ITPI20130018A1 - DECORATIVE LAYERED GLASS AND RELATED PRODUCTION METHOD. - Google Patents
DECORATIVE LAYERED GLASS AND RELATED PRODUCTION METHOD.Info
- Publication number
- ITPI20130018A1 ITPI20130018A1 IT000018A ITPI20130018A ITPI20130018A1 IT PI20130018 A1 ITPI20130018 A1 IT PI20130018A1 IT 000018 A IT000018 A IT 000018A IT PI20130018 A ITPI20130018 A IT PI20130018A IT PI20130018 A1 ITPI20130018 A1 IT PI20130018A1
- Authority
- IT
- Italy
- Prior art keywords
- glass
- layer
- decorative
- adhesive
- laminated glass
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 11
- 239000010410 layer Substances 0.000 claims description 41
- 239000011521 glass Substances 0.000 claims description 37
- 239000000463 material Substances 0.000 claims description 36
- 239000005340 laminated glass Substances 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 25
- 239000000853 adhesive Substances 0.000 claims description 17
- 230000001070 adhesive effect Effects 0.000 claims description 17
- 239000002184 metal Substances 0.000 claims description 16
- 229910052751 metal Inorganic materials 0.000 claims description 16
- 239000007769 metal material Substances 0.000 claims description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000012790 adhesive layer Substances 0.000 claims description 10
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 9
- 239000004925 Acrylic resin Substances 0.000 claims description 8
- 229920000178 Acrylic resin Polymers 0.000 claims description 8
- 239000002313 adhesive film Substances 0.000 claims description 7
- 235000019441 ethanol Nutrition 0.000 claims description 7
- 238000013517 stratification Methods 0.000 claims description 7
- 239000004033 plastic Substances 0.000 claims description 6
- 229920003023 plastic Polymers 0.000 claims description 6
- 230000008878 coupling Effects 0.000 claims description 5
- 238000010168 coupling process Methods 0.000 claims description 5
- 238000005859 coupling reaction Methods 0.000 claims description 5
- 239000012815 thermoplastic material Substances 0.000 claims description 5
- 238000009499 grossing Methods 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 238000005498 polishing Methods 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000005530 etching Methods 0.000 claims description 3
- 239000002985 plastic film Substances 0.000 claims description 3
- 229920006255 plastic film Polymers 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000003892 spreading Methods 0.000 claims description 2
- 230000007480 spreading Effects 0.000 claims description 2
- 230000000694 effects Effects 0.000 description 14
- 230000008569 process Effects 0.000 description 8
- 239000000049 pigment Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 229910000906 Bronze Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000005329 float glass Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- 229920006352 transparent thermoplastic Polymers 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10165—Functional features of the laminated safety glass or glazing
- B32B17/10247—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44F—SPECIAL DESIGNS OR PICTURES
- B44F1/00—Designs or pictures characterised by special or unusual light effects
- B44F1/02—Designs or pictures characterised by special or unusual light effects produced by reflected light, e.g. matt surfaces, lustrous surfaces
- B44F1/04—Designs or pictures characterised by special or unusual light effects produced by reflected light, e.g. matt surfaces, lustrous surfaces after passage through surface layers, e.g. pictures with mirrors on the back
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44F—SPECIAL DESIGNS OR PICTURES
- B44F1/00—Designs or pictures characterised by special or unusual light effects
- B44F1/06—Designs or pictures characterised by special or unusual light effects produced by transmitted light, e.g. transparencies, imitations of glass paintings
- B44F1/066—Designs or pictures characterised by special or unusual light effects produced by transmitted light, e.g. transparencies, imitations of glass paintings comprising at least two transparent elements, e.g. sheets, layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
- B32B2037/1276—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives water-based adhesive
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2311/00—Metals, their alloys or their compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2315/00—Other materials containing non-metallic inorganic compounds not provided for in groups B32B2311/00 - B32B2313/04
- B32B2315/08—Glass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2451/00—Decorative or ornamental articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/22—Removing surface-material, e.g. by engraving, by etching
- B44C1/225—Removing surface-material, e.g. by engraving, by etching by engraving
Landscapes
- Laminated Bodies (AREA)
- Joining Of Glass To Other Materials (AREA)
Description
DESCRIZIONE DELL’INVENZIONE DESCRIPTION OF THE INVENTION
TITOLO TITLE
VETRO STRATIFICATO DECORATIVO E RELATIVO METODO DI PRODUZIONE DECORATIVE LAMINATED GLASS AND RELATIVE PRODUCTION METHOD
SETTORE TECNICO TECHNICAL FIELD
La presente invenzione concerne un vetro stratificato decorativo del tipo comprendente almeno due pannelli di vetro accoppiati mediante interposizione di una pellicola di materiale plastico scelto tra PVB, EVA o TPU, ed in cui tra i due pannelli à ̈ interposto almeno un ulteriore strato idoneo a realizzare un effetto decorativo. The present invention relates to a decorative laminated glass of the type comprising at least two glass panels coupled by interposition of a film of plastic material chosen from PVB, EVA or TPU, and in which at least one further layer suitable for making a decorative effect.
