ES478426A1 - Cyclopropane carboxylic acid esters - Google Patents
Cyclopropane carboxylic acid estersInfo
- Publication number
- ES478426A1 ES478426A1 ES478426A ES478426A ES478426A1 ES 478426 A1 ES478426 A1 ES 478426A1 ES 478426 A ES478426 A ES 478426A ES 478426 A ES478426 A ES 478426A ES 478426 A1 ES478426 A1 ES 478426A1
- Authority
- ES
- Spain
- Prior art keywords
- image
- hydrogen
- group
- atom
- bound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/42—Singly bound oxygen atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C61/00—Compounds having carboxyl groups bound to carbon atoms of rings other than six-membered aromatic rings
- C07C61/16—Unsaturated compounds
- C07C61/40—Unsaturated compounds containing halogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Indole Compounds (AREA)
- Heterocyclic Compounds Containing Sulfur Atoms (AREA)
- Furan Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
Novel compounds having insecticidal and acaricidal activity which is retained over long periods of time under outdoor conditions have the general formula: < IMAGE > in which: A represents CF3-C IDENTICAL C-, < IMAGE > in which X represents a hydrogen, fluorine, chlorine or bromine atom, and Y represents a chlorine or bromine atom, and R represents < IMAGE > the group < IMAGE > is bound to the 2 or 3 position, < IMAGE > in which R<1> represents a hydrogen atom, -CN or -C IDENTICAL CH, R<2> represents a 3-phenoxy, 3- benzyl, 4-allyl or 4-propargyl group, R<3> represents a hydrogen atom or an alkyl group and is bound to the 2 or 3 position, R<4> represents a benzyl, benzoyl, phenoxy, allyl or propargyl group and is bound to the 4 or 5 position, Z represents an oxygen or sulphur atom, R<5> and R<6> each independently represent an alkyl group having 1 to 3 carbon atoms or R<5> and R<6> together with the atoms to which they are bonded represent an aromatic, heteroaromatic or aliphatic, saturated or unsaturated orthocondensed ring, R<7> and R<8> independently represent a hydrogen or halogen atom or CH3, and R<9> represents a phenyl, vinyl substituted vinyl or phenoxy group. Novel intermediates of formula I wherein R is hydrogen or C1-C4 alkyl are also described.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT2071478A IT1095450B (en) | 1978-02-28 | 1978-02-28 | 3-Poly:fluoro-propyl cyclopropane-carboxylate ester derivs. - with insecticidal and acaricidal activities |
| IT20713/78A IT1095449B (en) | 1978-02-28 | 1978-02-28 | NEW PYRETROIDS |
| IT3131078A IT1160403B (en) | 1978-12-27 | 1978-12-27 | 3-Poly:fluoro-propyl cyclopropane-carboxylate ester derivs. - with insecticidal and acaricidal activities |
| IT1970379A IT1166603B (en) | 1979-01-30 | 1979-01-30 | 3-Poly:fluoro-propyl cyclopropane-carboxylate ester derivs. - with insecticidal and acaricidal activities |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES478426A1 true ES478426A1 (en) | 1979-12-16 |
Family
ID=27452781
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES478426A Expired ES478426A1 (en) | 1978-02-28 | 1979-02-27 | Cyclopropane carboxylic acid esters |
Country Status (28)
| Country | Link |
|---|---|
| JP (1) | JPS54130537A (en) |
| AR (1) | AR241108A1 (en) |
| AU (1) | AU531296B2 (en) |
| BE (1) | BE874515A (en) |
| BG (3) | BG48921A3 (en) |
| BR (1) | BR7901221A (en) |
| CA (1) | CA1237439A (en) |
| CH (1) | CH638485A5 (en) |
| DD (2) | DD148767A5 (en) |
| DE (1) | DE2907609A1 (en) |
| DK (1) | DK161830C (en) |
| ES (1) | ES478426A1 (en) |
| FR (1) | FR2442826A1 (en) |
| GB (1) | GB2015519B (en) |
| GR (1) | GR72544B (en) |
| HU (1) | HU185607B (en) |
| IL (1) | IL56739A0 (en) |
| IN (1) | IN150228B (en) |
| KE (1) | KE3293A (en) |
| LU (1) | LU80981A1 (en) |
| MX (1) | MX5698E (en) |
| NL (1) | NL7901460A (en) |
| NO (2) | NO152582C (en) |
| NZ (1) | NZ189791A (en) |
| PL (1) | PL135350B1 (en) |
| PT (1) | PT69283A (en) |
| RO (1) | RO77772A (en) |
| YU (1) | YU48279A (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2831193A1 (en) * | 1978-07-15 | 1980-01-24 | Bayer Ag | FLUORALKENYL-SUBSTITUTED CYCLOPROPANCARBONIC ACID ESTERS AND THEIR USE AS INSECTICIDES |
| DE2965744D1 (en) * | 1978-10-27 | 1983-07-28 | Ici Plc | Process for separating optical isomers of substituted cyclopropane carboxylic acids; amine salts of substituted cyclopropane carboxylic acids; a substituted cyclopropane carboxylic acid |
