IL104425A - Reducing the content of formaldehyde in tiny capsule preparations - Google Patents
Reducing the content of formaldehyde in tiny capsule preparationsInfo
- Publication number
- IL104425A IL104425A IL10442593A IL10442593A IL104425A IL 104425 A IL104425 A IL 104425A IL 10442593 A IL10442593 A IL 10442593A IL 10442593 A IL10442593 A IL 10442593A IL 104425 A IL104425 A IL 104425A
- Authority
- IL
- Israel
- Prior art keywords
- formaldehyde
- process according
- prepolymer
- amino resin
- herbicide
- Prior art date
Links
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 title claims abstract description 87
- 239000003094 microcapsule Substances 0.000 title claims abstract description 41
- 239000000203 mixture Substances 0.000 title claims abstract description 31
- 238000009472 formulation Methods 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 claims abstract description 41
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 31
- 229920003180 amino resin Polymers 0.000 claims abstract description 21
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 15
- 239000000243 solution Substances 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 14
- 239000000839 emulsion Substances 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 14
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical group O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 claims description 14
- 239000011344 liquid material Substances 0.000 claims description 13
- VTNQPKFIQCLBDU-UHFFFAOYSA-N Acetochlor Chemical group CCOCN(C(=O)CCl)C1=C(C)C=CC=C1CC VTNQPKFIQCLBDU-UHFFFAOYSA-N 0.000 claims description 11
- DEDOPGXGGQYYMW-UHFFFAOYSA-N molinate Chemical group CCSC(=O)N1CCCCCC1 DEDOPGXGGQYYMW-UHFFFAOYSA-N 0.000 claims description 11
- 239000002775 capsule Substances 0.000 claims description 10
- 239000004009 herbicide Substances 0.000 claims description 10
- 239000012071 phase Substances 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 9
- 229920000642 polymer Polymers 0.000 claims description 9
- 239000007864 aqueous solution Substances 0.000 claims description 7
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- -1 methylol groups Chemical group 0.000 claims description 5
- 238000009833 condensation Methods 0.000 claims description 4
- 238000011065 in-situ storage Methods 0.000 claims description 4
- 239000012074 organic phase Substances 0.000 claims description 4
- NGFUWANGZFFYHK-UHFFFAOYSA-N 1,3,3a,4,6,6a-hexahydroimidazo[4,5-d]imidazole-2,5-dione;formaldehyde Chemical compound O=C.N1C(=O)NC2NC(=O)NC21 NGFUWANGZFFYHK-UHFFFAOYSA-N 0.000 claims description 3
- GUVLYNGULCJVDO-UHFFFAOYSA-N EPTC Chemical group CCCN(CCC)C(=O)SCC GUVLYNGULCJVDO-UHFFFAOYSA-N 0.000 claims description 3
- 238000012695 Interfacial polymerization Methods 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 150000003931 anilides Chemical class 0.000 claims description 3
- 239000008346 aqueous phase Substances 0.000 claims description 3
- HKPHPIREJKHECO-UHFFFAOYSA-N butachlor Chemical compound CCCCOCN(C(=O)CCl)C1=C(CC)C=CC=C1CC HKPHPIREJKHECO-UHFFFAOYSA-N 0.000 claims description 3
- MSYLJRIXVZCQHW-UHFFFAOYSA-N formaldehyde;6-phenyl-1,3,5-triazine-2,4-diamine Chemical compound O=C.NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 MSYLJRIXVZCQHW-UHFFFAOYSA-N 0.000 claims description 3
- 239000000417 fungicide Substances 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000002917 insecticide Substances 0.000 claims description 3
- 238000005191 phase separation Methods 0.000 claims description 3
- MFOUDYKPLGXPGO-UHFFFAOYSA-N propachlor Chemical compound ClCC(=O)N(C(C)C)C1=CC=CC=C1 MFOUDYKPLGXPGO-UHFFFAOYSA-N 0.000 claims description 3
- 239000005508 Dimethachlor Substances 0.000 claims description 2
- YLPGTOIOYRQOHV-UHFFFAOYSA-N Pretilachlor Chemical compound CCCOCCN(C(=O)CCl)C1=C(CC)C=CC=C1CC YLPGTOIOYRQOHV-UHFFFAOYSA-N 0.000 claims description 2
- 239000002535 acidifier Substances 0.000 claims description 2
