JP3217176B2 - Method and apparatus for manufacturing float glass - Google Patents

Method and apparatus for manufacturing float glass

Info

Publication number
JP3217176B2
JP3217176B2 JP04225593A JP4225593A JP3217176B2 JP 3217176 B2 JP3217176 B2 JP 3217176B2 JP 04225593 A JP04225593 A JP 04225593A JP 4225593 A JP4225593 A JP 4225593A JP 3217176 B2 JP3217176 B2 JP 3217176B2
Authority
JP
Japan
Prior art keywords
glass ribbon
glass
molten metal
bath
metal bath
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP04225593A
Other languages
Japanese (ja)
Other versions
JPH06227831A (en
Inventor
督博 鏡味
憲一 小村
経博 宮田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
AGC Inc
Original Assignee
Asahi Glass Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Glass Co Ltd filed Critical Asahi Glass Co Ltd
Priority to JP04225593A priority Critical patent/JP3217176B2/en
Publication of JPH06227831A publication Critical patent/JPH06227831A/en
Application granted granted Critical
Publication of JP3217176B2 publication Critical patent/JP3217176B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B18/00Shaping glass in contact with the surface of a liquid
    • C03B18/02Forming sheets
    • C03B18/04Changing or regulating the dimensions of the molten glass ribbon
    • C03B18/06Changing or regulating the dimensions of the molten glass ribbon using mechanical means, e.g. restrictor bars, edge rollers
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B18/00Shaping glass in contact with the surface of a liquid
    • C03B18/02Forming sheets
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B18/00Shaping glass in contact with the surface of a liquid
    • C03B18/02Forming sheets
    • C03B18/20Composition of the atmosphere above the float bath; Treating or purifying the atmosphere above the float bath
    • C03B18/22Controlling or regulating the temperature of the atmosphere above the float tank

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、フロートガラスの製造
方法およびその装置に関する。
The present invention relates to a method and an apparatus for producing float glass.

【0002】[0002]

【従来の技術】フロートガラスの製造においては、溶融
金属を収容した浴槽の水平な浴面に溶融ガラスを連続的
に供給しながらガラスリボンを形成し、ガラスリボンを
浴槽の出口から引き上げる延伸力で目標厚に成形され
る。次いで、ガラスリボンは、溶融金属浴槽出口より引
き出され、リフトアウトロール上を搬送され、徐冷窯に
搬入され、徐冷される。ガラスリボンは、溶融金属浴槽
出口と徐冷窯との間では、外気に触れその温度の影響を
受ける。厚の厚い例えば2mm以上の板ガラスを生産
する場合に発生する反りは、通常永久歪域で生成するた
め、徐冷窯内の上流すなわち徐冷域の温度(ソーダライ
ムガラスでは通常480℃〜530℃)のコントロール
で対応できる。そのため、溶融金属浴槽出口と徐冷窯と
の間での温度分布は反りにほとんど影響しない。
2. Description of the Related Art In the production of float glass, a glass ribbon is formed while continuously supplying molten glass to a horizontal bath surface of a bath tub containing molten metal, and the glass ribbon is drawn by a drawing force pulling up from an outlet of the bath tub. It is molded to the target thickness. Next, the glass ribbon is pulled out from the outlet of the molten metal bath, conveyed on a lift-out roll, carried into a lehr, and gradually cooled. The glass ribbon is exposed to the outside air between the molten metal bath outlet and the lehr, and is affected by the temperature. Warping that occurs when producing thick thick example 2mm or more glass sheets of Mi, in order to generate a normal permanent deformation zone, (usually 480 ° C. to 530 ° C. in a soda-lime glass) upstream that is, the temperature of the annealing zone in the annealing furnace kill in pairs response in the control. Therefore, the temperature distribution between the outlet of the molten metal bath and the kiln has almost no influence on the warpage.

【0003】一方、厚の薄い例えば2mm以下の薄板
ガラスの成形においては、より高温の530〜600℃
の温度域で温度分布が反りに影響を与える。すなわち、
2mm以下の薄板ガラスの成形においては、530〜6
00℃の温度域で生じる一時歪により容易に変形が生
じ、その後の徐冷窯内の温度コントロールでは前記変形
が修復されないまま、製品に反りとなって残課題があ
った。
On the other hand, in the molding of thin e.g. 2mm or less of the thin glass of Thickness, higher temperature of five hundred and thirty to six hundred ° C.
The temperature distribution affects the warpage in the temperature range of. That is,
In forming thin glass having a thickness of 2 mm or less, 530 to 6
Easily deformed by transient distortion occurs at 00 temperature range of ℃ occurs while the deformation at a temperature controlled subsequent slow the cooling kiln may not be repaired, there is a residual Ru problems become warped product.

