IE56617B1 - Process for washing clothes in a machine with a liquid detergent and device for applying the process - Google Patents
Process for washing clothes in a machine with a liquid detergent and device for applying the processInfo
- Publication number
- IE56617B1 IE56617B1 IE986/85A IE98685A IE56617B1 IE 56617 B1 IE56617 B1 IE 56617B1 IE 986/85 A IE986/85 A IE 986/85A IE 98685 A IE98685 A IE 98685A IE 56617 B1 IE56617 B1 IE 56617B1
- Authority
- IE
- Ireland
- Prior art keywords
- washing
- machine
- liquid
- drum
- clothes
- Prior art date
Links
- 238000005406 washing Methods 0.000 title claims abstract description 64
- 239000007788 liquid Substances 0.000 title claims abstract description 40
- 239000003599 detergent Substances 0.000 title claims abstract description 23
- 238000000034 method Methods 0.000 title claims abstract description 19
- 230000008569 process Effects 0.000 title claims abstract description 18
- 239000012263 liquid product Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 description 15
- 239000000203 mixture Substances 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000000047 product Substances 0.000 description 6
- -1 colourants Substances 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 239000002253 acid Substances 0.000 description 3
- 239000002671 adjuvant Substances 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000009987 spinning Methods 0.000 description 3
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005360 mashing Methods 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000000375 suspending agent Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920000388 Polyphosphate Chemical class 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 239000004067 bulking agent Substances 0.000 description 1
- 210000001217 buttock Anatomy 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 230000003165 hydrotropic effect Effects 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000001205 polyphosphate Chemical class 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F39/00—Details of washing machines not specific to a single type of machines covered by groups D06F9/00 - D06F27/00
- D06F39/02—Devices for adding soap or other washing agents
- D06F39/024—Devices for adding soap or other washing agents mounted on the agitator or the rotating drum; Free body dispensers
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Detergent Compositions (AREA)
- Detail Structures Of Washing Machines And Dryers (AREA)
- Treatment Of Fiber Materials (AREA)
Abstract
Process for washing clothes in a washing machine, which comprises using a liquid detergent which is released gradually into the washing medium from a special device placed in the drum of the machine at the same time as the clothes instead of being released from the dispenser provided for the detergent on the washing machine. The rechargeable device is a container provided with a filling orifice and with vents for the liquid. The container may be a flat-bottomed sphere or a ring.
Description
The present invention relates to a process for Mashing and cleaning clothes in a Mashing machine with a liquid detergent which is introduced gradually into the washing raediu® from a rechargeable device placed in the drum of the machine together with the clothes to be washed; , the invention also relates to the device for carrying out this process.
Liquid detergent compositions for washing clothes ί are commercially available» They have a variety of advan10 tageous properties compared with the numerous granular detergent compositions, but they have not become as widely used as might have been expected in view of their properties, because they are to some extent unsuitable for use in the majority of washing machines currently on the market» In fact, whether these machines are front loaders with a horizontal rotary drum, or top loaders, the dis= pensers for the measure of detergent used for each washing cycle are generally rather unsuitable for holding liquid detergents and subsequently dispersing them in the washing bath, the majority of the machines currently used by housewives in fact having been designed at a time when only powdered or granular detergents were on the raarketo The applicant Company has found that part of the liquid detergent composition placed in the dispenser of the machine before it is switched on 1s often unable to be used for the wash» In fact, the whole of the washing product is carried away with the first few ml of water Introduced Into the machine, and, in most cases, this water goes directly info filling the emptying circuits of the machine, in which the previous washing operation had only left «ί * very small quantity of water» , When the washing product has entered this circuit, virtually none of if will migrate info the washing bath with which the clothes are impregnated, either during the filling of the machine or during the actual wash, and it $ be eliminated with the first emptying operation» The losses, i»ee the unutilized washing product/ can be substantial, particularly in certain types of washing machine» Λ considerable proportion of the liquid composition placed in the dispenser provided for a solid washing product is not utilized* The magnitude of this loss depends especially on the volume of the emptying circuit upstream of the pump, the water inlet speed and the position of the water inlet point. One can understand that, in a number of cases, a method for washing in a machine using a liquid detergent is more costly than it ought to be, and it is not surprising that the housewife, unaware of the losses incurred, prefers not to use a liquid detergent despite its advantageous properties.
