IT1394568B1 - PROCEDURE FOR THE ENHANCEMENT OF NATURAL GAS WITH HIGH CONTENT OF HYDROGEN SULPHORATE - Google Patents

PROCEDURE FOR THE ENHANCEMENT OF NATURAL GAS WITH HIGH CONTENT OF HYDROGEN SULPHORATE

Info

Publication number
IT1394568B1
IT1394568B1 ITMI2009A001115A ITMI20091115A IT1394568B1 IT 1394568 B1 IT1394568 B1 IT 1394568B1 IT MI2009A001115 A ITMI2009A001115 A IT MI2009A001115A IT MI20091115 A ITMI20091115 A IT MI20091115A IT 1394568 B1 IT1394568 B1 IT 1394568B1
Authority
IT
Italy
Prior art keywords
sulphorate
enhancement
hydrogen
procedure
natural gas
Prior art date
Application number
ITMI2009A001115A
Other languages
Italian (it)
Inventor
Angelis Alberto De
Elia Luigi D
Original Assignee
Eni Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eni Spa filed Critical Eni Spa
Priority to ITMI2009A001115A priority Critical patent/IT1394568B1/en
Priority to RU2011153109/04A priority patent/RU2522443C2/en
Priority to CA2766037A priority patent/CA2766037A1/en
Priority to PCT/IB2010/001344 priority patent/WO2010150063A1/en
Publication of ITMI20091115A1 publication Critical patent/ITMI20091115A1/en
Application granted granted Critical
Publication of IT1394568B1 publication Critical patent/IT1394568B1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • C01B17/48Sulfur dioxide; Sulfurous acid
    • C01B17/50Preparation of sulfur dioxide
    • C01B17/508Preparation of sulfur dioxide by oxidation of sulfur compounds
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0211Processes for making hydrogen or synthesis gas containing a reforming step containing a non-catalytic reforming step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042Purification by adsorption on solids
    • C01B2203/043Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0455Purification by non-catalytic desulfurisation
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/0485Composition of the impurity the impurity being a sulfur compound
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06Integration with other chemical processes
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06Integration with other chemical processes
    • C01B2203/061Methanol production
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • C01B2203/1052Nickel or cobalt catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • C01B2203/1052Nickel or cobalt catalysts
    • C01B2203/1058Nickel catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
    • C01B2203/1211Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235Hydrocarbons
    • C01B2203/1241Natural gas or methane
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14Details of the flowsheet
    • C01B2203/146At least two purification steps in series

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
ITMI2009A001115A 2009-06-24 2009-06-24 PROCEDURE FOR THE ENHANCEMENT OF NATURAL GAS WITH HIGH CONTENT OF HYDROGEN SULPHORATE IT1394568B1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
ITMI2009A001115A IT1394568B1 (en) 2009-06-24 2009-06-24 PROCEDURE FOR THE ENHANCEMENT OF NATURAL GAS WITH HIGH CONTENT OF HYDROGEN SULPHORATE
RU2011153109/04A RU2522443C2 (en) 2009-06-24 2010-06-02 Method for quality improvement of natural gas with high content of hydrogen sulphide
CA2766037A CA2766037A1 (en) 2009-06-24 2010-06-02 Process for upgrading natural gas with a high hydrogen sulfide content
PCT/IB2010/001344 WO2010150063A1 (en) 2009-06-24 2010-06-02 Process for upgrading natural gas with a high hydrogen sulfide content

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI2009A001115A IT1394568B1 (en) 2009-06-24 2009-06-24 PROCEDURE FOR THE ENHANCEMENT OF NATURAL GAS WITH HIGH CONTENT OF HYDROGEN SULPHORATE

Publications (2)

Publication Number Publication Date
ITMI20091115A1 ITMI20091115A1 (en) 2010-12-25
IT1394568B1 true IT1394568B1 (en) 2012-07-05

Family

ID=41693527

Family Applications (1)

Application Number Title Priority Date Filing Date
ITMI2009A001115A IT1394568B1 (en) 2009-06-24 2009-06-24 PROCEDURE FOR THE ENHANCEMENT OF NATURAL GAS WITH HIGH CONTENT OF HYDROGEN SULPHORATE

Country Status (4)

Country Link
CA (1) CA2766037A1 (en)
IT (1) IT1394568B1 (en)
RU (1) RU2522443C2 (en)
WO (1) WO2010150063A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109721028B (en) * 2017-10-27 2020-09-11 中国石油化工股份有限公司 Method for preparing hydrogen by reforming methane and hydrogen sulfide
WO2022023365A1 (en) * 2020-07-28 2022-02-03 Totalenergies Se Process to conduct an endothermic thio-reforming reaction of hydrocarbons in an installation comprising electrified fluidized bed reactor

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB293172A (en) * 1927-05-26 1928-07-05 Ig Farbenindustrie Ag Improvements in the manufacture and production of carbon disulphide
US2788262A (en) * 1953-05-01 1957-04-09 Pan American Petroleum Corp Process for preparation of carbon disulfide
GB1126465A (en) * 1964-09-14 1968-09-05 Ivor Gray Nixon Manufacture of hydrogen and carbon disulphide
US3388971A (en) * 1965-06-07 1968-06-18 Seymour C. Schuman Production of hydrogen
US4695443A (en) * 1985-02-14 1987-09-22 Stauffer Chemical Company Autothermal process for the production of carbon disulfide and hydrogen sulfide
RU2216506C1 (en) * 2002-02-26 2003-11-20 Институт катализа им. Г.К.Борескова СО РАН Method for preparing hydrogen and elemental sulfur from hydrogen sulfide
DE102004013283A1 (en) * 2004-03-18 2005-10-13 Guennadi, Berner Combined production of carbon disulfide and sulfuric acid from sulfur, without use of natural gas fuel, by using heat from oxidation of sulfur to drive the endothermic carbon disulfide production reaction
BRPI0608825B1 (en) * 2005-04-21 2017-06-06 Shell Int Research system and method for oil and / or gas production
WO2010102653A1 (en) * 2009-03-13 2010-09-16 Eni S.P.A. Process for the abatement of hydrogen sulphide from compositions containing it with simultaneous production of hydrogen

Also Published As

Publication number Publication date
RU2011153109A (en) 2013-07-27
WO2010150063A1 (en) 2010-12-29
ITMI20091115A1 (en) 2010-12-25
RU2522443C2 (en) 2014-07-10
CA2766037A1 (en) 2010-12-29

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