IT1095450B - 3-Poly:fluoro-propyl cyclopropane-carboxylate ester derivs. - with insecticidal and acaricidal activities - Google Patents

3-Poly:fluoro-propyl cyclopropane-carboxylate ester derivs. - with insecticidal and acaricidal activities

Info

Publication number
IT1095450B
IT1095450B IT2071478A IT2071478A IT1095450B IT 1095450 B IT1095450 B IT 1095450B IT 2071478 A IT2071478 A IT 2071478A IT 2071478 A IT2071478 A IT 2071478A IT 1095450 B IT1095450 B IT 1095450B
Authority
IT
Italy
Prior art keywords
insecticidal
fluoro
poly
carboxylate ester
alkyl
Prior art date
Application number
IT2071478A
Other languages
Italian (it)
Other versions
IT7820714A0 (en
Inventor
Paolo Piccardi
Francesco Corda
Franco Gozzo
Augusto Menconi
Original Assignee
Montedison Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montedison Spa filed Critical Montedison Spa
Publication of IT7820714A0 publication Critical patent/IT7820714A0/en
Priority to IT2071478A priority Critical patent/IT1095450B/en
Priority to BG044136A priority patent/BG48921A3/en
Priority to BG044135A priority patent/BG48333A3/en
Priority to NO790621A priority patent/NO152582C/en
Priority to NL7901460A priority patent/NL7901460A/en
Priority to BR7901221A priority patent/BR7901221A/en
Priority to DK080379A priority patent/DK161830C/en
Priority to BG042659A priority patent/BG48931A3/en
Priority to GR58472A priority patent/GR72544B/el
Priority to US06/015,104 priority patent/US4258202A/en
Priority to IN173/CAL/79A priority patent/IN150228B/en
Priority to PT69283A priority patent/PT69283A/en
Priority to IL56739A priority patent/IL56739A0/en
Priority to GB7906851A priority patent/GB2015519B/en
Priority to YU00482/79A priority patent/YU48279A/en
Priority to ES478426A priority patent/ES478426A1/en
Priority to FR7904952A priority patent/FR2442826A1/en
Priority to PL1979213760A priority patent/PL135350B1/en
Priority to AU44631/79A priority patent/AU531296B2/en
Priority to DE19792907609 priority patent/DE2907609A1/en
Priority to HU79MO1039A priority patent/HU185607B/en
Priority to DD79218658A priority patent/DD148767A5/en
Priority to CS131579A priority patent/CS222280B2/en
Priority to CA000322525A priority patent/CA1237439A/en
Priority to CH194279A priority patent/CH638485A5/en
Priority to DD79211259A priority patent/DD142281A5/en
Priority to RO79101065A priority patent/RO77772A/en
Priority to MX797764U priority patent/MX5698E/en
Priority to OA56747A priority patent/OA06196A/en
Priority to AR275649A priority patent/AR241108A1/en
Priority to BE0/193748A priority patent/BE874515A/en
Priority to JP2204779A priority patent/JPS54130537A/en
Priority to RO7996740A priority patent/RO77307A/en
Priority to NZ189791A priority patent/NZ189791A/en
Priority to LU80981A priority patent/LU80981A1/en
Priority to TR2062479A priority patent/TR20624A/en
Priority to NO792716A priority patent/NO153098C/en
Priority to SU802891757A priority patent/SU1053744A3/en
Priority to KE3293A priority patent/KE3293A/en
Application granted granted Critical
Publication of IT1095450B publication Critical patent/IT1095450B/en