Thus, by making it possible to overcome these unavoidable losses, the present invention is particularly useful.
It relates to an improved process for washing and cleaning clothes in a washing machine of a common type, which comprises using a detergent in the liquid state, the viscosity of which is such that it can flow freely, even at room temperature. In this improved process, the said detergent is released progressively into the washing bath from a device placed in the drum of the machine together with the clothes to be washed, instead of being introduced from the dispenser provided by the washing machine manufacturer for holding the washing product.
According to the Invention there Is provided a process for treating laundry in a washing machine with 30 a liquid product contained in a device which is placed in the drum of the machine,with the laundry to be washed, it being possible for the said device to move freely inside the drum, after which the machine is started and the washing cycle is allowed to run, the treatment being the washing of the laundry, and this washing being performed with a liquid detergent contained in the said device, which has unclosed orifices, the detergent passing progressively into the laundry and the washing liquor as soon as the drum begins to rotate.
The process consists in pouring into an appropriate device a predetermined quantity ~ depending especially on the quantity of clothes to be cashed, the degree of soiling and the capacity of the machine - of a liquid detergent, then placing the device in the drum of the machine together uith the clothes to be uashed, and then switching on and allowing the usual uashing cycle of the machine to proceed; the device containing the washing product will preferably be placed towards the top of the tank, in the drum. Thus, as the drum in the majority of present-day washing machines does not start to rotate until the tank has filled, the device will only start to empty when it is in the presence of a sufficient quantify of water fo prevent prolonged contact of the dry or just da rap clothes with the concentrated detergent» However, if is also possible to place the device af the bottom of the drum, especially in the case where the drua starts to rotate as soon as the water is admitted, or even in the middle of the clothes» The housewife will have no difficulty in choosing the position best suited fo the particular circumstances of her wash» | When spinning has ended, the device is removed from the washing machine together with the clean clothes and put aside for subsequent use» This device, which is another subject of the invention, possesses af least one filling orifice, the dimensions of which are sufficient to enable the washing agent to be introduced easily, irrespective of its viscosity and the shape and mouth of the washing agent container» This orifice is provided with adapted closure means which can be movable and may or may not be fixed to the body of the device, including plugs, caps and the like, or can be a permanent fixture like funnels fixed around the neck of the orifice and entering the device, of which the length and diameter at the inner end are such that a liquid which has entered the device is practically unable fo come out again» Xt can be seen that, in the latter case, the? filling orifice can be Identical to one of the liquid vents with which the device must be provided» The number and shape of these liquid vents are not critical; it 1s possible to have a single vent, two to ten vents or a multitude of very small vents up to about 100; preference is given fo devices provided with two to four vents through which the liquid will be released gradually» The diameter of the vents is generally between 2 mm and 10 mm in the case of the devices which have from 2 to 0 of these» Xt is obvious that, as not all the Liquid vents are generally provided with closure systems, they roust be located above the maximum filling Level of the device; on the other hand, their respective positions are arbitrary» Those skilled in the art will be capable of determining, by means of routine experiments, the number of these vents β as e function of their shep^p their position and the viscosity of the liquid washing agent used, so that the whole of the said agent is discharged into the washing bath in about 1 fo 10 minutes, preferably in about 3 minutes* Sf is obviously necessary fo make allowances for the fact that, for a given device filled with a given washing agent, the emptying time will depend on the diameter of the drum $ of the machine in which if is used, its