IT1137270B - Catalizzatore e procedimento per l'idroraffinazione di cariche di idrocarburi a tenori elevati di costituenti indesiderabili quali metalli, resine e asfalteni - Google Patents

Catalizzatore e procedimento per l'idroraffinazione di cariche di idrocarburi a tenori elevati di costituenti indesiderabili quali metalli, resine e asfalteni

Info

Publication number
IT1137270B
IT1137270B IT22674/81A IT2267481A IT1137270B IT 1137270 B IT1137270 B IT 1137270B IT 22674/81 A IT22674/81 A IT 22674/81A IT 2267481 A IT2267481 A IT 2267481A IT 1137270 B IT1137270 B IT 1137270B
Authority
IT
Italy
Prior art keywords
asphaltenes
resins
metals
catalyst
high levels
Prior art date
Application number
IT22674/81A
Other languages
English (en)
Other versions
IT8122674A0 (it
Inventor
Page Jean Francois Le
Alain Billon
Jacquin Yves
Original Assignee
Catalyse Soc Prod Francais
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Catalyse Soc Prod Francais filed Critical Catalyse Soc Prod Francais
Publication of IT8122674A0 publication Critical patent/IT8122674A0/it
Application granted granted Critical
Publication of IT1137270B publication Critical patent/IT1137270B/it

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
IT22674/81A 1980-07-02 1981-07-01 Catalizzatore e procedimento per l'idroraffinazione di cariche di idrocarburi a tenori elevati di costituenti indesiderabili quali metalli, resine e asfalteni IT1137270B (it)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8014787A FR2486094B1 (it) 1980-07-02 1980-07-02

Publications (2)

Publication Number Publication Date
IT8122674A0 IT8122674A0 (it) 1981-07-01
IT1137270B true IT1137270B (it) 1986-09-03

Family

ID=9243796

Family Applications (1)

Application Number Title Priority Date Filing Date
IT22674/81A IT1137270B (it) 1980-07-02 1981-07-01 Catalizzatore e procedimento per l'idroraffinazione di cariche di idrocarburi a tenori elevati di costituenti indesiderabili quali metalli, resine e asfalteni

Country Status (7)

Country Link
US (1) US4395329A (it)
JP (1) JPS5740588A (it)
DE (1) DE3125339A1 (it)
FR (1) FR2486094B1 (it)
IT (1) IT1137270B (it)
MX (1) MX7395E (it)
NL (1) NL8103132A (it)

Families Citing this family (48)