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Esters of formula (I) are new. In (I), A is CF3-C=C-, -CF3-CX=CH- or CF3-C(XY)-CH2-; X is H,F,CL or Br; Y is Cl or Br; R is a gp. -CH2. CR7=CR8. CH2R9, -CH2C=CCH2R9 or (II) - (IV); R1 is H, CN or C=CH; in (III) CHR1 is attached at the 2 or 3 position; R2 is 3-phenoxy, 3-benzyl, 4-allyl, 4-propargyl; R3 is H or alkyl, attached at the 2 or 3 position; R4 is benzyl, benzoyl, phenyl, allyl or propargyl attached at the 4 or 5 position; Y1 is O or S; R5 and R6 are each 1-3C alkyl or together complete an aliphatic, heteroaromatic or aromatic ring (satd. or unsatd.); R7 and R8 are each H, halo or CH3; and R9 is phenyl, opt. substd. vinyl or phenoxy. Also new are cpds. (II) in which R is replaced by H or 1-4C alkyl. (I) are insecticides more effective and more stable than known natural or synthetic pyrethrins, and also have acaricidal activity. (II) are intermediates for (I).
IT2071478A 1978-02-28 1978-02-28 3-Poly:fluoro-propyl cyclopropane-carboxylate ester derivs. - with insecticidal and acaricidal activities IT1095450B (en)

Priority Applications (39)

Application Number Priority Date Filing Date Title
IT2071478A IT1095450B (en) 1978-02-28 1978-02-28 3-Poly:fluoro-propyl cyclopropane-carboxylate ester derivs. - with insecticidal and acaricidal activities
BG044136A BG48921A3 (en) 1978-02-28 1979-02-06 Method for destroying of insects
BG044135A BG48333A3 (en) 1978-02-28 1979-02-06 Method for preparing of 2, 2- dimethyl cyclopropane carbonic acid derivatives
NO790621A NO152582C (en) 1978-02-28 1979-02-23 INSECTICID AGENT CONTAINING AS ACTIVE COMPONENT ONE OR MORE 3-SUBSTITUTED 2,2-DIMETHYL-CYCLOPROPANCARBOXYL ACID ESTERS
NL7901460A NL7901460A (en) 1978-02-28 1979-02-23 INSECTICIDE PYRETHROIDS, CYCLOPROPANECARBON ACIDS AND ESTER INTERMEDIATE PRODUCTS AND METHODS FOR PREPARING THEM.
BR7901221A BR7901221A (en) 1978-02-28 1979-02-23 PROCESS FOR THE PREPARATION OF INSECTICID AND ACARICIDE COMPOUNDS
DK080379A DK161830C (en) 1978-02-28 1979-02-23 ESTERS OF 2,2-DIMETHYLYCYCLOPROPANCARBOXYL ACID DERIVATIVES, PROCEDURES FOR THE PRODUCTION THEREOF, INSECTICID AND ACARICID AGENTS AND PROCEDURES TO FIGHT AGAINST PLANTS
BG042659A BG48931A3 (en) 1978-02-28 1979-02-26 Method for preparing of pyretroids
GR58472A GR72544B (en) 1978-02-28 1979-02-26
US06/015,104 US4258202A (en) 1978-02-28 1979-02-26 Cyclopropanecarboxylic acids and esters
IN173/CAL/79A IN150228B (en) 1978-02-28 1979-02-26
PT69283A PT69283A (en) 1978-02-28 1979-02-26 Pyrethroids
IL56739A IL56739A0 (en) 1978-02-28 1979-02-26 Cyclorpropanecarboxylic acid derivatives,their preparationand their use as insecticides and acaricides
AU44631/79A AU531296B2 (en) 1978-02-28 1979-02-27 Pyrethroids
YU00482/79A YU48279A (en) 1978-02-28 1979-02-27 Process for preparing insecticidic and acaricidic compounds
ES478426A ES478426A1 (en) 1978-02-28 1979-02-27 Cyclopropane carboxylic acid esters
FR7904952A FR2442826A1 (en) 1978-02-28 1979-02-27 NEW CLASS OF PYRETHROIDS AND THEIR USE AS INSECTICIDES
PL1979213760A PL135350B1 (en) 1978-02-28 1979-02-27 METHOD OF OBTAINING NOVEL PYRETROIDES AND INSECTICIDE AND / OR ACARICIDE
GB7906851A GB2015519B (en) 1978-02-28 1979-02-27 Cyclopropane carboxylic acid esters