speed of rotation and even how full of clothes the drum is,, The device can be made of a variety of materials, which must be unbreakable and withstand temperatures up to about 100°Co A large number of synthetic polymers will be suitable, for example low density po lyethylene, poly^* propylene or other elastomers» Xn a preferred embodiment of the invention, the waLls of the device will be made of a transparent material or will have a transparent window so that the housewife can see the level which the liquid has reached in the device during the filling operation, in order fo avoid any in~ advertent overflow* Xn a preferred embodiment, the device carries reference marks indicating the volume of liquid introduced when the reference mark is reached; if will then be possible to use the same device for washing machines of different capacities or to adapt the quantify of washing agent fo the operation which is to be carried out» Furthermore, to eliminate any risk of premature wear on the clothes by rubbing, the device has a smooth outer surface and no sharp corners; its walls are relan tively stiff, however, so that the device is not made difficult to handle when full by the deformation of the walls resulting from the pressure exerted by the fingers gripping the device* Xn a preferred embodiment, the device will have a * sufficiently wide base for It to be perfectly stable and for if not to be knocked over by a clumsy movement, especially while it is being filled with the washing agent* I Means for fixing the device to the drum of the machine, such as suction discs or hooks, are provided in a variant of the device of the Invention» They make It possible to restrict the noise caused by the device rolling in the drum during the washing cycle and the rubbing of the device against the clothes during spinning; in any case,, the device is held against the walls of the drum with the clothes» V? Xn the clothes washing and cleaning process according to the invention, the device described above is fi lled with a liquid detergent with a viscosity which is gen10 ©rally between and 0o4 Pa This comprises the usual components, ieeo st Least one surface-active agent with a liquid vehicle, and, if appropriate, detergency adjuvants (builders), foais regulators, enzymes and enzyme stabilisers bleaching agents, soil suspending agents and textile con15 ditionerSo The liquid detergent compositions used in the washing process of the invention can also contain fluorescent brighteners, perfumes, colourants, opacifiers, antioxidants, bactericides, bulking agents and the like» The surface-active agents present in the compositions used in the process of the invention can be anionic, non-ionic, erapholytic or zwitterionic; wixtures of these can also be used» Examples of these surface-active agents are given in Patent Application EP-A-0,028,865; a cationic surface-active agent can also be added, as in the said patent application, page 5, line 32 to page 7, Line 21» The quantity of surface-active agents present in the liquid compositions is generally between 5« and 701? by weight of the whole, and if generally depends on whether or not defer gency adjuvants are present; if the latter are present, the quantify is smaller» Among the well-known adjuvants, there may be mentioned the alkali metal salts of phosphates and polyphosphates, of nitrilotriacetic acid and of citric 1 acid, or alternatively the synthetic zeolites.» The liquid vehicle of the composition can be wafer, an organic solvent such as aliphatic sonoalcohols and polyalcohols having up to ό carbon atoms and their ethers, or mixtures thereof» Among tho optional compounds in the liquid washing Β conposition, there way be mentioned the well-known sequestering agents such as polyacrylates, polymaleates and copolymers of unsaturated adds and methyl vinyl ether, and also soil suspending agents such as polyvinylpyrrolidone and the sodium salt of carbonymethyLcelLulose, hydrotropic agents such as salts of alkyLaryIsulphonic acids, and foam regulators such as C16 to C22 fatty acids and polysiloxanesr, A IL these compounds can be introduced Into v liquid washing compositions which can be used in the pro cess according to the invention, in variable quantities [ well known to the specialists Polydia IkyLsiloxanes can also be introduced into the Liquid washing compositions for their softening properties» The quantity of liquid washing agent used in the process according to the invention obviously depends on the composition of the agent, the nature and state of the clothes to be uashed and the capacity of the washing machine.
