IL37109A - Fungicidal composition containing 1,3-bis(-3-alkoxycarbonyl-2-thioureido)benzene and another ingredient - Google Patents
Fungicidal composition containing 1,3-bis(-3-alkoxycarbonyl-2-thioureido)benzene and another ingredientInfo
- Publication number
- IL37109A IL37109A IL37109A IL3710971A IL37109A IL 37109 A IL37109 A IL 37109A IL 37109 A IL37109 A IL 37109A IL 3710971 A IL3710971 A IL 3710971A IL 37109 A IL37109 A IL 37109A
- Authority
- IL
- Israel
- Prior art keywords
- bis
- thioureido
- fungicidal composition
- zinc
- composition according
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 30
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 title claims description 25
- 230000000855 fungicidal effect Effects 0.000 title claims description 20
- 239000004615 ingredient Substances 0.000 title description 2
- 206010039509 Scab Diseases 0.000 claims description 10
- 229940076134 benzene Drugs 0.000 claims description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 9
- 208000015181 infectious disease Diseases 0.000 claims description 9
- 239000011701 zinc Substances 0.000 claims description 9
- 229910052725 zinc Inorganic materials 0.000 claims description 9
- YIKWKLYQRFRGPM-UHFFFAOYSA-N 1-dodecylguanidine acetate Chemical compound CC(O)=O.CCCCCCCCCCCCN=C(N)N YIKWKLYQRFRGPM-UHFFFAOYSA-N 0.000 claims description 8
- 241000196324 Embryophyta Species 0.000 claims description 7
- 240000001987 Pyrus communis Species 0.000 claims description 5
- 235000014443 Pyrus communis Nutrition 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- YKSNLCVSTHTHJA-UHFFFAOYSA-L maneb Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S YKSNLCVSTHTHJA-UHFFFAOYSA-L 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- -1 3-methoxycarbonyl-2-thioureido Chemical group 0.000 claims description 4
- MYODENLXTDMHTA-UHFFFAOYSA-N 7a-(trichloromethylsulfanyl)-4,5-dihydro-3ah-isoindole-1,3-dione Chemical compound C1=CCCC2C(=O)NC(=O)C21SC(Cl)(Cl)Cl MYODENLXTDMHTA-UHFFFAOYSA-N 0.000 claims description 4
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- URXFYTKCCMASJX-UHFFFAOYSA-N ethyl n-[[3-(ethoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate Chemical compound CCOC(=O)NC(=S)NC1=CC=CC(NC(=S)NC(=O)OCC)=C1 URXFYTKCCMASJX-UHFFFAOYSA-N 0.000 claims description 4
- AWYFNIZYMPNGAI-UHFFFAOYSA-N ethylenebis(dithiocarbamic acid) Chemical class SC(=S)NCCNC(S)=S AWYFNIZYMPNGAI-UHFFFAOYSA-N 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- AMHNZOICSMBGDH-UHFFFAOYSA-L zineb Chemical compound [Zn+2].[S-]C(=S)NCCNC([S-])=S AMHNZOICSMBGDH-UHFFFAOYSA-L 0.000 claims description 4
- 241000317942 Venturia <ichneumonid wasp> Species 0.000 claims description 3
- 230000003213 activating effect Effects 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 230000000087 stabilizing effect Effects 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- LDVVMCZRFWMZSG-OLQVQODUSA-N (3ar,7as)-2-(trichloromethylsulfanyl)-3a,4,7,7a-tetrahydroisoindole-1,3-dione Chemical compound C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)Cl)C(=O)[C@H]21 LDVVMCZRFWMZSG-OLQVQODUSA-N 0.000 claims description 2
- 239000005745 Captan Substances 0.000 claims description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 2
- GNVMUORYQLCPJZ-UHFFFAOYSA-M Thiocarbamate Chemical compound NC([S-])=O GNVMUORYQLCPJZ-UHFFFAOYSA-M 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 239000011717 all-trans-retinol Substances 0.000 claims description 2
- 235000019169 all-trans-retinol Nutrition 0.000 claims description 2
- 229940117949 captan Drugs 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- HKIOYBQGHSTUDB-UHFFFAOYSA-N folpet Chemical compound C1=CC=C2C(=O)N(SC(Cl)(Cl)Cl)C(=O)C2=C1 HKIOYBQGHSTUDB-UHFFFAOYSA-N 0.000 claims description 2
- 229920000940 maneb Polymers 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- 239000011572 manganese Substances 0.000 claims description 2
