ITVI20090090A1 - CONVERSION PROCEDURE OF THE CHICKEN IN SOLID FUEL WITH SEPARATION OF ORGANIC FLUID MIXTURE. - Google Patents

CONVERSION PROCEDURE OF THE CHICKEN IN SOLID FUEL WITH SEPARATION OF ORGANIC FLUID MIXTURE. Download PDF

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Publication number
ITVI20090090A1
ITVI20090090A1 IT000090A ITVI20090090A ITVI20090090A1 IT VI20090090 A1 ITVI20090090 A1 IT VI20090090A1 IT 000090 A IT000090 A IT 000090A IT VI20090090 A ITVI20090090 A IT VI20090090A IT VI20090090 A1 ITVI20090090 A1 IT VI20090090A1
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IT
Italy
Prior art keywords
separation
manure
biomass
water
organic fluid
Prior art date
Application number
IT000090A
Other languages
Italian (it)
Inventor
Savino Sartori
Original Assignee
Savino Sartori
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Savino Sartori filed Critical Savino Sartori
Priority to IT000090A priority Critical patent/ITVI20090090A1/en
Priority to PCT/IB2010/051792 priority patent/WO2010122525A1/en
Priority to EP10727858A priority patent/EP2421943A1/en
Publication of ITVI20090090A1 publication Critical patent/ITVI20090090A1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • C10L5/42Solid fuels essentially based on materials of non-mineral origin on animal substances or products obtained therefrom, e.g. manure
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Sludge (AREA)
  • Processing Of Solid Wastes (AREA)
  • Extraction Or Liquid Replacement (AREA)

Description

DESCRIZIONE dell'invenzione avente per titolo: DESCRIPTION of the invention having as title:

"PROCEDIMENTO DI CONVERSIONE DELLA POLLINA IN "PROCEDURE FOR CONVERSION OF POLLINA IN

SOLIDO CON SEPARAZIONE DI UNA MISCELA FLUIDA ORGANICA” SOLID WITH SEPARATION OF AN ORGANIC FLUID MIX "

Oggetto della presente invenzione è un procedimento di trattamento termico eseguito in modo continuo o discontinuo (per cariche) in un reattore (1 ), sotto vuoto, con temperature di processo tra i 250°C e i 400°C , con vaporizzazione dell'umidità naturale della stessa pollina e/o alimentazione di vapore da un generatore esterno (2), avente il vapore funzione di trasportare le molecole organiche vaporizzate per effetto della temperatura e derivale dalla decomposizione termica. The object of the present invention is a heat treatment process carried out continuously or discontinuously (by batches) in a reactor (1), under vacuum, with process temperatures between 250 ° C and 400 ° C, with vaporization of natural humidity of the same manure and / or steam supply from an external generator (2), having the function of transporting the organic molecules vaporized due to the effect of temperature and deriving from thermal decomposition.

La temperatura di volatilizzazione e decomposizione viene ottenuta mediante riscaldamento a temperatura controllata della superficie esterna del reattore, utilizzando un vettore termico idoneo, proveniente da un generatore (6), quale l' olio diatermico o meglio una miscela eutettica di sali fusi aventi una temperatura di fusione a partire da 135°C e utilizzabili fino ad una massimo di 480 °C. The volatilization and decomposition temperature is obtained by heating the external surface of the reactor at a controlled temperature, using a suitable thermal vector, coming from a generator (6), such as diathermic oil or better a eutectic mixture of molten salts having a temperature of melting from 135 ° C and usable up to a maximum of 480 ° C.

Il ciclo di trattamento dei materiale per il processo continuo prevede un tempo di ritenzione della pollina (o della biomassa similare) idoneo al raggiungimento della temperatura obiettivo di non meno di 60 minuti primi, con permanenza in temperatura per un tempo non inferiore a 30 minuti primi. Analogamente un ciclo discontinuo si attua con un tempo di riscaldo di 60/120 minuti primi, secondo la massa caricata, e una permanenza in temperatura non inferiore a 30 minuti primi, seguito da raffreddamento naturale o per mezzo di una corrente dì vapore a bassa temperatura ( 80÷120° C}, per accelerarne lo scarico in condizioni atmosferiche . The material treatment cycle for the continuous process foresees a retention time of the manure (or similar biomass) suitable for reaching the target temperature of not less than 60 minutes, with temperature permanence for a time of not less than 30 minutes. . Similarly, a discontinuous cycle takes place with a heating time of 60/120 minutes, according to the loaded mass, and a temperature permanence of not less than 30 minutes, followed by natural cooling or by means of a stream of steam at low temperature. (80 ÷ 120 ° C}, to accelerate the discharge in atmospheric conditions.

