IL43615A - Rubber mixtures containing reinforcing additives - Google Patents
Rubber mixtures containing reinforcing additivesInfo
- Publication number
- IL43615A IL43615A IL43615A IL4361573A IL43615A IL 43615 A IL43615 A IL 43615A IL 43615 A IL43615 A IL 43615A IL 4361573 A IL4361573 A IL 4361573A IL 43615 A IL43615 A IL 43615A
- Authority
- IL
- Israel
- Prior art keywords
- rubber
- silica
- mixture
- silicate
- group
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract 21
- 229920001971 elastomer Polymers 0.000 title claims abstract 20
- 239000005060 rubber Substances 0.000 title claims abstract 20
- 239000012758 reinforcing additive Substances 0.000 title claims 2
- 150000001282 organosilanes Chemical class 0.000 claims abstract 9
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract 6
- 239000000945 filler Substances 0.000 claims abstract 6
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000000654 additive Substances 0.000 claims abstract 2
- 238000004132 cross linking Methods 0.000 claims abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 4
- 239000002245 particle Substances 0.000 claims 3
- 239000000470 constituent Substances 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 125000000000 cycloalkoxy group Chemical group 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 16
- 239000000377 silicon dioxide Substances 0.000 abstract 8
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 abstract 4
- 239000005995 Aluminium silicate Substances 0.000 abstract 2
- 244000043261 Hevea brasiliensis Species 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- 239000005864 Sulphur Substances 0.000 abstract 2
- 235000012211 aluminium silicate Nutrition 0.000 abstract 2
- 229920003052 natural elastomer Polymers 0.000 abstract 2
- 229920001194 natural rubber Polymers 0.000 abstract 2
- VTHOKNTVYKTUPI-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSSCCC[Si](OCC)(OCC)OCC VTHOKNTVYKTUPI-UHFFFAOYSA-N 0.000 abstract 2
- 229920000459 Nitrile rubber Polymers 0.000 abstract 1
- 239000005062 Polybutadiene Substances 0.000 abstract 1
- 125000004414 alkyl thio group Chemical group 0.000 abstract 1
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 abstract 1
- 229910000323 aluminium silicate Inorganic materials 0.000 abstract 1
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 abstract 1
- 229920005549 butyl rubber Polymers 0.000 abstract 1
- 229920003193 cis-1,4-polybutadiene polymer Polymers 0.000 abstract 1
- 229920003211 cis-1,4-polyisoprene Polymers 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 abstract 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 abstract 1
- ZQHHNIRCFUUKOC-UHFFFAOYSA-N methoxy-[3-(3-methoxysilylpropyltrisulfanyl)propyl]silane Chemical compound CO[SiH2]CCCSSSCCC[SiH2]OC ZQHHNIRCFUUKOC-UHFFFAOYSA-N 0.000 abstract 1
- 229920001084 poly(chloroprene) Polymers 0.000 abstract 1
- 229920002857 polybutadiene Polymers 0.000 abstract 1
- 229920001897 terpolymer Polymers 0.000 abstract 1
- NQRACKNXKKOCJY-UHFFFAOYSA-N trimethoxy-[3-(3-trimethoxysilylpropyldisulfanyl)propyl]silane Chemical compound CO[Si](OC)(OC)CCCSSCCC[Si](OC)(OC)OC NQRACKNXKKOCJY-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/548—Silicon-containing compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/28—Compounds of silicon