La presente invenzione concerne anche un metodo per la realizzazione di pannelli di vetro stratificato decorativo. The present invention also relates to a method for making decorative laminated glass panels.
STATO DELL’ARTE STATE OF THE ART
Vetri stratificati decorativi che hanno l’effetto di una superficie interna metallizzata sono noti. Questi vetri stratificati sono ottenuti secondo la tecnica nota accoppiando almeno due pannelli di vetro tra i quali à ̈ interposto almeno uno strato intermedio il quale viene verniciato o rivestito con vernici a base di resine contenenti pigmenti metallici. Un esempio di un metodo per la produzione di vetro stratificato decorativo come sopra sommariamente delineato à ̈ fornito in EP 0565494 in cui su una faccia di un pannello di vetro à ̈ applicato uno strato in resina epossidica trasparente sul quale viene trasferito un motivo decorativo il quale viene poi ricoperto con uno strato di una vernice contenente pigmenti dorati o argentati. Infine, viene eseguita la stratificazione del vetro accoppiando tramite riscaldamento al lato verniciato un ulteriore pannello di vetro con interposizione di una pellicola di PVB. I pannelli in vetro stratificato ottenuti con il metodo sopra delineato presentano motivi decorativi con effetto metallizzato che tuttavia risulta relativamente opaco e con colori artefatti rispetto a quelli della foglia metallica. Decorative laminated glass which has the effect of a metallized internal surface are known. These laminated glasses are obtained according to the known technique by coupling at least two glass panels between which at least an intermediate layer is interposed which is painted or coated with resin-based paints containing metal pigments. An example of a method for the production of decorative laminated glass as summarily outlined above is provided in EP 0565494 in which a transparent epoxy resin layer is applied to one face of a glass panel on which a decorative motif is transferred which it is then covered with a layer of a varnish containing gold or silver pigments. Finally, the stratification of the glass is carried out by coupling a further glass panel with the interposition of a PVB film to the painted side by heating. The laminated glass panels obtained with the method outlined above have decorative motifs with a metallic effect which, however, is relatively opaque and with artificial colors compared to those of the metal leaf.
Sono noti anche supporti decorativi, quali mattonelle, piastrelle, o cornici in legno, o simili, sui quali un motivo decorativo ad effetto metallizzato à ̈ ottenuto applicando sul supporto uno strato di materiale metallico in foglia tramite interposizione di uno specifico adesivo. In alcuni casi, i suddetti supporti sui quali à ̈ riportato il motivo decorativo realizzato mediante applicazione di materiale metallico in foglia, vengono stratificati, mediante applicazione sullo strato metallico in foglia di un pannello in vetro, ad esempio accoppiando quest’ultimo a caldo mediante interposizione di una pellicola di un materiale termoplastico, quale PVB, oppure vengono verniciati, ad esempio con una resina epossidica o poliuretanica, in modo da formare uno strato protettivo trasparente. In ogni caso, in questa tipologia di prodotti decorativi, il materiale metallico in foglia à ̈ visibile solo da un lato in quanto il pannello che funge da supporto per l’applicazione del materiale metallico in foglia à ̈ scelto in un materiale sostanzialmente non trasparente. La necessità di applicare il materiale in foglia metallica su un supporto non trasparente deriva dal fatto che, qualunque sia il supporto, l’adesivo utilizzato per fissare il materiale metallico in foglia al supporto non à ̈, una volta essiccato, perfettamente trasparente oppure presenta zone di non perfetta trasparenza che, in ogni caso, alterano l’effetto estetico del metallo in foglia. Per questo motivo, vale a dire per rendere non visibili le suddette imperfezioni, quando gli elementi decorativi vengono realizzati con materiale metallico in foglia, si preferisce convenzionalmente utilizzare supporti non trasparenti facendo in modo che l’effetto decorativo derivante dalla presenza del materiale metallico in foglia sia visibile solo dal lato opposto a quello di incollaggio del materiale metallico in foglia stesso. Decorative supports are also known, such as tiles, tiles, or wooden frames, or the like, on which a decorative pattern with a metallic effect is obtained by applying a layer of metallic leaf material to the support by interposing a specific adhesive. In some cases, the aforementioned supports on which the decorative motif made by applying metallic leaf material is shown are stratified by applying a glass panel to the metal leaf layer, for example by hot coupling the latter by means of interposition of a film of a thermoplastic material, such as PVB, or they are painted, for example with an epoxy or polyurethane resin, so as to form a transparent protective layer. In any case, in this type of decorative products, the metal leaf material is visible only from one side as the panel that acts as a support for the application of the metal leaf material is chosen in a substantially non-transparent material. . The need to apply the metal leaf material on a non-transparent substrate derives from the fact that, whatever the substrate, the adhesive used to fix the metal leaf material to the substrate is not, once dried, perfectly transparent or has areas of imperfect transparency which, in any case, alter the aesthetic effect of the metal in the leaf. For this reason, that is to say to make the aforementioned imperfections invisible, when the decorative elements are made with metallic leaf material, it is conventionally preferred to use non-transparent supports ensuring that the decorative effect deriving from the presence of the metallic material in leaf is visible only from the side opposite to that of gluing of the metal material in the leaf itself.
