IL45077A - Process for treating water and an adsorber resin used therein - Google Patents
Process for treating water and an adsorber resin used thereinInfo
- Publication number
- IL45077A IL45077A IL45077A IL4507774A IL45077A IL 45077 A IL45077 A IL 45077A IL 45077 A IL45077 A IL 45077A IL 4507774 A IL4507774 A IL 4507774A IL 45077 A IL45077 A IL 45077A
- Authority
- IL
- Israel
- Prior art keywords
- adsorber resin
- resin
- adsorber
- groups
- matrix
- Prior art date
Links
- 239000011347 resin Substances 0.000 title claims abstract 23
- 229920005989 resin Polymers 0.000 title claims abstract 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract 7
- 125000003118 aryl group Chemical group 0.000 claims abstract 9
- 239000011159 matrix material Substances 0.000 claims abstract 8
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims abstract 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract 6
- 150000001412 amines Chemical class 0.000 claims abstract 4
- 229920000642 polymer Polymers 0.000 claims abstract 4
- 229910021529 ammonia Inorganic materials 0.000 claims abstract 3
- 229920000620 organic polymer Polymers 0.000 claims abstract 3
- 125000001309 chloro group Chemical group Cl* 0.000 claims abstract 2
- 239000000126 substance Substances 0.000 claims abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 6
- -1 chlormethyl groups Chemical group 0.000 claims 6
- 150000001875 compounds Chemical class 0.000 claims 6
- 229920001577 copolymer Polymers 0.000 claims 6
- 229920002554 vinyl polymer Polymers 0.000 claims 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 2
- 125000004202 aminomethyl group Chemical group [H]N([H])C([H])([H])* 0.000 claims 2
- 229910052801 chlorine Inorganic materials 0.000 claims 2
- 239000000460 chlorine Substances 0.000 claims 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 2
- 125000000467 secondary amino group Chemical class [H]N([*:1])[*:2] 0.000 claims 2
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 claims 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 claims 1
- 229920000768 polyamine Polymers 0.000 claims 1
- 239000004793 Polystyrene Substances 0.000 abstract 1
- 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 abstract 1
- 229940116441 divinylbenzene Drugs 0.000 abstract 1
- 229920002223 polystyrene Polymers 0.000 abstract 1
- 239000010865 sewage Substances 0.000 abstract 1
- 239000002352 surface water Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/28—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
- C08J9/286—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum the liquid phase being a solvent for the monomers but not for the resulting macromolecular composition, i.e. macroporous or macroreticular polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/285—Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
- C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/20—Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Water Supply & Treatment (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Hydrology & Water Resources (AREA)
- Analytical Chemistry (AREA)
- Materials Engineering (AREA)
- Water Treatment By Sorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
- Treatment Of Water By Ion Exchange (AREA)
Abstract
1429756 Purifying water BAYER AG 18 June 1974 [23 June 1973] 26915/74 Heading C1C Oleophilic odour- and taste-producing substances are removed from water by treating it with an insoluble macroporous adsorber resin, comprising a matrix based on cross-linked organic polymer containing aromatic nuclei, the polymer being substituted by chloromethyl groups. Some of the Cl atoms may be replaced by reaction with ammonia or amines. In examples surface water and water obtained from the biological treatment of sewage is treated with a polystyrene cross-linked with divinyl-benzene which is chloromethylated and subsequently reacted with aqueous NH 3 .
[GB1429756A]
Claims (23)
1. A process for removing oleophilic odour- and taste-producing substances from water, in which the water is treated with an insoluble macroporous adsorber resin comprising a matrix based on a crosslinked organic polymer containing aromatic nuclei, the polymer being substituted by c loromethyl groups a
2. A process as claimed in claim 1, in which the adsorber resin is partially aminated by reacting some of the chlorine atoms in the chlormethyl groups with ammonia or an amine.
3. A process as claimed in claim 1 or 2, wherein the matrix of the adsorber resin is a copolymer of an aromatic monovinyl compound and at least one aromatic polyvinyl compound.
4. . A process as claimed in any of claims 1 to 3, wherein the matrix of the adsorber resin is a copolymer of styrene and divinylbenzene .
