IE80905B1 - Fungicidal seed treatment using phosphorous acid or its salts - Google Patents
Fungicidal seed treatment using phosphorous acid or its saltsInfo
- Publication number
- IE80905B1 IE80905B1 IE940516A IE940516A IE80905B1 IE 80905 B1 IE80905 B1 IE 80905B1 IE 940516 A IE940516 A IE 940516A IE 940516 A IE940516 A IE 940516A IE 80905 B1 IE80905 B1 IE 80905B1
- Authority
- IE
- Ireland
- Prior art keywords
- seeds
- phosphorous acid
- pvthium
- absence
- salt
- Prior art date
Links
- 150000003839 salts Chemical class 0.000 title claims abstract description 25
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 230000000855 fungicidal effect Effects 0.000 title claims description 12
- 208000031888 Mycoses Diseases 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 7
- 239000011149 active material Substances 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 17
- 241000196324 Embryophyta Species 0.000 claims description 16
- 235000013339 cereals Nutrition 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 241000209510 Liliopsida Species 0.000 claims description 8
- 239000000417 fungicide Substances 0.000 claims description 7
- 240000005979 Hordeum vulgare Species 0.000 claims description 6
- 235000007340 Hordeum vulgare Nutrition 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 239000004094 surface-active agent Substances 0.000 claims description 5
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 4
- 230000035784 germination Effects 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- -1 2-tetrahydrofuryl Chemical group 0.000 claims description 3
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 3
- LDVVMCZRFWMZSG-OLQVQODUSA-N (3ar,7as)-2-(trichloromethylsulfanyl)-3a,4,7,7a-tetrahydroisoindole-1,3-dione Chemical compound C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)Cl)C(=O)[C@H]21 LDVVMCZRFWMZSG-OLQVQODUSA-N 0.000 claims description 2
- 125000002941 2-furyl group Chemical group O1C([*])=C([H])C([H])=C1[H] 0.000 claims description 2
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical group O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 claims description 2
- BSYNRYMUTXBXSQ-UHFFFAOYSA-N Aspirin Chemical compound CC(=O)OC1=CC=CC=C1C(O)=O BSYNRYMUTXBXSQ-UHFFFAOYSA-N 0.000 claims description 2
- 235000007319 Avena orientalis Nutrition 0.000 claims description 2
- 244000075850 Avena orientalis Species 0.000 claims description 2
- 239000005745 Captan Substances 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims description 2
- 235000007164 Oryza sativa Nutrition 0.000 claims description 2
- 241000918585 Pythium aphanidermatum Species 0.000 claims description 2
- 241000209056 Secale Species 0.000 claims description 2
- 235000007238 Secale cereale Nutrition 0.000 claims description 2
- 239000005843 Thiram Substances 0.000 claims description 2
- 235000019714 Triticale Nutrition 0.000 claims description 2
- 241000209140 Triticum Species 0.000 claims description 2
- 235000021307 Triticum Nutrition 0.000 claims description 2
- 240000008042 Zea mays Species 0.000 claims description 2
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 claims description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 2
- 229960001138 acetylsalicylic acid Drugs 0.000 claims description 2
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 125000003277 amino group Chemical group 0.000 claims description 2
- 125000000852 azido group Chemical group *N=[N+]=[N-] 0.000 claims description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 2
- 229940117949 captan Drugs 0.000 claims description 2
- 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 claims description 2
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 claims description 2
- 201000010099 disease Diseases 0.000 claims description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims description 2
- RDYMFSUJUZBWLH-SVWSLYAFSA-N endosulfan Chemical compound C([C@@H]12)OS(=O)OC[C@@H]1[C@]1(Cl)C(Cl)=C(Cl)[C@@]2(Cl)C1(Cl)Cl RDYMFSUJUZBWLH-SVWSLYAFSA-N 0.000 claims description 2
- JLYXXMFPNIAWKQ-GNIYUCBRSA-N gamma-hexachlorocyclohexane Chemical compound Cl[C@H]1[C@H](Cl)[C@@H](Cl)[C@@H](Cl)[C@H](Cl)[C@H]1Cl JLYXXMFPNIAWKQ-GNIYUCBRSA-N 0.000 claims description 2
- JLYXXMFPNIAWKQ-UHFFFAOYSA-N gamma-hexachlorocyclohexane Natural products ClC1C(Cl)C(Cl)C(Cl)C(Cl)C1Cl JLYXXMFPNIAWKQ-UHFFFAOYSA-N 0.000 claims description 2
- 125000000842 isoxazolyl group Chemical group 0.000 claims description 2
- 229960002809 lindane Drugs 0.000 claims description 2
- 235000009973 maize Nutrition 0.000 claims description 2
- 125000004184 methoxymethyl group Chemical group [H]C([H])([H])OC([H])([H])* 0.000 claims description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 2