SINTESI DELL’INVENZIONE SUMMARY OF THE INVENTION
Scopo della presente invenzione à ̈ allora quello di proporre un vetro stratificato decorativo comprendente elementi decorativi adatti a realizzare un effetto metallizzato. The purpose of the present invention is therefore to propose a decorative laminated glass comprising decorative elements suitable for achieving a metallized effect.
Ulteriore scopo della presente invenzione à ̈ quello di realizzare prodotti decorativi sostanzialmente bidimensionali contenenti materiale metallico in foglia in cui tali elementi decorativi siano visibili da entrambi i lati di tali prodotti. A further object of the present invention is that of realizing substantially two-dimensional decorative products containing metallic leaf material in which said decorative elements are visible from both sides of said products.
Ulteriore scopo della presente invenzione à ̈ quello di proporre un metodo per la realizzazione di pannelli di vetro stratificato decorativo in cui l’effetto decorativo sia di tipo metallizzato. A further object of the present invention is to propose a method for making decorative laminated glass panels in which the decorative effect is of the metallized type.
Un altro scopo della presente invenzione à ̈ quello di proporre un metodo per la realizzazione di vetro stratificato decorativo comprendente almeno uno strato intermedio costituito da materiale metallico in foglia. Another object of the present invention is to propose a method for making decorative laminated glass comprising at least an intermediate layer consisting of metallic leaf material.
Secondo un aspetto della presente invenzione gli scopi suddetti ed altri ancora sono raggiunti per mezzo di un dispositivo secondo quanto espresso e caratterizzato nella rivendicazione indipendente 1. According to an aspect of the present invention, the aforementioned and other purposes are achieved by means of a device according to what is expressed and characterized in independent claim 1.
Le rivendicazioni dipendenti dalla rivendicazione 1 espongono altre caratteristiche della presente invenzione o varianti dell’idea di soluzione principale. The claims dependent on claim 1 disclose other characteristics of the present invention or variants of the main solution idea.
Un vetro stratificato decorativo convenzionalmente comprende almeno due pannelli di vetro tra i quali à ̈ interposto una pellicola di materiale plastico scelto tra TPU, PVB o EVA. A decorative laminated glass conventionally comprises at least two glass panels between which a film of plastic material chosen from TPU, PVB or EVA is interposed.
Secondo un aspetto caratteristico della presente invenzione il vetro del’invenzione comprende un primo strato intermedio costituito da un pellicola adesiva ad elevata trasparenza interposto tra uno strato di vetro e detta pellicola di materiale plastico, ed un secondo strato intermedio costituito da materiale metallico in foglia di spessore compreso tra 0,01 e 1 micrometri, detto strato di materiale metallico in foglia essendo interposto tra detta pellicola adesiva ad elevata trasparenza e detta pellicola in materiale plastico. According to a characteristic aspect of the present invention, the glass of the invention comprises a first intermediate layer consisting of a highly transparent adhesive film interposed between a layer of glass and said film of plastic material, and a second intermediate layer consisting of metallic leaf material with a thickness of between 0.01 and 1 micrometers, said layer of metal sheet material being interposed between said highly transparent adhesive film and said plastic film.
Il prodotto decorativo piano sopra delineato ha la peculiarità di comprendere, quale elemento decorativo, un materiale metallico in foglia il quale à ̈ visibile, sostanzialmente senza differenze estetiche, da entrambi i lati del prodotto. The flat decorative product outlined above has the peculiarity of including, as a decorative element, a metallic leaf material which is visible, substantially without aesthetic differences, from both sides of the product.
Vantaggiosamente la suddetta pellicola adesiva ad elevata trasparenza à ̈ costituita da un adesivo a base di resina acrilica in dispersione idro-alcolica composto da una percentuale in peso di resina acrilica non superiore al 4%, una percentuale in peso di acqua compresa tra il 40% ed il 70%, ed una percentuale in peso di alcol, scelto tra alcol isopropilico e alcol etilico, compresa tra il 20% ed il 50%. Advantageously, the aforementioned high transparency adhesive film is constituted by an adhesive based on acrylic resin in hydro-alcoholic dispersion composed of a percentage by weight of acrylic resin not higher than 4%, a percentage by weight of water comprised between 40% and 70%, and a percentage by weight of alcohol, chosen from isopropyl alcohol and ethyl alcohol, between 20% and 50%.