- C09C1/30—Silicic acid
- C09C1/3081—Treatment with organo-silicon compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Nanotechnology (AREA)
- Composite Materials (AREA)
- Polymers & Plastics (AREA)
- Physics & Mathematics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
1439247 Reinforced rubber compositions comprising a sulphur-containing organosilane DEUTSCHE GOLD-UND SILBER-SCHEIDEANSTALT 13 Nov 1973 [13 Nov 1972] 52637/73 Headings C3E C3P and C3Q A rubber mixture comprises a cross-linking system, at least one sulphur-containing organosilane of formula in which Z represents a group of formula in which each R<SP>1</SP> represents a C 1 to C 4 -alkyl group or a phenyl radical and each R<SP>2</SP> represents a C 1 to C 8 -alkoxy group, a C 5 to C 8 -cycloalkoxy group, or a C 1 to C 8 -linear or branched alkylmercapto group, the R<SP>1</SP> and R<SP>2</SP> groups in the same compound being the same or different; Alk represents a C 1 to C 18 -divalent, optionally unsaturated, linear, branched or cyclo-aliphatic hydrocarbon group and n is from 2 to 6 and one or more silica or silicate filler. A preformed mixture of the organosilane and silica or silicate may be added to the rubber and other components of the compounded rubber. Examples are given in which the rubber mixtures prepared comprise (a) bis - [3 - methoxysilyl - propyl] - trisulphide, silica and natural rubber; (b) bis-[3- triethoxysilylpropyl]- tetrasulphide with silica and cis - 1,4 - polyisoprene, or with silica and aluminium silicate, or kaolin, and butadiene-styrene rubber, or with silica and butadiene-acrylonitrile rubber, butyl-rubber, polychloroprene, ethylene-propylene terpolymer rubber or a mixture of butadiene-styrene rubber and cis-1,4-polybutadiene; (c) a preformed mixture of bis-[3-triethoxysilylpropyl]- tetrasulphide and silica added to a mixture of butadiene-styrene rubber and polybutadiene or to natural rubber; and (d) bis-[3-trimethoxysilylpropyl]-disulphide, silica and butadienestyrene rubber. The rubber mixtures also contain conventional additives.
[GB1439247A]
Claims (6)
1. , Rubber mixtures comprising at least one rubber, a crosslinking system, one or more silicate fillers, optionally in · combination 'with barbon black and, if desired, other conventional rubber auxiliaries and as reinforcing additive, one or more organosilanes of the general formula in which Z represents where R is an alkyl (C^-C^) or phenyl radical and R is an al oxy group with 1 to 8, preferably 1 to 4 carbon atoms, a cycloalkoxy group with 5 to 8 carbon atoms,.' Alk -' ' _ ' represents a divalent, optionally unsaturated, linear or •branched aliphatic, cycloaliphatic or aromatic hydrocarbon radical with 1 to 18 carbon atoms, more particularly with 1 to 6 end preferably with 2 or 3 carbon atoms, and .n is a number fro 2 to 6, more particularly from 2 to 4, preferably from 3 to 4#
2. Rubber mixtures according to Claim 1, wherein the organosilane or a mixture of organosilanes ia applied to" the surface of the silicate filler particles.
3. Rubber mixtures according to Claim 1 substantially as described herein with reference to the Examples.
4. Additives for rubber mixtures according to Claims 1 or 2, comprising a mixture of at least one silicate filler and at least one organosilane of the formula I in Claim 1.