Diversamente dai processi di pirolisi o gassificazione, che possono essere egualmente controllali nel processo di riscaldo onde orientare e determinare il tipo di gas prodotto e generalmente con riscaldo diretto con bruciatore e/o a spese di una combustione di parte della materia prima utilizzata, il processo di cracking realizzato in corrente di vapore sotto vuoto evita le ossidazioni e il realizzarsi di catrami, avendo il vapore una funzione diluente inibente i processi di ristrutturazione molecolare via carbo catione e/o radicalica in fase di gas e consentendo il rapido trasporto delle molecole evaporate o ottenute dalla dissociazione fuori del reattore e condensate con condensatori (3) a miscela o a superficie. Unlike pyrolysis or gasification processes, which can be equally controlled in the heating process in order to orient and determine the type of gas produced and generally with direct heating with the burner and / or at the expense of a combustion of part of the raw material used, the process of cracking carried out in a steam current under vacuum avoids oxidation and the creation of tars, since the steam has a diluent function that inhibits the molecular restructuring processes via carbo cation and / or radicals in the gas phase and allows the rapid transport of the evaporated or obtained molecules from dissociation outside the reactor and condensed with mixture or surface condensers (3).

La condensazione del vapore unitamente alle molecole volatili inibisce la formazione dì incrostazioni sugli scambiatori di raffreddamento e condensazione, oltre alla inibizione di reazioni indesiderate di condensazione tra molecole diverse. The condensation of the vapor together with the volatile molecules inhibits the formation of encrustations on the cooling and condensation exchangers, as well as the inhibition of undesired condensation reactions between different molecules.

Le molecole organiche separate nel corso del ciclo di trattamento, che si presentano con pesi molecolari diversi e strutture chimiche con gruppi funzionali diversi e condensate unitamente all'acqua, sono facilmente separabili dall’acqua stessa con processi di evaporazione e strippaggio, io un evaporatore (4), ottenendo un olio e un distillato avente un TOC inferiore a 5,000 mg/l e azoto ammoniacale inferiore a 1500 mg/l e assenza di elementi quali cloro, zolfo in misura superiore a 10 mg/l L’olio separato, nel caso della pollina, contiene dal 7 al 10% di Azoto nelle diverse forme ammoniacali e amminiche e azoto negli stati di ossidazione superiori, contenenti ossigeno in concentrazione inferiore a 1000 mg/kg. The organic molecules separated during the treatment cycle, which have different molecular weights and chemical structures with different functional groups and condensed together with water, are easily separable from the water itself with evaporation and stripping processes, i an evaporator ( 4), obtaining an oil and a distillate having a TOC lower than 5,000 mg / l and ammonia nitrogen lower than 1500 mg / l and absence of elements such as chlorine, sulfur in excess of 10 mg / l The separated oil, in the case of manure , contains from 7 to 10% of nitrogen in the various ammonia and amino forms and nitrogen in the higher oxidation states, containing oxygen in a concentration lower than 1000 mg / kg.

L’olio ottenuto ha caratteristiche di elevata biodegradabilità tanto da poter essere alimentato negli impianti di biogas nella misura possibile dal bilancio di alimento del sistema accettore. The oil obtained has high biodegradability characteristics so that it can be fed into biogas plants to the extent possible from the feed balance of the acceptor system.

Né nella fase carbonizzata, né nell’olio, né nel condensato acquoso si sono rilevate presenze di diossine o furani . Neither in the carbonized phase, nor in the oil, nor in the aqueous condensate were there any presence of dioxins or furans.

Il processo consente l' ottenimento di tre flussi ben caratterizzati: acqua, una miscela fluida organica, definita impropriamente olio, e carbone, idonei ad essere scaricati, stoccati e trasportati cor una propria composizione con caratteristiche tali da essere considerati non più un rifiuto ma materie prime secondarie o derivate da biomasse, I l carbone inoltre non presenta alcun odore sensibile e, data la sua stabilità chimica, può essere insilato per alimentare cicli di combustione con assenza di produzione di NOxe presenta una analisi tipica del carbone di legna. The process allows to obtain three well-characterized flows: water, an organic fluid mixture, improperly defined as oil, and coal, suitable to be unloaded, stored and transported in their own composition with characteristics such as to be considered no longer waste but materials. furthermore, coal has no sensible odor and, given its chemical stability, it can be ensiled to feed combustion cycles with no NOx production and presents a typical analysis of charcoal.