Ancora vantaggiosamente lo strato intermedio di materiale metallico in foglia presenta interruzioni costituite da predefiniti motivi decorativi. Still advantageously, the intermediate layer of metallic leaf material has interruptions consisting of predefined decorative motifs.
Secondo un altro aspetto della presente invenzione gli scopi suddetti sono raggiunti per mezzo di un metodo per la produzione di un vetro stratificato decorativo comprendente almeno due pannelli di vetro, in cui il metodo prevede fasi di: According to another aspect of the present invention, the above purposes are achieved by means of a method for the production of a decorative laminated glass comprising at least two glass panels, in which the method involves steps of:
ï€ applicazione su un lato di uno dei due pannelli di vetro di un sottile strato di un adesivo a base di resina acrilica allo stato liquido, ï € application on one side of one of the two glass panels of a thin layer of an adhesive based on liquid acrylic resin,
ï€ parziale essiccazione di detto strato adesivo, ï € partial drying of said adhesive layer,
ï€ stesura “a libro†su detto strato adesivo parzialmente essiccato di una pluralità di fogli metallici di spessore compreso tra 0,01 e 1 micrometri, â € œbook-like 'spreading on said partially dried adhesive layer of a plurality of metal sheets with a thickness of between 0.01 and 1 micrometers,
ï€ brunitura dello strato di materiale metallico in foglia ottenuto, ï € bluing of the layer of metallic leaf material obtained,
ï€ stratificazione di detto vetro mediante accoppiamento del secondo di detti due pannelli di vetro mediante interposizione, tra detto secondo pannello di vetro e detto strato di materiale metallico in foglia, di una pellicola in materiale plastico scelto tra TPU, PVB o EVA. ï € stratification of said glass by coupling the second of said two glass panels by interposing, between said second glass panel and said layer of sheet metal material, a film of plastic material chosen from TPU, PVB or EVA.
Il metodo dell’invenzione si caratterizza per la peculiare applicazione a libro di materiale metallico in foglia eseguita su un supporto costituito da un pannello di vetro, tale applicazione essendo resa possibile dalla tipologia di adesivo che viene interposto tra il pannello di vetro ed il materiale in foglia. The method of the invention is characterized by the peculiar book application of sheet metal material performed on a support consisting of a glass panel, this application being made possible by the type of adhesive that is interposed between the glass panel and the material in leaf.
Vantaggiosamente, tra la fase di brunitura e la fase di stratificazione del vetro vengono eseguite operazioni di incisione dello strato di materiale metallico in foglia, volte ad asportare porzioni di detto strato al fine di realizzare predefiniti motivi decorativi. Advantageously, between the burnishing step and the stratification step of the glass, etching operations are carried out on the layer of metallic leaf material, aimed at removing portions of said layer in order to create predefined decorative motifs.
Alternativamente, predefiniti motivi decorativi vengono realizzati aggiungendo, prima della fase di applicazione dell’adesivo, una fase di applicazione provvisoria sul pannello di vetro di una maschera, costituita da uno strato di materiale comprendente aperture aventi la forma del motivo decorativo da realizzare, e, successivamente alla fase di applicazione su detta maschera dello strato adesivo, il quale in questo caso viene applicato sulla maschera, una fase di rimozione della suddetta maschera. Alternatively, predefined decorative motifs are created by adding, before the adhesive application step, a temporary application step on the glass panel of a mask, consisting of a layer of material comprising openings having the shape of the decorative motif to be created, and , subsequent to the step of applying the adhesive layer on said mask, which in this case is applied to the mask, a step of removing the aforementioned mask.
BREVE DESCRIZIONE DEI DISEGNI BRIEF DESCRIPTION OF THE DRAWINGS
Queste ed altre caratteristiche dell’invenzione risulteranno più facilmente comprensibili dalla seguente descrizione di forme realizzative preferite della stessa, fornite come esempi non limitativi, con riferimento alle figure allegate nelle quali: These and other characteristics of the invention will be easier to understand from the following description of preferred embodiments thereof, provided as non-limiting examples, with reference to the attached figures in which:
- la figura 1 mostra una prima forma realizzativa di un vetro stratificato secondo la presente invenzione: la fig. 1a mostra una schematica vista laterale, le fig. 1b e 1c mostrano viste frontali di tipici esempi di motivi decorativi ottenuti con la suddetta prima forma realizzativa; - figure 1 shows a first embodiment of a laminated glass according to the present invention: fig. 1a shows a schematic side view, figs. 1b and 1c show front views of typical examples of decorative motifs obtained with the aforementioned first embodiment;
- la figura 2 mostra una seconda forma realizzativa di un vetro stratificato secondo la presente invenzione: la fig. 2a mostra una schematica vista laterale, la fig. 2b mostra una vista frontale di un tipico esempio di motivo decorativo ottenuto con la suddetta seconda forma realizzativa. - figure 2 shows a second embodiment of a laminated glass according to the present invention: fig. 2a shows a schematic side view, fig. 2b shows a front view of a typical example of a decorative motif obtained with the aforementioned second embodiment.