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 claims 3
- 229960002447 thiram Drugs 0.000 claims 3
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 claims 2
- 241000237519 Bivalvia Species 0.000 claims 1
- 239000005764 Dithianon Substances 0.000 claims 1
- 239000005802 Mancozeb Substances 0.000 claims 1
- 239000005809 Metiram Substances 0.000 claims 1
- 239000005823 Propineb Substances 0.000 claims 1
- 239000005870 Ziram Substances 0.000 claims 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims 1
- 150000004056 anthraquinones Chemical class 0.000 claims 1
- LKNFSJXXGBLRAI-UHFFFAOYSA-N carbamodithioic acid;ethene Chemical class C=C.NC(S)=S.NC(S)=S LKNFSJXXGBLRAI-UHFFFAOYSA-N 0.000 claims 1
- 235000020639 clam Nutrition 0.000 claims 1
- PYZSVQVRHDXQSL-UHFFFAOYSA-N dithianon Chemical compound S1C(C#N)=C(C#N)SC2=C1C(=O)C1=CC=CC=C1C2=O PYZSVQVRHDXQSL-UHFFFAOYSA-N 0.000 claims 1
- WHDGWKAJBYRJJL-UHFFFAOYSA-K ferbam Chemical compound [Fe+3].CN(C)C([S-])=S.CN(C)C([S-])=S.CN(C)C([S-])=S WHDGWKAJBYRJJL-UHFFFAOYSA-K 0.000 claims 1
- 229920000257 metiram Polymers 0.000 claims 1
- VKJILRXHHIMQNS-UHFFFAOYSA-L n,n-dimethylcarbamothioate;iron(2+) Chemical compound [Fe+2].CN(C)C([O-])=S.CN(C)C([O-])=S VKJILRXHHIMQNS-UHFFFAOYSA-L 0.000 claims 1
- KKMLIVYBGSAJPM-UHFFFAOYSA-L propineb Chemical compound [Zn+2].[S-]C(=S)NC(C)CNC([S-])=S KKMLIVYBGSAJPM-UHFFFAOYSA-L 0.000 claims 1
- 239000000417 fungicide Substances 0.000 description 10
- 235000011430 Malus pumila Nutrition 0.000 description 7
- 235000015103 Malus silvestris Nutrition 0.000 description 7
- 239000000843 powder Substances 0.000 description 6
- 241000220225 Malus Species 0.000 description 5
- 241000489964 Fusicladium Species 0.000 description 4
- ORWLTMJXWWQMEY-UHFFFAOYSA-N methyl N-[[3-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate Chemical compound COC(=O)NC(NC1=CC(=CC=C1)NC(=S)NC(=O)OC)=S ORWLTMJXWWQMEY-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 201000010099 disease Diseases 0.000 description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 244000141359 Malus pumila Species 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 241000228452 Venturia inaequalis Species 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000007900 aqueous suspension Substances 0.000 description 2
- 230000003389 potentiating effect Effects 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241001006642 Venturia pyrina Species 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 230000001274 anti-cryptogamic effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical class CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 1
- 239000002420 orchard Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- KZOJQMWTKJDSQJ-UHFFFAOYSA-M sodium;2,3-dibutylnaphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CCCC)C(CCCC)=CC2=C1 KZOJQMWTKJDSQJ-UHFFFAOYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 230000008511 vegetative development Effects 0.000 description 1
- 230000003442 weekly effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D235/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings
- C07D235/02—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings condensed with carbocyclic rings or ring systems
- C07D235/04—Benzimidazoles; Hydrogenated benzimidazoles
- C07D235/24—Benzimidazoles; Hydrogenated benzimidazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
- C07D235/30—Nitrogen atoms not forming part of a nitro radical
- C07D235/32—Benzimidazole-2-carbamic acids, unsubstituted or substituted; Esters thereof; Thio-analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
37109/2 -2-7 i: i7'0|7w K-3)-D':--i,3 o'^'Dan mnos ' oii? o»v¾on FUNGICIDAL COMPOSITION CONTAINING 1.3-BIS- (-3-ALKOXYCARBONYL-2-THIOUREIDO) BENZENE AND ANOTHER INGREDIENT the weight ratio of the two components being between 1:20 and 20: 1.
