IL72967A - Regeneration of 2-layer crystalline lithium aluminates with aqueous li+solutions and method of extracting li+ions from a brine - Google Patents

Regeneration of 2-layer crystalline lithium aluminates with aqueous li+solutions and method of extracting li+ions from a brine

Info

Publication number
IL72967A
IL72967A IL72967A IL7296784A IL72967A IL 72967 A IL72967 A IL 72967A IL 72967 A IL72967 A IL 72967A IL 7296784 A IL7296784 A IL 7296784A IL 72967 A IL72967 A IL 72967A
Authority
IL
Israel
Prior art keywords
brine
regeneration
ions
extracting
aqueous
Prior art date
Application number
IL72967A
Other languages
English (en)
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of IL72967A publication Critical patent/IL72967A/xx

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/16—Organic material
    • B01J39/17—Organic material containing also inorganic materials, e.g. inert material coated with an ion-exchange resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/08—Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/10—Inorganic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J47/00—Ion-exchange processes in general; Apparatus therefor
    • B01J47/018—Granulation; Incorporation of ion-exchangers in a matrix; Mixing with inert materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
    • C01F7/04—Preparation of alkali metal aluminates; Aluminium oxide or hydroxide therefrom
    • C01F7/043—Lithium aluminates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/78—Compounds containing aluminium and two or more other elements, with the exception of oxygen and hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/10—Particle morphology extending in one dimension, e.g. needle-like
    • C01P2004/11—Particle morphology extending in one dimension, e.g. needle-like with a prismatic shape

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treatment Of Water By Ion Exchange (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)
  • Manufacture And Refinement Of Metals (AREA)
IL72967A 1980-12-18 1984-09-17 Regeneration of 2-layer crystalline lithium aluminates with aqueous li+solutions and method of extracting li+ions from a brine IL72967A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/217,614 US4348295A (en) 1980-12-18 1980-12-18 Crystalline lithium aluminates

Publications (1)

Publication Number Publication Date
IL72967A true IL72967A (en) 1988-02-29

Family

ID=22811789

Family Applications (1)

Application Number Title Priority Date Filing Date
IL72967A IL72967A (en) 1980-12-18 1984-09-17 Regeneration of 2-layer crystalline lithium aluminates with aqueous li+solutions and method of extracting li+ions from a brine

Country Status (7)

Country Link
US (1) US4348295A (xx)
EP (1) EP0211983B1 (xx)
JP (1) JPS6174645A (xx)
AU (2) AU576518B2 (xx)
CA (1) CA1223742A (xx)
DE (1) DE3436701A1 (xx)
IL (1) IL72967A (xx)

