IT1166603B - 3-Poly:fluoro-propyl cyclopropane-carboxylate ester derivs. - with insecticidal and acaricidal activities - Google Patents

3-Poly:fluoro-propyl cyclopropane-carboxylate ester derivs. - with insecticidal and acaricidal activities

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Publication number
IT1166603B
IT1166603B IT1970379A IT1970379A IT1166603B IT 1166603 B IT1166603 B IT 1166603B IT 1970379 A IT1970379 A IT 1970379A IT 1970379 A IT1970379 A IT 1970379A IT 1166603 B IT1166603 B IT 1166603B
Authority
IT
Italy
Prior art keywords
insecticidal
fluoro
poly
carboxylate ester
alkyl
Prior art date
Application number
IT1970379A
Other languages
Italian (it)
Other versions
IT7919703A0 (en
Inventor
Paolo Piccardi
Francesco Corda
Franco Gozzo
Augusto Menconi
Angelo Longoni
Original Assignee
Montedison Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montedison Spa filed Critical Montedison Spa
Publication of IT7919703A0 publication Critical patent/IT7919703A0/en
Priority to IT1970379A priority Critical patent/IT1166603B/en
Priority to BG044135A priority patent/BG48333A3/en
Priority to BG044136A priority patent/BG48921A3/en
Priority to BR7901221A priority patent/BR7901221A/en
Priority to DK080379A priority patent/DK161830C/en
Priority to NO790621A priority patent/NO152582C/en
Priority to NL7901460A priority patent/NL7901460A/en
Priority to IL56739A priority patent/IL56739A0/en
Priority to BG042659A priority patent/BG48931A3/en
Priority to GR58472A priority patent/GR72544B/el
Priority to IN173/CAL/79A priority patent/IN150228B/en
Priority to PT69283A priority patent/PT69283A/en
Priority to US06/015,105 priority patent/US4328237A/en
Priority to CS131579A priority patent/CS222280B2/en
Priority to GB7906851A priority patent/GB2015519B/en
Priority to EG12679A priority patent/EG14225A/en
Priority to ES478426A priority patent/ES478426A1/en
Priority to CH194279A priority patent/CH638485A5/en
Priority to DD79218658A priority patent/DD148767A5/en
Priority to FR7904952A priority patent/FR2442826A1/en
Priority to PL1979213760A priority patent/PL135350B1/en
Priority to CA000322525A priority patent/CA1237439A/en
Priority to DD79211259A priority patent/DD142281A5/en
Priority to YU00482/79A priority patent/YU48279A/en
Priority to AU44631/79A priority patent/AU531296B2/en
Priority to DE19792907609 priority patent/DE2907609A1/en
Priority to HU79MO1039A priority patent/HU185607B/en
Priority to BE0/193748A priority patent/BE874515A/en
Priority to LU80981A priority patent/LU80981A1/en
Priority to MX797764U priority patent/MX5698E/en
Priority to RO7996740A priority patent/RO77307A/en
Priority to AR275649A priority patent/AR241108A1/en
Priority to RO79101065A priority patent/RO77772A/en
Priority to NZ189791A priority patent/NZ189791A/en
Priority to JP2204779A priority patent/JPS54130537A/en
Priority to TR2037979A priority patent/TR20379A/en
Priority to NO792716A priority patent/NO153098C/en
Priority to US06/273,541 priority patent/US4379163A/en
Priority to US06/430,474 priority patent/US4482570A/en
Priority to KE3293A priority patent/KE3293A/en
Application granted granted Critical
Publication of IT1166603B publication Critical patent/IT1166603B/en