- 235000009566 rice Nutrition 0.000 claims description 2
- 229960002447 thiram Drugs 0.000 claims description 2
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 claims description 2
- 241000228158 x Triticosecale Species 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- 241000308375 Graminicola Species 0.000 claims 1
- 239000005906 Imidacloprid Substances 0.000 claims 1
- YXLXNENXOJSQEI-UHFFFAOYSA-L Oxine-copper Chemical compound [Cu+2].C1=CN=C2C([O-])=CC=CC2=C1.C1=CN=C2C([O-])=CC=CC2=C1 YXLXNENXOJSQEI-UHFFFAOYSA-L 0.000 claims 1
- 229940056881 imidacloprid Drugs 0.000 claims 1
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 claims 1
- RONFGUROBZGJKP-UHFFFAOYSA-N iminoctadine Chemical compound NC(N)=NCCCCCCCCNCCCCCCCCN=C(N)N RONFGUROBZGJKP-UHFFFAOYSA-N 0.000 claims 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims 1
- 239000011248 coating agent Substances 0.000 abstract description 7
- 238000000576 coating method Methods 0.000 abstract description 7
- 230000001681 protective effect Effects 0.000 abstract description 3
- 239000013543 active substance Substances 0.000 abstract 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 7
- 241000233639 Pythium Species 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 3
- 231100000674 Phytotoxicity Toxicity 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 230000000149 penetrating effect Effects 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- PPDBOQMNKNNODG-UHFFFAOYSA-N 5-[(4-chlorophenyl)methylidene]-2,2-dimethyl-1-(1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol Chemical compound C1=NC=NN1CC1(O)C(C)(C)CCC1=CC1=CC=C(Cl)C=C1 PPDBOQMNKNNODG-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000004495 emulsifiable concentrate Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 230000000885 phytotoxic effect Effects 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 238000009331 sowing Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 241000257303 Hymenoptera Species 0.000 description 1
- 241001231770 Pythium aristosporum Species 0.000 description 1
- 241001622888 Pythium vanterpoolii Species 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 241000534944 Thia Species 0.000 description 1
- 150000001412 amines Chemical group 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000008268 mayonnaise Substances 0.000 description 1
- 235000010746 mayonnaise Nutrition 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000004550 soluble concentrate Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical class NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/26—Phosphorus; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/48—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
- C08G77/50—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms by carbon linkages
Abstract
The invention relates to a coating for seeds to protect them from fungal diseases which contains an inert and acceptable in agriculture carrier and at least one active substance chosen from the group consisting of a phosphorous acid and its salts and a method for applying this coating to seeds. The coating provides a good protective effect.[BY4699C1]
Description
Fungicidal seed treatment usino- iphosohoz-ous acid or its salts The present invention relates to the protection of monocotyledon plant seeds against attacks from fungal diseases.
It is known that it is possible to control fungal diseases of plants by foliar application of phosphorous acid and its derivatives (Patent GB X,459„539> but this application has not been used in 10 practice because of the phytotoxicity of compositions containing these ingredients (European Patent Application 230^209), It has now surprisingly been found that it is possible to obtain compositions having a good protective effect on seeds, and plants resulting from the germination of these seeds, by .protecting the seeds with phosphorous acid or a derivative thereof,, without this protection being disturbed by excessive phytotoxicity.
The present invention accordingly provides seeds of monocotyledon plants comprising as fungicide from 5 to 500 g/q of phosphorous acid or a salt.thereof in the absence of 2-(4-chlorobenzylidene)-5,5-dimethyl-l-(1H1,2,4-triazol-l-ylmethyl)-l-cyclopentanol and in the absence of compounds of formula wherein R represents methyl, chloro, nitro or azido, W represents -CH (CH3) COOCH3 or in which X represents CH or N, Y represents methoxymethyl, chloromethyl, cyclopropyl, 2furyl, 2-tetrahydrofuryl, isoxazolyl or benzyl, and m represents 1 or 2, or, when R represents chloro in the meta-position relative to the amino group and at the same time w represents a butyrolactone ring, m represents 0, 1 or 2 .