5. A process as claimed in any of claims 1 to 3> wherein the matrix of the adsorber resin is a copolymer of styrene and ethylene glycol dimethacrylate .
6. A process as claimed in any of claims 1 to 3, wherein the matrix of the adsorber resin is a copolymer of styrene and 1 , 3.5-diacryloylhexahydro- -triazine .
7. A process as claimed in any of claims 1 to 3, wherein the matrix of the adsorber resin is a copolymer of an alkylstyrene with divinylbenzene.
8. A process as claimed in any of claims 1 to 7, wherein the adsorber resin contains from 1 to 50$ of at least one polyvinyl compound as monomeric units.
9. . A process as claimed in any of claims 1 to 8 , wherein the adsorber resin contains from 3 to J0 of monomeric units of at least one polyvinyl compound.
10. . A process as claimed in any of claims 1 to 9 , wherein the adsorber resin has a porosity of from 20 to 80fi by volume.
11. 1 1 . A process as claimed in any of claims 1 to 10 , wherein the adsorber resin has a porosity of from 30 to 60 by volume.
12. . A process as claimed in any of claims 1 to 11 , wherein the adsorber resin has an active surface of from 10 to 1000 m2/g.
13. . A process as claimed in any of claims 1 to 12 , wherein the adsorber resin has an active surface of from
14. A process as claimed in any of claims 1 to 13 , wherein the adsorber resin contains from 0. 05 to 1 . 2 chlormethyl groups per aromatic nucleus.
15. .· A process as claimed in any of claims 1 to 1 , wherein the adsorber resin has a chlorine content of from 5 to 2 $ by weight.
16. . A process as claimed in any of claims 2 to 15 , wherein the amine used for aminating the adsorber resins containing chlormethyl groups is a primary or secondary amine or a polyamine containing primary or secondary amino groups, alone or in admixture.
17. . A process as claimed in claim 1 , substantially as herein described with reference t) any of the specific Examples. e A 15 090 - 12 -
18.. Water, when treated by a process as claimed in any of claims 1 to 17.
19. An insoluble adsorber resin comprising a matrix based on a crosslinked organic polymer containing aromatic nuclei, in which the polymer is substituted by 0.05 to 1.2 chlormethyl groups per aromatic nucleus and the chlorine in the chlormethyl groups is partially reacted with ammonia or an amine to form aminomethyl groups, the ratio of the resulting aminomethyl groups to the chlormethyl groups being in the range of from 1 : 99 to 90 : 10.
20. A resin as claimed in claim 19» in which the polymer is a copolymer of an aromatic monovinyl compound and at least one aromatic polyvinyl compound.