The devices according to the invention can contain from approximately 100 to 400 ml of Liquid and their total infernal volume will be from about 150 ml fo about 500 ml, but it is perfectly possible to design smaller devices for very effective washing agents or Larger devices for washing machines used in service enterprises» Different devices according fo the invention are described below, by way of examples, with reference fo the attached drawings: - Figure 1-1 is a plan view and figure 1-2 is a sectional view along the Line A-A of a device according to the invention, with its plug« - Figure 2 Is a sectional view of a device according fo the invention in the form of a flat-bottomed sphere, with a hinged lid and two liquid vents» θ Figure 5 is a sectional view of a device according to the invention in the form of a ring, with four * liquid vents» The device in Figure 1 has a maximum diameter of 105 mm and a height of 65 wa without the screw plug» The assembly 1 is siade of transparent polyethylene. The waLls have a thickness of Οθό ®ra„ The diameter of the filling s orifice 2 is 4>0 gem end the diameter of the two liquid vents 3 is 5 mm; the vents are 45 taw from the bottom of the container (distance measured vertically).» The body of the device carries two level marks & corresponding to volumes of 130 ml and 180 ml respect1welyo A wire ending in hooks, which can fit into the holes made in the surface ΐτ of the drums, may optionally be clamped around the neck of the device» The device in Figure 2 ia a hollow sphere of die10 meter @0 tais, which is truncated so that the container rests on a flat bottom, and of which the lockable lid 1 with a hinge 2 is in the shape of a spherical portion matching the shape of the sphere and the liquid introduction orifice 3 which has been made therein by cutting along a plane» The device, made of opaque polypropylene, has a transparent window 6 in which two volume marks 5 are drawn. The liquid vents 6, of which there are three, are located above the upper filling level» The device in Figure 3 is a hollow ring of enter20 nal diameter 6 cm and internal diameter 3 cm, in which a cm circular hole has been made in order to serve as the filling orifice 1» This orifice 1 is provided with a lid 2 having a hinge 3 and a locking device 4a Four orifices of diameter 3 ma are made in the upper part of the ring» EKAHPLE 1 Xn a specific example of how the process according to the invention is carried out, the device of the inven» tion shown in Figure 1 is filled with 220 ml of a liquid washing agent consisting ofs Percentage (by weight) sodium dodecylbenzenesulphonate (linear dodecyl) 11»3 triethanolamine a lkyI(copra)-sulphate 4»0 ethoxylated alcohol <£13-17; TCgH^O) 12e0 fatty add (C-jg *° l0«0 f oleic acid 5»0 diethyLenetri aminepentamethyIphosphoni c acid 0»$ ethanol 8«ύ fl. 0 propanediol 3»0 klaOH for a final pH of 7»7 secondary components The filled device Is placed in a commercial frontloading washing machine, on top of the clothes fo be washed, and the washing and spinning cycle is allowed to proceed normally» Af the end of the operation, the clothes and the device are removed from the machine» The device contains onty a few drops of water and can be put away for subsequent use» EXAMPLE 2 3.2 kg of clothes are introduced info a top-loading washing machine of 5 teg capacity, the drum of which starts to rotate while the tank is filling with wafer» Before the machine is closed, a device according to figure 1, filled wit 180 ml of a liquid washing agent of viscosity 0»12 Pa0S, is placed on the clofhesQ St is found that all the washing agent passes into the washing bath in 1 minute 30 seconds after the drum has started rotating, the complete machine cycle lasting about 50 mi nates.
ElUflPLE 3 A wash is carried out under the same conditions es in Example 2, but with a PHILIPS washing machine; in this case, the device releases the washing agent in 5 minutes» I 1
Claims (4)
1. CLAIMS;, 1» A process for treating laundry in a washing machine with a liquid product contained in a device which is placed in the drum of the machine, with the laundry to be washed, it being possible for the said device to move freely inside the drum, after which the machine is started and the washing cycle is allowed to run, the treatment being the washing of the laundry, and this washing being performed with a liquid detergent con tained in the said device, which has unclosed orifices, the detergent passing progressively into the laundry and the washing liquor as soon as the drum begins to rotate.
2. A process according to Claim 1, wherein a predetermined amount of liquid detergent is poured into the device, which has a filling orifice for this purpose, and wherein, at the end of washing the device is recovered and can be reused.
3. » A process according to one of Claims 1 or 2, wherein the device is placed towards the top of the drum filled with laundry.