DESCRIZIONE DELL'IMPIANTO SYSTEM DESCRIPTION

L’impianto è costituito da un reattore (1 ). generalmente ad asse orizzontale o sub orizzontale, alimentato sotto vuoto a mezzo di cantere sezionate da valvole, con prevuoto tra alimentazioni successive e continue, mentre nel caso di cariche discontinue il vuoto viene applicato al completamento della carica. The plant consists of a reactor (1). generally with a horizontal or sub-horizontal axis, fed under vacuum by means of tubes sectioned by valves, with pre-vacuum between successive and continuous feeds, while in the case of discontinuous charges the vacuum is applied upon completion of the charge.

Un agitatore con asse palettate provoca la miscelazione e l'avanzamento del materiale dalla bocca di ingresso verso la bocca di uscita con velocità variabile, secondo la natura del prodotto e la sua umidità. A stirrer with a bladed axis causes the mixing and advancement of the material from the inlet to the outlet with variable speed, according to the nature of the product and its humidity.

Vapore viene iniettato al bisogno sul lato di alimento da un generatore di vapore (2) e estratto verso lo scarico con le sostanze volatizzate passando attraverso un condensatore (3) e quindi al sistema del vuoto (5) avente un effetto di scru degli Nella camera esterna al reattore viene alimentato il fluido diatermico di riscaldo, proveniente da un generatore (6), tipicamente miscela di sali eutettici nel campo da 135 a 480° C riscaldati con i tradizionali sistemi quali energia elettrica, gas caldi da combustione, combustione dello stesso carbone prodotto; la generazione di sali eutettici si accompagna anche alla produzione del vapore di trasporto. Steam is injected as needed on the feed side by a steam generator (2) and extracted towards the discharge with the volatized substances passing through a condenser (3) and then to the vacuum system (5) having a scrubbing effect in the chamber. the diathermic heating fluid, coming from a generator (6), is fed outside the reactor, typically a mixture of eutectic salts in the range from 135 to 480 ° C heated with traditional systems such as electricity, hot combustion gases, combustion of the same coal product; the generation of eutectic salts is also accompanied by the production of transport steam.

La miscela aequa/olio viene separata con le tecniche evaporative tradizionali io un evaporatore 14), con separazione dell'olio e rinvio dell’acqua in esubero al trattamento acque convenzionale di fermentazione biologica aerobica/anaerobica o al riciclo parziale per la generazione di vapore. The aequa / oil mixture is separated with traditional evaporative techniques or an evaporator 14), with separation of the oil and return of the excess water to conventional water treatment of aerobic / anaerobic biological fermentation or to partial recycling for the generation of steam.

Claims (6)

DESCRIZIONE dell’invenzione avente per TITOLO: "PROCEDIMENTO DI CONVERSIONE DELLA POLLINA IN C SOLIDO CON SEPARAZIONE DI UNA MISCELA FLUIDA ORGANICA" RIVENDICAZIONI 1 . Si rivendica un processo di trattamento della pollina e analoghe biomasse operato per riscaldamento sotto vuoto, in corrente di vapore a temperatura tra 250°C e 400° C. DESCRIPTION of the invention with TITLE: "PROCEDURE FOR CONVERSION OF POLLINA IN C SOLID WITH SEPARATION OF AN ORGANIC FLUID MIX " CLAIMS 1. A process for treating manure and similar biomass is claimed, operated by heating under vacuum, in a steam stream at a temperature between 250 ° C and 400 ° C. 2. Si rivendica l'utilizzo di un generatore di calore con sali fusi o ad olio diatermico operante fino a 480°C per riscaldare il reattore all'interno del quale è alimentata la pollina o la biomassa da trattare. 2. The use of a heat generator with molten salts or diathermic oil operating up to 480 ° C to heat the reactor into which the manure or biomass to be treated is fed is claimed. 3. Si rivendica l'utilizzo di un condensatore a superficie (scambiatore di calore) per la condensazione del vapore di trasporto e delle sostanze volatili prodotte con temperatura di condensazione tra 0°C e 100°C. Lo scambiatore può essere raffreddato ad acqua o ad aria. 3. The use of a surface condenser (heat exchanger) for the condensation of the transport vapor and of the volatile substances produced with a condensation temperature between 0 ° C and 100 ° C is claimed. The exchanger can be water-cooled or air-cooled. 4. Si rivendica l' utilizzo di un sistema del vuoto di tipo a miscela con eiettore Venturi utilizzante come liquido vettore lo stesso condensato od acqua, 4. The use of a mixture type vacuum system with Venturi ejector using the same condensate or water as carrier liquid is claimed, 5. Si rivendica l'utilizzo di un evaporatore nelle sue versioni tradizionali per la separazione della fase organica dall’acqua condensata. 5. The use of an evaporator in its traditional versions for the separation of the organic phase from condensed water is claimed. 6. Si rivendica l'utilizzo del processo definito per la pollina ad ogni altra biomassa utilizzando analogo processo e vettori termici.6. The use of the process defined for manure is claimed for any other biomass using a similar process and thermal vectors.
IT000090A 2009-04-24 2009-04-24 CONVERSION PROCEDURE OF THE CHICKEN IN SOLID FUEL WITH SEPARATION OF ORGANIC FLUID MIXTURE. ITVI20090090A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
IT000090A ITVI20090090A1 (en) 2009-04-24 2009-04-24 CONVERSION PROCEDURE OF THE CHICKEN IN SOLID FUEL WITH SEPARATION OF ORGANIC FLUID MIXTURE.
PCT/IB2010/051792 WO2010122525A1 (en) 2009-04-24 2010-04-23 Process for converting biomass to solid fuel
EP10727858A EP2421943A1 (en) 2009-04-24 2010-04-23 Process for converting biomass to solid fuel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT000090A ITVI20090090A1 (en) 2009-04-24 2009-04-24 CONVERSION PROCEDURE OF THE CHICKEN IN SOLID FUEL WITH SEPARATION OF ORGANIC FLUID MIXTURE.