As used herein, the term seeds includes any generative part (propagation material) of the plant which can be used for the reproduction of the latter. This includes not only seed grains (seeds within the narrow meaning), but also artificial seeds such as, for example, those described in Patent Applications FR 9305192 or PCT/FR 91/00984 (published under the number WO 92/10087).
The seeds may be natural or artificial seeds of monocotyledon plants.
The presence of another fungicide is not necessary, and in particular the triasole 2-(4chlorobenzylidene)~5,5~fii»efchyl-’3.-{lH-l,2,4-fcriaz0X-X~ ylmethyl) -X-cyclopentanol (the use of whxch with a second fungicide which aiay be inter alia phosphorous acid or a phosphite salt is described in European specification No. 467792) is not used, but the presence of other fungicides is optional as described below.
Phosphorous acid, also known as phosphonic acid, has the formula H-p(o$ 2 (.abbreviated as H3PO3J . Its salts are known as phosphites, and can be Mono- or dxsalts, preferably alkali metal or ammomwa salts, in particular Na2HPO3„ K2SPO3 or NH4H2PO3.
On a practical level, the effective amount of phosphorous acid or salt thereof is generally between 5 and 500 g/q (q is the abbreviation of quintal = 100 kg).
The seed grains comprise a proportion of 5 to 5 500 g of active material per quintal of seed grain and preferably 5 to 300 g/quintal, preferably applied by coating.
The active material of phosphorous type is preferably chosen such that its solubility in water at 20’C is greater than 0.1 g/1, more preferentially still greater than 0.,5 g/1 and more preferentially still greater than 50 g/l„ Active materials-of lower solubility can also be used but it is then necessary to use fairly complicated formulations, for example wettable powders IS or aqueous suspensions. The use of active materials of sufficiently high solubility as it has just been defined is advantageous in that it makes it possible to treat seeds using simple solutions,, which is extremely economic.
The invention further provides young plants resulting from the germination of the seeds which have just been defined, these young plants being at the one- or twoleaf stage.
That such young plants are obtained is all 25 the more remarkable since it could be expected that the residual phosphorous acid has a phytotoxic effect with respect to plants resulting from the germination, in the same way that it had a phytotoxic effect in foliar treatment.
The Invention Is particularly advantageous la protecting, against fungal diseases, seeds corresponding to crops.included in the group comprising cereals, ia particular wheat, barley, rye, winter barley, oats, triticale, maize or rice., The invention is particularly advantageous in protecting seeds against * diseases belonging to the group comprisIng Pythium arrhenoaaaes, Pythium qramxnicola, Pythium toruiosna, Pythium vanterpoolii, Pythium myriotvlum,, Pythium periiluai, Pythium aristosporum, Pythium aphanidennatum. * damping-off, *' root rot, * young plant collar rot.
The invention further provides the use of a fungicidal composition comprising: at least one active material chosen from phosphorous acid and its salts, at least one inert vehicle which is acceptable in agriculture, and a surface-active agent which is acceptable in agriculture, in the absence of 2-(4-chlorobenzylidene)-5,5dimethyl-l-(1H-I,2,4-triazol-l-ylmethyl)-1-cyclopentanol and in the absence of compounds of formula (I) as hereinbefore defined, for protecting seeds of monocotyledon plants against fungal diseases, wherein the phosphorous acid or salt thereof is applied to the seeds in an amount of from 5 to 500 g/q.
The compositions used in the invention commonly contain between 0.5 and 95% (by weight) of active material of phosphorous type. Preferably, the amount of active material of phosphorous type in these treatment formulations is greater than 5% (by weight).
The present invention also provides a method for protecting seeds of monocotyledon plants against fungal diseases, which comprises applying thereto from 5 to 500 g/q of phosphorous acid or a salt thereof in the absence of 2-(4-chlorobenzylidene)-5,5-dimethyl-l-(1H1,2,4-triazol-l-ylmethvl)-l-cyclopentanol and in the absence of compounds of formula (I) as hereinbefore defined and/or applying thereto an amount of a fungicidal composition as defined above which is effective to apply from 5 to 500 g/q of phosphorous acid or a salt thereof. According to this method of the invention, application of the fungicidal active material of phosphorous type is carried out using compositions comprising at least 5% of active material of phosphorous type, preferably at least %.