4. » A process according to Claim 1, substantially as hereinbefore described*
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8406151A FR2563250B1 (en) | 1984-04-18 | 1984-04-18 | METHOD FOR WASHING LAUNDRY IN A MACHINE WITH A LIQUID DETERGENT, AND DEVICE FOR ITS APPLICATION |
Publications (2)
Publication Number | Publication Date |
---|---|
IE850986L IE850986L (en) | 1985-10-18 |
IE56617B1 true IE56617B1 (en) | 1991-10-09 |
Family
ID=9303280
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IE986/85A IE56617B1 (en) | 1984-04-18 | 1985-04-17 | Process for washing clothes in a machine with a liquid detergent and device for applying the process |
Country Status (14)
Country | Link |
---|---|
EP (1) | EP0151549B2 (en) |
JP (1) | JP2564263B2 (en) |
AT (2) | AT392096B (en) |
BE (1) | BE902094A (en) |
CA (1) | CA1243855A (en) |
CH (1) | CH653718A5 (en) |
DE (3) | DE8509911U1 (en) |
ES (2) | ES285826Y (en) |
FR (1) | FR2563250B1 (en) |
GB (1) | GB2157717B (en) |
GR (1) | GR850934B (en) |
IE (1) | IE56617B1 (en) |
IT (1) | IT1184370B (en) |
NL (1) | NL8500968A (en) |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2587001B1 (en) * | 1985-09-11 | 1990-02-09 | Procter & Gamble France | METERING AND DIFFUSER DEVICE, WHICH CAN BE INCORPORATED IN A CONTAINER, PARTICULARLY FOR LIQUID PRODUCTS |
DE3542504A1 (en) * | 1985-10-03 | 1987-06-04 | Miele & Cie | Metering cup for administering washing agent in a washing machine |
FR2606753B1 (en) * | 1986-06-30 | 1990-05-11 | Procter & Gamble France | DEVICE FOR DISPENSING POWDER LAUNDRY IN WASHING MACHINES |
JPS6341120A (en) * | 1986-08-08 | 1988-02-22 | Mitsui Petrochem Ind Ltd | Internal stabilizing body for manufacturing device of tubular film |
FR2612955B1 (en) * | 1987-03-25 | 1989-07-28 | Procter & Gamble | METHOD FOR WASHING LAUNDRY AND CONTAINER FOR IMPLEMENTING SAME |
FR2617138B1 (en) * | 1987-03-25 | 1989-11-03 | Procter & Gamble | MULTI-COMPARTMENT CONTAINER FOR SINGLE USE, OBTAINING AND APPLYING, PARTICULARLY FOR WASHING LAUNDRY |
FR2628451B2 (en) * | 1987-05-06 | 1991-08-30 | Procter & Gamble | PROCESS FOR WASHING AND SOFTENING MACHINE LAUNDRY |
FR2627198B1 (en) * | 1988-02-11 | 1990-08-03 | Procter & Gamble | IMPROVED MACHINE WASHING PROCESS |
EP0331542B1 (en) * | 1988-02-03 | 1996-05-08 | The Procter & Gamble Company | Method and device for washing laundry in a washing machine |
FR2627199B1 (en) * | 1988-02-11 | 1990-08-03 | Procter & Gamble | DEVICE FOR WASHING LAUNDRY IN A MACHINE |
US4835804A (en) * | 1988-03-25 | 1989-06-06 | The Procter & Gamble Company | Multiple compartment container laundering method |
FR2641551B2 (en) * | 1988-05-18 | 1991-11-22 | Procter & Gamble | METHOD AND DEVICE FOR WASHING LAUNDRY IN A MACHINE WITH A PARTICULATE PRODUCT |
FR2631639B1 (en) * | 1988-05-18 | 1991-06-21 | Procter & Gamble | METHOD FOR WASHING LAUNDRY IN A MACHINE WITH A PARTICULATE PRODUCT AND DEVICE FOR IMPLEMENTING SAME |
FR2631640B1 (en) * | 1988-05-18 | 1990-08-31 | Procter & Gamble | METHOD AND DEVICE FOR WASHING LAUNDRY IN A MACHINE WITH A PARTICULATE PRODUCT |
DE3906030A1 (en) * | 1989-02-27 | 1990-08-30 | Andreas Paetau | Contact-delaying container for operating a washing machine with liquid soap |
FR2669944B1 (en) * | 1990-11-30 | 1994-02-04 | Procter & Gamble | DEVICE FOR WASHING LAUNDRY IN A MACHINE AND METHOD OF IMPLEMENTING SAME. |