BACKGROUND OF THE INVENTION It is known that the fight against cryptogamic disease harmful to cultivated plants holds special importance because such diseases can cause serious harm to agricultural cultivations and greatly impair the economic value of the crop.
When there are used in agriculture chemical products having an anticryptogarnic or fungicidal action it is therefore necessary to obtain effective results, in order to be able to increase commercially the agricultural production of high quality.
The object of the present invention is to provide improved fungicidal compositions for use in agriculture.
SUMMARY OF THE INVENTION The compositions in accordance with the invention comprise a mixture of at least one compound (i) of the formult in which R is an alkyl group with from 1 to 4. carbon atoms, with at least one compound (il) selected from: dodecyl guanidine acetate (Dodina) 1 , -dithiqanthraquinone ('Carbon!trile (Dithianon) trichloromethylthiotetrahydrophthalimide (Captan) trichloromethylthiophthalimide (Phaltan) zinc ethylenebisdithiocarbamate (Zineb) manganese ethylenebisdithiocarbamate (Maneb) t with the addition of activants such as surfactants, suspending! agents, adhesive agents, or stabilizing agents and even with the possible addition of fertilizers or trace elements both for application to the vegetation and to the soil.
The potentiating effect observed in the fungicidal mixtures of the invention, besides being useful against various cryptogamic diseases, is particularly evident in the use of the mixtures themselves in the fight against apple scab (Venturia inae'qualis or Fusicladium dentriticum) or agaiji pear scab ( Fusicladium pyrinum or Venturia p.yrina) and above all in the first phase of the vegetative development of fruit| i bearing plants.
The production of the mixture in accordance with the invention is carried out in accordance with a process which comprises mechanical mixing of the individual preselected components and adding to these surface active, suspending, dispersing, stabilizing and activating agents and inert and possibly fertilizing substances,- mixing and then grinding the| whole until a fineness of the particles less than 50 microns is obtained.
. There will now be quoted hereinunder some examples to illustrate the invention in greater detail. The first two of these relate to the formulation of compositions in accordance with the invention, the others to some of its practical appli cations. However, . these do not in any way constitute a limitation of the invention.
EXAMPLE I- . kg of 1,2 bis-( 3-methoxycarboriyl-2-thioureido )-ben zene, 30 kg of dodecyl guanidine acetate, '5 kg of · ethoxylated stearic acid amides, 2 kg of sodium dibutylnaphthalenesulpho nate, .5 kg' of Sodium ligninsulphonate and 2-8 kg of fine silic powder, are taken and mixed accurately. The whole is crushed finely in a powder mill until particles of diameter less than 50 microns are obtained.
EXAMPLE II kg of 1,2 bis-( 3-ethoxycarbonyl-2-thiou'reido )-benze ne, 50 kg of the complex salt of zinc and dimethyl- and ethy_l enebis-dithiocarbamic acids (Zireb), 5 kg- of sodium dibutyl-naphthalenesulphonate, 2 kg of the sodium salt of. the forma_l' dehyde condensate of naphthalenesulphonip acid,' 5 kg sodium ligninsulphonate , and 23 kg of fine silica powder are taken.
The whole is mixed in a powder mixer and crushed in a mill to obtain a powder with particles of fineness less than 50 microns.
One obtains a powder which can be employed both for spraying on the vegetation and for sprinkling as it is on the ground.