【0004】[0004]

【発明が解決しようとする課題】本発明は、従来の技術
が有していた上記課題を解消し、反りのない薄板ガラス
の製造できるフロートガラスの製造方法およびその装置
の提供を目的とする。
SUMMARY OF THE INVENTION An object of the present invention is to solve the above-mentioned problems of the prior art and to provide a method and apparatus for manufacturing a float glass capable of manufacturing a thin glass sheet without warpage.

【0005】[0005]

【課題を解決するための手段】本発明は、溶融金属を収
容した溶融金属浴槽の水平な浴面に溶融ガラスを連続的
に供給しながらガラスリボンを形成し、ガラスリボンを
溶融金属浴槽の出口から引き上げる延伸力で目標厚
成形し、該ガラスリボンを徐冷窯に搬送するフロートガ
ラスの製造方法において、該溶融金属浴槽の出口と徐冷
窯との間において、ガラスリボンの幅方向の温度分布を
調整することを特徴とするフロートガラスの製造方法お
よびその装置である。
According to the present invention, a glass ribbon is formed while continuously supplying molten glass to a horizontal bath surface of a molten metal bath containing molten metal, and the glass ribbon is discharged from the molten metal bath. molded into the target thickness at a stretching force to pull from a method of manufacturing a float glass for conveying the glass ribbon annealing kiln, between the outlet and the annealing kiln of the molten metal bath, in the width direction of the glass ribbon A method and apparatus for manufacturing a float glass characterized by adjusting a temperature distribution.

【0006】以下図面に基づいて説明する。図1は本発
明の製造方法を実施するのに好適な装置の断面図であ
る。ガラスリボン1は溶融金属浴槽2内で所望の厚
幅に成形された後、浴槽下流端上部に設けた電熱ヒータ
3により最終的に塑性変形し得る温度に調整され、リフ
トアウトロール4およびレヤーロール5の牽引力によっ
て溶融金属浴槽2の出口より引き出され、リフトアウト
ロール4上を搬送される。
A description will be given below with reference to the drawings. FIG. 1 is a sectional view of an apparatus suitable for carrying out the manufacturing method of the present invention. Glass ribbon 1 is desired Thickness in the molten metal bath 2,
After being formed into a width, the temperature is adjusted to a temperature at which plastic deformation can be finally performed by an electric heater 3 provided at the upper end of the bathtub downstream end, and is pulled out from the outlet of the molten metal bathtub 2 by the pulling force of the lift-out roll 4 and the layer roll 5. It is transported on the lift-out roll 4.

【0007】次いで、ガラスリボン1は徐冷窯6内に搬
送される。溶融金属浴槽2の出口と徐冷窯6の入口との
間には、後述するように温度調整装置19が設けてあ
り、ガラスリボン1が外気に触れ幅方向の温度分布が変
動するのを防いでいる。溶融金属浴槽2には上部構造に
設けたパイプ7から水素と窒素の還元性混合ガスが供給
され、浴槽内は常に大気圧以上に保持される。ガラスリ
ボン1が引き出される溶融金属浴槽2の出口からは還元
性雰囲気が流出している。
Next, the glass ribbon 1 is transported into the annealing furnace 6. A temperature adjusting device 19 is provided between the outlet of the molten metal bath 2 and the inlet of the lehr 6, as described later, to prevent the glass ribbon 1 from contacting the outside air and fluctuating the temperature distribution in the width direction. In. A molten mixed gas of hydrogen and nitrogen is supplied to the molten metal bath 2 from a pipe 7 provided in the upper structure, and the inside of the bath is always maintained at a pressure higher than the atmospheric pressure. A reducing atmosphere flows out of an outlet of the molten metal bath 2 from which the glass ribbon 1 is drawn.