In the present account, the term vehicle denotes a natural or synthetic, organic or inorganic material with which the active material is combined to facilitate its application to the seed., This vehicle is thus generally inert and it must to® acceptable ia agriculture, especially on the treated seed. Th© vehicle can be solid (clays, natural or synthetic silicates, silica, resins, waxes, solid fertilizers and the like) or, preferably, liquid (water, alcohols, ketones, petroleum fractions, aromatic or paraffinic hydrocarbons, chlorinated hydrocarbons# and the like)„ As has bees said above, liquid vehicles are preferred, is, particular1 those in which the phosphorous active material is soluble, sore especially water and aqueous solutioas.
The surface-active agent ear be as emulsifying# dispersing or wetting agent of ionic or noaioaic type. There say be mentioned# for example, salts of polyacrylic acids# salts of ligaosulphoaic acids# salts of phenolsulphoaie or naphthalenesulphoaic acids# polycoadeasafces of ethylene oxide with fatty .alcohols or with fatty acids or with fatty amines# substituted phenols (especially alkylphenols ©r arylphenols), salts of esters of sulphosuecinic acids, taurine derivatives (especially alkyltauratas), or phosphoric esters of polyoxyethylenated phenols or alcohols. The presence of at least one surface-active agent is often required.
These compositions can also contain any kind of other ingredients such as# for example, protective colloids, adhesives# thickening agents# thixotropic agents# penetrating agents# stabilising agents# sequestering agents# pigments, dyes or polymers.
More generally, the compositions used in the invention can he combined with all the solid or liquid additives corresponding to the conventional formulating techniques for application of seed treatment in particular. 7a While oa this sub j act f, it will Jsa noted that# is the vocabulary of fcho«e «killed is the »rt, the hara seed treatment is faat naialy relates to the treatnemt of seed grains.
Tb· application techniques are well known te those «killed is the art and they can he used without disadvantage in the context o *tpjhr,<® tje* reseat invention.
Mention nay be sa&a, fox example# of fila— coating ©r coating. Coating is preferred is the invention becanse of its siaplicityj it is sufficient te stir or six the seed to he treated with the fungicidal cospoaitioa® according to the invention.
Asoug the seapositiess# «olid or liquid coxspesifcioaa nay generally be mentioned.
IS There nay ba nastiaaed# as fexss of ligaifi coBpoeitioa» ar those intended to constitute liquid cosaaaaitioas at the tine of application# solutions„ in particular water-solnble ecneestratw» # aanlsifiable cosaeatratas # «wsXeieae # «ascension eeaceatratae ©r 0 wettable powders (or powder to he sprayed J. · The enulaifiahle or soluble concentrates ao*t often ccisapri»* i© to 90% of active material while eanlsioa® or eolations ready for application contain, far their port, o.ox to 20% of active material.
Tar in addition tc the solvent# the emulsifiable concentrates e«s contain# when thia is necessary, 2 to 20% of suitable additives «uch as, stabilising agents# surface-active agents# penetrating srxitH is agents# corrosion inhibitors,, dyes or the abovementioned adhesives.
From these concentrates, it is possible to obtain, by dilution'with water, emulsions of any desired concentration, which are particularly suitable for application to· seeds..
The wettable powders (or powder to be sprayed) are generally prepared se that they contain 2© to §<5% off active material, aad they generally contain, ia addition to the solid vehicle, ffrcsa 0 to 5% off a wetting agent, from 3 to io% off a dispersing agent .and, whan this is necessary, from o to io% off one or more stabilising agents and/or other additives, such as pigments, dyes, penetrating agents, adhesives, antidumping agents, and the like.
As has already been said, aqueous dispersions and -.emulsions, for example the compositions obtained ay diluting a wettable powder or aa emulsifiable concentrate according to the invention with water, may be used in the present invention. Emulsions can he off the water-in—oil or oilin-water type and they can have a thick consistency, like that of a «mayonnaise.
Among these compositions, a person skilled in the art will advantageously choose that or those which are suitable depending on the conditions sf use. la the invention, the phosphorous derivative can be used alone er as a mixture, in particular with fungicides or insecticides, especially captan, thiram, aspirin or Its salts and esters, salicylic acid or Its salts asd esters, guazatxae, cssiae-copper, tefXutbrxa or anthraquinone, and insecticides such as S xmidaclcprid, lindane and endosulfan, as well as mixtures of these various products.
The following Examples illustrate the invention.
Bxamgle 1 100 g of barley seed grains were treated with 1.5 ml of an aqueous phosphorous acid or sodium aonophosphite (MaH2PO3) solution. The concentration of the treatment solution was calculated so as to obtain, on the seed, the dosage (ia g/q) of product shown in the Table below. For a dosage of loo g/q, the concentration of phosphorous acid in the water was 75 g/1.