EXAMPLE III To combat apple scab (Venturia inaequalis or Fusicla-dium dentriticum) apple-trees of the variety Red Delicious are sprayed by means of a pressure pump with aqueous suspensions of the fungicides listed below during the period of cryptogamic infection from the opening of the buds to the end of the primary infection, at weekly intervals, obtaining the results listed below, in which the efficiency is calculated as the reduction of the cryptogamic infection with regard to plants not treated with fungicides placed in the midst of plants sprinkled with anticryptogamics.
Fungicides used and dosage % efficiency against th 2 apple fruit scab ■ 1a) 1 ,.3-bis( 3-ethoxycarbonyl-2- thioureido ) -benzene 0.04% 50 2a) complex salt of zinc and dimethyl-and ethylenebisdithio- carbamic acids (Zireb) 0.08 .22 3a) 1 , 3-bis( 3-ethoxycarbonyl-2- thioureido )benzene 0.04% + complex s'alt' of zinc and 'dimethy-and ethylenebis-dithiocarbamic acids 0.08% 96 1b) 1 , 3-bis( 3-methoxycarbonyl-2-thioureido ) benzene 0.02% 2b) dodecyl guanidine acetate 0.02% 3b) 1 , 3-bis-( 3-methoxycarbonyl-2- thioureido ) -benzene 0.02% + dodecyl guanidine acetate 0.02% It will be observed that the fungicidal mixtures are. more effective than the sum of the efficiency; of the products used on their own at the same dosage.
With the use of the fungicidal mixtures of this invention there! are thus obtained results which are unexpectedly superior.
EXAMPLE IV Pear trees of the variety Passacrassana are sprayed at intervals of 6 days with aqueous mixtures containing the fungicides listed below, beginning the treatment with the opening of the buds.
At the end of the season of primary infection of pear scabs (Fusicladiun pyrinum or Venturia pyrina) the efficiency of the various products is noted in terms of the reduction in the infection on the fruits by comparison with untreated plants, obtaining the results quoted hereinunder: Fungicides- used and dosage % efficiency against x pear scabs 1a) 1 , 3-bis-( 3-ethoxycarbonyl-2- — : thioureido) -benzene 0.04% 41 2a) trichloromethylthio-tetra- • hydrophthalimide 0.05% 32 3a) , 3-bis-( 3-ethoxycarbonyl-2- . . ' . thioureido )-benzene 0.04% + · trichloromethylthiotetra- hydrophthalimide 0.05% 92 1b) 1 , 3-bis- ( 3-methoxycarbonyl-2- thioureido) -benzene 0.01 % 42 2b) dodecyl guanidine acetate 0.02% 36 3b) 1 , 3-bis-( 3-methoxycarbonyl-1-2- It will be observed · that the mixture of fungicides listed above have a far greater efficiency than the sum of th efficiencies of.' the fungicides used on .their own, thus demons trating an unexpected greater effectiveness. ' EXAMPLE V Aqueous suspensions of the fungicides listed below are sprayed on apple trees of the variety Imperatore, the treatments beginning with the opening of the buds and continuing every 5 days up to the end '.of the primary infection of apple scab ( Venturia inaequalis or Fusicladium dentriticum.) .At that time the efficiency of the various fungicidal mixtures is observed in terms of the reduction in the infection of scab with respect to plants of the same orchard left without treajt ment and there' are obtained the results quoted here.
Fungicidal compounds and dosage % efficiency apple scab 1a) 1 , 3-bis( 3-ethoxycarbonyl-2- thioureido )-benzene 0.04% 48 2a) zinc and manganese ethyiene- bisdi thiocarbamate 0.< 26 1 , 3-bis- ( 3-ethox'ycarbonyl-2 thioureido ) -benzene + zinc and manganese ethylenebisdi thiocarbamate 0.08% . 91 1b) 1 , 3-bis-( 3-methoxycarbonyl-2- / thioureido) benzene 0.015% 42 2b) trichloromethylthio-tetrahydro- phthalimide 0.05% '36. 3b) 1 , 3-bis-( 3-methoxycarbonyl-2- thioureido ) -benzene 0.015% + trichioromethylthio-tetrahydro- phthalimide 0.05% 96 The efficiency of the fungicides used in the mixtures is clearly higher than the sum of the efficiencies of the fungicides used on their own, thus demonstrating a potentiating effect of the mixtures of fungicides.