5. A process for the production of rubber mixtures according to Claim 1, wherein at least one organosilane of the formula I in Claim 1 is first mixed uniformly with a silicate iller, or with a proportion thereof, and the resulting mixture is worked into and uniformly distributed in the rubber mixture or the other constituents of the rubber mixture,
6. A process according to Claim 5, wherein the organo-silane(s) is/are first applied to the surface of the filler particles and the coated filler particles are added to, and uniformly distributed in, the rubber mixture or the other constituents of the rubber mixture. For the Applicants
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19722255577 DE2255577C3 (en) | 1972-11-13 | Reinforcement additives in vulcanizable rubber compounds |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IL43615A0 IL43615A0 (en) | 1974-03-14 |
| IL43615A true IL43615A (en) | 1976-10-31 |
Family
ID=5861596
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL43615A IL43615A (en) | 1972-11-13 | 1973-11-12 | Rubber mixtures containing reinforcing additives |
Country Status (25)
| Country | Link |
|---|---|
| JP (1) | JPS5120208B2 (en) |
| AR (1) | AR200663A1 (en) |
| AT (1) | AT327536B (en) |
| BE (1) | BE807222A (en) |
| BG (1) | BG25805A3 (en) |
| BR (1) | BR7308892D0 (en) |
| CA (1) | CA991836A (en) |
| CH (1) | CH592131A5 (en) |
| CS (1) | CS198130B2 (en) |
| DD (1) | DD107935A5 (en) |
| ES (1) | ES420455A1 (en) |
| FR (1) | FR2206330B1 (en) |
| GB (1) | GB1439247A (en) |
| HU (1) | HU168915B (en) |
| IL (1) | IL43615A (en) |
| IN (1) | IN140550B (en) |
| IT (1) | IT997728B (en) |
| LU (1) | LU68780A1 (en) |
| NL (1) | NL173534C (en) |
| PH (1) | PH12064A (en) |
| PL (1) | PL87778B1 (en) |
| RO (1) | RO67260A (en) |
| SE (1) | SE396760B (en) |
| SU (1) | SU522804A3 (en) |
| ZA (1) | ZA738688B (en) |
Families Citing this family (71)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2010287B (en) * | 1977-11-28 | 1982-08-11 | Ici Ltd | Stabilised siliceous filler compositions and their use in polymers especially vulcanisable elastomers |
| DE2819638C3 (en) | 1978-05-05 | 1986-11-13 | Degussa Ag, 6000 Frankfurt | Vulcanizable halogen rubber compounds |
| JPS5667348A (en) * | 1979-11-08 | 1981-06-06 | Mitsuboshi Belting Ltd | Rubber composition |
| JPS5833423B2 (en) * | 1980-10-28 | 1983-07-19 | 三ツ星ベルト株式会社 | toothed belt |
| FR2512037B1 (en) * | 1981-09-03 | 1986-02-14 | Rhone Poulenc Chim Base | ELASTOMERIC COMPOSITION REINFORCED BY SILICA WITH A LARGE SPECIFIC SURFACE |
| US4522970A (en) * | 1984-06-25 | 1985-06-11 | The Goodyear Tire & Rubber Company | Tire with tread rubber containing medium vinyl polybutadiene with clay and carbon black |
| DE4437645C2 (en) * | 1994-10-21 | 2000-05-31 | Uniroyal Englebert Gmbh | Tire comprising a tire tread made from a vulcanized rubber compound |
| FR2743564A1 (en) | 1996-01-11 | 1997-07-18 | Michelin & Cie | RUBBER COMPOSITIONS FOR SILICA-BASED TIRE CASINGS CONTAINING A REINFORCING ADDITIVE BASED ON A FUNCTIONALIZED POLYORGANOSILOXANE AND AN ORGANOSILANE COMPOUND. |