The treatment was carried out by simple aixxag/stxrring, for 1 min, so as to obtain seeds comprising various concentrations of phosphorous acid as shows, in the Table below.
These seed grains ware deposited in pots containing a mixture of peat and pozsolana- One millilitre of gythium mycelium ground preparation was inoculated into each pot by spraying the earth. There were approximately 20 seed grains per pot.
The seed grains germinated and, is days after sowing, the state of the plants was observed with xs respect to control seed grains not treated with phosphorous acid and with, respect to control seed grains not inoculated with gythiua» All the plants which had survived had two leaves. So phytotoxicity was observed in any case® The results were the followings Fungicidal Dose in Efficiency expr eased as agent g/q percentage * ^5fW Pvthiua arrhenosaanes ml ·» μ» wiw -%*J W *' ato b-—·^ «·* «5«>b <0· «Μ ttaavulλΛ ·λΑλλμ,ΧλΑriu. vHJ n^?,23l so ¢0 40 add 100 100 so Sodium 1Q0 75 20 «η 4* ;£&> 'Iff <£5) Up»Cp 200 100 70 400 10'0 100 seo 100 100 Untreated e 0 Q control inoculated with Pwthiuss i'TeZ the nusher of surviving treated seedlings expressed as a percentage of the number of surviving seedlings which had received neither the fungicidal agent nor the inoculation with gvthiua.
Bsarale 2 i ι Barley seed grains were treated, as in pie X, with aqueous dipotassiua phosphite solution.
To obtain a dosage of 240 g/q ©f product oa the seeds, 10© g of seeds were treated with 1.5 ml of a solution containing ss g/1 of KgHPO3.
The seed grains thus treated were sown is as open field and the state of the crop was observed 72 days after sowing with respect to an untreated control® Both crops were affected by fungal attacks io cf T'vthl'as arrhenomanes. As compared with the untreated plants, the plants treated according to the invention contained 2.8 times sore roots and were greater in number by 24.3%. The weight of dry matter off the roots cf the treated plants compared with the untreated plants was greater by 39%.
Claims (15)
1. Seeds of monocotyledon plants comprising as fungicide from 5 to 500 g/q of phosphorous acid or a salt thereof in the absence of 2-(4-chlorobensylidene)-5,5dimethyl-1-(1H-1,2,4-triazol-l-ylmethyl)-1-cyclopentanol and in the absence of compounds of formula ('CH3)j?a 0) wherein R represents methyl, chloro, nitro or azido, W represents -CH (CH 3 ) COOCH 3 or in which X represents CH or N, Y represents methoxymethyl, chloromethyl, cyclopropyl, 2furyl, 2-tetrahydrofuryl, isoxazolyl or benzyl, and m represents 1 or 2, or, when R represents chloro in the meta-position relative to the amino group and at the same time W represents a butyrolactone ring, m represents 0, l or 2 .
2. Seeds according to claim 1 which are cereal seeds . Seeds according to claim 2 which are seeds of 1
3. Wheat, barley, rye, winter barley, oats, triticale, maize or rice.
4. Seeds according to any one of claims 1 to 3 which comprise phosphorous acid or an alkali metal or ammonium 5. Salt thereof.
5. Seeds according to any one of claims 1 to 3 which comprise a phosphorous acid .salt having a solubility in water at 20°C greater than 0.1 g/1.
6. Seeds according to claim 5 wherein the 10 phosphorous acid salt has a solubility in water at 20°C greater than 0.5 g/1.
7. Seeds according to any one of claims 1 to 6, which also comprise a second active material chosen from captan, thiram, guazatine, oxine-copper, imidacloprid, 15 lindane and endosulfan.
8. . Seeds according to any one of claims 1 to 6, which also comprise a second active material chosen from aspirin, its salts and esters and salicyclic acid and its salts and esters. 20
9. Method for protecting seeds of monocotyledon plants against fungal diseases, which comprises applying thereto from 5 to 500 g/q of phosphorous acid or a salt thereof in the absence of 2-(4-chlorobensyliaene)-5,5dimethyl-1- (1H-1,2,4-triazol-l-ylmethyl)-l-cyclopentanol 25 and in the absence of compounds of formula (I) as defined in claim 1.