Families Citing this family (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4461714A (en) * 1980-12-18 1984-07-24 The Dow Chemical Company Method of making crystalline 2-layer lithium aluminates in ion exchange resins
US4540509A (en) * 1980-12-18 1985-09-10 The Dow Chemical Company Crystalline 3-layer lithium aluminates
US4477367A (en) * 1980-12-18 1984-10-16 The Dow Chemical Company Crystalline 2-layer lithium-hydroxy aluminates
US4348295A (en) * 1980-12-18 1982-09-07 The Dow Chemical Company Crystalline lithium aluminates
EP0103034A1 (en) * 1982-09-09 1984-03-21 The Dow Chemical Company Crystalline lithium aluminates and a process for the preparation thereof
US4594335A (en) * 1984-05-11 1986-06-10 The Dow Chemical Company Transition metal aluminates
US4519924A (en) * 1984-06-11 1985-05-28 The Dow Chemical Lithium stearate aluminate as lubricant additive
PT80599B (pt) * 1984-06-11 1987-10-20 Dow Chemical Co Processo para melhorar as propriedades anti-friccao de fluidos de lubrificacao usando metalo-organo-aluminatos como aditivos lubrificantes
CA1290137C (en) * 1984-06-11 1991-10-08 John L. Burba, Iii Intercalations of crystalline lithium aluminates
IL79304A (en) * 1985-07-05 1990-07-12 Dow Chemical Co Mixed metal hydroxides for thickening water or hydrophilic fluids
US5389349A (en) * 1993-05-24 1995-02-14 Bauman; William C. Recovery of lithium values from brines
US5599516A (en) 1993-05-24 1997-02-04 Fmc Corporation Recovery of lithium values from brines
US6555078B1 (en) * 1996-09-26 2003-04-29 Fmc Corporation Method of preparing lithium salts
AU2008302364A1 (en) * 2007-09-17 2009-03-26 Areva Federal Services Llc A process for removal of aluminum oxides from aqueous media
US9527753B1 (en) 2009-04-24 2016-12-27 Geothermal Energy Project, Llc Production of zinc chloride and zinc sulfate from geothermal brines
US9051827B1 (en) 2009-09-02 2015-06-09 Simbol Mining Corporation Selective removal of silica from silica containing brines
US8454816B1 (en) 2009-09-11 2013-06-04 Simbol Inc. Selective recovery of manganese and zinc from geothermal brines
US8637428B1 (en) 2009-12-18 2014-01-28 Simbol Inc. Lithium extraction composition and method of preparation thereof
US8597521B1 (en) 2009-06-24 2013-12-03 Simbol Inc. Selective removal of silica from silica containing brines
US10190030B2 (en) 2009-04-24 2019-01-29 Alger Alternative Energy, Llc Treated geothermal brine compositions with reduced concentrations of silica, iron and lithium
US9034294B1 (en) 2009-04-24 2015-05-19 Simbol, Inc. Preparation of lithium carbonate from lithium chloride containing brines
US8901032B1 (en) 2010-10-29 2014-12-02 Simbol Inc. Porous activated alumina based sorbent for lithium extraction
US8753594B1 (en) 2009-11-13 2014-06-17 Simbol, Inc. Sorbent for lithium extraction
US8741256B1 (en) 2009-04-24 2014-06-03 Simbol Inc. Preparation of lithium carbonate from lithium chloride containing brines
US8518232B1 (en) 2011-06-29 2013-08-27 Simbol Inc. Selective recovery of manganese, lead and zinc
US9644126B2 (en) 2009-06-24 2017-05-09 Simbol, Inc. Treated geothermal brine compositions with reduced concentrations of silica, iron, and zinc
US9534276B1 (en) 2011-06-29 2017-01-03 Geothermal Energy Project, Llc Separation of manganese from brine
US10683563B2 (en) 2009-06-24 2020-06-16 Terralithium Llc Treated geothermal brine compositions with reduced concentrations of silica, iron and manganese
US9644866B2 (en) 2009-06-24 2017-05-09 Simbol, Inc. Treated brine compositions with reduced concentrations of potassium, rubidium, and cesium
US10935006B2 (en) 2009-06-24 2021-03-02 Terralithium Llc Process for producing geothermal power, selective removal of silica and iron from brines, and improved injectivity of treated brines
US9650555B2 (en) 2009-06-24 2017-05-16 Simbol, Inc. Treated geothermal brine compositions with reduced concentrations of iron and silica
US9249478B2 (en) 2009-09-11 2016-02-02 Simbol, Inc. Selective recovery of manganese, lead and zinc
CA2789771C (en) 2010-02-17 2022-06-14 Simbol Mining Corp. Highly pure lithium carbonate prepared using reverse osmosis
US8309043B2 (en) 2010-12-06 2012-11-13 Fmc Corporation Recovery of Li values from sodium saturate brine
GB201107344D0 (en) 2011-05-04 2011-06-15 Isis Innovation Method for the preparation of layered double hydroxides
FR3015460A1 (fr) * 2013-12-23 2015-06-26 Eramet Procede de preparation d'un materiau adsorbant mis en forme par precipitation de nitrate d'aluminium et d'aluminate de sodium et procede d'extraction de lithium utilisant ledit materiau
KR20170078617A (ko) * 2014-10-30 2017-07-07 알베마를 코포레이션 염수로부터 리튬 유가물의 회수를 위한 흡착제
JP6681975B2 (ja) * 2015-08-28 2020-04-15 アルベマール・コーポレーシヨン リチウム含有ブラインからリチウム有価物を回収するための工程
US10266915B2 (en) 2016-04-14 2019-04-23 Ut-Battelle, Llc Composition for recovery of lithium from brines, and process of using said composition
US11365128B2 (en) 2017-06-15 2022-06-21 Energysource Minerals Llc Process for selective adsorption and recovery of lithium from natural and synthetic brines
US10604414B2 (en) 2017-06-15 2020-03-31 Energysource Minerals Llc System and process for recovery of lithium from a geothermal brine
WO2019173716A1 (en) 2018-03-08 2019-09-12 Ut-Battelle, Llc Lithium extraction composite for recovery of lithium from brines, and process of using said composition
US11235282B2 (en) 2018-03-09 2022-02-01 Terralithium Llc Processes for producing lithium compounds using forward osmosis
US11174532B1 (en) 2018-03-09 2021-11-16 Terralithium Llc Processes for producing lithium compounds using reverse osmosis
RU2751393C1 (ru) * 2020-12-18 2021-07-13 Федеральное государственное бюджетное учреждение науки Институт химии твердого тела и механохимии Сибирского отделения Российской академии наук Способ получения монофазного пентаалюмината лития
FR3141456A1 (fr) 2022-10-26 2024-05-03 Saint-Gobain Centre De Recherches Et D'etudes Europeen Produit comprenant de la bayérite lithiée et procédé de fabrication d’un tel produit
WO2023170361A1 (fr) 2022-03-07 2023-09-14 Saint-Gobain Centre De Recherche Et D'etudes Europeen Produit comprenant de la bayerite lithiee et procede de fabrication d'un tel produit
US11904297B1 (en) 2023-01-11 2024-02-20 Iliad Ip Company, Llc Process for manufacturing lithium selective adsorption/separation media

