IL31250A - Process for the preparation of salts of hydroxylamine - Google Patents
Process for the preparation of salts of hydroxylamineInfo
- Publication number
- IL31250A IL31250A IL31250A IL3125068A IL31250A IL 31250 A IL31250 A IL 31250A IL 31250 A IL31250 A IL 31250A IL 3125068 A IL3125068 A IL 3125068A IL 31250 A IL31250 A IL 31250A
- Authority
- IL
- Israel
- Prior art keywords
- catalyst
- activity
- hydroxylamine
- activator
- reaction
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 23
- 150000003839 salts Chemical class 0.000 title claims description 12
- 238000002360 preparation method Methods 0.000 title claims description 10
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical class ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 title description 27
- 239000003054 catalyst Substances 0.000 claims description 73
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 38
- 239000012190 activator Substances 0.000 claims description 19
- 238000006243 chemical reaction Methods 0.000 claims description 18
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 17
- 229910052763 palladium Inorganic materials 0.000 claims description 16
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 15
- 150000001875 compounds Chemical class 0.000 claims description 15
- 229910052739 hydrogen Inorganic materials 0.000 claims description 15
- 239000001257 hydrogen Substances 0.000 claims description 15
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 239000002184 metal Substances 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 8
- 230000000737 periodic effect Effects 0.000 claims description 7
- 229910002651 NO3 Inorganic materials 0.000 claims description 4
- -1 nitrate ions Chemical class 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 description 44
- 238000002474 experimental method Methods 0.000 description 21
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 17
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 15
- 239000000243 solution Substances 0.000 description 13
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 12
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 10
- 229910017604 nitric acid Inorganic materials 0.000 description 10
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 9
- 239000007788 liquid Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
- 239000012429 reaction media Substances 0.000 description 8
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- 229940119177 germanium dioxide Drugs 0.000 description 6
- 239000012295 chemical reaction liquid Substances 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- 229910052697 platinum Inorganic materials 0.000 description 5
- 229910021529 ammonia Inorganic materials 0.000 description 4
- 229910052732 germanium Inorganic materials 0.000 description 4
- 230000000977 initiatory effect Effects 0.000 description 4
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000003213 activating effect Effects 0.000 description 3
- 229910052785 arsenic Inorganic materials 0.000 description 3
- 229910052745 lead Inorganic materials 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052753 mercury Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 description 2
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- 229910052797 bismuth Inorganic materials 0.000 description 2
- 239000007853 buffer solution Substances 0.000 description 2
- XIEPJMXMMWZAAV-UHFFFAOYSA-N cadmium nitrate Inorganic materials [Cd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XIEPJMXMMWZAAV-UHFFFAOYSA-N 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910052738 indium Inorganic materials 0.000 description 2