Claims (3)
1. WHAT WE CLAIM IS: 1 ) A fungicidal composition comprising a mixture of at least one compound (i) of the general formula: in which R is san alkyl group with 1 to carbon atoms, with a least one compound (il) selected from: dodecyl guanidine acetate (Dodina) 1 , -dithi$anthraquinone -^,(3-c¾.rbonitrile (Dithianon) trichloromethi-lthio - tetrahydrophthalimide (Captan) trichloromethylthio - phthalimide (Phaltan) zinc ethylenebisdithiocarbamate (Zineb) manganese ethylenebisdithiocarbamate (Maneb) manganese and zinc ethylenebisdithiocarbamate (Mancozeb) zinc propylenebisdi.thiocarbamate (Propineb) zinc ethylenebisdithiocarbamate/thiuram complex (Metiram)] tetramethylthiuram disulphide (TMTD) zinc dimethyldithiocarbamate (Ziram) iron dimethylthiocarbamate (Ferbam) . / complex salt of zinc and dimethyl- and ethylenebisdithio carbamic acids (Zireb).
2. ) A fungicidal composition according to Claim 1, in whji the ratio by weight of the component or -components I with the component or components II is between 1:20 and '20:1.
3. ) A composition according to Claim 2, in which the [said ratio is between 1:10 and 10:1. - ) A composition according to Claim 1, 2 or 3 additionc 1 comprising one or more surface active and/or suspending and/o dispersing and/or stabilizing. and/or activating agents and/or 5) A fungicidal compositioraccording to any of Clams 1 to 4 "comprising 1 , 3-bis-(3-ethoxycarbonyl-2-thioureido)-benzene and the complex salt of zinc and dimethyl- and ethyle nebis - dithiocarbamic acids. 6) A fungicidal composition according to any-, of Claims 1 to 4 comprising 1 , 3-bis-( 3-ethoxycarbonyl-2-thioureido)-benzene and dodecyl guanidine acetate. 7) A fungicidal composition according to any of Claims 1 to 4 comprising 1, 3-bis-( 3-ethoxycarbonyl-2-thioureido )ben zene and trichloromethylthio-tetrahydrophthalimide . 8) A fungicidal composition according to any of Claims 1 to 4 comprising 1 , 3-bis- ( 3-methoxycarbonyl-2-thioureido ) ben zene and the complex salt of zinc and dimethyl- and ethylene bis-dithiocarbamic acids. 9) A fungicidal composition according to any of Claims 1 to 4 comprising 1 , 3-bis- ( 3-methoxycarbonyl-2-thioureido ) ben zene and dodecyl guanidine acetate. 10) A fungicidal composition according to any of Claims 1 to 4 comprising 1 , 3-bis-( 3-methoxycarbonyl-2-thioureido )ben zene and trichloromethylthio-tetrahydrophthalimide. 11 ) Ά fungicidal composition substantially as described [with specific reference to any of Examples I to VI. .' 12) A process for producing fungicidal compositions according to any of the foregoing claims which comprises mech nically mixing the individual components I and II, optionally adding surface active, suspending, dispersing, stabilizing or activating agents and/or inert or fertilising substances, mix-} in and then grinding the whole to a. particle size' less than 50 microns. 13) A method of combatting cryptogamic infections in (plants by application thereto of a fungicidal composition, in accordance with any ,of Claims 1 .to 11. 14) A method according to Claim 13 when applied to appl trees or pear trees against infections of scab (Venturia inae
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT2642370 | 1970-06-23 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IL37109A0 IL37109A0 (en) | 1971-08-25 |