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US4549957A (en) * 1981-06-17 1985-10-29 Amoco Corporation Hydrotreating catalyst and process
US4581129A (en) * 1982-04-12 1986-04-08 Union Oil Company Of California Hydrorefining with a regenerated catalyst
US4485183A (en) * 1982-04-12 1984-11-27 Union Oil Company Of California Regeneration and reactivation of deactivated hydrorefining catalyst
JPS58219293A (ja) * 1982-06-15 1983-12-20 Chiyoda Chem Eng & Constr Co Ltd 重質油の水素化分解方法
FR2528721B1 (fr) * 1982-06-17 1986-02-28 Pro Catalyse Ste Fse Prod Cata Catalyseur supporte presentant une resistance accrue aux poisons et son utilisation en particulier pour l'hydrotraitement de fractions petrolieres contenant des metaux
FR2538812B1 (fr) * 1982-12-29 1985-10-11 Pro Catalyse Utilisation d'un catalyseur supporte pour l'hydrotraitement d'une charge d'hydrocarbures
FR2538811A1 (fr) * 1982-12-30 1984-07-06 Inst Francais Du Petrole Procede de traitement d'une huile lourde ou d'une fraction d'huile lourde pour les convertir en fractions plus legeres
FR2538814B1 (fr) * 1982-12-30 1986-06-27 Inst Francais Du Petrole Procede de traitement d'une huile lourde ou d'une fraction d'huile lourde pour les convertir en fractions plus legeres
FR2538813A1 (fr) * 1982-12-31 1984-07-06 Inst Francais Du Petrole Procede d'hydrotraitement convertissant en au moins deux etapes une fraction lourde d'hydrocarbures contenant des impuretes soufrees et des impuretes metalliques
US4818743A (en) * 1983-04-07 1989-04-04 Union Oil Company Of California Desulfurization catalyst and the catalyst prepared by a method
US4548709A (en) * 1983-04-29 1985-10-22 Mobil Oil Corporation Hydrotreating petroleum heavy ends in aromatic solvents with dual pore size distribution alumina catalyst
US4520128A (en) * 1983-12-19 1985-05-28 Intevep, S.A. Catalyst having high metal retention capacity and good stability for use in the demetallization of heavy crudes and method of preparation of same
US4642179A (en) * 1983-12-19 1987-02-10 Intevep, S.A. Catalyst for removing sulfur and metal contaminants from heavy crudes and residues
US4588709A (en) * 1983-12-19 1986-05-13 Intevep, S.A. Catalyst for removing sulfur and metal contaminants from heavy crudes and residues
JPS60219295A (ja) * 1984-04-16 1985-11-01 Res Assoc Residual Oil Process<Rarop> 重質炭化水素油の水素化処理方法
US4746419A (en) * 1985-12-20 1988-05-24 Amoco Corporation Process for the hydrodemetallation hydrodesulfuration and hydrocracking of a hydrocarbon feedstock
JPS62201643A (ja) * 1986-02-28 1987-09-05 Nippon Oil Co Ltd 水素化触媒の製造法
US4789462A (en) * 1986-09-29 1988-12-06 Chevron Research Company Reverse-graded catalyst systems for hydrodemetalation and hydrodesulfurization
US4738944A (en) * 1986-12-05 1988-04-19 Union Oil Company Of California Ni-P-Mo catalyst and hydroprocessing use thereof
US4846961A (en) * 1986-12-05 1989-07-11 Union Oil Company Of California Hydroprocessing catalyst with a Ni-P-Mo
US4870044A (en) * 1987-03-12 1989-09-26 Phillips Petroleum Company Treated alumina material for fixed hydrofining beds
US4802974A (en) * 1987-03-12 1989-02-07 Phillips Petroleum Company Hydrofining employing treated alumina material in fixed beds
US4888104A (en) * 1988-09-06 1989-12-19 Intevep, S.A. Catalytic system for the hydroconversion of heavy oils
US5868923A (en) * 1991-05-02 1999-02-09 Texaco Inc Hydroconversion process
US5177047A (en) * 1991-10-02 1993-01-05 Chevron Research And Technology Company High activity resid catalyst
US5275990A (en) * 1991-10-31 1994-01-04 Amoco Corporation Process for regenerating a spent resid hydroprocessing catalyst using a group IIA metal
US5221656A (en) * 1992-03-25 1993-06-22 Amoco Corporation Hydroprocessing catalyst
CA2093412C (en) * 1992-04-20 2002-12-31 Gerald Verdell Nelson Novel hydroconversion process employing catalyst with specified pore size distribution
US5399259A (en) * 1992-04-20 1995-03-21 Texaco Inc. Hydroconversion process employing catalyst with specified pore size distribution
MX9305801A (es) † 1992-09-29 1994-07-29 Texaco Development Corp Proceso de hidroconversion novedoso que emplea catalizador con distribucion especificada de tamaño de poro.
US5322829A (en) * 1993-03-15 1994-06-21 Amoco Corporation Resid hydrotreating catalyst and process
US5928499A (en) * 1993-10-01 1999-07-27 Texaco Inc Hydroconversion process employing catalyst with specified pore size distribution, median pore diameter by surface area, and pore mode by volume
US5468371A (en) * 1994-04-11 1995-11-21 Texaco Inc. Catalyst for residual conversion demonstrating reduced toluene insolubles
US6015485A (en) * 1994-05-13 2000-01-18 Cytec Technology Corporation High activity catalysts having a bimodal mesopore structure
US5968348A (en) * 1994-05-16 1999-10-19 Texaco Inc. Hydroconversion process employing a phosphorus loaded NiMo catalyst with specified pore size distribution
US5620592A (en) * 1994-07-29 1997-04-15 Chevron U.S.A. Inc. Low macropore resid conversion catalyst
CN1054393C (zh) * 1997-07-22 2000-07-12 中国石油化工总公司 一种渣油加氢脱金属催化剂
US6387248B2 (en) 1997-11-06 2002-05-14 Texaco Inc. Method of preparing a catalyst for use in the hydrotreating of high boiling hydrocarbon feedstocks
US6156190A (en) * 1998-03-20 2000-12-05 China Petrochemical Corporation Conversion process of hydrocarbon oils
CA2266194C (en) * 1998-03-20 2007-09-18 China Petrochemical Corporation A catalyst containing molybdenum and/or tungsten for hydrotreating light oil distillates and preparation method thereof
EP1060794B2 (en) † 1998-12-08 2014-01-15 Japan Energy Corporation Catalyst for hydrofining and method for preparation thereof
JP4538014B2 (ja) * 1998-12-08 2010-09-08 株式会社ジャパンエナジー 水素化精製用触媒
US6508999B1 (en) * 2000-11-21 2003-01-21 Shell Oil Company Aluminum trihydroxide phase
US6589908B1 (en) * 2000-11-28 2003-07-08 Shell Oil Company Method of making alumina having bimodal pore structure, and catalysts made therefrom
JP4638610B2 (ja) * 2001-01-05 2011-02-23 日本ケッチェン株式会社 水素化処理用触媒並びに水素化処理方法
JP4612229B2 (ja) * 2001-06-08 2011-01-12 日本ケッチェン株式会社 重質炭化水素油の水素化処理用触媒並びに水素化処理方法
US8110527B2 (en) 2006-08-11 2012-02-07 China Petroleum & Chemical Corporation Alumina having a complex pore structure, and catalyst and process for selective hydrogenation of cracking gasoline
US20130105357A1 (en) * 2011-10-27 2013-05-02 Shell Oil Company Self-activating hydroprocessing catalyst and process for treating heavy hydrocarbon feedstocks