10. Method according to claim 9 wherein the fungal disease is III.HHJ-XXIU.-a. J·^·. ΐ 4 a disease caused by Pvthium arrhenomanes. Pvthium graminicola. Pvthium torulosutn. Pvthium vanterpoolii, Pvthium myriotvlum. Pvthium periilum. Pvthium aristosporum. or Pvthium aphanidermaturn damping-off, root rot, or young plant collar rot.
11. Young plants, resulting from the germination of seed according to any one of claims 1 to 8.
12. Use of a fungicidal composition comprising: at least one active material chosen from phosphorous acid and its salts, at least one inert vehicle which is acceptable in agriculture, and a surface-active agent which is acceptable in agriculture, in the absence of 2-(4-chlorobensvlidene)-5,5dimethyl-l-(1H-1,2,4-triazol-l-ylmethyl)-1-cyclopentanol and in the absence of compounds of formula (I) as defined in claim 1, for protecting seeds of monocotyledon plants against fungal diseases, wherein the phosphorous acid or salt thereof is applied to the seeds in an amount of from 5 to 500 g/q.
13. Use according to claim 12, wherein the composition contains between 0.5 and 95% by weight of the said active material.
14. Use according to claim 12 or 13, wherein the inert vehicle is liquid. S 5
15. Use according to claim 14 wherein the inert vehicle is water.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9307866A FR2706736B1 (en) | 1993-06-23 | 1993-06-23 |
Publications (2)
Publication Number | Publication Date |
---|---|
IE940516A1 IE940516A1 (en) | 1994-12-28 |
IE80905B1 true IE80905B1 (en) | 1999-06-16 |
Family
ID=9448642
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IE940516A IE80905B1 (en) | 1993-06-23 | 1994-06-22 | Fungicidal seed treatment using phosphorous acid or its salts |
Country Status (35)
Country | Link |
---|---|
JP (1) | JPH0759411A (en) |
KR (1) | KR100353181B1 (en) |
CN (1) | CN1051907C (en) |
AT (1) | AT406002B (en) |
AU (1) | AU679738B2 (en) |
BE (1) | BE1008436A5 (en) |
BR (1) | BR9401843A (en) |
CA (1) | CA2126656A1 (en) |
CH (1) | CH688601A5 (en) |
CO (1) | CO4340594A1 (en) |
CZ (1) | CZ287051B6 (en) |
DE (1) | DE4422025B4 (en) |
DK (1) | DK74494A (en) |
ES (1) | ES2070792B1 (en) |
FR (1) | FR2706736B1 (en) |
GB (1) | GB2279252B (en) |
GR (1) | GR940100307A (en) |
HR (1) | HRP940363B1 (en) |
HU (1) | HU214299B (en) |
IE (1) | IE80905B1 (en) |
IL (1) | IL110068A (en) |
IT (1) | IT1269941B (en) |
LU (1) | LU88502A1 (en) |
NL (1) | NL9401039A (en) |
NZ (1) | NZ260826A (en) |
PL (1) | PL303948A1 (en) |
PT (1) | PT101533B (en) |
RO (1) | RO113936B1 (en) |
RU (1) | RU2140728C1 (en) |
SE (1) | SE9402200L (en) |
SI (1) | SI9400260B (en) |
SK (1) | SK283983B6 (en) |
TW (1) | TW292964B (en) |
UA (1) | UA39171C2 (en) |
ZA (1) | ZA944509B (en) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GR1008462B (en) * | 1998-01-16 | 2015-04-08 | Novartis Ag, | Use of neonicotinoids in pest control |
CA2328300C (en) | 1998-04-16 | 2011-02-01 | Aventis Cropscience S.A. | Novel use of antifungal and/or antibacterial and/or antiviral compounds |
FR2777423A1 (en) * | 1998-04-16 | 1999-10-22 | Rhone Poulenc Agrochimie | Increasing plant physiological responses to elicitors using antifungal and/or antibacterial and/or antiviral agents |
AU2003241637B2 (en) * | 1998-04-17 | 2005-03-24 | Mattersmiths Holdings Limited | A biocidal composition containing phosphite ions |
AU3541499A (en) * | 1998-04-17 | 1999-11-08 | Mattersmiths Holdings Limited | A biocidal composition containing phosphite ions |