DESCRIZIONE DELLE FORME REALIZZATIVE PREFERITE DESCRIPTION OF THE PREFERRED MANUFACTURING FORMS
La fig. 1a mostra schematicamente la struttura di un pannello di vetro stratificato decorativo, 1, secondo la presente invenzione. Il vetro stratificato 1 comprende due pannelli di vetro, 2, 3, tra i quali sono compresi uno strato di adesivo ad elevata trasparenza, 4, una pellicola di materiale termoplastico trasparente, 5, quale PVB o simili, e, interposto tra questi, uno strato di materiale metallico in foglia, 6, costituito da una pluralità di fogli di materiale metallico di spessore compreso tra 0,01 micron e 1 micron parzialmente sovrapposti. Fig. 1a schematically shows the structure of a decorative laminated glass panel, 1, according to the present invention. The laminated glass 1 comprises two glass panels, 2, 3, between which are comprised a layer of highly transparent adhesive, 4, a film of transparent thermoplastic material, 5, such as PVB or the like, and, interposed between these, one layer of metal sheet material, 6, consisting of a plurality of partially superimposed sheets of metal material with a thickness of between 0.01 micron and 1 micron.
Il suddetto vetro stratificato 1 Ã ̈ ottenuto grazie ad un peculiare processo di produzione. The aforementioned laminated glass 1 is obtained thanks to a peculiar production process.
Su un primo pannello di vetro 2, vantaggiosamente vetro di tipo float, viene applicato uno strato di un adesivo 4 allo stato liquido costituito da resine acriliche in dispersione idro-alcolica in cui preferibilmente, la percentuale di resina acrilica à ̈ inferiore al 4% in peso, la percentuale di acqua à ̈ non inferiore al 57% in peso e la percentuale di alcool à ̈ non inferiore al 38% in peso. On a first glass panel 2, advantageously float glass, is applied a layer of an adhesive 4 in the liquid state consisting of acrylic resins in hydro-alcoholic dispersion in which preferably, the percentage of acrylic resin is less than 4% in weight, the percentage of water is not less than 57% by weight and the percentage of alcohol is not less than 38% by weight.
Vantaggiosamente, l’alcool presente nel suddetto adesivo à ̈ alcool isopropilico e / o alcol etilico di gradazione pari ad almeno il 99%. Advantageously, the alcohol present in the aforesaid adhesive is isopropyl alcohol and / or ethyl alcohol with a strength of at least 99%.
L’adesivo allo stato liquido viene lasciato essiccare per circa 30 minuti, o comunque per un tempo tale da permettere la formazione di una pellicola solida ma ancora adesiva, dopodiché viene applicato lo strato di materiale metallico in foglia 6. L’applicazione del suddetto materiale metallico in foglia avviene secondo una tecnica nota cosiddetta “a libro†. La suddetta tecnica consiste nel prelevare singolarmente, tramite un pennello, foglietti di materiale metallico di spessore vantaggiosamente compreso tra 0,01 e 0,08 micron, e stenderli sul suddetto adesivo 3 affiancati l’uno all’altro e parzialmente sovrapposti, fino a ricoprire l’intera superficie su cui deve essere presente un effetto decorativo metallizzato che, nel presente esempio realizzativo, à ̈ l’intera superficie del pannello di vetro 2 su cui à ̈ applicato lo strato adesivo 4. The adhesive in the liquid state is left to dry for about 30 minutes, or in any case for a time that allows the formation of a solid but still adhesive film, after which the layer of metallic leaf material is applied. 6. Application of the aforementioned metallic material in leaf takes place according to a known technique called â € œbookâ €. The aforementioned technique consists in taking individually, using a brush, sheets of metal material with a thickness advantageously between 0.01 and 0.08 microns, and spread them on the aforementioned adhesive 3 side by side and partially overlapping, until to cover the entire surface on which a metallic decorative effect must be present which, in this embodiment example, is the entire surface of the glass panel 2 on which the adhesive layer 4 is applied.