- XCSGPAVHZFQHGE-UHFFFAOYSA-N alachlor Chemical compound CCC1=CC=CC(CC)=C1N(COC)C(=O)CCl XCSGPAVHZFQHGE-UHFFFAOYSA-N 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- SCCDDNKJYDZXMM-UHFFFAOYSA-N dimethachlor Chemical compound COCCN(C(=O)CCl)C1=C(C)C=CC=C1C SCCDDNKJYDZXMM-UHFFFAOYSA-N 0.000 claims description 2
- STEPQTYSZVCJPV-UHFFFAOYSA-N metazachlor Chemical compound CC1=CC=CC(C)=C1N(C(=O)CCl)CN1N=CC=C1 STEPQTYSZVCJPV-UHFFFAOYSA-N 0.000 claims description 2
- 230000001069 nematicidal effect Effects 0.000 claims description 2
- 239000005645 nematicide Substances 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 230000002363 herbicidal effect Effects 0.000 claims 6
- GNVMUORYQLCPJZ-UHFFFAOYSA-M Thiocarbamate Chemical compound NC([S-])=O GNVMUORYQLCPJZ-UHFFFAOYSA-M 0.000 claims 4
- 229960004279 formaldehyde Drugs 0.000 claims 3
- 239000011162 core material Substances 0.000 claims 1
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 claims 1
- 230000000855 fungicidal effect Effects 0.000 claims 1
- 239000003815 herbicide antidote Substances 0.000 claims 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 7
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 7
- 235000011114 ammonium hydroxide Nutrition 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 5
- 239000000575 pesticide Substances 0.000 description 5
- 229920000877 Melamine resin Polymers 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000013270 controlled release Methods 0.000 description 4
- 239000000706 filtrate Substances 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 241000254173 Coleoptera Species 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 150000003558 thiocarbamic acid derivatives Chemical class 0.000 description 3
- UENGBOCGGKLVJJ-UHFFFAOYSA-N 2-chloro-1-(2,4-difluorophenyl)ethanone Chemical compound FC1=CC=C(C(=O)CCl)C(F)=C1 UENGBOCGGKLVJJ-UHFFFAOYSA-N 0.000 description 2
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 2
- BMTAFVWTTFSTOG-UHFFFAOYSA-N Butylate Chemical compound CCSC(=O)N(CC(C)C)CC(C)C BMTAFVWTTFSTOG-UHFFFAOYSA-N 0.000 description 2
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 2
- DFCAFRGABIXSDS-UHFFFAOYSA-N Cycloate Chemical compound CCSC(=O)N(CC)C1CCCCC1 DFCAFRGABIXSDS-UHFFFAOYSA-N 0.000 description 2
- SPANOECCGNXGNR-UITAMQMPSA-N Diallat Chemical compound CC(C)N(C(C)C)C(=O)SC\C(Cl)=C\Cl SPANOECCGNXGNR-UITAMQMPSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- OKUGPJPKMAEJOE-UHFFFAOYSA-N S-propyl dipropylcarbamothioate Chemical compound CCCSC(=O)N(CCC)CCC OKUGPJPKMAEJOE-UHFFFAOYSA-N 0.000 description 2
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 239000000729 antidote Substances 0.000 description 2
- 229940075522 antidotes Drugs 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000003337 fertilizer Substances 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229920005552 sodium lignosulfonate Polymers 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 229940124530 sulfonamide Drugs 0.000 description 2
- 150000003456 sulfonamides Chemical class 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- VONWPEXRCLHKRJ-UHFFFAOYSA-N 2-chloro-n-phenylacetamide Chemical compound ClCC(=O)NC1=CC=CC=C1 VONWPEXRCLHKRJ-UHFFFAOYSA-N 0.000 description 1
- 125000004200 2-methoxyethyl group Chemical group [H]C([H])([H])OC([H])([H])C([H])([H])* 0.000 description 1
- 229920003270 Cymel® Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- VDKDFKRKAPXHBH-UHFFFAOYSA-N [3-(2-sulfanylpropanoyloxy)-2,2-bis(2-sulfanylpropanoyloxymethyl)propyl] 2-sulfanylpropanoate Chemical compound CC(S)C(=O)OCC(COC(=O)C(C)S)(COC(=O)C(C)S)COC(=O)C(C)S VDKDFKRKAPXHBH-UHFFFAOYSA-N 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 150000003869 acetamides Chemical class 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229940051881 anilide analgesics and antipyretics Drugs 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 239000005667 attractant Substances 0.000 description 1
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 239000003124 biologic agent Substances 0.000 description 1