US5388298A (en) * | 1990-11-30 | 1995-02-14 | The Procter & Gamble Company | Device for the machine washing of clothes and the method of utilizing said device |
FR2669943B1 (en) * | 1990-11-30 | 1994-02-11 | Procter And Gamble Cy | EQUIPMENT FOR THE WASHING OF LAUNDRY IN A MACHINE AND ITS METHOD OF IMPLEMENTATION. |
GB2255985A (en) * | 1991-04-04 | 1992-11-25 | Unilever Plc | Detergent dispenser |
IT1254893B (en) * | 1992-04-21 | 1995-10-11 | DISPENSING DEVICE FOR DETERGENTS | |
IT228562Y1 (en) * | 1992-06-26 | 1998-04-27 | Mira Lanza S P A Ora S R L | DISPENSER-DISPENSER FOR LIQUID DETERGENT FOR WASHING MACHINES. |
EP0872544A1 (en) | 1997-04-14 | 1998-10-21 | The Procter & Gamble Company | Dry effervescent granules and granular compositions comprising the same |
WO1999024654A1 (en) * | 1997-11-06 | 1999-05-20 | Mendiola Gonzalez Jose Francis | Reusable device for the cleaning of textile materials and the like |
EP1072715A1 (en) | 1999-07-19 | 2001-01-31 | The Procter & Gamble Company | A dispensing device for a detergent tablet |
US6955067B2 (en) * | 2002-03-28 | 2005-10-18 | The Procter & Gamble Company | Smart dosing device |
US6996869B2 (en) * | 2002-11-25 | 2006-02-14 | Ecolab, Inc. | Dispensing cartridge and method of dispensing a product from a dispensing cartridge |
EP1813708B1 (en) * | 2006-01-31 | 2019-02-20 | The Procter and Gamble Company | Dosing and dispensing device |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US326185A (en) * | 1885-09-15 | Dentist s or photographer s chair | ||
US2941309A (en) * | 1956-12-13 | 1960-06-21 | Whirlpool Co | Clothes dampener for clothes driers |
US3095722A (en) * | 1961-06-02 | 1963-07-02 | Donald L Fox | Device for dispensing water or fabric conditioning substances in clothes washers |
US3108722A (en) * | 1961-09-19 | 1963-10-29 | Procter & Gamble | Dispenser for fabric softener |
US3174647A (en) * | 1962-04-09 | 1965-03-23 | Morris Nison | Free body dispensers |
US3180538A (en) * | 1963-04-24 | 1965-04-27 | Elwood B Brown | Automatic fluid dispenser |
US3400808A (en) * | 1966-03-01 | 1968-09-10 | Colgate Palmolive Co | Combination dispensing and measuring vessel |
US3399806A (en) * | 1967-05-01 | 1968-09-03 | Procter & Gamble | Delayed opening dispenser |
US4014105A (en) * | 1970-10-20 | 1977-03-29 | Colgate-Palmolive Company | Article, apparatus and method for conditioning fibrous materials with liquid conditioning composition |
AU3394971A (en) * | 1970-10-20 | 1973-04-05 | Colgate Palmolive Co | Conditioning of fabrics |
JPS5147412U (en) * | 1974-10-05 | 1976-04-08 | ||
CA1112004A (en) * | 1976-07-12 | 1981-11-10 | Emiel M. Demessemaekers | Fabric treating articles and process |
US4260054A (en) * | 1980-02-11 | 1981-04-07 | Lever Brothers Company | Laundry additive pouch |
US4356099A (en) * | 1980-05-16 | 1982-10-26 | Lever Brothers Company | Fabric treatment products |
-
1984
- 1984-04-18 FR FR8406151A patent/FR2563250B1/en not_active Expired
-
1985
- 1985-04-02 DE DE8509911U patent/DE8509911U1/en not_active Expired
- 1985-04-02 ES ES1985285826U patent/ES285826Y/en not_active Expired
- 1985-04-02 BE BE0/214769A patent/BE902094A/en unknown
- 1985-04-02 GB GB08508600A patent/GB2157717B/en not_active Expired
- 1985-04-02 DE DE19853512050 patent/DE3512050A1/en not_active Withdrawn
