IL28932A - Preparation of borate esters from hydrocarbons and alcohols produced from these esters - Google Patents
Preparation of borate esters from hydrocarbons and alcohols produced from these estersInfo
- Publication number
- IL28932A IL28932A IL28932A IL2893267A IL28932A IL 28932 A IL28932 A IL 28932A IL 28932 A IL28932 A IL 28932A IL 2893267 A IL2893267 A IL 2893267A IL 28932 A IL28932 A IL 28932A
- Authority
- IL
- Israel
- Prior art keywords
- alkanol
- alkane
- heat
- reaction
- esters
- Prior art date
Links
- 229930195733 hydrocarbon Natural products 0.000 title claims description 19
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 19
- 150000002148 esters Chemical class 0.000 title claims description 5
- 150000001298 alcohols Chemical class 0.000 title claims description 3
- 150000001642 boronic acid derivatives Chemical class 0.000 title claims 5
- 238000002360 preparation method Methods 0.000 title description 2
- 238000006243 chemical reaction Methods 0.000 claims description 28
- 239000004215 Carbon black (E152) Substances 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 16
- 238000002791 soaking Methods 0.000 claims description 14
- 239000007789 gas Substances 0.000 claims description 9
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 7
- 150000002432 hydroperoxides Chemical class 0.000 claims description 7
- 229910001882 dioxygen Inorganic materials 0.000 claims description 6
- 150000001639 boron compounds Chemical class 0.000 claims description 5
- 230000001590 oxidative effect Effects 0.000 claims description 5
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000011541 reaction mixture Substances 0.000 claims description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 5
- 239000007795 chemical reaction product Substances 0.000 claims 2
- 150000001924 cycloalkanes Chemical class 0.000 claims 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims 2
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 230000003301 hydrolyzing effect Effects 0.000 claims 1
- VGTPKLINSHNZRD-UHFFFAOYSA-N oxoborinic acid Chemical compound OB=O VGTPKLINSHNZRD-UHFFFAOYSA-N 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 description 19
- 230000003647 oxidation Effects 0.000 description 17
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 5
- 229910052796 boron Inorganic materials 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000004677 hydrates Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- -1 peroxy oxygen Chemical compound 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- ARTGXHJAOOHUMW-UHFFFAOYSA-N boric acid hydrate Chemical compound O.OB(O)O ARTGXHJAOOHUMW-UHFFFAOYSA-N 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000005502 peroxidation Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010723 turbine oil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/04—Esters of boric acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
- C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
- C07C29/52—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only in the presence of mineral boron compounds with, when necessary, hydrolysis of the intermediate formed
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US59364666A | 1966-11-14 | 1966-11-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| IL28932A true IL28932A (en) | 1971-07-28 |
Family
ID=24375555
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL28932A IL28932A (en) | 1966-11-14 | 1967-11-13 | Preparation of borate esters from hydrocarbons and alcohols produced from these esters |
Country Status (10)
| Country | Link |
|---|---|
| JP (1) | JPS4930818B1 (nl) |
| BE (1) | BE706330A (nl) |
| CH (1) | CH479625A (nl) |
| DE (1) | DE1668221C3 (nl) |
| ES (1) | ES347126A1 (nl) |
| FR (1) | FR1553849A (nl) |
| GB (1) | GB1207680A (nl) |
| IL (1) | IL28932A (nl) |
| LU (1) | LU54840A1 (nl) |
| NL (1) | NL153204B (nl) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1590958A (en) * | 1976-12-31 | 1981-06-10 | Ici Ltd | Oxidation of cyclohexane |
-
1967
- 1967-11-06 NL NL676715023A patent/NL153204B/nl not_active IP Right Cessation
- 1967-11-07 GB GB50541/67A patent/GB1207680A/en not_active Expired
- 1967-11-10 BE BE706330D patent/BE706330A/xx not_active IP Right Cessation
- 1967-11-10 LU LU54840D patent/LU54840A1/xx unknown
- 1967-11-13 FR FR1553849D patent/FR1553849A/fr not_active Expired
- 1967-11-13 IL IL28932A patent/IL28932A/en unknown
- 1967-11-13 CH CH1579267A patent/CH479625A/fr not_active IP Right Cessation
- 1967-11-14 ES ES347126A patent/ES347126A1/es not_active Expired
- 1967-11-14 DE DE1668221A patent/DE1668221C3/de not_active Expired
- 1967-11-14 JP JP42072867A patent/JPS4930818B1/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| BE706330A (fr) | 1968-05-10 |
| DE1668221B2 (de) | 1980-03-06 |
| FR1553849A (nl) | 1969-01-17 |
| DE1668221A1 (de) | 1971-09-02 |
| NL6715023A (nl) | 1968-05-15 |
| JPS4930818B1 (nl) | 1974-08-16 |
| CH479625A (fr) | 1969-10-15 |
| DE1668221C3 (de) | 1980-11-06 |
| GB1207680A (en) | 1970-10-07 |
| NL153204B (nl) | 1977-05-16 |
| ES347126A1 (es) | 1969-01-01 |
| LU54840A1 (nl) | 1969-07-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3957876A (en) | Process for the oxidation of cyclohexane | |
| US2548435A (en) | Oxidation of aromatic hydrocarbons | |
| US2404438A (en) | Process for the manufacture of olefin oxides | |
| US2862973A (en) | Di-tertiary-alkyl peroxide production | |
| KR870000056B1 (ko) | 사이클로 헥사놀 및 사이클로 헥사논의 제조방법 | |
| US2715145A (en) | Manufacture of phenol | |
| US2010358A (en) | Process for the oxidation of isoaldehydes | |
| US2615921A (en) | Hydrocarbon oxidation | |
| US2571901A (en) | Chlorinating process | |
| US3907901A (en) | Continuous process for preparing cumene hydroperoxide | |
| US3093686A (en) | Production of cyclic alcohols | |
| IL28932A (en) | Preparation of borate esters from hydrocarbons and alcohols produced from these esters | |
| GB1019437A (en) | Process for preparing dichlorinated ethylene derivatives | |
| US5220075A (en) | Initiated peroxidation of secondary carbon in alkanes and cycloalkanes | |
| US3969387A (en) | Metalic-organo-peroxide and organo-metalic-peroxide and preparation thereof | |
| US3510526A (en) | Process for the preparation of hydroperoxides | |
| US2974173A (en) | Acetaldehyde manufacture | |
| US2843633A (en) | Process for the production of hydroperoxides | |
| US3340304A (en) | Selective oxidation of cyclohexane to cyclohexanone | |
| US2735871A (en) | Treatment of aralkyl hydroperoxides | |
| US2619510A (en) | Manufacture of isopropyl benzene hydroperoxide | |
| GB700546A (en) | Hydroperoxides | |
| US3524891A (en) | Boric acid oxidation process | |
| US4322558A (en) | Oxidation process | |
| US3479394A (en) | Process for the oxidation of cycloalkanes |