| DE19816972A1 (en) * | 1998-04-17 | 1999-11-11 | Pku Pulverkautschuk Union Gmbh | Rubber powders containing powdered, modified fillers, process for their production and use |
| ES2186389T3 (en) | 1998-07-22 | 2003-05-01 | Michelin Soc Tech | COUPLING SYSTEM (WHITE LOAD / DIENIC ELASTOMERO) BASED ON POLYISULFURED ALCOXISILANO, CINC DITIOFOSFATO AND GUANIDINICO DERIVATIVE. |
| US7687107B2 (en) | 1999-08-19 | 2010-03-30 | Ppg Industries Ohio, Inc. | Process for producing chemically modified amorphous precipitated silica |
| US6649684B1 (en) | 1999-08-19 | 2003-11-18 | Ppg Industries Ohio, Inc. | Chemically treated fillers and polymeric compositions containing same |
| AU6916000A (en) * | 1999-08-19 | 2001-04-24 | Dow Corning Corporation | Process for producing chemically modified fillers |
| CA2395904A1 (en) | 1999-12-30 | 2001-07-12 | Michelin Recherche Et Technique S.A. | Rubber composition for tyres, comprising a coupling agent (white filler/elastomer) with an ester function |
| FR2803301B1 (en) * | 1999-12-30 | 2002-03-15 | Rhodia Chimie Sa | NOVEL COMPOUNDS BASED ON FUNCTIONALIZED SILANES, THEIR PREPARATION METHODS AND THEIR USE IN THE FIELD OF RUBBER MATERIALS |
| FR2803300B1 (en) * | 1999-12-30 | 2002-03-15 | Rhodia Chimie Sa | NOVEL COMPOUNDS BASED ON FUNCTIONALIZED SILANES, THEIR PREPARATION METHODS AND THEIR USE IN THE FIELD OF RUBBER MATERIALS |
| FR2804121A1 (en) | 2000-01-24 | 2001-07-27 | Michelin Soc Tech | Rubber composition for manufacture of tires comprises filled elastomer with polysulfide coupling agent and dihydro pyridine derivative |
| FR2804120A1 (en) | 2000-01-24 | 2001-07-27 | Michelin Soc Tech | Use of mixture of aldimine and guanidine derivative as coupling agent activator in silica or alumina filled diene rubber compositions for fabrication of tire parts, especially treads |
| DE10012407A1 (en) | 2000-03-15 | 2001-09-20 | Bayer Ag | Rubber mixtures, useful for the production of tire tread contain a polyether, a filler and optionally other processing aids and/or crosslinking agents. |
| KR20030010732A (en) | 2000-06-16 | 2003-02-05 | 소시에떼 드 테크놀로지 미쉐린 | Rubber composition for tyre comprising a multifunctional polyorganosiloxane as coupling agent |
| WO2003002649A1 (en) | 2001-06-28 | 2003-01-09 | Societe De Technologie Michelin | Tyre tread reinforced with silica having a very low specific surface area |
| JP4536374B2 (en) * | 2001-06-28 | 2010-09-01 | ソシエテ ド テクノロジー ミシュラン | Tire tread reinforced with low specific surface area silica |
| BR0211293B1 (en) | 2001-07-25 | 2011-11-01 | process for continuously producing an elastomeric composition. | |
| BR0116626A (en) * | 2001-10-30 | 2003-12-23 | Pirelli | Vehicle wheel tire, elastomeric composition, tread for vehicle wheel tires, and cross-linked elastomeric manufactured article |
| US7964128B2 (en) | 2001-12-19 | 2011-06-21 | Pirelli Pneumatici S.P.A. | Process and apparatus for continuously producing an elastomeric composition |
| FR2833958B1 (en) * | 2001-12-20 | 2005-08-19 | Rhodia Chimie Sa | ORGANOSILIC COMPOUNDS USABLE IN PARTICULAR AS COUPLING AGENT, ELASTOMER(S) COMPOSITIONS CONTAINING THEM AND ELASTOMER(S) ARTICLES PREPARED FROM SUCH COMPOSITIONS |