GB9902665D0 (en) * | 1999-02-05 | 1999-03-31 | Mandops Uk Ltd | Foliar fertiliser |
FR2819992B1 (en) * | 2001-01-31 | 2007-05-11 | Jean Louis Soyez | POTASSIUM ACIDIC PHOSPHITE FUNGICIDE COMPOSITION FOR THE CONTROL OF CRYPTOMATIC PLANT DISEASES, AND PROCESSING METHOD |
FR2819991B1 (en) * | 2001-01-31 | 2005-11-11 | Jean Louis Soyez | POTASSIUM ACID PHOSPHITE FUNGICIDE COMPOSITION FOR THE CONTROL OF CRYPTOGAMIC PLANT DISEASES AND METHOD OF TREATMENT |
WO2002076215A1 (en) * | 2001-03-19 | 2002-10-03 | Sankyo Company,Limited | Agricultural/horticultural compositions |
DE60331948D1 (en) * | 2002-12-04 | 2010-05-12 | Hokkai Sankyo Co Ltd | PROCESS FOR THE PROTECTION OF WHEAT FROM MYCOTOXIN FAILURE |
CL2007003747A1 (en) * | 2006-12-22 | 2008-07-18 | Bayer Cropscience Ag | PESTICIDE COMPOSITION INCLUDING FOSETIL-AL AND AN INSECTICIDE COMPOUND; AND METHOD FOR CONTROLLING FITOPATOGEN FUNDS OR DANIN INSECTICIDES OF THE PLANTS, CROPS OR SEEDS THAT INCLUDE APPLYING SUCH COMPOSITION. |
RU2538137C1 (en) * | 2013-11-27 | 2015-01-10 | Алексей Георгиевич Бородкин | AGENT FOR PROTECTION OF BULBS OF TULIPS, GLADIOLI AND MONTBRETIA AGAINST FUSARIOSE, GRAY MOULD AND FUNGUS Penicillium |
RU2607026C1 (en) * | 2015-10-30 | 2017-01-10 | Алексей Георгиевич Бородкин | Remedy for protection of bulbs of iris, hyacinth and daffodils from fungal diseases |
CN108849983A (en) * | 2018-08-01 | 2018-11-23 | 吉林省八达农药有限公司 | The purposes and crop seed inorganic agent and processing method of potassium phosphite |
RU2733902C1 (en) * | 2019-11-25 | 2020-10-08 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Кубанский государственный аграрный университет имени И.Т. Трубилина" | Method for increasing efficiency of presowing treatment of rice seeds with copper in conditions of krasnodar region |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TR19072A (en) * | 1973-11-26 | 1978-05-01 | Pepro | FUNGISID LEVELS WHICH REQUIRE PHOSPHORUS TILES |
US4119724A (en) * | 1973-11-26 | 1978-10-10 | Pepro | Fungicidal compositions containing phosphorous acid and derivatives thereof |
DE3702769A1 (en) * | 1987-01-30 | 1988-08-11 | Shell Agrar Gmbh & Co Kg | FUNGICIDAL AGENT |
FR2588448B1 (en) * | 1985-10-14 | 1987-11-20 | Rhone Poulenc Agrochimie | FUNGICIDE COMPOSITION BASED ON A DERIVATIVE OF PHOSHOROUS ACID AND PYROXYFUR |
EP0230209A3 (en) * | 1985-12-16 | 1987-08-12 | Ciba-Geigy Ag | Microbicides |
HU200062B (en) * | 1986-05-21 | 1990-04-28 | Mezoegazdasagi Gepgyarto Valla | Method for acidic-basic dressing seed-corns first rice seed-corn |
US4859466A (en) * | 1986-12-23 | 1989-08-22 | Ciba-Geigy Corporation | Microbicides |
FR2655816B1 (en) * | 1989-12-14 | 1994-04-29 | Rhone Poulenc Agrochimie | DISPERSABLE GRANULES OF FUNGICIDE PRODUCTS. |
FR2663196A1 (en) * | 1990-06-13 | 1991-12-20 | Rhone Poulenc Agrochimie | FUNGICIDE COMPOSITION BASED ON TRIAZOLE AND OTHER ACTIVE MATTER FOR SEED TREATMENT. |
US5206228A (en) * | 1991-10-29 | 1993-04-27 | Rhone-Poulenc Ag Company | Control of arthropod pests with phosphorous acid and mono-esters and salts thereof |
DE4142974C2 (en) * | 1991-12-24 | 1996-05-30 | Alexander Burkhart Gross Und E | Fungicidal compositions |
-
1993
- 1993-06-23 FR FR9307866A patent/FR2706736B1/fr not_active Expired - Fee Related
-
1994
- 1994-06-20 BE BE9400588A patent/BE1008436A5/en not_active Expired - Fee Related
- 1994-06-20 IL IL11006894A patent/IL110068A/en not_active IP Right Cessation
- 1994-06-21 HR HR940363A patent/HRP940363B1/en not_active IP Right Cessation
