IN2014DN05910A - - Google Patents
Info
- Publication number
- IN2014DN05910A IN2014DN05910A IN5910DEN2014A IN2014DN05910A IN 2014DN05910 A IN2014DN05910 A IN 2014DN05910A IN 5910DEN2014 A IN5910DEN2014 A IN 5910DEN2014A IN 2014DN05910 A IN2014DN05910 A IN 2014DN05910A
- Authority
- IN
- India
- Prior art keywords
- polymer
- less
- dbi
- vinyl
- itaconate
- Prior art date
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/12—Esters of phenols or saturated alcohols
- C08F222/14—Esters having no free carboxylic acid groups, e.g. dialkyl maleates or fumarates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
- B05D3/0254—After-treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/10—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by other chemical means
- B05D3/107—Post-treatment of applied coatings
- B05D3/108—Curing
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- C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
- C08F22/10—Esters
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- C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
- C08F22/36—Amides or imides
- C08F22/38—Amides
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- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
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- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
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- C08F222/04—Anhydrides, e.g. cyclic anhydrides
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- C08F26/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
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- C08F26/08—N-Vinyl-pyrrolidine
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- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
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- C08F8/00—Chemical modification by after-treatment
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Abstract
There are described vinyl sequential copolymers (and processes for making them) comprising (a) at least 8. 5 wt % preferably >=20 wt % of a higher itaconate diester (preferably dibutyl itaconate DBI); (b) less than 23 wt % acid monomer but also sufficient to have an acid value less than 150 mg KOH/g of polymer (c) optionally with less than 50 wt % of other itaconate monomers and (d) optionally less than 77 wt %of other monomers not (a) to (c). The DBI may be biorenewable. One embodiment is an aqueous dispersion of the vinyl sequential polymer of two phases: A) 40 to 90 wt % of a vinyl polymer A with Tg from 50 to 30°C; and B) 10 to 60 wt % of a vinyl polymer B with Tg from 50 to 130°C; where DBI is used to prepare A and/or B and polymer A has from 0.1 to 10 wt % of at least one acid functional olefinically unsaturated monomer.
Applications Claiming Priority (10)
Application Number | Priority Date | Filing Date | Title |
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EP12153840 | 2012-02-03 | ||
EP12153842 | 2012-02-03 | ||
EP12153838 | 2012-02-03 | ||
EP12153839 | 2012-02-03 | ||
EP12175786 | 2012-07-10 | ||
EP12175785 | 2012-07-10 | ||
EP12175782 | 2012-07-10 | ||
EP12175784 | 2012-07-10 | ||
EP12175788 | 2012-07-10 | ||
PCT/EP2013/052173 WO2013113937A1 (en) | 2012-02-03 | 2013-02-04 | Polymer, process and composition |
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