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US3180820A (en) * 1962-08-15 1965-04-27 Universal Oil Prod Co Dual zone hydrorefining process
CA943944A (en) * 1967-10-27 1974-03-19 Michael C. Chervenak Catalysts, methods of preparation of same and processes for using same
DD115149A1 (it) * 1973-06-28 1975-09-12
US3904550A (en) * 1973-10-19 1975-09-09 Exxon Research Engineering Co Hydrocarbon conversion catalyst comprising alumina and aluminum phosphate
US3898155A (en) * 1973-12-19 1975-08-05 Gulf Research Development Co Heavy oil demetallization and desulfurization process
US3867282A (en) * 1974-03-27 1975-02-18 Mobil Oil Corp Process for oil demetalation and desulfurization with cobalt-molybdenum impregnated magnesium aluminate spinel
NL7412337A (nl) * 1974-09-18 1976-03-22 Shell Int Research Werkwijze voor de bereiding van nieuwe kata- lysatoren.
US4134856A (en) * 1975-04-18 1979-01-16 Toa Nenryo Kogyo Kabushiki Kaisha Catalyst for hydro-refining hydrocarbon oils
US4003828A (en) * 1975-07-23 1977-01-18 Exxon Research And Engineering Company Catalyst and process for removing sulfur and metal contaminants from hydrocarbon feedstocks
CA1069486A (en) * 1975-11-10 1980-01-08 Nalco Chemical Company Method of preparing a controlled pore volume alumina with citric acid
US4102822A (en) * 1976-07-26 1978-07-25 Chevron Research Company Hydrocarbon hydroconversion catalyst and the method for its preparation
CA1102778A (en) * 1976-09-07 1981-06-09 Richard G. Stellman Hydroconversion catalyst and process
US4066572A (en) * 1976-10-12 1978-01-03 Nalco Chemical Company Phospha-alumina gel and method of preparation
US4225421A (en) * 1979-03-13 1980-09-30 Standard Oil Company (Indiana) Process for hydrotreating heavy hydrocarbons
US4317778A (en) * 1980-12-29 1982-03-02 Standard Oil Company (Sohio) Preparation of maleic anhydride using fluidized catalysts

Also Published As

Publication number Publication date
JPS5740588A (en) 1982-03-06
IT8122674A0 (it) 1981-07-01
DE3125339C2 (it) 1993-07-29
FR2486094A1 (it) 1982-01-08
US4395329A (en) 1983-07-26
FR2486094B1 (it) 1985-03-22
NL8103132A (nl) 1982-02-01
MX7395E (es) 1988-09-20
DE3125339A1 (de) 1982-05-06
JPH0257594B2 (it) 1990-12-05

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Legal Events

Date Code Title Description
TA Fee payment date (situation as of event date), data collected since 19931001

Effective date: 19970729