- 1994-06-22 BR BR9401843A patent/BR9401843A/en not_active IP Right Cessation
- 1994-06-22 CO CO94026984A patent/CO4340594A1/en unknown
- 1994-06-22 DK DK074494A patent/DK74494A/en not_active Application Discontinuation
- 1994-06-22 IE IE940516A patent/IE80905B1/en not_active IP Right Cessation
- 1994-06-22 CH CH01983/94A patent/CH688601A5/en not_active IP Right Cessation
- 1994-06-22 PL PL94303948A patent/PL303948A1/en unknown
- 1994-06-22 RU RU94021634A patent/RU2140728C1/en not_active IP Right Cessation
- 1994-06-22 SE SE9402200A patent/SE9402200L/en unknown
- 1994-06-22 AU AU64849/94A patent/AU679738B2/en not_active Ceased
- 1994-06-22 UA UA94005273A patent/UA39171C2/en unknown
- 1994-06-22 TW TW083105647A patent/TW292964B/zh not_active IP Right Cessation
- 1994-06-22 ES ES09401363A patent/ES2070792B1/en not_active Expired - Fee Related
- 1994-06-22 CZ CZ19941548A patent/CZ287051B6/en not_active IP Right Cessation
- 1994-06-22 GB GB9412469A patent/GB2279252B/en not_active Expired - Fee Related
- 1994-06-22 AT AT0123494A patent/AT406002B/en not_active IP Right Cessation
- 1994-06-22 LU LU88502A patent/LU88502A1/en unknown
- 1994-06-23 NL NL9401039A patent/NL9401039A/en active Search and Examination
- 1994-06-23 DE DE4422025A patent/DE4422025B4/en not_active Expired - Fee Related
- 1994-06-23 KR KR1019940014506A patent/KR100353181B1/en not_active IP Right Cessation
- 1994-06-23 NZ NZ260826A patent/NZ260826A/en not_active IP Right Cessation
- 1994-06-23 RO RO94-01093A patent/RO113936B1/en unknown
- 1994-06-23 SI SI9400260A patent/SI9400260B/en not_active IP Right Cessation
- 1994-06-23 PT PT101533A patent/PT101533B/en not_active IP Right Cessation
- 1994-06-23 SK SK759-94A patent/SK283983B6/en not_active IP Right Cessation
- 1994-06-23 CA CA002126656A patent/CA2126656A1/en not_active Abandoned
- 1994-06-23 IT ITMI941312A patent/IT1269941B/en active IP Right Grant
- 1994-06-23 JP JP6141735A patent/JPH0759411A/en active Pending
- 1994-06-23 HU HU9401897A patent/HU214299B/en unknown
- 1994-06-23 CN CN94107075A patent/CN1051907C/en not_active Expired - Fee Related
- 1994-06-23 GR GR940100307A patent/GR940100307A/en not_active IP Right Cessation
- 1994-06-23 ZA ZA944509A patent/ZA944509B/en unknown
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA2211105C (en) | Insecticidal combinations including an insecticide from the chloronicotinyl family and an insecticide having a pyrazole, pyrrole or phenylimidazole group | |
US5877194A (en) | Combinations of a fungicide containing an azole group with an insecticide containing a pyrazole, pyrrole or phenylimidazole group | |
IE80905B1 (en) | Fungicidal seed treatment using phosphorous acid or its salts | |
AP351A (en) | Mixed agrochemical combination. | |
GB2264641A (en) | Fungicidal compositions | |
CA2745619C (en) | Bioregulatory combination of active agents | |
EP0613619B1 (en) | Microbicides | |
JP3714692B2 (en) | Disinfectant composition | |
US5977156A (en) | Fungicidal pyrazoles | |
HU227789B1 (en) | Fungicide composition containing two triazole-derivatives as active ingredients and use thereof | |
US9034794B2 (en) | Method for post-emergence crabgrass control | |
SK47394A3 (en) | Method of improvement of growth and/or health of plants, especially cereals with acting of derivative of triazole type | |
FR2711893A1 (en) | Combination of a fungicide having an azole group with an insecticide having a pyrazole, pyrrole or phenylimidazole group |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
MM4A | Patent lapsed |