【0008】溶融金属浴槽2内の圧力低下ならびに酸素
の侵入によって溶融金属浴槽2内の溶融金属8が汚染さ
れるのを防ぐため、ガラスリボンと接触しないレベルに
ドレープ9を配置する。ガラスリボン1が引き出される
溶融金属浴槽2の出口から流出する還元性雰囲気はガラ
スリボン1の上面に沿って燃焼し、該燃焼で生じるフレ
ームによってガラスリボン1の幅方向で温度変動や局部
加熱が生じる。したがって、ドレープ9は、これらの熱
により変形し下面レベルが不均衡になるのを避けるた
め、ステンレス製のものを使用するのが望ましい。
In order to prevent the molten metal 8 in the molten metal bath 2 from being contaminated by the pressure drop in the molten metal bath 2 and the intrusion of oxygen, the drape 9 is arranged at a level not in contact with the glass ribbon. Glass ribbon 1 is pulled out
Reducing atmosphere flowing out of the outlet of the molten metal bath 2 is burned along the upper surface of the glass ribbon 1, the temperature change and local heating occurs in the width direction of the glass ribbon 1 by frame <br/> over arm caused by the combustion . Therefore, it is desirable to use a drape 9 made of stainless steel in order to prevent the drape 9 from being deformed by the heat and causing the lower surface level to be unbalanced.

【0009】リフトアウトロールの下方には、ドロス
ボックス10が設けられ、ドロスボックス10内で溶融
金属浴槽2の出口とリフトアウトロールとの間にはガ
ラスリボン1の進行方向と直交する方向にパイプ11が
設けられている。このパイプ11は、ガラスリボンの下
面中央付近で窒素等の不活性ガスを噴出している。該不
活性ガスは400〜600℃に予熱した後噴出すること
が好ましい。これは、不活性ガスによってガラスリボン
が局部的に冷却されるのを防ぐためである。不活性ガス
は浴槽2から流出する還元性雰囲気中の水素濃度を希釈
し、前述の燃焼フレームによる温度変動や局部加熱を抑
制できるとともに浴槽内の圧力低下や浴槽内の汚染を防
止できる。
[0009] Under the lift-out roll 4, dross box 10 is provided, a direction perpendicular to the traveling direction of the glass ribbon 1 between the inside dross box 10 and the outlet and the lift-out roll 4 of the molten metal bath 2 Is provided with a pipe 11. This pipe 11 blows out an inert gas such as nitrogen near the center of the lower surface of the glass ribbon. The inert gas is preferably ejected after preheating to 400 to 600 ° C. This is to prevent the glass ribbon from being locally cooled by the inert gas. The inert gas dilutes the hydrogen concentration in the reducing atmosphere flowing out of the bathtub 2 and suppresses temperature fluctuations and local heating caused by the combustion flame.
Anti-contamination of the pressure drop and the bathtub in the bathtub along with the kill in control
Kill at stop.

【0010】リフトアウトロール4の上方には、鋼材製
のドレープフード12が設けてあり、ドレープフード1
2の上面は、断熱材13により覆われており、放熱を防
止している。ガラスリボン1とリフトアウトロール4の
接点の上部にそれぞれドレープ9を配置している。ドレ
ープ9、9の間には、ドレープフード12に密着してド
レープヒータ14が設けてあり、ガラスリボン1の幅方
向の温度分布を調整できるようになっている。17はド
ロスボックスヒータであり、ドレープヒータ14と同様
ガラスリボン1の幅方向の温度分布を調整できるように
なっている。
A drape hood 12 made of steel is provided above the lift out roll 4.
2 is covered with a heat insulating material 13 to prevent heat radiation. A drape 9 is arranged above the contact point between the glass ribbon 1 and the lift-out roll 4. A drape heater 14 is provided between the drapes 9 and 9 in close contact with the drape hood 12 so that the temperature distribution in the width direction of the glass ribbon 1 can be adjusted. Reference numeral 17 denotes a dross box heater, which can adjust the temperature distribution in the width direction of the glass ribbon 1 similarly to the drape heater 14.

【0011】図2は図1の上部構造の平面図であり、電
熱ヒータの配置を示している。ドレープフード12内で
はドレープ9、9間に2列のドレープヒータ14を配置
し、各ドレープヒータは幅方向に細分化されており、ガ
ラスリボン1の上面温度を精密にコントロールできる。
FIG. 2 is a plan view of the upper structure of FIG. 1, showing the arrangement of the electric heater. Is in the drape hood 12 disposed drape heater 14 of two rows between drape 9,9, each drape heater is subdivided in the width direction, cut with precision controls the upper surface temperature of the glass ribbon 1.