DE19792907609 DE2907609A1 (en) 1978-02-28 1979-02-27 NEW PYRETHROIDS, THEIR PRODUCTION AND USE
HU79MO1039A HU185607B (en) 1978-02-28 1979-02-27 Process for producing cyclopropan-carboxylic acid derivatives
DD79218658A DD148767A5 (en) 1978-02-28 1979-02-27 METHOD FOR THE PRODUCTION OF INSECTICIDAL AND ACARICIDAL COMPOUNDS
CS131579A CS222280B2 (en) 1978-02-28 1979-02-27 Insecticide and acaricide means and method of making the active substances
CA000322525A CA1237439A (en) 1978-02-28 1979-02-27 2,2-dimethylcyclopropane carboxylic acid derivatives
CH194279A CH638485A5 (en) 1978-02-28 1979-02-27 PYRETROIDS AND THEIR PREPARATION PROCESSES.
DD79211259A DD142281A5 (en) 1978-02-28 1979-02-27 PROCEDURE FOR THE CONTROL OF INSECTS AND ACARES
RO79101065A RO77772A (en) 1978-02-28 1979-02-28 PROCESS FOR THE PREPARATION OF 2,2-DIMETHYLCYCLOPROPANCARBOXYLIC ACID DERIVATIVES
MX797764U MX5698E (en) 1978-02-28 1979-02-28 PROCEDURE FOR PREPARING ESTERS OF 2,2-DIMETHYL CYCLOPROPANCARBOXYLIC ACIDS
OA56747A OA06196A (en) 1978-02-28 1979-02-28 New pyrethroids usable as insecticides.
AR275649A AR241108A1 (en) 1978-02-28 1979-02-28 PYRETHROID INSECTICIDES, CYCLOPROPANCARBOXYLIC ACIDS AND INTERMEDIATE ESTERS AND THEIR PREPARATION PROCEDURES
BE0/193748A BE874515A (en) 1978-02-28 1979-02-28 NEW CLASS OF PYRETHROIDS AND THEIR USE AS INSECTICIDES
JP2204779A JPS54130537A (en) 1978-02-28 1979-02-28 Pyrethroid insecticide*cyclopropane carboxylic acid and ester intermediate and their manufacture
RO7996740A RO77307A (en) 1978-02-28 1979-02-28 PROCESS FOR OBTAINING ESTERS OF 2,2-DIMETHYLECYCLOPROPANCARBOXYLIC ACIDS
NZ189791A NZ189791A (en) 1978-02-28 1979-02-28 2,2-cyclopropanecarboxylic acid esters and pesticidal compositions
LU80981A LU80981A1 (en) 1978-02-28 1979-02-28 NEW CLEASSE OF PYRETHROIDS AND THEIR USE AS INSECTICIDES
TR2062479A TR20624A (en) 1978-02-28 1979-02-28 NEW CYCLOPROPANKARBOXYLIC ACIDS AND ESTERS
NO792716A NO153098C (en) 1978-02-28 1979-08-21 3-SUBSTITUTED 2,2-DIMETHYL-CYCLOPROPANCARBOXYL ACIDES AND LOWER ALKYLESTERS THEREOF USE AS OUTSIDE MATERIALS IN THE PREPARATION OF PYRETHROIDS WITH INSECTICID EFFECT
SU802891757A SU1053744A3 (en) 1978-02-28 1980-03-12 Process for preparing ethers of 2,2-dimethylcyclopropane carboxylic acids
KE3293A KE3293A (en) 1978-02-28 1983-06-08 Pyrethrols insecticides cyclopropanecarboxylic acids

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT2071478A IT1095450B (en) 1978-02-28 1978-02-28 3-Poly:fluoro-propyl cyclopropane-carboxylate ester derivs. - with insecticidal and acaricidal activities

Publications (2)

Publication Number Publication Date
IT7820714A0 IT7820714A0 (en) 1978-02-28
IT1095450B true IT1095450B (en) 1985-08-10

Family

ID=11170960

Family Applications (1)

Application Number Title Priority Date Filing Date
IT2071478A IT1095450B (en) 1978-02-28 1978-02-28 3-Poly:fluoro-propyl cyclopropane-carboxylate ester derivs. - with insecticidal and acaricidal activities

Country Status (2)

Country Link
IT (1) IT1095450B (en)
TR (1) TR20624A (en)

Also Published As

Publication number Publication date
IT7820714A0 (en) 1978-02-28
TR20624A (en) 1982-03-09

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