- VEMKTZHHVJILDY-UXHICEINSA-N bioresmethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UXHICEINSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 150000002019 disulfides Chemical class 0.000 description 1
- 239000012990 dithiocarbamate Substances 0.000 description 1
- 150000004659 dithiocarbamates Chemical class 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000008393 encapsulating agent Substances 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000005745 ethoxymethyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])* 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 150000002462 imidazolines Chemical class 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 150000002917 oxazolidines Chemical class 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000003016 pheromone Substances 0.000 description 1
- 239000005648 plant growth regulator Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 125000005554 pyridyloxy group Chemical class 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000003128 rodenticide Substances 0.000 description 1
- 210000000998 shell membrane Anatomy 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 150000003548 thiazolidines Chemical class 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/20—After-treatment of capsule walls, e.g. hardening
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Medicinal Preparation (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US82374092A | 1992-01-22 | 1992-01-22 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IL104425A0 IL104425A0 (en) | 1993-05-13 |
| IL104425A true IL104425A (en) | 1996-10-31 |
Family
ID=25239596
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL10442593A IL104425A (en) | 1992-01-22 | 1993-01-18 | Reducing the content of formaldehyde in tiny capsule preparations |
Country Status (18)
| Country | Link |
|---|---|
| EP (1) | EP0623052B1 (enExample) |
| JP (1) | JPH07507001A (enExample) |
| KR (1) | KR100261629B1 (enExample) |
| CN (2) | CN1056724C (enExample) |
| AT (1) | ATE142904T1 (enExample) |
| AU (1) | AU660779B2 (enExample) |
| DE (1) | DE69304891T2 (enExample) |
| DK (1) | DK0623052T3 (enExample) |
| DZ (1) | DZ1660A1 (enExample) |
| EG (1) | EG20408A (enExample) |
| ES (1) | ES2091598T3 (enExample) |
| GR (1) | GR3021078T3 (enExample) |
| HU (1) | HU214297B (enExample) |
| IL (1) | IL104425A (enExample) |
| MX (1) | MX9300336A (enExample) |
| TN (1) | TNSN93008A1 (enExample) |
| TR (1) | TR26610A (enExample) |
| WO (1) | WO1993014865A1 (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6544540B2 (en) | 1998-07-29 | 2003-04-08 | Syngenta Limited | Base-triggered release microcapsules |
| WO2001096260A1 (en) * | 2000-06-14 | 2001-12-20 | Chisso Corporation | Method for producing coated bioactive granule |
| KR100374772B1 (ko) * | 2000-11-02 | 2003-03-04 | 애경화학 주식회사 | 저점도 메톡시 메틸 멜라민 수지의 제조방법 |
| KR100367970B1 (ko) * | 2000-12-01 | 2003-01-24 | 애경화학 주식회사 | 알콜그룹으로 에테르화된 알콕시 메틸 멜라민 수지의제조방법 |
| KR100634492B1 (ko) | 2004-03-30 | 2006-10-17 | 임대우 | 잔류 포름알데히드를 저감시킨 마이크로캡슐 및 이를이용하여 제조된 원단 |
| US20070138673A1 (en) * | 2005-12-15 | 2007-06-21 | Kaiping Lee | Process for Preparing a High Stability Microcapsule Product and Method for Using Same |
| ES2864019T3 (es) | 2006-03-30 | 2021-10-13 | Fmc Corp | Microencapsulación de Clomazona por medio de un proceso de refinado y microcápsulas específicas producidas de la misma |
| US9206381B2 (en) | 2011-09-21 | 2015-12-08 | Ecolab Usa Inc. | Reduced misting alkaline cleaners using elongational viscosity modifiers |
| US9637708B2 (en) | 2014-02-14 | 2017-05-02 | Ecolab Usa Inc. | Reduced misting and clinging chlorine-based hard surface cleaner |
| ES2809023T3 (es) | 2016-05-23 | 2021-03-02 | Ecolab Usa Inc | Composiciones desinfectantes, de higienización, de limpieza ácida con reducción de la formación de neblina a través del uso de polímeros de emulsión de agua en aceite de alto peso molecular |