- 1985-04-02 AT AT0098885A patent/AT392096B/en not_active IP Right Cessation
- 1985-04-02 EP EP85400652A patent/EP0151549B2/en not_active Expired - Lifetime
- 1985-04-02 ES ES541873A patent/ES9100004A1/en not_active Expired
- 1985-04-02 IT IT20202/85A patent/IT1184370B/en active
- 1985-04-02 AT AT85400652T patent/ATE44987T1/en not_active IP Right Cessation
- 1985-04-02 DE DE8585400652T patent/DE3571842D1/en not_active Expired
- 1985-04-02 CH CH1426/85A patent/CH653718A5/en not_active IP Right Cessation
- 1985-04-02 NL NL8500968A patent/NL8500968A/en not_active Application Discontinuation
- 1985-04-16 CA CA000479281A patent/CA1243855A/en not_active Expired
- 1985-04-17 GR GR850934A patent/GR850934B/el not_active IP Right Cessation
- 1985-04-17 IE IE986/85A patent/IE56617B1/en not_active IP Right Cessation
- 1985-04-18 JP JP60083585A patent/JP2564263B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
ATA98885A (en) | 1990-07-15 |
ES285826Y (en) | 1986-06-01 |
IE850986L (en) | 1985-10-18 |
ES9100004A1 (en) | 1990-07-01 |
IT8520202A0 (en) | 1985-04-02 |
JPS6133695A (en) | 1986-02-17 |
DE3512050A1 (en) | 1985-10-31 |
EP0151549A3 (en) | 1985-11-06 |
CH653718A5 (en) | 1986-01-15 |
FR2563250B1 (en) | 1986-12-26 |
IT1184370B (en) | 1987-10-28 |
DE8509911U1 (en) | 1985-06-20 |
GB2157717A (en) | 1985-10-30 |
BE902094A (en) | 1985-10-02 |
EP0151549A2 (en) | 1985-08-14 |
FR2563250A1 (en) | 1985-10-25 |
GR850934B (en) | 1985-07-18 |
GB2157717B (en) | 1987-05-07 |
EP0151549B1 (en) | 1989-07-26 |
AT392096B (en) | 1991-01-25 |
DE3571842D1 (en) | 1989-08-31 |
ATE44987T1 (en) | 1989-08-15 |
CA1243855A (en) | 1988-11-01 |
ES285826U (en) | 1985-11-01 |
NL8500968A (en) | 1985-06-03 |
JP2564263B2 (en) | 1996-12-18 |
EP0151549B2 (en) | 1995-10-04 |
GB8508600D0 (en) | 1985-05-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
IE56617B1 (en) | Process for washing clothes in a machine with a liquid detergent and device for applying the process | |
AU601070B2 (en) | Solid block wash chemical | |
US4687121A (en) | Solid block chemical dispenser for cleaning systems | |
US5129120A (en) | Process for washing fabrics in a machine | |
CA1269070A (en) | Combined closure and measuring device | |
US5262132A (en) | Solid detergent dispensing system | |
AU2011239759B2 (en) | Gradual -release dosing device and seal of a domestic-use apparatus | |
EP0559829A1 (en) | Device for the machine washing of clothes and the method of utilizing said device. | |
JPH10512836A (en) | Combination of containers and soap products | |
US9650739B2 (en) | Gradual-release dosing device and seal of a domestic-use apparatus | |
AU619737B2 (en) | Process for washing linen and container for implementing it | |
GB2402679A (en) | Automatic washing machine detergent dispensing device | |
EP0346113B2 (en) | Washing process | |
JP7256136B2 (en) | METHOD AND SYSTEM FOR REDUCING VARIATION IN AUTOMATIC LOADING AMOUNT OF AUTOMATIC WASHER | |
US6095380A (en) | Dosing device for a highly viscous liquid | |
JPH1052321A (en) | Partially washing liquid detergent product | |
EP0637346A1 (en) | Device for treating textile articles. | |
US5176292A (en) | Combined closure and measuring device | |
WO2015185432A1 (en) | Laundry fluid dispensing product |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
MM4A | Patent lapsed |