| DE2919820A1 (en) * | 1979-05-16 | 1980-11-20 | Bayer Ag | FLUOR-SUBSTITUTED OXYALKENYL-CYCLOPROPANCARBONIC ACID ESTERS, METHODS FOR THE PRODUCTION THEREOF AND THEIR USE AS INSECTICIDES AND ACARICIDES |
| EP0022608B1 (en) * | 1979-07-13 | 1983-07-06 | Imperial Chemical Industries Plc | Process for the preparation of cyclopropane carboxylic acid esters |
| IT1131883B (en) * | 1980-07-02 | 1986-06-25 | Montedison Spa | INTERMAEDI PROCESS FOR STEREOSELECTIVE SYNTHESIS OF CYCLOPROPANCARBOXYLATES FOR PYRETROIDS |
| IL83606A (en) * | 1986-08-27 | 1992-03-29 | Montedison Spa | Esters of 3-(3-substituted-3,3-difluoro-1-propenyl)2,2-dimethyl-cyclopropanecarboxylic acid,their preparation and their use as insecticides and acaricides |
| DE3900275A1 (en) * | 1989-01-07 | 1990-07-12 | Basf Ag | SUBSTITUTED CYCLOPROPANCARBONIC ACID PROPARGYL ESTERS, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE FOR CONTROLLING Pests |
| FR2687152A1 (en) * | 1992-02-07 | 1993-08-13 | Roussel Uclaf | NOVEL PYRETHRINOUID ESTERS DERIVED FROM FURANIC OR THIOPHENIC ALCOHOL, PROCESS FOR THEIR PREPARATION AND THEIR USE AS PESTICIDES |
| US6072074A (en) * | 1998-05-08 | 2000-06-06 | Sumitomo Chemical Company Limited | Process for producing 3-propynyl-2-2-dimethylcycloprophane-carboxylic acid and its lower akyl esters |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS515450B1 (en) | 1971-06-29 | 1976-02-20 | ||
| DE2326077C2 (en) | 1972-05-25 | 1985-12-12 | National Research Development Corp., London | Unsaturated cyclopropanecarboxylic acids and their derivatives, their preparation and insecticides containing them |
| JPS5283720A (en) * | 1976-01-01 | 1977-07-12 | Kuraray Co Ltd | Substituted cyclopropanecarboxylic acid derivatives, and insecticides and acaricides containing a-substituted cyclopropanecarboxylic acid deri vatives |
| US4130655A (en) * | 1976-07-12 | 1978-12-19 | Ciba-Geigy Corporation | Pesticidal 2,2-dimethyl-3-isobutyl-cyclopropionates |
| DE2638356A1 (en) * | 1976-08-26 | 1978-03-02 | Bayer Ag | METHOD FOR PRODUCING VINYL-SUBSTITUTED CYCLOPROPANCARBONIC ACID ESTERS |
| US4183948A (en) * | 1977-01-24 | 1980-01-15 | Imperial Chemical Industries Limited | Halogenated esters |
| GB2008572B (en) * | 1977-11-28 | 1982-01-27 | Ici Ltd | Manufacture of esters |
| IN150399B (en) * | 1978-01-20 | 1982-09-25 | Fmc Corp |
-
1979
- 1979-02-06 BG BG044136A patent/BG48921A3/en unknown
- 1979-02-06 BG BG044135A patent/BG48333A3/en unknown
- 1979-02-23 DK DK080379A patent/DK161830C/en not_active IP Right Cessation
- 1979-02-23 NO NO790621A patent/NO152582C/en unknown
- 1979-02-23 NL NL7901460A patent/NL7901460A/en not_active Application Discontinuation
- 1979-02-23 BR BR7901221A patent/BR7901221A/en unknown
- 1979-02-26 GR GR58472A patent/GR72544B/el unknown
- 1979-02-26 BG BG042659A patent/BG48931A3/en unknown
- 1979-02-26 IN IN173/CAL/79A patent/IN150228B/en unknown
- 1979-02-26 PT PT69283A patent/PT69283A/en unknown
- 1979-02-26 IL IL56739A patent/IL56739A0/en not_active IP Right Cessation
- 1979-02-27 GB GB7906851A patent/GB2015519B/en not_active Expired
- 1979-02-27 DD DD79218658A patent/DD148767A5/en not_active IP Right Cessation
- 1979-02-27 YU YU00482/79A patent/YU48279A/en unknown
- 1979-02-27 CA CA000322525A patent/CA1237439A/en not_active Expired
- 1979-02-27 PL PL1979213760A patent/PL135350B1/en unknown
- 1979-02-27 CH CH194279A patent/CH638485A5/en unknown
- 1979-02-27 HU HU79MO1039A patent/HU185607B/en unknown
- 1979-02-27 ES ES478426A patent/ES478426A1/en not_active Expired
- 1979-02-27 AU AU44631/79A patent/AU531296B2/en not_active Expired
- 1979-02-27 DE DE19792907609 patent/DE2907609A1/en active Granted
- 1979-02-27 FR FR7904952A patent/FR2442826A1/en active Granted
- 1979-02-27 DD DD79211259A patent/DD142281A5/en not_active IP Right Cessation
- 1979-02-28 MX MX797764U patent/MX5698E/en unknown
- 1979-02-28 NZ NZ189791A patent/NZ189791A/en unknown
- 1979-02-28 LU LU80981A patent/LU80981A1/en unknown
- 1979-02-28 BE BE0/193748A patent/BE874515A/en not_active IP Right Cessation
- 1979-02-28 AR AR275649A patent/AR241108A1/en active
- 1979-02-28 JP JP2204779A patent/JPS54130537A/en active Granted
- 1979-02-28 RO RO79101065A patent/RO77772A/en unknown
- 1979-08-21 NO NO792716A patent/NO153098C/en unknown
-
1983
- 1983-06-08 KE KE3293A patent/KE3293A/en unknown
Also Published As
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 19970519 |