【0012】図3は図1の下部構造の平面図である。温
度調整室の下部構造でリフトアウトロールが収納され
るドロスボックス10は鋼材構造であり、従来の装置で
は積極的に保温されていなかったが、本発明が実施され
る薄板ガラスを製造する装置では、ドロスボックス10
内面全域を断熱材15で覆い下部および側部への放熱
を防止している点に特徴がある。各リフトアウトロール
4下部には浴槽2と徐冷窯6の間の気流を遮断するため
にグラファイト製のシールブロック16が据え付けらて
いる。
FIG. 3 is a plan view of the lower structure of FIG. The dross box 10 in which the lift-out rolls 4 are housed in the lower part of the temperature control chamber is made of a steel material and is not actively kept warm by the conventional apparatus, but is an apparatus for manufacturing thin glass in which the present invention is implemented. Then, dross box 10
It is characterized the entire inner surface to a point that prevents heat radiation to the lower and side covered with a heat insulating material 15. A seal block 16 made of graphite is installed below each lift-out roll 4 in order to shut off an air flow between the bathtub 2 and the lehr 6.

【0013】ドロスボックス10内のリフトアウトロー
ル4、4の間には2列のドロスボックスヒータ17がガ
ラスリボン1をはさんで前記ドレープヒータ14と対向
するように配設されている。ドロスボックスヒータ17
も同様に幅方向に細分化されておりガラスリボン1の下
面温度を精密に調整できる。ドロスボックスヒータ17
に関しては側方からの放熱を防止する効果をねらい側方
部のみ配置することでも十分に効果がある。
Two rows of dross box heaters 17 are arranged between the lift-out rolls 4 and 4 in the dross box 10 so as to face the drape heater 14 with the glass ribbon 1 interposed therebetween. Dross box heater 17
Cut at precisely adjusted even lower surface temperature of the glass ribbon 1 are subdivided similarly in the widthwise direction. Dross box heater 17
Regarding the above, it is sufficiently effective to dispose only the side portions to prevent the heat radiation from the side.

【0014】薄板ガラスに発生する反りは、この溶融金
属浴槽2の出口と徐冷窯6との入口との間において、ガ
ラスリボン1の上下面の温度差ならびにガラスリボン1
の幅方向の温度分布に起因して発生する熱変形である。
したがって、このガラスリボン1の上下面の温度差を小
さくし、このガラスリボン1の幅方向の温度分布を平坦
にするようにドレープヒータ、ドロスボックスヒータ等
により調整する。ガラスリボン1は該領域で精密に温度
調整された後徐冷窯6へ搬送される。18は天蓋であ
る。
The warpage generated in the thin glass is caused by the temperature difference between the upper and lower surfaces of the glass ribbon 1 and the glass ribbon 1 between the outlet of the molten metal bath 2 and the inlet of the lehr 6.
Is a thermal deformation that occurs due to the temperature distribution in the width direction.
Therefore, the temperature difference between the upper and lower surfaces of the glass ribbon 1 is reduced, and the temperature distribution in the width direction of the glass ribbon 1 is adjusted by a drape heater, a dross box heater, and the like. The glass ribbon 1 is conveyed to the annealing furnace 6 after the temperature is precisely adjusted in the area. 18 is a canopy.

【0015】[0015]

【作用】2mm以下の薄板ガラスの成形では、徐冷域よ
りも高温域で生じる一時歪によって容易に変形が生じ、
その後の徐冷過程でこの変形が修復されず、製品に反り
として残る。前記温度域は、500〜600℃に相当
し、ガラスリボンの粘度η(単位:ポアズ)はlogη
=11〜17の領域である。
In the formation of a thin glass sheet having a thickness of 2 mm or less, deformation is easily caused by temporary strain generated in a higher temperature range than in a gradually cooled region.
This deformation is not repaired in the subsequent slow cooling process and remains as warpage in the product. The temperature range corresponds to 500 to 600 ° C., a glass ribbon viscosity eta (unit: poise) is logη
= 11-17.

【0016】本発明において、ドロスボックスの積極的
な保温によって可塑状態にあるガラスリボンの上下およ
び幅方向の不均一な温度降下を抑え、かつ上下および幅
方向に細分化された電熱ヒータによって精密に温度調整
することにより、薄板ガラスの成形において反りの発生
を抑できる。
In the present invention, the non-uniform temperature drop in the vertical and width directions of the glass ribbon in the plastic state is suppressed by the active heat retention of the dross box, and precisely by the electric heater subdivided in the vertical and width directions. by adjusting the temperature, it suppression of warpage in the molding of thin glass.

