IE43164B1 - Liquid fine washing agent - Google Patents

Liquid fine washing agent

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Publication number
IE43164B1
IE43164B1 IE1414/76A IE141476A IE43164B1 IE 43164 B1 IE43164 B1 IE 43164B1 IE 1414/76 A IE1414/76 A IE 1414/76A IE 141476 A IE141476 A IE 141476A IE 43164 B1 IE43164 B1 IE 43164B1
Authority
IE
Ireland
Prior art keywords
washing agent
component
agent
weight
washing
Prior art date
Application number
IE1414/76A
Other versions
IE43164L (en
Original Assignee
Exquisit Kosmetik Gmbh
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Publication date
Application filed by Exquisit Kosmetik Gmbh filed Critical Exquisit Kosmetik Gmbh
Publication of IE43164L publication Critical patent/IE43164L/en
Publication of IE43164B1 publication Critical patent/IE43164B1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/526—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 are polyalkoxylated
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Disclosed is a liquid fine washing agent, which, in addition to good washing properties, has an excellent fiber-caring effect and, in particular, bestows a soft feel to textiles treated therewith. The washing agent achieving these objectives contains about 7 to 40% by weight of at least one nonionic surface-active agent, especially at least one C10-C20-alkylpolyglycol ether and/or C6-C20-alkylphenolpolyglycol ether; about 3 to 15% by weight of at least one C8-C20 fatty acid polyglycol diester; and about 1 to 7% by weight of a quaternary ammonium compound with textile-softening properties, especially a di-C10-C22-alkyldimethyl or - ethylammonium halide.

