IL31734A - Preservatives for bread and pastry containing mixed anhydrides of sorbic and palmitic or stearic acid together with alkali chlorides and process for the preparation thereof - Google Patents
Preservatives for bread and pastry containing mixed anhydrides of sorbic and palmitic or stearic acid together with alkali chlorides and process for the preparation thereofInfo
- Publication number
- IL31734A IL31734A IL31734A IL3173469A IL31734A IL 31734 A IL31734 A IL 31734A IL 31734 A IL31734 A IL 31734A IL 3173469 A IL3173469 A IL 3173469A IL 31734 A IL31734 A IL 31734A
- Authority
- IL
- Israel
- Prior art keywords
- chloride
- acid
- palmitic
- stearic acid
- sorbic
- Prior art date
Links
- WSWCOQWTEOXDQX-MQQKCMAXSA-N sorbic acid group Chemical group C(\C=C\C=C\C)(=O)O WSWCOQWTEOXDQX-MQQKCMAXSA-N 0.000 title claims description 30
- 238000000034 method Methods 0.000 title claims description 21
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 title claims description 19
- 150000008064 anhydrides Chemical class 0.000 title claims description 18
- 235000014594 pastries Nutrition 0.000 title claims description 15
- 239000008117 stearic acid Substances 0.000 title claims description 11
- 235000021314 Palmitic acid Nutrition 0.000 title claims description 10
- 235000021355 Stearic acid Nutrition 0.000 title claims description 10
- 235000008429 bread Nutrition 0.000 title claims description 10
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 title claims description 10
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 title claims description 10
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 title claims description 9
- 239000003755 preservative agent Substances 0.000 title claims description 9
- 239000003513 alkali Substances 0.000 title description 27
- 150000001805 chlorine compounds Chemical class 0.000 title description 4
- 238000002360 preparation method Methods 0.000 title description 3
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims description 24
- 235000010199 sorbic acid Nutrition 0.000 claims description 24
- 239000004334 sorbic acid Substances 0.000 claims description 24
- 229940075582 sorbic acid Drugs 0.000 claims description 24
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 21
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 16
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 14
- 239000002904 solvent Substances 0.000 claims description 14
- 239000011780 sodium chloride Substances 0.000 claims description 11
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 10
- 239000004283 Sodium sorbate Substances 0.000 claims description 10
- WTBAHSZERDXKKZ-UHFFFAOYSA-N octadecanoyl chloride Chemical compound CCCCCCCCCCCCCCCCCC(Cl)=O WTBAHSZERDXKKZ-UHFFFAOYSA-N 0.000 claims description 10
- 235000010241 potassium sorbate Nutrition 0.000 claims description 10
- 229940069338 potassium sorbate Drugs 0.000 claims description 10
- 239000004302 potassium sorbate Substances 0.000 claims description 10
- 235000019250 sodium sorbate Nutrition 0.000 claims description 10
- ARBOVOVUTSQWSS-UHFFFAOYSA-N hexadecanoyl chloride Chemical compound CCCCCCCCCCCCCCCC(Cl)=O ARBOVOVUTSQWSS-UHFFFAOYSA-N 0.000 claims description 9
- LROWVYNUWKVTCU-STWYSWDKSA-M sodium sorbate Chemical compound [Na+].C\C=C\C=C\C([O-])=O LROWVYNUWKVTCU-STWYSWDKSA-M 0.000 claims description 9
- 235000011164 potassium chloride Nutrition 0.000 claims description 8
- 239000001103 potassium chloride Substances 0.000 claims description 8
- 238000009835 boiling Methods 0.000 claims description 7
- 239000003208 petroleum Substances 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000003960 organic solvent Substances 0.000 claims description 4
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 150000001338 aliphatic hydrocarbons Chemical group 0.000 claims description 2
- 230000002335 preservative effect Effects 0.000 claims 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000000194 fatty acid Substances 0.000 description 16
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 14
- 235000014113 dietary fatty acids Nutrition 0.000 description 13
- 229930195729 fatty acid Natural products 0.000 description 13
- 235000002639 sodium chloride Nutrition 0.000 description 11
- 150000004665 fatty acids Chemical class 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 8
- WSWCOQWTEOXDQX-MQQKCMAXSA-M (E,E)-sorbate Chemical compound C\C=C\C=C\C([O-])=O WSWCOQWTEOXDQX-MQQKCMAXSA-M 0.000 description 7
- -1 fatty acid chlorides Chemical class 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- 229940075554 sorbate Drugs 0.000 description 7
- 239000000047 product Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 150000001447 alkali salts Chemical class 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 150000008065 acid anhydrides Chemical class 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 238000000855 fermentation Methods 0.000 description 2
- 230000004151 fermentation Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 238000006701 autoxidation reaction Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000002250 progressing effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21D—TREATMENT OF FLOUR OR DOUGH FOR BAKING, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS
- A21D2/00—Treatment of flour or dough by adding materials thereto before or during baking
- A21D2/08—Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
- A21D2/14—Organic oxygen compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/54—Preparation of carboxylic acid anhydrides
- C07C51/56—Preparation of carboxylic acid anhydrides from organic acids, their salts, their esters or their halides, e.g. by carboxylation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Food Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Bakery Products And Manufacturing Methods Therefor (AREA)
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19681668118 DE1668118C3 (de) | 1968-03-16 | 1968-03-16 | Verfahren zur Herstellung eines Gemisches aus gemischten Anhydriden der Sorbinsäure mit Palmitinsäure oder Stearinsäure und Natrium- oder Kaliumchlorid sowie dessen Verwendung als Konservierungsmittel für Brot und Backwaren |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IL31734A0 IL31734A0 (en) | 1969-05-28 |
| IL31734A true IL31734A (en) | 1972-10-29 |
Family
ID=5686078
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL31734A IL31734A (en) | 1968-03-16 | 1969-03-04 | Preservatives for bread and pastry containing mixed anhydrides of sorbic and palmitic or stearic acid together with alkali chlorides and process for the preparation thereof |
Country Status (5)
| Country | Link |
|---|---|
| CH (1) | CH510608A (enrdf_load_stackoverflow) |
| ES (1) | ES364828A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2004078A1 (enrdf_load_stackoverflow) |
| GB (1) | GB1259622A (enrdf_load_stackoverflow) |
| IL (1) | IL31734A (enrdf_load_stackoverflow) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2447242A1 (de) * | 2010-10-29 | 2012-05-02 | LANXESS Deutschland GmbH | Verfahren zur Herstellung von all-E-Sorbinsäureanhydrid |
-
1969
- 1969-03-04 IL IL31734A patent/IL31734A/en unknown
- 1969-03-13 CH CH382269A patent/CH510608A/de not_active IP Right Cessation
- 1969-03-14 ES ES364828A patent/ES364828A1/es not_active Expired
- 1969-03-17 GB GB1259622D patent/GB1259622A/en not_active Expired
- 1969-03-17 FR FR6907524A patent/FR2004078A1/fr not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| ES364828A1 (es) | 1971-01-01 |
| CH510608A (de) | 1971-07-31 |
| GB1259622A (enrdf_load_stackoverflow) | 1972-01-05 |
| FR2004078A1 (enrdf_load_stackoverflow) | 1969-11-21 |
| IL31734A0 (en) | 1969-05-28 |
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