FR2442826A1 - NEW CLASS OF PYRETHROIDS AND THEIR USE AS INSECTICIDES - Google Patents

NEW CLASS OF PYRETHROIDS AND THEIR USE AS INSECTICIDES

Info

Publication number
FR2442826A1
FR2442826A1 FR7904952A FR7904952A FR2442826A1 FR 2442826 A1 FR2442826 A1 FR 2442826A1 FR 7904952 A FR7904952 A FR 7904952A FR 7904952 A FR7904952 A FR 7904952A FR 2442826 A1 FR2442826 A1 FR 2442826A1
Authority
FR
France
Prior art keywords
pyrethroids
insecticides
new class
relates
new
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7904952A
Other languages
French (fr)
Other versions
FR2442826B1 (en
Inventor
Paolo Piccardi
Francesco Corda
Franco Gozzo
Augusto Menconi
Angelo Longoni
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Montedison SpA
Original Assignee
Montedison SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from IT2071478A external-priority patent/IT1095450B/en
Priority claimed from IT20713/78A external-priority patent/IT1095449B/en
Priority claimed from IT3131078A external-priority patent/IT1160403B/en
Priority claimed from IT1970379A external-priority patent/IT1166603B/en
Application filed by Montedison SpA filed Critical Montedison SpA
Publication of FR2442826A1 publication Critical patent/FR2442826A1/en
Application granted granted Critical
Publication of FR2442826B1 publication Critical patent/FR2442826B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/42—Singly bound oxygen atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C61/00—Compounds having carboxyl groups bound to carbon atoms of rings other than six-membered aromatic rings
    • C07C61/16—Unsaturated compounds
    • C07C61/40—Unsaturated compounds containing halogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Indole Compounds (AREA)
  • Heterocyclic Compounds Containing Sulfur Atoms (AREA)
  • Furan Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

La présente invention a pour objet une nouvelle classe de pyréthroïdes. Elle se rapporte plus particulièrement à de nouveau esters des acides 2,2-diméthylcyclopropanecarboxyliques substitués en position 3 du noyau cyclopropyle par une chaîne polyhalogénée, saturée ou non saturée, formée de 3 atomes de carbone. Elle se rapporte également à la préparation de ces composés et à leur emploi en tant qu'insecticides.The present invention relates to a new class of pyrethroids. It relates more particularly to new esters of 2,2-dimethylcyclopropanecarboxylic acids substituted in position 3 of the cyclopropyl ring by a polyhalogenated chain, saturated or unsaturated, formed of 3 carbon atoms. It also relates to the preparation of these compounds and their use as insecticides.

FR7904952A 1978-02-28 1979-02-27 NEW CLASS OF PYRETHROIDS AND THEIR USE AS INSECTICIDES Granted FR2442826A1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
IT2071478A IT1095450B (en) 1978-02-28 1978-02-28 3-Poly:fluoro-propyl cyclopropane-carboxylate ester derivs. - with insecticidal and acaricidal activities
IT20713/78A IT1095449B (en) 1978-02-28 1978-02-28 NEW PYRETROIDS
IT3131078A IT1160403B (en) 1978-12-27 1978-12-27 3-Poly:fluoro-propyl cyclopropane-carboxylate ester derivs. - with insecticidal and acaricidal activities
IT1970379A IT1166603B (en) 1979-01-30 1979-01-30 3-Poly:fluoro-propyl cyclopropane-carboxylate ester derivs. - with insecticidal and acaricidal activities

Publications (2)

Publication Number Publication Date
FR2442826A1 true FR2442826A1 (en) 1980-06-27
FR2442826B1 FR2442826B1 (en) 1984-07-06

Family

ID=27452781

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7904952A Granted FR2442826A1 (en) 1978-02-28 1979-02-27 NEW CLASS OF PYRETHROIDS AND THEIR USE AS INSECTICIDES

Country Status (28)