【0017】[0017]

【発明の効果】本発明によれば、薄板ガラスの成形にお
いてガラスリボンの温度を高温域で精密に調整し反りの
発生を抑できる。また通常厚のガラスの製造におい
ても曲率500mR(メートルアール)以上の表面平滑
性を有する高平坦度ガラスを製造できる。
According to the present invention, the temperature of the glass ribbon can suppression precisely adjusted warpage in a high temperature range in the molding of thin glass. The wear usually high flatness glass having a curvature 500MR (meters radius) or more surface smoothness even in the production of glass Thickness in manufacturing.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明が実施される装置の断面図FIG. 1 is a sectional view of an apparatus in which the present invention is implemented.

【図2】図1の上部構造の平面図FIG. 2 is a plan view of the superstructure of FIG. 1;

【図3】図1の下部構造の平面図FIG. 3 is a plan view of the lower structure of FIG. 1;

【符号の説明】[Explanation of symbols]

1:ガラスリボン 2:溶融金属浴槽 4:リフトアウトロール 6:徐冷窯 10:ドロスボックス 12:ドレープフード 14:ドレープヒータ 17:ドロスボックスヒータ 18:天蓋 19:温度調節装置 1: glass ribbon 2: molten metal bath 4: lift-out roll 6: slow cooling kiln 10: dross box 12: drape hood 14: drape heater 17: dross box heater 18: canopy 19: temperature controller

Claims (4)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】溶融金属を収容した溶融金属浴槽の水平な
浴面に溶融ガラスを連続的に供給しながらガラスリボン
を形成し、ガラスリボンを溶融金属浴槽の出口から引き
上げる延伸力で目標厚に成形し、該ガラスリボンを徐
冷窯に搬送するフロートガラスの製造方法において、該
溶融金属浴槽の出口と徐冷窯との間において、ガラスリ
ボンの幅方向の温度分布を調整することを特徴とするフ
ロートガラスの製造方法。
1. A glass ribbon formed while continuously supplying molten glass on a horizontal bath surface of the molten metal bath containing a molten metal, the target Thickness at a stretching force to pull the glass ribbon from the exit of the molten metal bath In the method for manufacturing a float glass in which the glass ribbon is conveyed to an annealing furnace, the temperature distribution in the width direction of the glass ribbon is adjusted between an outlet of the molten metal bath and the annealing furnace. Method for producing float glass.
【請求項2】溶融金属を収容した溶融金属浴槽の水平な
浴面に溶融ガラスを連続的に供給しながらガラスリボン
を形成し、ガラスリボンを溶融金属浴槽の出口から引き
上げる延伸力で目標厚に成形し、該ガラスリボンを徐
冷窯に搬送するフロートガラスの製造装置において、該
溶融金属浴槽の出口と徐冷窯との間に、ガラスリボンの
幅方向の温度分布を調整する温度調整装置を設けたこと
を特徴とするフロートガラスの製造装置。
Wherein the glass ribbon is formed while continuously supplying molten glass on a horizontal bath surface of the molten metal bath containing a molten metal, the target Thickness at a stretching force to pull the glass ribbon from the exit of the molten metal bath In a float glass manufacturing apparatus for forming a glass ribbon into a glass ribbon and transferring the glass ribbon to a lehr, a temperature controller for adjusting a temperature distribution in a width direction of the glass ribbon between an outlet of the molten metal bath and the lehr. An apparatus for manufacturing float glass, comprising:
【請求項3】前記浴槽出口において、ガラスリボンを引
き上げつつ移送するリフトアウトロールがドロスボック
ス内に配設され、ドロスボックスが断熱構造体である請
求項2に記載のフロートガラスの製造装置。
Wherein in said bath outlet, lift-out roll for transferring while pulling the glass ribbon is disposed in the dross box, dross box according to <br/> Motomeko 2 Ru insulating structure der float Glass manufacturing equipment.
【請求項4】前記浴槽出口において、浴槽内に充填され
ている還元性雰囲気の燃焼を緩和する装置を有する請
項2または3に記載のフロートガラスの製造装置。
Wherein in said bath outlet, apparatus for manufacturing a float glass according to Motomeko 2 or 3 that have a device to mitigate the burning of reducing atmosphere filled in the tub.
JP04225593A 1993-02-05 1993-02-05 Method and apparatus for manufacturing float glass Expired - Lifetime JP3217176B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP04225593A JP3217176B2 (en) 1993-02-05 1993-02-05 Method and apparatus for manufacturing float glass

Publications (2)

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JPH06227831A JPH06227831A (en) 1994-08-16
JP3217176B2 true JP3217176B2 (en) 2001-10-09

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Country Link
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