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Esters of formula (I) are new. In (I), A is CF3-C=C-, -CF3-CX=CH- or CF3-C(XY)-CH2-; X is H,F,CL or Br; Y is Cl or Br; R is a gp. -CH2. CR7=CR8. CH2R9, -CH2C=CCH2R9 or (II) - (IV); R1 is H, CN or C=CH; in (III) CHR1 is attached at the 2 or 3 position; R2 is 3-phenoxy, 3-benzyl, 4-allyl, 4-propargyl; R3 is H or alkyl, attached at the 2 or 3 position; R4 is benzyl, benzoyl, phenyl, allyl or propargyl attached at the 4 or 5 position; Y1 is O or S; R5 and R6 are each 1-3C alkyl or together complete an aliphatic, heteroaromatic or aromatic ring (satd. or unsatd.); R7 and R8 are each H, halo or CH3; and R9 is phenyl, opt. substd. vinyl or phenoxy. Also new are cpds. (II) in which R is replaced by H or 1-4C alkyl. (I) are insecticides more effective and more stable than known natural or synthetic pyrethrins, and also have acaricidal activity. (II) are intermediates for (I).
IT1970379A 1978-02-28 1979-01-30 3-Poly:fluoro-propyl cyclopropane-carboxylate ester derivs. - with insecticidal and acaricidal activities IT1166603B (en)

Priority Applications (40)

Application Number Priority Date Filing Date Title
IT1970379A IT1166603B (en) 1979-01-30 1979-01-30 3-Poly:fluoro-propyl cyclopropane-carboxylate ester derivs. - with insecticidal and acaricidal activities
BG044135A BG48333A3 (en) 1978-02-28 1979-02-06 Method for preparing of 2, 2- dimethyl cyclopropane carbonic acid derivatives
BG044136A BG48921A3 (en) 1978-02-28 1979-02-06 Method for destroying of insects
BR7901221A BR7901221A (en) 1978-02-28 1979-02-23 PROCESS FOR THE PREPARATION OF INSECTICID AND ACARICIDE COMPOUNDS
DK080379A DK161830C (en) 1978-02-28 1979-02-23 ESTERS OF 2,2-DIMETHYLYCYCLOPROPANCARBOXYL ACID DERIVATIVES, PROCEDURES FOR THE PRODUCTION THEREOF, INSECTICID AND ACARICID AGENTS AND PROCEDURES TO FIGHT AGAINST PLANTS
NO790621A NO152582C (en) 1978-02-28 1979-02-23 INSECTICID AGENT CONTAINING AS ACTIVE COMPONENT ONE OR MORE 3-SUBSTITUTED 2,2-DIMETHYL-CYCLOPROPANCARBOXYL ACID ESTERS
NL7901460A NL7901460A (en) 1978-02-28 1979-02-23 INSECTICIDE PYRETHROIDS, CYCLOPROPANECARBON ACIDS AND ESTER INTERMEDIATE PRODUCTS AND METHODS FOR PREPARING THEM.
IL56739A IL56739A0 (en) 1978-02-28 1979-02-26 Cyclorpropanecarboxylic acid derivatives,their preparationand their use as insecticides and acaricides
BG042659A BG48931A3 (en) 1978-02-28 1979-02-26 Method for preparing of pyretroids
GR58472A GR72544B (en) 1978-02-28 1979-02-26
IN173/CAL/79A IN150228B (en) 1978-02-28 1979-02-26
PT69283A PT69283A (en) 1978-02-28 1979-02-26 Pyrethroids
US06/015,105 US4328237A (en) 1978-02-28 1979-02-26 Pyrethroids
PL1979213760A PL135350B1 (en) 1978-02-28 1979-02-27 METHOD OF OBTAINING NOVEL PYRETROIDES AND INSECTICIDE AND / OR ACARICIDE
GB7906851A GB2015519B (en) 1978-02-28 1979-02-27 Cyclopropane carboxylic acid esters
EG12679A EG14225A (en) 1978-12-27 1979-02-27 Pyretaroids
ES478426A ES478426A1 (en) 1978-02-28 1979-02-27 Cyclopropane carboxylic acid esters
CH194279A CH638485A5 (en) 1978-02-28 1979-02-27 PYRETROIDS AND THEIR PREPARATION PROCESSES.
DD79218658A DD148767A5 (en) 1978-02-28 1979-02-27 METHOD FOR THE PRODUCTION OF INSECTICIDAL AND ACARICIDAL COMPOUNDS