Country Link
JP (1) JPS54130537A (en)
AR (1) AR241108A1 (en)
AU (1) AU531296B2 (en)
BE (1) BE874515A (en)
BG (3) BG48921A3 (en)
BR (1) BR7901221A (en)
CA (1) CA1237439A (en)
CH (1) CH638485A5 (en)
DD (2) DD148767A5 (en)
DE (1) DE2907609A1 (en)
DK (1) DK161830C (en)
ES (1) ES478426A1 (en)
FR (1) FR2442826A1 (en)
GB (1) GB2015519B (en)
GR (1) GR72544B (en)
HU (1) HU185607B (en)
IL (1) IL56739A0 (en)
IN (1) IN150228B (en)
KE (1) KE3293A (en)
LU (1) LU80981A1 (en)
MX (1) MX5698E (en)
NL (1) NL7901460A (en)
NO (2) NO152582C (en)
NZ (1) NZ189791A (en)
PL (1) PL135350B1 (en)
PT (1) PT69283A (en)
RO (1) RO77772A (en)
YU (1) YU48279A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0043143A2 (en) * 1980-07-02 1982-01-06 Montedison S.p.A. Process for stereoselectively synthetizing cyclopropane carboxylates as intermediates for pyrethroids
EP0555153A1 (en) * 1992-02-07 1993-08-11 Roussel Uclaf Pyrethrinoide esters, derivatives of furan- or thiophenalcohol, process for their preparation and application thereof as pesticides

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2831193A1 (en) * 1978-07-15 1980-01-24 Bayer Ag FLUORALKENYL-SUBSTITUTED CYCLOPROPANCARBONIC ACID ESTERS AND THEIR USE AS INSECTICIDES
DE2965744D1 (en) * 1978-10-27 1983-07-28 Ici Plc Process for separating optical isomers of substituted cyclopropane carboxylic acids; amine salts of substituted cyclopropane carboxylic acids; a substituted cyclopropane carboxylic acid
DE2919820A1 (en) * 1979-05-16 1980-11-20 Bayer Ag FLUOR-SUBSTITUTED OXYALKENYL-CYCLOPROPANCARBONIC ACID ESTERS, METHODS FOR THE PRODUCTION THEREOF AND THEIR USE AS INSECTICIDES AND ACARICIDES
EP0022608B1 (en) * 1979-07-13 1983-07-06 Imperial Chemical Industries Plc Process for the preparation of cyclopropane carboxylic acid esters
IL83606A (en) * 1986-08-27 1992-03-29 Montedison Spa Esters of 3-(3-substituted-3,3-difluoro-1-propenyl)2,2-dimethyl-cyclopropanecarboxylic acid,their preparation and their use as insecticides and acaricides
DE3900275A1 (en) * 1989-01-07 1990-07-12 Basf Ag SUBSTITUTED CYCLOPROPANCARBONIC ACID PROPARGYL ESTERS, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE FOR CONTROLLING Pests
US6072074A (en) * 1998-05-08 2000-06-06 Sumitomo Chemical Company Limited Process for producing 3-propynyl-2-2-dimethylcycloprophane-carboxylic acid and its lower akyl esters

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2392964A1 (en) * 1977-01-24 1978-12-29 Ici Ltd NEW CYCLOPROPANE DERIVATIVES, THEIR PREPARATION PROCESS AND THEIR APPLICATION AS INSECTICIDES
EP0003336A2 (en) * 1978-01-20 1979-08-08 FMC Corporation Insecticidal perhaloalkylvinylcyclopropanecarboxylates

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS515450B1 (en) 1971-06-29 1976-02-20
DE2326077C2 (en) 1972-05-25 1985-12-12 National Research Development Corp., London Unsaturated cyclopropanecarboxylic acids and their derivatives, their preparation and insecticides containing them
JPS5283720A (en) * 1976-01-01 1977-07-12 Kuraray Co Ltd Substituted cyclopropanecarboxylic acid derivatives, and insecticides and acaricides containing a-substituted cyclopropanecarboxylic acid deri vatives
US4130655A (en) * 1976-07-12 1978-12-19 Ciba-Geigy Corporation Pesticidal 2,2-dimethyl-3-isobutyl-cyclopropionates
DE2638356A1 (en) * 1976-08-26 1978-03-02 Bayer Ag METHOD FOR PRODUCING VINYL-SUBSTITUTED CYCLOPROPANCARBONIC ACID ESTERS
GB2008572B (en) * 1977-11-28 1982-01-27 Ici Ltd Manufacture of esters

