IL44734A - Oxidation of carbon monoxide and hydrocarbons - Google Patents
Oxidation of carbon monoxide and hydrocarbonsInfo
- Publication number
- IL44734A IL44734A IL44734A IL4473474A IL44734A IL 44734 A IL44734 A IL 44734A IL 44734 A IL44734 A IL 44734A IL 4473474 A IL4473474 A IL 4473474A IL 44734 A IL44734 A IL 44734A
- Authority
- IL
- Israel
- Prior art keywords
- oxidation
- effected
- carrier
- contact
- supported catalyst
- Prior art date
Links
- 230000003647 oxidation Effects 0.000 title claims 22
- 238000007254 oxidation reaction Methods 0.000 title claims 22
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims 2
- 229910002091 carbon monoxide Inorganic materials 0.000 title claims 2
- 229930195733 hydrocarbon Natural products 0.000 title claims 2
- 150000002430 hydrocarbons Chemical class 0.000 title claims 2
- 238000000034 method Methods 0.000 claims 22
- 239000003054 catalyst Substances 0.000 claims 19
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 12
- 239000000463 material Substances 0.000 claims 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 6
- 229910052802 copper Inorganic materials 0.000 claims 6
- 239000010949 copper Substances 0.000 claims 6
- 229910002804 graphite Inorganic materials 0.000 claims 6
- 239000010439 graphite Substances 0.000 claims 6
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims 5
- 238000001354 calcination Methods 0.000 claims 5
- 239000011572 manganese Substances 0.000 claims 5
- 150000000703 Cerium Chemical class 0.000 claims 4
- 229910052748 manganese Inorganic materials 0.000 claims 4
- 229910052759 nickel Inorganic materials 0.000 claims 4
- 239000002253 acid Substances 0.000 claims 3
- 150000004645 aluminates Chemical class 0.000 claims 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 2
- 229910052684 Cerium Inorganic materials 0.000 claims 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims 2
- 239000007864 aqueous solution Substances 0.000 claims 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 2
- 239000007789 gas Substances 0.000 claims 2
- 150000003839 salts Chemical class 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- 150000007513 acids Chemical class 0.000 claims 1
- 239000004480 active ingredient Substances 0.000 claims 1
- 229940022504 aluminum oxide paste Drugs 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 1
- 239000001569 carbon dioxide Substances 0.000 claims 1
- 229910000420 cerium oxide Inorganic materials 0.000 claims 1
- 238000002485 combustion reaction Methods 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 230000003301 hydrolyzing effect Effects 0.000 claims 1
- 239000004615 ingredient Substances 0.000 claims 1
- AMWRITDGCCNYAT-UHFFFAOYSA-L manganese oxide Inorganic materials [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 229910044991 metal oxide Inorganic materials 0.000 claims 1
- 150000004706 metal oxides Chemical class 0.000 claims 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 229910000480 nickel oxide Inorganic materials 0.000 claims 1
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical class [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 claims 1
- 150000002823 nitrates Chemical class 0.000 claims 1
- 230000001590 oxidative effect Effects 0.000 claims 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical class [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229940112824 paste Drugs 0.000 claims 1
- 230000001131 transforming effect Effects 0.000 claims 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/944—Simultaneously removing carbon monoxide, hydrocarbons or carbon making use of oxidation catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/889—Manganese, technetium or rhenium
- B01J23/8892—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Claims (18)
1. WHAT WE CLAIM IS:
2. A process for oxidizing carbon monoxide and hydrocarbons, particularly those which are contained in exhaust gas from internal combustion engines in contact with one or more oxygen-containing gases to carbon dioxide and water, which comprises effecting the oxidation at temperatures within the range 150 and 800°C in contact with a carrier- supported catalyst comprising a mixture of aluminates of copper, manganese and nickel as its active ingredients, andpure aluminum oxide as its carrier, the total proportions of aluminates being within the range 10 and 5 weighty. A process as claimed in claim , wherein the oxidation is effected at temperatures within the range 200 and 700°C.
3. A process as claimed in claim 1 , wherein the oxidation is effected at temperatures within the range 300 and 600°C.
4. A process as claimed in any one of claims 1 to 3, wherein the oxidation is effected in contact with a carrier-supported catalyst containing the aluminates in a total proportion within the range 20 and 35 weight^.