| EP3464541B1 (en) | 2016-05-23 | 2020-04-29 | Ecolab USA Inc. | Reduced misting alkaline and neutral cleaning, sanitizing, and disinfecting compositions via the use of high molecular weight water-in-oil emulsion polymers |
| CN110392528A (zh) | 2017-03-01 | 2019-10-29 | 埃科莱布美国股份有限公司 | 通过高分子量聚合物减少吸入危险的消毒剂和杀菌剂 |
| CA3146010C (en) | 2019-07-12 | 2024-06-04 | Ecolab Usa Inc. | Reduced mist alkaline cleaner via the use of alkali soluble emulsion polymers |
| KR102662265B1 (ko) * | 2022-04-06 | 2024-04-30 | 애경케미칼주식회사 | 암모니아 및 자일렌을 이용한 아미노-포름알데하이드 수지 잔류 포름알데하이드의 고효율 제거방법 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4046741A (en) * | 1976-02-17 | 1977-09-06 | Stauffer Chemical Company | Post-treatment of polyurea microcapsules |
| US4305838A (en) * | 1978-09-27 | 1981-12-15 | Kanzaki Paper Manufacturing Company, Limited | Process for removing aldehyde from dispersions of microcapsules |
| US4956129A (en) * | 1984-03-30 | 1990-09-11 | Ici Americas Inc. | Microencapsulation process |
| ATE30522T1 (de) * | 1984-03-30 | 1987-11-15 | Stauffer Chemical Co | Mikrokapseln und verfahren zur mikroeinkapselung. |
| EP0188807B2 (de) * | 1984-12-24 | 1993-05-26 | Papierfabrik August Koehler AG | Verfahren zur Mikroverkapselung von Ölen mit darin gelösten Farbreaktionspartnern, danach hergestellte Mikrokapseln und deren Verwendung in Farbreaktionsaufzeichnungssystemen |
| JPS644242A (en) * | 1987-06-24 | 1989-01-09 | Toa Gosei Chem Ind | Manufacture of microcapsule |
-
1993
- 1993-01-18 IL IL10442593A patent/IL104425A/en not_active IP Right Cessation
- 1993-01-20 DZ DZ930004A patent/DZ1660A1/fr active
- 1993-01-21 EP EP93904559A patent/EP0623052B1/en not_active Expired - Lifetime
- 1993-01-21 KR KR1019940702505A patent/KR100261629B1/ko not_active Expired - Fee Related
- 1993-01-21 ES ES93904559T patent/ES2091598T3/es not_active Expired - Lifetime
- 1993-01-21 JP JP5513316A patent/JPH07507001A/ja active Pending
- 1993-01-21 WO PCT/US1993/000531 patent/WO1993014865A1/en not_active Ceased
- 1993-01-21 AT AT93904559T patent/ATE142904T1/de not_active IP Right Cessation
- 1993-01-21 HU HU9402020A patent/HU214297B/hu not_active IP Right Cessation
- 1993-01-21 DE DE69304891T patent/DE69304891T2/de not_active Expired - Fee Related
- 1993-01-21 DK DK93904559.7T patent/DK0623052T3/da active
- 1993-01-21 AU AU35882/93A patent/AU660779B2/en not_active Ceased
- 1993-01-22 TN TNTNSN93008A patent/TNSN93008A1/fr unknown
- 1993-01-22 CN CN93101739A patent/CN1056724C/zh not_active Expired - Fee Related
- 1993-01-22 TR TR93/0067A patent/TR26610A/xx unknown
- 1993-01-22 MX MX9300336A patent/MX9300336A/es not_active IP Right Cessation
- 1993-01-22 CN CNB991243749A patent/CN1226921C/zh not_active Expired - Fee Related
- 1993-01-23 EG EG4193A patent/EG20408A/xx active
-
1996
- 1996-09-19 GR GR960402270T patent/GR3021078T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE69304891D1 (de) | 1996-10-24 |
| CN1256071A (zh) | 2000-06-14 |
| KR100261629B1 (ko) | 2000-07-15 |
| EP0623052B1 (en) | 1996-09-18 |
| HU214297B (hu) | 1998-03-02 |
| GR3021078T3 (en) | 1996-12-31 |
| EP0623052A1 (en) | 1994-11-09 |
| CN1077083A (zh) | 1993-10-13 |
| AU660779B2 (en) | 1995-07-06 |
| AU3588293A (en) | 1993-09-01 |
| WO1993014865A1 (en) | 1993-08-05 |
| HUT68678A (en) | 1995-07-28 |
| DE69304891T2 (de) | 1997-02-06 |
| IL104425A0 (en) | 1993-05-13 |
| KR950700122A (ko) | 1995-01-16 |
| ATE142904T1 (de) | 1996-10-15 |
| CN1226921C (zh) | 2005-11-16 |
| DK0623052T3 (enExample) | 1997-02-24 |
| EG20408A (en) | 1999-02-28 |
| JPH07507001A (ja) | 1995-08-03 |
| HU9402020D0 (en) | 1994-09-28 |
| CN1056724C (zh) | 2000-09-27 |
| DZ1660A1 (fr) | 2002-02-17 |
| MX9300336A (es) | 1993-07-01 |
| ES2091598T3 (es) | 1996-11-01 |
| TNSN93008A1 (fr) | 1994-03-17 |
| TR26610A (tr) | 1995-03-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FF | Patent granted | ||
| KB | Patent renewed | ||
| KB | Patent renewed | ||
| KB | Patent renewed | ||
| KB | Patent renewed | ||
| MM9K | Patent not in force due to non-payment of renewal fees |