| AU2003206843A1 (en) | 2002-02-07 | 2003-09-02 | Societe De Technologie Michelin | Running tread for tyre |
| DE10223658A1 (en) | 2002-05-28 | 2003-12-18 | Degussa | Organosilicon compounds, process for their preparation and their use |
| ATE464172T1 (en) | 2002-07-11 | 2010-04-15 | Pirelli | METHOD AND DEVICE FOR CONTINUOUSLY PRODUCING AN ELASTOMER MIXTURE |
| DE10354616A1 (en) | 2003-11-21 | 2005-06-23 | Degussa Ag | rubber compounds |
| RU2308469C1 (en) * | 2006-01-24 | 2007-10-20 | Семен Моисеевич Кавун | Curable rubber compound for low-hysteresis tire treads with improved catenation properties and wear resistance |
| DE102006008670A1 (en) | 2006-02-24 | 2007-08-30 | Degussa Gmbh | rubber compounds |
| JP5164375B2 (en) * | 2006-12-20 | 2013-03-21 | 株式会社ブリヂストン | Rubber composition containing organosilicon compound and pneumatic tire using the same |
| JP4985935B2 (en) * | 2006-12-20 | 2012-07-25 | 信越化学工業株式会社 | Compounding agent for rubber |
| US7968635B2 (en) | 2006-12-28 | 2011-06-28 | Continental Ag | Tire compositions and components containing free-flowing filler compositions |
| US8592506B2 (en) | 2006-12-28 | 2013-11-26 | Continental Ag | Tire compositions and components containing blocked mercaptosilane coupling agent |
| US7737202B2 (en) | 2006-12-28 | 2010-06-15 | Momentive Performance Materials Inc. | Free-flowing filler composition and rubber composition containing same |
| US7968636B2 (en) | 2006-12-28 | 2011-06-28 | Continental Ag | Tire compositions and components containing silated cyclic core polysulfides |
| US7960460B2 (en) | 2006-12-28 | 2011-06-14 | Momentive Performance Materials, Inc. | Free-flowing filler composition and rubber composition containing same |
| US7968633B2 (en) | 2006-12-28 | 2011-06-28 | Continental Ag | Tire compositions and components containing free-flowing filler compositions |
| US7781606B2 (en) | 2006-12-28 | 2010-08-24 | Momentive Performance Materials Inc. | Blocked mercaptosilane coupling agents, process for making and uses in rubber |
| US7696269B2 (en) | 2006-12-28 | 2010-04-13 | Momentive Performance Materials Inc. | Silated core polysulfides, their preparation and use in filled elastomer compositions |
| US7687558B2 (en) | 2006-12-28 | 2010-03-30 | Momentive Performance Materials Inc. | Silated cyclic core polysulfides, their preparation and use in filled elastomer compositions |
| US7968634B2 (en) | 2006-12-28 | 2011-06-28 | Continental Ag | Tire compositions and components containing silated core polysulfides |
| JP5503137B2 (en) * | 2008-12-04 | 2014-05-28 | 株式会社ブリヂストン | Organosilicon compound, and rubber composition and tire using the same |
| FR2940290B1 (en) | 2008-12-22 | 2010-12-31 | Michelin Soc Tech | BLOCKED MERCAPTOSILANE COUPLING AGENT |
| FR2945815B1 (en) | 2009-05-20 | 2011-07-01 | Michelin Soc Tech | RUBBER COMPOSITION COMPRISING AN ORGANOSILANE COUPLING AGENT |
| FR2947552B1 (en) | 2009-05-20 | 2011-08-26 | Michelin Soc Tech | ORGANOSILANE COUPLING AGENT |
| JP5373721B2 (en) * | 2010-08-30 | 2013-12-18 | 株式会社ブリヂストン | Process for producing modified natural rubber |