5. A process as claimed in any one of claims 1 to 4, wherein the oxidation is effected in contact with a carrier-supported catalyst containing copper, manganese and nickel in a ratio by weight within the range (2-4) : (1-2) : (0.1-1).
6. A process as claimed in any one of claims 1 to 5, wherein the oxidation is effected in contact with a carrier-supported catalyst having between 0.5 and 10 weighty of cerium in oxide form as an additional ingredient deposited thereon.
7. A process as claimed in claim 6, wherein the oxidation is effected in contact with a carrier-supported catalyst having between 1 and 7 weight^ of cerium in oxide form deposit- ed thereon.
8. ) A process as claimed in any one of claims 1 to 7, wherein the oxidation is effected in contact with a carrier- supported catalyst having a compressive strength within the range 3 and 14· kg/mm.
9. ) A process as claimed in claim 8, wherein the oxidation is effected in contact with a carrier-supported catalyst having a compressive strength within the range 4 and 10 kg/mm.
10. ) A process as claimed in any one of claims 1 to 9, wherein the oxidation is effected in contact with a carrier-supported catalyst made by transforming pure aluminum oxide into moulded material; calcining the moulded material at temperatures within the range 1000 and 1200°C; impregnating the calcined moulded material with an aqueous solution of one or more salts of copper, nickel and manganese with a decomposable acid; decomposing the metal salts applied to the moulded material at temperatures within the. range 300 and 600°C; and calcining the resulting metal oxide-containing moulded material at temperatures within the range 800 and 1200°C.
11. ) A process as claimed in claim 10, wherein the oxidation is '· effected in contact with. a carrier-supported catalyst made by impregnating the calcined moulded material with an aqueous solution of a cerium salt of a readily decomposable acid; drying the cerium salt applied to the moulded material at temperatures within the range 130 and 150°C; decomposing · the dry cerium salt on the moulded material by gradual heating at temperatures within the range 200 and 300°C and within the range 450 and 550°C, respectively; and calcining the resulting cerium oxide-containing moulded material at temperatures within the range 700 and 900 C.
12. ) A process as claimed in claim 10, wherein the oxidation is effected in contact with a carrier-supported catalyst made from pure aluminum oxide, the aluminum oxide being produced by hydrolyzing aluminum chloride with the use of an oxyhydrogen flame.
13. ) A process as claimed in claim 10 or 12, wherein the oxidation is effected in contact with a carrier-supported catalyst made from aluminum oxide, the aluminum oxide being stirred into water and the resulting paste being dried at 100°C.
14. ) A process as claimed in claim 13, wherein the oxidation is effected in contact with a carrier-supported catalyst made from the dried aluminum oxide paste.
15. ) A process as claimed in any one of claims 10 and 12 to 14, wherein the oxidation is effected in contact with a carrier-supported catalyst made from aluminum oxide moulded in admixture with graphite.
16. ) A process as claimed in claim 15, wherein the oxidation is effected in contact with a carrier-supported catalyst • made from aluminum oxide moulded in admixture with between 3 and 10 weight^, preferably 5 weight^, of graphite'.
17. ) A process as claimed in any one of claims 10 and 12 to 16, wherein the oxidation is effected in contact with a carrier-supported catalyst made from aluminum oxide moulded in admixture with graphite and freed therefrom prior to calcining the moulded .aluminum oxide, the graphite being burned off.
