるフロートバスから徐冷窯
にかけての、ガラス帯の移動状況、ガラス帯両耳部の冷
却手段の1例(ガラス帯両耳部への冷却媒体の吹付けの
例)を示す概略部分縦断面図である。
FIG. 1 shows a moving state of a glass strip from a float bath to a slow cooling kiln in sheet glass production, and an example of cooling means for both ears of a glass strip (an example of spraying a cooling medium to both ears of a glass strip). It is a general | schematic partial longitudinal cross-sectional view shown.

【図2】図2Aは、図1にかかるガラス帯両耳部の冷却
状況を示す概略部分斜視図、図2Bは図2Aの拡大部分
斜視図である。
FIG. 2A is a schematic partial perspective view showing a cooling state of both ears of a glass strip according to FIG. 1, and FIG. 2B is an enlarged partial perspective view of FIG. 2A.

【符号の説明】[Explanation of symbols]

1 フロートバス 2 溶融金属錫浴 3 ガラス帯 4 ガラス帯の耳部 5 ガラス帯の中央部 6 徐冷窯 7 リフトアウトロール 8 移送ロール 9 ブロウイング手段(吹付け用ノズル) DESCRIPTION OF SYMBOLS 1 Float bath 2 Molten tin bath 3 Glass band 4 Edge of glass band 5 Central part of glass band 6 Slow-cooling kiln 7 Lift-out roll 8 Transfer roll 9 Blowing means (spray nozzle)

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】フロート板ガラス製造におけるフロートバ
ス出口ないし徐冷窯上流域において、ガラス帯の両耳部
を強制冷却することにより、ガラス帯の幅方向における
中央部が凸状の、横断面アーチ型を形成して、搬送ロー
ルとは非接触とすることを特徴とするフロート板ガラス
の形成方法。
1. An arc-shaped cross section in which a central portion in a width direction of a glass band is convex by forcibly cooling both ears of a glass band at a float bath outlet or an upstream region of a lehr in a float glass sheet production. And forming the float glass out of contact with a transport roll.
【請求項2】フロートバス出口ないし徐冷窯上流域の適
宜箇所において、ガラス帯の両耳部への冷却用媒体のブ
ロウイング手段を配設したことを特徴とする請求項1記
載のフロート板ガラスの形成方法に用いるフロート板ガ
ラスの形成装置。
2. A float glass sheet according to claim 1, wherein blow means for blowing a cooling medium to both ears of the glass strip is provided at an appropriate position from the float bath outlet to the upstream area of the lehr. For forming a float glass sheet used in the method for forming a glass sheet.
【請求項3】フロートバス出口ないし徐冷窯上流域の適
宜箇所において、ガラス帯の両耳部に冷却用媒体を導く
配管を近接させたことを特徴とする請求項1記載のフロ
ート板ガラスの形成方法に用いるフロート板ガラスの形
成装置。
3. The float glass sheet according to claim 1, wherein a pipe for guiding a cooling medium is brought close to both ears of the glass strip at an appropriate position from the float bath outlet to the upstream area of the lehr. An apparatus for forming a float glass sheet used in the method.
JP10248382A 1998-09-02 1998-09-02 Forming of float sheet glass and its formation apparatus Pending JP2000072457A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10248382A JP2000072457A (en) 1998-09-02 1998-09-02 Forming of float sheet glass and its formation apparatus

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10248382A JP2000072457A (en) 1998-09-02 1998-09-02 Forming of float sheet glass and its formation apparatus

Publications (1)

Publication Number Publication Date
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008120535A1 (en) * 2007-04-03 2008-10-09 Asahi Glass Company, Limited Process for producing flat glass, apparatus for forming buffer layer of flat glass, and flat glass producing equipment
JP2014136667A (en) * 2013-01-18 2014-07-28 Nippon Electric Glass Co Ltd Glass substrate with protective film
CN104496158A (en) * 2014-12-27 2015-04-08 蚌埠玻璃工业设计研究院 Coagulation liquid guide top cover for special float glass tin bath
CN106477864A (en) * 2016-11-25 2017-03-08 中国建材国际工程集团有限公司 Temperature control mechanism between float glass process annealing kiln and seal box and temperature control method

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008120535A1 (en) * 2007-04-03 2008-10-09 Asahi Glass Company, Limited Process for producing flat glass, apparatus for forming buffer layer of flat glass, and flat glass producing equipment
JP5223861B2 (en) * 2007-04-03 2013-06-26 旭硝子株式会社 Sheet glass manufacturing method, sheet glass buffer layer forming apparatus, and sheet glass manufacturing equipment
JP2014136667A (en) * 2013-01-18 2014-07-28 Nippon Electric Glass Co Ltd Glass substrate with protective film
CN104496158A (en) * 2014-12-27 2015-04-08 蚌埠玻璃工业设计研究院 Coagulation liquid guide top cover for special float glass tin bath
CN106477864A (en) * 2016-11-25 2017-03-08 中国建材国际工程集团有限公司 Temperature control mechanism between float glass process annealing kiln and seal box and temperature control method
CN106477864B (en) * 2016-11-25 2022-06-03 中国建材国际工程集团有限公司 Temperature control mechanism between float annealing kiln and sealing box and temperature adjusting method

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