Preferibilmente, la foglia metallica à ̈ costituita da un materiale o lega scelto tra oro, argento, bronzo o rame, ma potrebbe anche essere altro materiale o lega metallica. Preferably, the metal leaf is made up of a material or alloy chosen from gold, silver, bronze or copper, but it could also be another metal material or alloy.
Una volta completamente essiccato lo strato adesivo 4 si procede ad eseguire la levigatura / lucidatura della superficie libera, 6a, dello strato di materiale metallico in foglia 6. Questa operazione, svolta manualmente o meccanicamente tramite opportuni utensili, Ã ̈ volta ad eliminare imperfezioni superficiali per ottenere una maggiore lucentezza dello strato di materiale metallico 6. Once the adhesive layer 4 is completely dry, proceed with the smoothing / polishing of the free surface, 6a, of the layer of metallic material in leaf 6. This operation, carried out manually or mechanically using suitable tools, is aimed at eliminating surface imperfections to obtain a higher gloss of the metallic material layer 6.
Successivamente, nel caso che nel vetro stratificato debbano essere ottenuti motivi decorativi quali quelli del pannello 10 di fig.1b che prevedono aree metallizzate, 101, ed aree non metallizzate, 102, e quindi trasparenti, viene eseguita l’incisione dei motivi decorativi. La fase di incisione, eseguita sulla superficie 6a della strato di materiale metallico in foglia, à ̈ volta ad asportare gli strati di materiale metallico 6 e di adesivo 4 dalle aree non metallizzate 102, e può avvenire utilizzando utensili manuali oppure utensili montati su macchine a controllo numerico o altro tipo di macchinari. Subsequently, if decorative motifs are to be obtained in the laminated glass such as those of the panel 10 of fig.1b which include metallized areas, 101, and non-metallized areas, 102, and therefore transparent, the decorative motifs are engraved. The etching step, carried out on the surface 6a of the layer of metal sheet material, is aimed at removing the layers of metal material 6 and adhesive 4 from the non-metallized areas 102, and can take place using manual tools or tools mounted on machines. numerical control or other type of machinery.
Una volta realizzato il motivo decorativo desiderato, viene eseguita la stratificazione del vetro secondo procedure di tecnica nota, tramite interposizione, tra lo strato di materiale metallico in foglia 6 ed un secondo pannello di vetro 3, di uno strato di materiale termoplastico. Più precisamente, nel caso, ad esempio, che il materiale termoplastico sia PVB, tra i suddetti strati metallico 6 e vetro 3 viene interposta una pellicola di PVB ed il processo di stratificazione avviene mediante riscaldamento e pressione l’uno contro l’altro degli elementi da congiungere. Il processo di stratificazione può ovviamente avvenire anche utilizzando un materiale di giunzione diverso quale EVA, TPU o un materiale ionoplastico quale quello commercialmente conosciuto come SGP, variando ovviamente in tal caso anche il processo di stratificazione. Once the desired decorative motif has been achieved, the stratification of the glass is carried out according to procedures of the known technique, by interposing a layer of thermoplastic material between the layer of metallic leaf material 6 and a second glass panel 3. More precisely, in the case, for example, that the thermoplastic material is PVB, a PVB film is interposed between the aforementioned metal layers 6 and glass 3 and the stratification process takes place by heating and pressing one against the other. of the elements to be joined. The layering process can obviously also take place using a different joining material such as EVA, TPU or an ionoplastic material such as the one commercially known as SGP, obviously varying in this case also the layering process.
Nel caso che il prodotto da realizzare abbia un effetto decorativo metallizzato, 111, uniforme su tutto il pannello, come nel caso del vetro stratificato 11 di fig.1c, il processo di stratificazione viene ovviamente realizzato senza preventivamente eseguire la suddetta fase di incisione di motivi decorativi. If the product to be made has a metallized decorative effect, 111, uniform over the entire panel, as in the case of the laminated glass 11 in fig. 1c, the layering process is obviously carried out without previously carrying out the aforementioned pattern engraving step decorative.
Con riferimento alla fig. 2a à ̈ indicato con 1’ un vetro stratificato decorativo secondo la presente invenzione ottenuto tramite una diversa forma realizzativa di un processo produttivo secondo l’invenzione. Al primo pannello di vetro 2 viene applicata una maschera, 7, in materiale plastico o cartaceo, riportante aperture di forma corrispondente ai motivi metallizzati che devono essere ottenuti nel vetro stratificato 1’. With reference to fig. 2a indicates 1â € ™ a decorative laminated glass according to the present invention obtained through a different embodiment of a production process according to the invention. A plastic or paper mask 7 is applied to the first glass panel 2, showing openings of a shape corresponding to the metallized motifs that must be obtained in the laminated glass 1â € ™.