18. ) A process as claimed in claim 17,' wherein the oxidation is effected in contact with a carrier-supported catalyst made from aluminum oxide moulded in admixture with graphite and freed therefrom prior to calcining the moulded aluminum oxide, the graphite being burned off at temperatures within the range 500 and 750°C, preferably 650°C. A process as claimed in. any one of claims 10 to 18, where in the oxidation is effected in contact with a carrier-supported catalyst, wherein nitrates are the copper, manganese, nickel and cerium salts of decomposable acids'. A process as claimed in claim 19, wherein the oxidation is effected in contact with a carrier-supported catalyst, wherein the copper, manganese and nickel nitrates have been decomposed at temperatures within the range 350 and 50°C . A process as claimed in any one of claims 10 and 12 to 20, wherein the oxidation is effected in contact with a carrier-supported catalyst, wherein the moulded material containing copper, manganese and nickel oxides has been calcined at temperatures within the range 950 and 1050°C. A process as claimed in any one of claims 1 to 21 conducted substantially as described in any one of Examples 3 to 5, 7, 8 and 11 herein. Atto rney s f o r A p p l i c a n t
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19732323251 DE2323251B2 (en) | 1973-05-09 | 1973-05-09 | PROCESS FOR OXIDIZATION OF CARBON MONOXIDE AND HYDROCARBONS |
| DE2412290A DE2412290C3 (en) | 1974-03-14 | 1974-03-14 | Process for the oxidation of carbon monoxide and hydrocarbons |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IL44734A0 IL44734A0 (en) | 1974-06-30 |
| IL44734A true IL44734A (en) | 1976-08-31 |
Family
ID=25765096
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL44734A IL44734A (en) | 1973-05-09 | 1974-04-29 | Oxidation of carbon monoxide and hydrocarbons |
Country Status (13)
| Country | Link |
|---|---|
| AT (1) | AT359983B (en) |
| CA (1) | CA1013547A (en) |
| CH (1) | CH603994A5 (en) |
| CS (1) | CS169764B2 (en) |
| DD (1) | DD110916A5 (en) |
| FR (1) | FR2228720B1 (en) |
| GB (1) | GB1462469A (en) |
| IL (1) | IL44734A (en) |
| IT (1) | IT1011403B (en) |
| NL (1) | NL179789C (en) |
| PL (1) | PL96886B1 (en) |
| RO (1) | RO71029A (en) |
| SE (1) | SE403642B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2513942C3 (en) * | 1975-03-29 | 1979-09-13 | Hoechst Ag, 6000 Frankfurt | Process for the production of a supported catalyst |
| WO1994012432A1 (en) * | 1992-12-02 | 1994-06-09 | Commonwealth Scientific And Industrial Research Organisation | Gas purification |
| CN114653375B (en) * | 2020-12-23 | 2024-05-14 | 中国科学院江西稀土研究院 | Catalyst for removing CO in sintering flue gas and preparation method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2065012A5 (en) * | 1969-10-06 | 1971-07-23 | Monsanto Co | |
| DD100635A5 (en) * | 1971-12-30 | 1973-10-05 | ||
| CA990478A (en) * | 1972-02-14 | 1976-06-08 | Abe Warshaw | Process and catalyst for treating combustion exhaust gas |
| DE2242915C3 (en) * | 1972-08-31 | 1980-08-14 | Hoechst Ag, 6000 Frankfurt | Process for the oxidation of carbon monoxide and / or hydrocarbons in exhaust gases from internal combustion engines |
-
1974
- 1974-04-11 CS CS2625A patent/CS169764B2/cs unknown
- 1974-04-29 GB GB1856874A patent/GB1462469A/en not_active Expired
- 1974-04-29 IL IL44734A patent/IL44734A/en unknown
- 1974-05-01 NL NLAANVRAGE7405849,A patent/NL179789C/en not_active IP Right Cessation
- 1974-05-06 SE SE7406031A patent/SE403642B/en not_active IP Right Cessation
- 1974-05-07 RO RO7478699A patent/RO71029A/en unknown
- 1974-05-07 AT AT376774A patent/AT359983B/en not_active IP Right Cessation
- 1974-05-07 DD DD178343A patent/DD110916A5/xx unknown
- 1974-05-07 IT IT50815/74A patent/IT1011403B/en active
- 1974-05-07 PL PL1974170878A patent/PL96886B1/en unknown
- 1974-05-08 CA CA199,243A patent/CA1013547A/en not_active Expired
- 1974-05-08 CH CH629374A patent/CH603994A5/xx not_active IP Right Cessation
- 1974-05-09 FR FR7416081A patent/FR2228720B1/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL7405849A (en) | 1974-11-12 |
| NL179789B (en) | 1986-06-16 |
| DD110916A5 (en) | 1975-01-12 |
| AT359983B (en) | 1980-12-10 |
| IL44734A0 (en) | 1974-06-30 |
| GB1462469A (en) | 1977-01-26 |
| CH603994A5 (en) | 1978-08-31 |
| NL179789C (en) | 1986-11-17 |
| ATA376774A (en) | 1980-05-15 |
| SE403642B (en) | 1978-08-28 |
| RO71029A (en) | 1982-02-26 |
| CS169764B2 (en) | 1976-07-29 |
| PL96886B1 (en) | 1978-01-31 |
| FR2228720A1 (en) | 1974-12-06 |
| FR2228720B1 (en) | 1978-07-13 |
| IT1011403B (en) | 1977-01-20 |
| CA1013547A (en) | 1977-07-12 |
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