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4116857A (en) * 1977-07-05 1978-09-26 The Dow Chemical Company Recovery of Mg++ from brines
US4116856A (en) * 1977-07-05 1978-09-26 The Dow Chemical Company Recovery of lithium from brines
US4116858A (en) * 1977-07-05 1978-09-26 The Dow Chemical Company Recovery of lithium from brines
US4221767A (en) * 1978-09-05 1980-09-09 The Dow Chemical Company Recovery of lithium from brines
US4284727A (en) * 1979-09-28 1981-08-18 Union Carbide Corporation Process for treating anion exchange resins
US4540509A (en) * 1980-12-18 1985-09-10 The Dow Chemical Company Crystalline 3-layer lithium aluminates
US4348295A (en) * 1980-12-18 1982-09-07 The Dow Chemical Company Crystalline lithium aluminates
US4376100A (en) * 1981-11-23 1983-03-08 The Dow Chemical Company Lithium halide brine purification
EP0103034A1 (en) * 1982-09-09 1984-03-21 The Dow Chemical Company Crystalline lithium aluminates and a process for the preparation thereof

Also Published As

Publication number Publication date
DE3436701A1 (de) 1986-04-10
AU576518B2 (en) 1988-09-01
DE3436701C2 (xx) 1989-01-19
JPH0421543B2 (xx) 1992-04-10
JPS6174645A (ja) 1986-04-16
CA1223742A (en) 1987-07-07
AU4615185A (en) 1987-02-19
AU3296684A (en) 1986-03-20
AU589133B2 (en) 1989-10-05
EP0211983B1 (en) 1990-07-04
EP0211983A1 (en) 1987-03-04
US4348295A (en) 1982-09-07

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