21. A resin as claimed in claim 19 or 20, having a porosity of from 20 to 80 by volume.
22. A resin as claimed in any of claims 19 to 21, having an active surface of from 10 to 1000 m^/g.
23. A resin as claimed in claim 19, substantially as herein described with reference to any of the specific Examples .
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2332103A DE2332103C3 (en) | 1973-06-23 | 1973-06-23 | Process for drinking and wastewater treatment |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IL45077A0 IL45077A0 (en) | 1974-09-10 |
| IL45077A true IL45077A (en) | 1976-10-31 |
Family
ID=5884938
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL45077A IL45077A (en) | 1973-06-23 | 1974-06-20 | Process for treating water and an adsorber resin used therein |
Country Status (12)
| Country | Link |
|---|---|
| JP (2) | JPS5734016B2 (en) |
| AU (1) | AU7015574A (en) |
| BE (1) | BE816690A (en) |
| BR (1) | BR7405039D0 (en) |
| DD (1) | DD126710A5 (en) |
| DE (1) | DE2332103C3 (en) |
| FR (1) | FR2234233B1 (en) |
| GB (2) | GB1429757A (en) |
| IL (1) | IL45077A (en) |
| IT (1) | IT1016125B (en) |
| NL (1) | NL7408298A (en) |
| ZA (1) | ZA744002B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52116642A (en) * | 1976-03-26 | 1977-09-30 | Yamasa Shoyu Co Ltd | Process for decoloring industrial waste water |
| CH634283A5 (en) * | 1978-02-24 | 1983-01-31 | Ciba Geigy Ag | METHOD FOR REMOVING HEAVY METAL IONS FROM AQUEOUS SOLUTIONS. |
| GB2166140B (en) * | 1984-10-27 | 1989-06-07 | Ion Exchange | Novel adsorbents for use in the purification of water and other chemicals and a process for preparing same |
| JPS61109716A (en) * | 1984-11-01 | 1986-05-28 | Taiyo Koryo Kk | Agent for inhibiting growth of dental caries bacteria |
| FR2655277A1 (en) * | 1989-12-06 | 1991-06-07 | Atochem | PROCESS FOR TREATING WATER WITH SIMULTANEOUS FLOCCULATION AND ADSORPTION USING PARTIALLY HYDROPHOBIC POLYELECTROLYTES |
| FR2655567A1 (en) * | 1989-12-06 | 1991-06-14 | Atochem | Water treatment process with simultaneous flocculation and adsorption with the aid of partially hydrophobic polyelectrolytes |
| KR100378894B1 (en) * | 1995-01-09 | 2003-06-18 | 에스 시이 죤 슨앤드 산 인코포레이티드 | Liquid bait for target insects and method of attracting and controlling target insects using same |
| CN111318266B (en) * | 2020-02-14 | 2022-01-28 | 南京师范大学 | Two-dimensional covalent organic framework modified ion exchange resin and preparation method and application thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3275548A (en) * | 1963-08-14 | 1966-09-27 | Dow Chemical Co | Removal of dissolved substances from aqueous dispersions |
| JPS5125232B1 (en) * | 1965-02-24 | 1976-07-29 | ||
| US3420709A (en) * | 1965-04-29 | 1969-01-07 | Diamond Shamrock Corp | Liquid purification by adsorption |
-
1973
- 1973-06-23 DE DE2332103A patent/DE2332103C3/en not_active Expired
-
1974
- 1974-06-18 AU AU70155/74A patent/AU7015574A/en not_active Expired
- 1974-06-18 GB GB595975A patent/GB1429757A/en not_active Expired
- 1974-06-18 GB GB2691574A patent/GB1429756A/en not_active Expired
- 1974-06-20 IL IL45077A patent/IL45077A/en unknown
- 1974-06-20 NL NL7408298A patent/NL7408298A/xx not_active Application Discontinuation
- 1974-06-20 BR BR5039/74A patent/BR7405039D0/en unknown
- 1974-06-21 BE BE145732A patent/BE816690A/en unknown
- 1974-06-21 FR FR7421762A patent/FR2234233B1/fr not_active Expired
- 1974-06-21 JP JP7033374A patent/JPS5734016B2/ja not_active Expired
- 1974-06-21 ZA ZA00744002A patent/ZA744002B/en unknown
- 1974-06-21 IT IT51647/74A patent/IT1016125B/en active
- 1974-06-24 DD DD179424A patent/DD126710A5/xx unknown
-
1981
- 1981-11-20 JP JP56185575A patent/JPS57115404A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| BE816690A (en) | 1974-12-23 |
| JPS57115404A (en) | 1982-07-17 |
| FR2234233B1 (en) | 1983-04-08 |
| JPS5037260A (en) | 1975-04-07 |
| BR7405039D0 (en) | 1975-01-28 |
| ZA744002B (en) | 1975-06-25 |
| DD126710A5 (en) | 1977-08-10 |
| GB1429756A (en) | 1976-03-24 |
| DE2332103B2 (en) | 1980-09-04 |
| DE2332103C3 (en) | 1981-11-12 |
| FR2234233A1 (en) | 1975-01-17 |
| DE2332103A1 (en) | 1975-01-16 |
| IT1016125B (en) | 1977-05-30 |
| JPS5734016B2 (en) | 1982-07-20 |
| AU7015574A (en) | 1975-12-18 |
| IL45077A0 (en) | 1974-09-10 |
| GB1429757A (en) | 1976-03-24 |
| NL7408298A (en) | 1974-12-30 |
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