Successivamente vengono eseguite, in modo analogo a quello precedentemente descritto, le fasi di applicazione dello strato adesivo 4 e di stesura “a libro “ dello strato in materiale metallico in foglia 6. Subsequently, the phases of application of the adhesive layer 4 and of the â € œbook-like â € œ drafting of the sheet metal layer 6 are carried out in a similar way to that previously described.
Una volta essiccato completamente l’adesivo 4, viene rimossa la maschera 7 cosicché lo strato adesivo 4 e lo strato in materiale metallico 6 rimangono aderenti al primo pannello di vetro 2 solo in corrispondenza delle aperture della maschera 7, creando quindi motivi decorativi metallizzati corrispondenti alle aperture presenti nella maschera 7. Operazioni di levigatura e / o lucidatura della superficie metallizzata 6a possono essere eseguite prima o dopo la rimozione della maschera 7, dopodiché viene eseguito il processo di stratificazione come precedentemente descritto. Once the adhesive 4 has dried completely, the mask 7 is removed so that the adhesive layer 4 and the metallic material layer 6 remain adherent to the first glass panel 2 only in correspondence with the openings of the mask 7, thus creating metallic decorative motifs. corresponding to the openings present in the mask 7. Smoothing and / or polishing operations of the metallized surface 6a can be performed before or after the removal of the mask 7, after which the layering process is carried out as previously described.
La variante appena descritta di un processo per la realizzazione di vetro stratificato decorativo secondo la presente invenzione viene vantaggiosamente impiegata per realizzare pannelli di vetro stratificato quale quello indicato con 10’ in fig. 2b, in cui i motivi decorativi ad effetto metallizzato, 101’ hanno una estensione superficiale piuttosto limitata rispetto alla superficie complessiva del pannello 10’. The variant just described of a process for producing decorative laminated glass according to the present invention is advantageously used to produce laminated glass panels such as that indicated with 10â € ™ in fig. 2b, in which the decorative motifs with a metallic effect, 101â € ™ have a rather limited surface extension compared to the overall surface of the panel 10â € ™.
Nei pannelli in vetro stratificato secondo l’invenzione la presenza di materiale metallico in foglia permette di ottenere effetti metallizzati esteticamente molto diversi e superiori rispetto a quelli ottenibili con i processi tradizionali che prevedono l’applicazione di vernici contenenti specifici pigmenti metallici. Inoltre, i pannelli ottenuti sono perfettamente bifacciali in quanto, da un punto di vista prettamente estetico, l’effetto metallizzato ottenuto risulta essere esattamente lo stesso sia dal lato del primo pannello di vetro 2 che dal lato del secondo pannello di vetro 3. Questo risultato à ̈ ottenuto grazie all’utilizzo dello strato adesivo 4, il quale, passando, durante l’essiccazione ad uno stato vischioso permette la stesura “a libro†del materiale metallico in foglia e, una volta completamente essiccato, ha un elevato grado di trasparenza. In the laminated glass panels according to the invention, the presence of metallic leaf material allows to obtain metallized effects that are aesthetically very different and superior to those obtainable with traditional processes which involve the application of paints containing specific metallic pigments. Furthermore, the panels obtained are perfectly double-sided since, from a purely aesthetic point of view, the metallized effect obtained is exactly the same both on the side of the first glass panel 2 and on the side of the second glass panel 3. This The result is obtained thanks to the use of the adhesive layer 4, which, passing, during drying to a viscous state, allows the â € œbookâ € drafting of the metallic leaf material and, once completely dried, has a high degree of transparency.
Ulteriori varianti realizzative possono ovviamente essere previste. Ad esempio, pannelli di vetro stratificato decorativo secondo l’invenzione possono anche prevedere lavorazioni di curvatura, di tempra o altre lavorazioni aventi effetti strutturali o estetici. Further construction variants can obviously be envisaged. For example, decorative laminated glass panels according to the invention can also include bending, tempering or other processes having structural or aesthetic effects.
I vantaggi del vetro stratificato decorativo dell’invenzione e del relativo metodo di produzione rimangono inalterati anche in presenza di ulteriori varianti o modifiche, apportate pur sempre rimanendo all’interno dell’ambito di protezione definito dalle rivendicazioni seguenti. The advantages of the decorative laminated glass of the invention and of the relative production method remain unchanged even in the presence of further variations or modifications, made while always remaining within the scope of protection defined by the following claims.