FR7904952A FR2442826A1 (en) 1978-02-28 1979-02-27 NEW CLASS OF PYRETHROIDS AND THEIR USE AS INSECTICIDES
CS131579A CS222280B2 (en) 1978-02-28 1979-02-27 Insecticide and acaricide means and method of making the active substances
CA000322525A CA1237439A (en) 1978-02-28 1979-02-27 2,2-dimethylcyclopropane carboxylic acid derivatives
DD79211259A DD142281A5 (en) 1978-02-28 1979-02-27 PROCEDURE FOR THE CONTROL OF INSECTS AND ACARES
YU00482/79A YU48279A (en) 1978-02-28 1979-02-27 Process for preparing insecticidic and acaricidic compounds
AU44631/79A AU531296B2 (en) 1978-02-28 1979-02-27 Pyrethroids
DE19792907609 DE2907609A1 (en) 1978-02-28 1979-02-27 NEW PYRETHROIDS, THEIR PRODUCTION AND USE
HU79MO1039A HU185607B (en) 1978-02-28 1979-02-27 Process for producing cyclopropan-carboxylic acid derivatives
JP2204779A JPS54130537A (en) 1978-02-28 1979-02-28 Pyrethroid insecticide*cyclopropane carboxylic acid and ester intermediate and their manufacture
BE0/193748A BE874515A (en) 1978-02-28 1979-02-28 NEW CLASS OF PYRETHROIDS AND THEIR USE AS INSECTICIDES
MX797764U MX5698E (en) 1978-02-28 1979-02-28 PROCEDURE FOR PREPARING ESTERS OF 2,2-DIMETHYL CYCLOPROPANCARBOXYLIC ACIDS
RO7996740A RO77307A (en) 1978-02-28 1979-02-28 PROCESS FOR OBTAINING ESTERS OF 2,2-DIMETHYLECYCLOPROPANCARBOXYLIC ACIDS
AR275649A AR241108A1 (en) 1978-02-28 1979-02-28 PYRETHROID INSECTICIDES, CYCLOPROPANCARBOXYLIC ACIDS AND INTERMEDIATE ESTERS AND THEIR PREPARATION PROCEDURES
RO79101065A RO77772A (en) 1978-02-28 1979-02-28 PROCESS FOR THE PREPARATION OF 2,2-DIMETHYLCYCLOPROPANCARBOXYLIC ACID DERIVATIVES
NZ189791A NZ189791A (en) 1978-02-28 1979-02-28 2,2-cyclopropanecarboxylic acid esters and pesticidal compositions
LU80981A LU80981A1 (en) 1978-02-28 1979-02-28 NEW CLEASSE OF PYRETHROIDS AND THEIR USE AS INSECTICIDES
TR2037979A TR20379A (en) 1979-01-30 1979-06-19 2,2-DIMETYL-CYCLOPROPANKARBOXYLIC ACIDS ESTERS AND THEIR USE AS INDEXTS
NO792716A NO153098C (en) 1978-02-28 1979-08-21 3-SUBSTITUTED 2,2-DIMETHYL-CYCLOPROPANCARBOXYL ACIDES AND LOWER ALKYLESTERS THEREOF USE AS OUTSIDE MATERIALS IN THE PREPARATION OF PYRETHROIDS WITH INSECTICID EFFECT
US06/273,541 US4379163A (en) 1978-02-28 1981-06-15 Pyrethroids
US06/430,474 US4482570A (en) 1978-02-28 1982-09-30 Pyrethroids
KE3293A KE3293A (en) 1978-02-28 1983-06-08 Pyrethrols insecticides cyclopropanecarboxylic acids

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT1970379A IT1166603B (en) 1979-01-30 1979-01-30 3-Poly:fluoro-propyl cyclopropane-carboxylate ester derivs. - with insecticidal and acaricidal activities

Publications (2)

Publication Number Publication Date
IT7919703A0 IT7919703A0 (en) 1979-01-30
IT1166603B true IT1166603B (en) 1987-05-05

Family

ID=11160509

Family Applications (1)

Application Number Title Priority Date Filing Date
IT1970379A IT1166603B (en) 1978-02-28 1979-01-30 3-Poly:fluoro-propyl cyclopropane-carboxylate ester derivs. - with insecticidal and acaricidal activities

Country Status (2)

Country Link
IT (1) IT1166603B (en)
TR (1) TR20379A (en)

Also Published As

Publication number Publication date
TR20379A (en) 1981-05-18
IT7919703A0 (en) 1979-01-30

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