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2392964A1 (en) * 1977-01-24 1978-12-29 Ici Ltd NEW CYCLOPROPANE DERIVATIVES, THEIR PREPARATION PROCESS AND THEIR APPLICATION AS INSECTICIDES
EP0003336A2 (en) * 1978-01-20 1979-08-08 FMC Corporation Insecticidal perhaloalkylvinylcyclopropanecarboxylates

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0043143A2 (en) * 1980-07-02 1982-01-06 Montedison S.p.A. Process for stereoselectively synthetizing cyclopropane carboxylates as intermediates for pyrethroids
EP0043143A3 (en) * 1980-07-02 1982-10-13 Montedison S.P.A. Process for stereoselectively synthetizing cyclopropane carboxylates as intermediates for pyrethroids
EP0555153A1 (en) * 1992-02-07 1993-08-11 Roussel Uclaf Pyrethrinoide esters, derivatives of furan- or thiophenalcohol, process for their preparation and application thereof as pesticides
FR2687152A1 (en) * 1992-02-07 1993-08-13 Roussel Uclaf NOVEL PYRETHRINOUID ESTERS DERIVED FROM FURANIC OR THIOPHENIC ALCOHOL, PROCESS FOR THEIR PREPARATION AND THEIR USE AS PESTICIDES
US5405865A (en) * 1992-02-07 1995-04-11 Roussel-Uclaf Pyrethroid esters

Also Published As

Publication number Publication date
JPH0212941B2 (en) 1990-03-30
DD142281A5 (en) 1980-06-18
FR2442826B1 (en) 1984-07-06
AU531296B2 (en) 1983-08-18
BE874515A (en) 1979-08-28
IL56739A0 (en) 1979-05-31
DE2907609A1 (en) 1979-09-13
GB2015519B (en) 1982-12-15
DE2907609C2 (en) 1991-02-14
NZ189791A (en) 1981-03-16
NO792716L (en) 1979-08-29
ES478426A1 (en) 1979-12-16
AR241108A2 (en) 1991-11-15
JPS54130537A (en) 1979-10-09
BG48921A3 (en) 1991-06-14
NO153098C (en) 1986-01-15
CH638485A5 (en) 1983-09-30
DK161830C (en) 1992-01-20
GB2015519A (en) 1979-09-12
DK161830B (en) 1991-08-19
NO790621L (en) 1979-08-29
HU185607B (en) 1985-03-28
RO77772A (en) 1981-11-24
DK80379A (en) 1979-09-18
IN150228B (en) 1982-08-21
AR241108A1 (en) 1991-11-15
NO152582C (en) 1985-10-23
BR7901221A (en) 1979-10-02
LU80981A1 (en) 1979-06-18
NO152582B (en) 1985-07-15
PT69283A (en) 1979-03-01
NO153098B (en) 1985-10-07
GR72544B (en) 1983-11-17
PL213760A1 (en) 1979-12-17
BG48333A3 (en) 1991-01-15
AU4463179A (en) 1979-09-06
PL135350B1 (en) 1985-10-31
DD148767A5 (en) 1981-06-10
YU48279A (en) 1983-04-30
CA1237439A (en) 1988-05-31
BG48931A3 (en) 1991-06-14
MX5698E (en) 1983-12-15
NL7901460A (en) 1979-08-30
KE3293A (en) 1983-07-01