| IL37109A true IL37109A (en) | 1974-12-31 |
Family
ID=11219454
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL37109A IL37109A (en) | 1970-06-23 | 1971-06-22 | Fungicidal composition containing 1,3-bis(-3-alkoxycarbonyl-2-thioureido)benzene and another ingredient |
| IL37108A IL37108A (en) | 1970-06-23 | 1971-06-22 | Fungicidal compositions containing 1-(butylcarbamoyl)-2-benzimidazole-n-methylcarbamate and another ingredient |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL37108A IL37108A (en) | 1970-06-23 | 1971-06-22 | Fungicidal compositions containing 1-(butylcarbamoyl)-2-benzimidazole-n-methylcarbamate and another ingredient |
Country Status (10)
| Country | Link |
|---|---|
| BE (2) | BE768891A (en) |
| CA (1) | CA973091A (en) |
| CH (2) | CH544492A (en) |
| DE (2) | DE2131817A1 (en) |
| FR (2) | FR2096430B3 (en) |
| GB (1) | GB1349956A (en) |
| IL (2) | IL37109A (en) |
| NL (2) | NL175254C (en) |
| TR (2) | TR17188A (en) |
| ZA (2) | ZA714031B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0236689A3 (en) * | 1986-01-27 | 1988-04-27 | Shell Internationale Researchmaatschappij B.V. | Fungicidal compositions |
| MD4077C1 (en) * | 2010-01-18 | 2011-07-31 | Государственный Университет Молд0 | Process for obtaining N, N-dimethylthioureidobenzoic acids |
-
1971
- 1971-06-18 CA CA115,985A patent/CA973091A/en not_active Expired
- 1971-06-21 ZA ZA714031A patent/ZA714031B/en unknown
- 1971-06-21 ZA ZA714032A patent/ZA714032B/en unknown
- 1971-06-22 IL IL37109A patent/IL37109A/en unknown
- 1971-06-22 NL NLAANVRAGE7108572,A patent/NL175254C/en not_active IP Right Cessation
- 1971-06-22 CH CH911571A patent/CH544492A/en not_active IP Right Cessation
- 1971-06-22 FR FR7122605A patent/FR2096430B3/fr not_active Expired
- 1971-06-22 CH CH911671A patent/CH544489A/en not_active IP Right Cessation
- 1971-06-22 FR FR7122606A patent/FR2096431B1/fr not_active Expired
- 1971-06-22 IL IL37108A patent/IL37108A/en unknown
- 1971-06-22 NL NL7108571A patent/NL7108571A/xx unknown
- 1971-06-23 TR TR17188A patent/TR17188A/en unknown
- 1971-06-23 TR TR16787A patent/TR16787A/en unknown
- 1971-06-23 BE BE768891A patent/BE768891A/en unknown
- 1971-06-23 DE DE19712131817 patent/DE2131817A1/en active Pending
- 1971-06-23 BE BE768893A patent/BE768893A/en unknown
- 1971-06-23 GB GB2950271A patent/GB1349956A/en not_active Expired
- 1971-06-23 DE DE19712131818 patent/DE2131818A1/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| ZA714032B (en) | 1972-02-23 |
| FR2096431B1 (en) | 1975-07-11 |
| CH544492A (en) | 1973-11-30 |
| NL7108572A (en) | 1971-12-27 |
| NL175254C (en) | 1984-10-16 |
| CH544489A (en) | 1973-11-30 |
| DE2131818A1 (en) | 1971-12-30 |
| TR17188A (en) | 1974-04-25 |
| FR2096430A3 (en) | 1972-02-18 |
| CA973091A (en) | 1975-08-19 |
| IL37109A0 (en) | 1971-08-25 |
| DE2131817A1 (en) | 1971-12-30 |
| FR2096430B3 (en) | 1974-04-05 |
| FR2096431A1 (en) | 1972-02-18 |
| IL37108A0 (en) | 1971-08-25 |
| IL37108A (en) | 1975-06-25 |
| BE768893A (en) | 1971-11-03 |
| NL7108571A (en) | 1971-12-27 |
| TR16787A (en) | 1973-05-01 |
| GB1349956A (en) | 1974-04-10 |
| BE768891A (en) | 1971-11-03 |
| ZA714031B (en) | 1972-02-23 |
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