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ITVI20090090A1 true ITVI20090090A1 (en) 2010-10-25

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EP (1) EP2421943A1 (en)
IT (1) ITVI20090090A1 (en)
WO (1) WO2010122525A1 (en)

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WO2013123529A1 (en) * 2012-02-16 2013-08-22 Biochar Now, Llc Airflow control and heat recovery in a managed kiln
US10160911B2 (en) 2012-02-16 2018-12-25 Biochar Now, Llc Exhaust system for a biochar kiln
US11135728B2 (en) 2012-02-16 2021-10-05 Biochar Now, Llc Lid assembly for portable biochar kiln
CA2862921A1 (en) 2012-02-16 2013-08-22 Biochar Now, Llc Controlled kiln and manufacturing system for biochar production
CA2863105A1 (en) 2012-03-11 2013-08-22 Biochar Now, Llc Airflow control and heat recovery in a managed kiln
US9878924B2 (en) 2015-02-06 2018-01-30 Biochar Now, Llc Contaminant removal from water bodies with biochar
US20170009141A1 (en) * 2015-07-06 2017-01-12 Worcester Polytechnic Institute Molten salt pyrolysis for bio-oil and chemicals
ITUB20156081A1 (en) * 2015-12-02 2017-06-02 Res Reliable Environmental Solutions Soc Cooperativa METHOD TO OBTAIN PELLETS FROM ANIMAL AND / OR VEGETABLE MATERIALS AND PELLETS SO OBTAINED
US10385273B2 (en) 2016-04-03 2019-08-20 Biochar Now, Llc Biochar kiln

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JPH10121074A (en) * 1996-10-18 1998-05-12 Shuzo Nakazono Method for converting animal dung into fuel
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GB1398230A (en) * 1972-07-05 1975-06-18 Univ California Method of heat treating excreta and products thereof
US4026037A (en) * 1975-02-18 1977-05-31 Adolf Buchholz Apparatus for steam drying
DD143467A1 (en) * 1979-05-04 1980-08-20 Berthold Zobel PROCESS FOR THE ECO-FRIENDLY DRYING OF GUELLE
DE3603317A1 (en) * 1986-02-04 1987-08-06 Wilfried Moesing Method of drying natural fertilisers and agricultural products, drying in a heated vacuum chamber after previous thickening and pressing
NL8902932A (en) * 1989-11-28 1991-06-17 Drese Jan Theo Evapn. of liq. manure or sepd. aq. fraction - with preceding removal of volatile components by stripping with air or steam
DE9107080U1 (en) * 1991-06-08 1992-10-01 Südfleisch GmbH, 8000 München Device for disposal of biomass with high water content
JPH10121074A (en) * 1996-10-18 1998-05-12 Shuzo Nakazono Method for converting animal dung into fuel
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Also Published As

Publication number Publication date
WO2010122525A1 (en) 2010-10-28
EP2421943A1 (en) 2012-02-29

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