Similar Documents

Publication Publication Date Title
FR2383927A1 (en) PYRIDYLMETHYL ESTERS SUBSTITUTES FOR CYCLOPROPANECARBOXYLIC ACIDS USED AS INSECTICIDES
FR2422620A1 (en) STILBENE DERIVATIVES, THEIR PREPARATION AND THEIR APPLICATION AS MEDICINAL PRODUCTS
FR2416216A1 (en) NEW ACYL ANILINES AND THEIR FUNGICIDE APPLICATION
FR2430412A1 (en) SUBSTITUTED PROPANOLAMINE DERIVATIVES USEFUL AS MEDICAMENTS AND PROCESS FOR THEIR PREPARATION
FR2390420A1 (en) NEW CYCLOPEPTIDIC DERIVATIVES, THEIR PREPARATION AND THEIR APPLICATION AS MEDICINAL PRODUCTS
FR2442826A1 (en) NEW CLASS OF PYRETHROIDS AND THEIR USE AS INSECTICIDES
FR2383165A1 (en) NEW DERIVATIVES OF PHENOXY-A-PHENOXY-ALKANECARBOXYLIC ACIDS, THEIR PREPARATION AND THEIR APPLICATION AS HERBICIDES
FR2354338A1 (en) N-PHOSPHONOMETHYLENE-MONOAMINOALCANE-MONO- AND POLYPHOSPHONIC ACIDS AND N-PHOSPHONOMETHYLENE-DIAMINOALCANE-POLYPHOSPHONIC ACIDS, AND THEIR PREPARATION
FR2361877A1 (en) NEW PROSTAGLANDIN-TYPE FREE ACID LACTONS, THEIR PREPARATION AND THE MEDICINAL PRODUCT CONTAINING THEM
FR2400018A1 (en) NEW IMIDAZOLINYLBENZOIC ACIDS, THEIR ESTERS AND THEIR SALTS, THEIR PREPARATION PROCESS AND THEIR APPLICATION AS INSECTICIDES
GB1495597A (en) Haloacylanilides as fungicidally active substances
FR2370724A1 (en) NEW ESTERS OF ALIPHATIC CARBOXYLIC ACIDS, THEIR PREPARATION AND THEIR APPLICATION FOR THE CONTROL OF PARASITES
FR2361326A1 (en) CYCLOHEXANE DERIVATIVES USEFUL AS ODORING AGENTS
FR2390424A1 (en) NEW DERIVATIVES OF SUBSTITUTED PHENYLACETIC ACID AMIDES, THEIR APPLICATION AS A MEDICINAL PRODUCT AND THEIR APPLICATION
FR2432015A1 (en) COMPOUNDS DERIVED FROM CYCLOHEXYLCARBOXYLIC ACID AND PROCESS FOR THEIR PREPARATION
FR2401160A1 (en) NEW VINCAMINOL ESTERS, THEIR PREPARATION AND THEIR APPLICATION AS MEDICINAL PRODUCTS
FR2375211A1 (en) NEW SULFAMOYLBENZOIC ACIDS, THEIR PREPARATION AND THEIR APPLICATION AS MEDICINAL PRODUCTS
FR2415635A1 (en) NEW 3- (N- (ACETOXYACETYL) -N-PHENYL) AMINO-TETRAHYDRO-2-FURANONE DERIVATIVES, THEIR PREPARATION AND THEIR APPLICATION AS MICROBICIDAL AGENTS
FR2378741A1 (en) GARYL GOXO ISOVALERIC ACIDS WITH ANTIPHLOGISTIC AND ANTALGIC PROPERTIES
FR2393787A1 (en) NEW ESTERS OF NAPHTHALENECARBOXYLIC ACIDS, THEIR PREPARATION AND THEIR APPLICATION AS PEST CONTROL AGENTS
FR2391218A1 (en) AZACYCLYL COMPOUNDS AND PROCESS FOR THEIR PREPARATION AND APPLICATION AS A MEDICINAL PRODUCT
FR2426689A1 (en) PROCESS FOR PREPARATION OF TETRAHYDROTHIOPYRANO (2, 3-B) INDOLE DERIVATIVES, NEW PRODUCTS THUS OBTAINED AND THEIR USE AS ANALGESIC AND ANTI-INFLAMMATORY AGENTS
FR2358448A1 (en) NEW 1: 2 COBALTIFIER COMPLEXES, THEIR PREPARATION AND THEIR APPLICATION AS COLORANTS
FR2384767A1 (en) NEW DERIVATIVES OF BENZO-HETEROXYCLYLGLYOXYLIC ACIDS, THEIR PREPARATION AND THEIR APPLICATION AS A MEDICINAL PRODUCT
ES513430A0 (en) "A PROCEDURE FOR THE PREPARATION OF EFFECTIVE COMPOSITIONS AGAINST MITES".

Legal Events

Date Code Title Description
ST Notification of lapse