- 229910000337 indium(III) sulfate Inorganic materials 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 235000011150 stannous chloride Nutrition 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- DJHGAFSJWGLOIV-UHFFFAOYSA-K Arsenate3- Chemical class [O-][As]([O-])([O-])=O DJHGAFSJWGLOIV-UHFFFAOYSA-K 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical group OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- FAPDDOBMIUGHIN-UHFFFAOYSA-K antimony trichloride Chemical compound Cl[Sb](Cl)Cl FAPDDOBMIUGHIN-UHFFFAOYSA-K 0.000 description 1
- GUNJVIDCYZYFGV-UHFFFAOYSA-K antimony trifluoride Chemical compound F[Sb](F)F GUNJVIDCYZYFGV-UHFFFAOYSA-K 0.000 description 1
- 125000000223 arsonoyl group Chemical group [H][As](*)(*)=O 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 229910000373 gallium sulfate Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- RBLWMQWAHONKNC-UHFFFAOYSA-N hydroxyazanium Chemical compound O[NH3+] RBLWMQWAHONKNC-UHFFFAOYSA-N 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- ORMNPSYMZOGSSV-UHFFFAOYSA-N mercury(II) nitrate Inorganic materials [Hg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ORMNPSYMZOGSSV-UHFFFAOYSA-N 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- GQPLMRYTRLFLPF-UHFFFAOYSA-N nitrous oxide Inorganic materials [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(I) nitrate Inorganic materials [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/082—Compounds containing nitrogen and non-metals and optionally metals
- C01B21/14—Hydroxylamine; Salts thereof
- C01B21/1409—Preparation
- C01B21/1418—Preparation by catalytic reduction of nitrogen oxides or nitrates with hydrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL676717085A NL148570B (nl) | 1967-12-14 | 1967-12-14 | Werkwijze voor het bereiden van zouten van hydroxylamine. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IL31250A0 IL31250A0 (en) | 1969-02-27 |
| IL31250A true IL31250A (en) | 1972-09-28 |
Family
ID=19801992
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL31250A IL31250A (en) | 1967-12-14 | 1968-12-09 | Process for the preparation of salts of hydroxylamine |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US3767758A (cs) |
| JP (1) | JPS493635B1 (cs) |
| AT (1) | AT292627B (cs) |
| BE (1) | BE725456A (cs) |
| BR (1) | BR6804858D0 (cs) |
| CH (1) | CH505754A (cs) |
| ES (1) | ES361385A1 (cs) |
| FR (1) | FR1597837A (cs) |
| GB (1) | GB1245786A (cs) |
| IL (1) | IL31250A (cs) |
| NL (1) | NL148570B (cs) |
| NO (1) | NO121889B (cs) |
| SE (1) | SE347947B (cs) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL7507119A (nl) * | 1975-06-16 | 1976-12-20 | Stamicarbon | Werkwijze voor de bereiding van een hydroxylamine- zout. |
| US4115523A (en) * | 1977-11-07 | 1978-09-19 | Allied Chemical Corporation | Synthesis of hydroxylamine from hydrogen sulfide and nitric oxide |
| DE3713733A1 (de) * | 1987-04-24 | 1988-11-17 | Basf Ag | Verfahren zur herstellung von hydroxylammoniumsalzen |
| DE3809554A1 (de) * | 1988-03-22 | 1989-10-12 | Basf Ag | Verfahren zur herstellung von hydroxylammoniumsalzen |
| DE4125599A1 (de) * | 1991-08-02 | 1993-02-04 | Basf Ag | Verfahren zur herstellung von hydroxylammoniumsalzen |
| BE1009767A3 (nl) * | 1995-11-10 | 1997-08-05 | Dsm Nv | Werkwijze voor de bereiding van hydroxylammoniumzouten. |
| BE1010719A3 (nl) * | 1996-10-28 | 1998-12-01 | Dsm Nv | Werkwijze voor de bereiding van hydroxylammoniumzouten. |
| US6024855A (en) * | 1997-08-15 | 2000-02-15 | Sachem, Inc. | Electrosynthesis of hydroxylammonium salts and hydroxylamine using a mediator |
| AU8784198A (en) * | 1997-08-15 | 1999-03-08 | Sachem, Inc. | Electrosynthesis of hydroxylammonium salts and hydroxylamine using a mediator, acatalytic film, methods of making the catalytic film, and electrosynthesis of c ompounds using the catalytic film |