Claims (8)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT000018A ITPI20130018A1 (en) | 2013-03-14 | 2013-03-14 | DECORATIVE LAYERED GLASS AND RELATED PRODUCTION METHOD. |
| PCT/IB2014/059387 WO2014140984A1 (en) | 2013-03-14 | 2014-03-03 | Decorative laminated glazing and method of manufacturing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT000018A ITPI20130018A1 (en) | 2013-03-14 | 2013-03-14 | DECORATIVE LAYERED GLASS AND RELATED PRODUCTION METHOD. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ITPI20130018A1 true ITPI20130018A1 (en) | 2014-09-15 |
Family
ID=48227446
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IT000018A ITPI20130018A1 (en) | 2013-03-14 | 2013-03-14 | DECORATIVE LAYERED GLASS AND RELATED PRODUCTION METHOD. |
Country Status (2)
| Country | Link |
|---|---|
| IT (1) | ITPI20130018A1 (en) |
| WO (1) | WO2014140984A1 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102014226529A1 (en) * | 2014-12-19 | 2016-06-23 | Bayerische Motoren Werke Aktiengesellschaft | CFRP-reinforced semi-transparent flat component, and a method for its production |
| BR202015022089U2 (en) * | 2015-09-09 | 2018-05-29 | Moreira Meira Diesley | PROVISION APPLIED ON POLYMERIC MATRIX COMPOSITE FOR DOORS, DIVISIONS, FURNITURE AND THE OTHER |
| AU2018286476A1 (en) * | 2017-06-14 | 2020-01-23 | F&S Bar Holdings Pty Ltd | Artisanal glass panels and methods of making the same |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0565494A1 (en) * | 1992-04-06 | 1993-10-13 | AXIVETRO S.r.l. | Method for the figurative and chromatic decoration of flat glass and articles of manufacture made thereby |
| WO2003074270A2 (en) * | 2002-02-28 | 2003-09-12 | Solutia Inc. | Embossed reflective laminates |
-
2013
- 2013-03-14 IT IT000018A patent/ITPI20130018A1/en unknown
-
2014
- 2014-03-03 WO PCT/IB2014/059387 patent/WO2014140984A1/en active Application Filing
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0565494A1 (en) * | 1992-04-06 | 1993-10-13 | AXIVETRO S.r.l. | Method for the figurative and chromatic decoration of flat glass and articles of manufacture made thereby |
| WO2003074270A2 (en) * | 2002-02-28 | 2003-09-12 | Solutia Inc. | Embossed reflective laminates |
Non-Patent Citations (1)
| Title |
|---|
| "Vacuum Deposition", 7 May 2012 (2012-05-07), XP002716991, Retrieved from the Internet <URL:http://web.archive.org/web/20120605053759/https://en.wikipedia.org/wiki/Vacuum_deposition> [retrieved on 20131129] * |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2014140984A1 (en) | 2014-09-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ITPI20130018A1 (en) | DECORATIVE LAYERED GLASS AND RELATED PRODUCTION METHOD. | |
| CN102069673A (en) | UV coating decorative plate and preparation method thereof | |
| KR101261090B1 (en) | Decoration Sheet Setting Printing Pattern With The Embo Pattern and Manufacturing Method Thereof | |
| JP2008087153A (en) | Decorative sheet and its execution structure | |
| KR100902599B1 (en) | Ornamental purpose board and the manufacture method to form built-in pattern on formica | |
| TW201741139A (en) | Decorative glass and method for manufacturing decorative glass | |
| CN107443816A (en) | Artistic glass and preparation method thereof | |
| KR101052039B1 (en) | Manufacturing method of decorative board | |
| KR101084380B1 (en) | Manufacture method of pearl pattern sheet | |
| CN108374536A (en) | A kind of light transmission wood facing, wall decoration and light transmission wood facing processing method | |
| KR101078867B1 (en) | Manufaturing method of decorative panel | |
| KR100928665B1 (en) | The art panel and manufacturing method | |
| JP6386890B2 (en) | Laminated decorative film, method for producing the same, and decorative article | |
| CN103802193B (en) | A kind of production method of third dimension dalle | |
| ES2668698T3 (en) | Procedure for generating high gloss surfaces without joints as well as objects with such a surface | |
| EP2829395A1 (en) | Multilayer stratified cladding for covering and decorating or making structures and objects or parts thereof. | |
| KR200455988Y1 (en) | A plaque manufactured by using a iridescent films | |
| JP3195168U (en) | Decorative plate | |
| CN203331679U (en) | Stereoscopic decoration plate | |
| KR102193731B1 (en) | Manufacturing device and method of panel using natural materials | |
| ITUB20156097A1 (en) | METHOD FOR THE REALIZATION OF A MULTILAYER PANEL IN COMPOSITE MATERIAL | |
| JP2009073077A (en) | Decorative plate and method of manufacturing the same | |
| KR20130098000A (en) | The flame retardant interior sheet and method of manufactring the same | |
| ITTO20121013A1 (en) | PROCESS PERFECTED FOR THE PRODUCTION OF DECORATIVE ELEMENTS, IN PARTICULAR FREGI | |
| ITMI20120244U1 (en) | MATERIAL IN PANELS FOR THE CONSTRUCTION OF FURNITURE AND FURNISHING ELEMENTS |