| JP5831354B2 (en) | 2011-05-16 | 2015-12-09 | 信越化学工業株式会社 | Rubber compounding agent, rubber composition and tire |
| JP2012240924A (en) | 2011-05-16 | 2012-12-10 | Shin-Etsu Chemical Co Ltd | Organosilicon compound and method for producing the same, compounding agent for rubber, rubber composition, and tire |
| BR112014009843A2 (en) | 2011-10-24 | 2017-04-18 | Bridgestone Americas Tire Operations Llc | silica-filled rubber composition and the method for making the same |
| JP2013119529A (en) | 2011-12-07 | 2013-06-17 | Shin-Etsu Chemical Co Ltd | Organosilicon compound and method for producing the same, compounding agent for rubber, and rubber composition |
| JP6248597B2 (en) | 2013-12-13 | 2017-12-20 | 信越化学工業株式会社 | Sulfur-containing organosilicon compound and production method thereof, compounding agent for rubber, and rubber composition |
| CN107922443B (en) * | 2015-08-27 | 2021-01-26 | 株式会社可乐丽 | Sulfur-containing organosilicon compound and resin composition |
| DE102015224450A1 (en) * | 2015-12-07 | 2017-06-08 | Evonik Degussa Gmbh | rubber compounds |
| JP6638603B2 (en) | 2016-09-07 | 2020-01-29 | 信越化学工業株式会社 | Rubber compounding agent and rubber composition |
| FR3057264B1 (en) | 2016-10-12 | 2020-05-29 | Arkema France | COMPOUNDS FOR NITROGEN ASSOCIATIVE GROUPS |
| FR3057265A1 (en) | 2016-10-12 | 2018-04-13 | Arkema France | DISSYMETRIC COMPOUNDS CARRYING ASSOCIATIVE GROUPS |
| WO2018206787A1 (en) * | 2017-05-12 | 2018-11-15 | Lanxess Deutschland Gmbh | Rubber mixtures containing sulfur-containing organosilicon compounds |
| DE102017211110A1 (en) | 2017-06-30 | 2019-01-03 | Continental Reifen Deutschland Gmbh | A method of producing a silane, a method of modifying a silicic acid with the silane and modified silicic acid |
| DE102017221231A1 (en) | 2017-11-28 | 2019-05-29 | Continental Reifen Deutschland Gmbh | Sulfur crosslinkable rubber compound, vulcanizate of the rubber mixture and vehicle tires |
| DE102018203652A1 (en) | 2018-03-12 | 2019-09-12 | Continental Reifen Deutschland Gmbh | Silane, rubber composition containing the silane and vehicle tire having the rubber composition in at least one component |
| DE102018203650A1 (en) | 2018-03-12 | 2019-09-12 | Continental Reifen Deutschland Gmbh | Silane, rubber composition containing the silane and vehicle tire having the rubber composition in at least one component |
| FR3079841B1 (en) | 2018-04-06 | 2020-10-09 | Michelin & Cie | PNEUMATIC CONTAINING A RUBBER COMPOSITION INCLUDING A NEW POLYSULFIDE COUPLING AGENT CARRIER OF NITROGEN ASSOCIATIVE GROUPS |
| FR3079842B1 (en) | 2018-04-06 | 2020-10-09 | Michelin & Cie | PNEUMATIC CONTAINING A RUBBER COMPOSITION INCLUDING A NEW POLYSULFIDE COUPLING AGENT CARRIER OF NITROGEN ASSOCIATIVE GROUPS |
| US20220073709A1 (en) * | 2018-12-27 | 2022-03-10 | Jeremy John MEHLEM | Rubber composition having alumina covering agent |
| JP7021650B2 (en) | 2019-02-15 | 2022-02-17 | 信越化学工業株式会社 | Rubber compositions and organosilicon compounds |
| DE102019213978A1 (en) * | 2019-09-13 | 2021-03-18 | Continental Reifen Deutschland Gmbh | Sulfur-crosslinkable rubber mixture, vulcanizate and vehicle tires |