| US6165341A (en) * | 1998-08-13 | 2000-12-26 | Sachem, Inc. | Catalytic film, methods of making the catalytic films, and electrosynthesis of compounds using the catalytic film |
| EP1275616A1 (en) * | 2001-07-11 | 2003-01-15 | Dsm N.V. | Process for the preparation of hydroxylammonium |
| TW200736162A (en) * | 2006-03-29 | 2007-10-01 | China Petrochemical Dev Corp | Method of manufacture hydroxylamine |
| TW200738555A (en) * | 2006-04-07 | 2007-10-16 | China Petrochemical Dev Corp | Method for manufacturing hydroxylamine |
| TW200738556A (en) * | 2006-04-11 | 2007-10-16 | China Petrochemical Dev Corp | Method for manufacturing hydroxylamine |
| TWI274041B (en) * | 2006-04-14 | 2007-02-21 | China Petrochemical Dev Corp | Method for manufacturing hydroxylamine |
| US8153092B2 (en) * | 2006-04-14 | 2012-04-10 | China Petrochemical Development Corporation | Method for manufacturing hydroxylamine |
| US7358203B1 (en) * | 2006-10-10 | 2008-04-15 | E.I. Du Pont De Nemours And Company | Stain-masking cut resistant fabrics and articles and processes for making same |
| US20080286522A1 (en) * | 2006-12-15 | 2008-11-20 | Subhotosh Khan | Honeycomb having a low coefficient of thermal expansion and articles made from same |
| EP1977994B9 (en) * | 2007-04-04 | 2010-05-19 | China Petrochemical Development Corporation | A method for preparing hydroxylamine |
| ES2370801T3 (es) | 2007-04-05 | 2011-12-22 | China Petrochemical Development Corporation | Método para preparar hidroxilamina. |
| US7624879B2 (en) * | 2007-12-10 | 2009-12-01 | E. I. Du Pont De Nemours And Company | Micropulp for filters |
| US7803247B2 (en) * | 2007-12-21 | 2010-09-28 | E.I. Du Pont De Nemours And Company | Papers containing floc derived from diamino diphenyl sulfone |
| KR102080950B1 (ko) | 2011-12-29 | 2020-02-24 | 캡 쓰리 비 브이 | 하이드록실아민의 연속 제조방법 |
| CN103359697B (zh) * | 2012-03-31 | 2016-12-28 | Cap Iii 有限公司 | 一种连续生产羟铵的方法 |
| CN103359696B (zh) * | 2012-03-31 | 2016-12-07 | Cap Iii 有限公司 | 一种连续生产羟铵的方法 |
| MY189942A (en) * | 2018-10-17 | 2022-03-22 | Cap Iii Bv | An improved process for the production of oximes |
-
1967
- 1967-12-14 NL NL676717085A patent/NL148570B/xx not_active IP Right Cessation
-
1968
- 1968-12-09 GB GB58349/68A patent/GB1245786A/en not_active Expired
- 1968-12-09 IL IL31250A patent/IL31250A/en unknown
- 1968-12-13 BR BR204858/68A patent/BR6804858D0/pt unknown
- 1968-12-13 FR FR1597837D patent/FR1597837A/fr not_active Expired
- 1968-12-13 NO NO5010/68A patent/NO121889B/no unknown
- 1968-12-13 AT AT1215168A patent/AT292627B/de not_active IP Right Cessation
- 1968-12-13 ES ES361385A patent/ES361385A1/es not_active Expired
- 1968-12-13 JP JP43091500A patent/JPS493635B1/ja active Pending
- 1968-12-13 BE BE725456D patent/BE725456A/xx unknown
- 1968-12-16 SE SE17236/68A patent/SE347947B/xx unknown
- 1968-12-16 CH CH1872368A patent/CH505754A/de not_active IP Right Cessation
-
1971
- 1971-07-01 US US00159063A patent/US3767758A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| NL6717085A (cs) | 1969-06-17 |
| NO121889B (cs) | 1971-04-26 |
| IL31250A0 (en) | 1969-02-27 |
| JPS493635B1 (cs) | 1974-01-28 |
| BR6804858D0 (pt) | 1973-04-12 |
| GB1245786A (en) | 1971-09-08 |
| DE1814574B2 (de) | 1975-11-27 |
| CH505754A (de) | 1971-04-15 |
| NL148570B (nl) | 1976-02-16 |
| ES361385A1 (es) | 1970-09-16 |
| BE725456A (cs) | 1969-06-13 |
| SE347947B (cs) | 1972-08-21 |
| DE1814574A1 (de) | 1969-07-24 |
| US3767758A (en) | 1973-10-23 |
| FR1597837A (cs) | 1970-06-29 |
| AT292627B (de) | 1971-09-10 |
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