| FR3140083B1 (en) | 2022-09-26 | 2024-08-09 | Arkema France | PROCESS FOR THE MANUFACTURE OF (METH)ACRYLIC ACID |
| FR3149895A1 (en) | 2023-06-19 | 2024-12-20 | Arkema France | PROCESS FOR PURIFYING LIGHT ACRYLATES |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1310379A (en) * | 1970-12-10 | 1973-03-21 | Ppg Industries Inc | Tire tread |
| BE787691A (en) * | 1971-08-17 | 1973-02-19 | Degussa | ORGANOSILICIC COMPOUNDS CONTAINING SULFUR |
-
1973
- 1973-10-30 BG BG024887A patent/BG25805A3/en unknown
- 1973-11-07 RO RO7376560A patent/RO67260A/en unknown
- 1973-11-08 PH PH15199A patent/PH12064A/en unknown
- 1973-11-09 IN IN2466/CAL/73A patent/IN140550B/en unknown
- 1973-11-09 DD DD174555A patent/DD107935A5/xx unknown
- 1973-11-09 CH CH1574973A patent/CH592131A5/xx not_active IP Right Cessation
- 1973-11-09 CS CS737719A patent/CS198130B2/en unknown
- 1973-11-12 AT AT949373A patent/AT327536B/en not_active IP Right Cessation
- 1973-11-12 HU HUDE831A patent/HU168915B/hu unknown
- 1973-11-12 IL IL43615A patent/IL43615A/en unknown
- 1973-11-12 FR FR7340119A patent/FR2206330B1/fr not_active Expired
- 1973-11-12 ES ES420455A patent/ES420455A1/en not_active Expired
- 1973-11-12 BE BE6044358A patent/BE807222A/en not_active IP Right Cessation
- 1973-11-12 LU LU68780A patent/LU68780A1/xx unknown
- 1973-11-12 IT IT53619/73A patent/IT997728B/en active
- 1973-11-12 SU SU1969801A patent/SU522804A3/en active
- 1973-11-12 SE SE7315311A patent/SE396760B/en unknown
- 1973-11-13 CA CA185,553A patent/CA991836A/en not_active Expired
- 1973-11-13 NL NLAANVRAGE7315530,A patent/NL173534C/en not_active IP Right Cessation
- 1973-11-13 JP JP48127653A patent/JPS5120208B2/ja not_active Expired
- 1973-11-13 GB GB5263773A patent/GB1439247A/en not_active Expired
- 1973-11-13 BR BR8892/73A patent/BR7308892D0/en unknown
- 1973-11-13 ZA ZA738688A patent/ZA738688B/en unknown
- 1973-11-13 AR AR250964A patent/AR200663A1/en active
- 1973-11-13 PL PL1973166509A patent/PL87778B1/pl unknown
Also Published As
| Publication number | Publication date |
|---|---|
| SU522804A3 (en) | 1976-07-25 |
| JPS5031A (en) | 1975-01-06 |
| IT997728B (en) | 1975-12-30 |
| BR7308892D0 (en) | 1974-09-24 |
| BG25805A3 (en) | 1978-12-12 |
| JPS5120208B2 (en) | 1976-06-23 |
| IN140550B (en) | 1976-11-27 |
| AT327536B (en) | 1976-02-10 |
| FR2206330A1 (en) | 1974-06-07 |
| IL43615A0 (en) | 1974-03-14 |
| AR200663A1 (en) | 1974-11-29 |
| NL7315530A (en) | 1974-05-15 |
| GB1439247A (en) | 1976-06-16 |
| ATA949373A (en) | 1975-04-15 |
| LU68780A1 (en) | 1975-03-06 |
| CH592131A5 (en) | 1977-10-14 |
| FR2206330B1 (en) | 1978-11-17 |
| DE2255577A1 (en) | 1974-06-06 |
| BE807222A (en) | 1974-05-13 |
| NL173534C (en) | 1984-02-01 |
| RO67260A (en) | 1981-09-24 |
| PH12064A (en) | 1978-10-18 |
| DD107935A5 (en) | 1974-08-20 |
| CA991836A (en) | 1976-06-29 |
| HU168915B (en) | 1976-08-28 |
| ES420455A1 (en) | 1976-07-16 |
| AU6244873A (en) | 1975-05-15 |
| PL87778B1 (en) | 1976-07-31 |
| NL173534B (en) | 1983-09-01 |
| ZA738688B (en) | 1974-09-25 |
| SE396760B (en) | 1977-10-03 |
| DE2255577B2 (en) | 1976-07-29 |
| CS198130B2 (en) | 1980-05-30 |
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