Description

This invention relates to a liquid fine washing agent, which, in addition to good washing properties, has an excellent fiber-caring effect and, in particular, bestows a soft feel to textiles treated therewith.
It has already been proposed, particularly in automatic washing machines, to go beyond the main washing cycle, in which the laundry is washed with a tensidecontaining, preferably an anion-active, detergent, in a so-called softening rinse cycle, where the laundry is contacted with a cation-active compound, most commonly a quaternary ammonium compound.
It has also been proposed to incorporate the washing and softening action into a single detergent composition. However, the practical utilization of these proposals has generally failed,mainly because anion-active and cationactive substances are incompatible and as a rule react by the formation of a deposit.
In addition, it has also been proposed (e.g. in the German Published Application 1 220 956) to prepare detergents with a softening effect by the compatible combination of a non-ionic surface-active agent with a cation-active softener in a quaternary nitrogen base.
The compositions previously proposed for this purpose, however, have the drawback that either their washing effect is generally too insignificant or a satisfactory softening effect cannot be obtained. Thus a 3164 demand exists for a single, compatible composition which will provide the desired washing and softening effect, both to a high degree.
It has now been found that a liquid fine washing agent may be prepared having both excellent washing properties as well as outstanding fiber-caring, particularly soft-rinsing,properties if there is added to an aqueous base a composition comprising about 7 to 40% by weight of non-ionic surface-active agent, especially a ciq_C20~ alkylpolyglycol ether and/or Cg-C20-alkylphenolpolyglycol ether; about 3 to 15% by weight of at least one Cg~C2Q fatty acid polyglycol diester; and about 1 to 7% by weight of at least one cationic component with textile-softening properties, especially a di-C10-C2o-alkyldimethyl-orethylammonium halide.
The novel compositions according to the invention preferably contain alkylpolyglycol ethers which have 1016 carbon atoms in the alkyl radical and are alkoxylated with 3 to 10 moles of ethylene oxide or propylene oxide. Outstandingly, suitable for use in these novel compositions are C^Q-^-alkylpolyglycol ethers with 5 to 7 ethylene oxide groups in the molecule.
Suitable Cg_C2Q-alkylphenolpolyglycol ethers which may be used in place of some or all of the alkylpolyglycol ethers, for example, are those having the general formula: R wherein R is a Cg_C2g-alkyl group and particularly a Cg_ -alkyl group and n is a whole number from 3 to 15, C^g-alkyl group and n is and particularly 5 to 10. 3164 other usable polyglycol ethers are, for example, polyether glycols, such as, for example, the block polymers of the general structure 110 (C2H4O) x~(C3H6O) y—<C2H4O) zH or HO(C3H6°)w—<c2H4O)m~_(C3H6°)nH whose molar weight is between about 1,000 and 15,000, and which are sold, for example, under the trade name Pluronic '* (see McCutcheons, Detergents Emulsifiers, 1974 Ed., pp. 137-138), (x is a number from 10 to 40, especially from 26 to 30; y and z are numbers from 10 to 60, especially from 30 to 40; m is a number from 10 to 50, especially from 36 to 40;· n is a number from 10 to 40, especially from 20 to 30). The’preparation and i the properties of these compounds are described in detail by K. Lindner, Tenside, Textilhilfsmittel, Waschrohstoffe (Tensides, Textile Aids, Washing Raw Materials) 2nd Ed. (Stuttgart, 1964), pp. 1052-1057.
Also usable are the fatty acid amide polyglycol ethers, whose preparation and properties are described by K. Lindner, Op, cit, pp. 912-914.
Preferred fatty acid amide polyglycol ethers are those having the structure: r_C—N—CH2— CII2—0 (CH2CH20) nH or ch2—ch2—o (ch2ch2o) nH 2va2u'n' R—C—N ch2—ch2—0 (ch2ch2o) wherein n and m are each a whole number from 1 to 20 and preferably from 5 to 15, and R is an alkyl radical with preferably 8 to 20 carbon atoms.
Needless to say, the corresponding propoxylates or 5 mixed propoxylate- ethoxylates may also be employed in place of the ethoxylation products. Suitable commercial products, for example, are known under the name Dionil (trade mark) produced by Chemische Werke Huels.
As Cg_C20~fatty acid polyglycol diesters the esters 10 of unsaturated fatty acids, for example oleic acid, are particularly suitable.
The polyglycol residue of the fatty acid polyglycol ether diester used in this invention has preferably a molecular weight of about 200 to about 800. A preferred fatty acid polyglycol diester is polyethylene glycol-600dioleate.
An especially suitable quaternary ammonium compound has been found to be a di-C^Q to C22-alkyldimethyl- or diethyl-ammonium chloride or -bromide, as sold, for Hoechst AG under the imidazoline derivatives example by the company Farbwerke trade mark Praepagen WKT.
Alternatively, quaternized of the general formula: R2?' -CR„ X V » - 6 wherein R is· H or an optionally substituted alkyl group with 1 to 18 carbon atoms, R' is an alkyl group with 8 to 22 carbon atoms, R1' is a lower alkyl group with 1 to 6 carbon atoms, and X is a monovalent anionic group, or long-chain alkyl pyridinium halides may be used as textile-softening agents.
These compounds and their texrile-softening properties are well-known and are described by K. Lindner, op. cit. pp. 987-995.
Suitable products are sold, for example, by the companies REWO, Schliichtern (Germany) under the trade mark Steinaquat, Servo B.V. under the trade mark Servamine KOV 4342 B, Ashland Chemical Co. under the trade mark Varisoft, especially Varisoft 475 and Dutton & Reinisch Ltd. under the trade mark Loraquat M 5040.
The novel liquid fine washing agents with softening action may contain further agents known per se in liquid detergents. Thus, the addition of other non) ionic, cationic and/or amphoteric tensides is possible.
The presence of considerable amounts of anion-active tensides is not possible because of their incompatibility with the softening ammonium compounds. Further suitableactive compounds which may be co-used are, for example, . betaines or long-chain alkylaminocarboxylic acids, amine oxides, for example, lauryldimethylamine oxide, other alkylene oxide adducts, for example, polyglyeol monoesters of saturated fatty acids, for example, polyethyleneglycol monostearate. Furthermore, the customary builders and synthesizing agents may be present in small proportions; the addition of other substances, known per se in washing agents, such as enzymes, brighteners, dirt carriers, urea, ethyl alcohol, propyl alcohol or isopropyl alcohol, is also possible.
The novel agent; may suitably also contain, for example, preserving agents and, if desirable, dyestuffs, opacifiers, etc. In short, the novel compositions according to the present invention may contain in addition to the specified agents any of the well known ingredients commonly found in washing compositions and one skilled in the art may select such agents depending upon the precise properties desired.
The pH value of the novel liquid detergents is normally between about 2 and 7; the range of pH 3 to pH 6 is preferred.
The turbidity points of the novel detergents are commonly between about 10° C and 65°C and preferably between 3o°C and 55°C.
The following Examples illustrate the invention.
Example 1 % by weight Clo to C12-alkylpolyglycol ether (6 ethylene oxide radicals/mole) (e.g. Marlipal KF (trade mark) of Chemische Werke Huels) polyethylene glycol-600-dioleate (e.g. Marlipal FS of Chemische Werke Huels) dialkyl dimethylammonium chloride (e.g. Praepagen WKT of Farbwerke Hoechst) formalin (40%) opacifier (e.g. fatty acid polyglycol ester) perfume staining solution (0.1% L-red solution) 13.0 7.0 4.0 0.2 0.6 0.6 0.3 water 74.3 - 8 Example 2 % by weight Clo to 0^2-alkylpolyglycol ether (6 ethylene oxide radicals) (e.g.
Marlipal KF of Chemische Werke Huels) 14.0 polyethyleneglycol-600-dioleate (e.g.
Marlipal FS of Chemische Werke Huels) 6.0 dicocos alkyl dimethylammonium chloride 4.0 formalin (40%) 0.2 opacifying agent (e.g. fatty acid polyglycol ester) 0.6 perfume 0.6 staining solution (0.1% L-red solution) 0.3 water 74.3 Polyethyleneglycol-600-dioleate may be replaced by polypropyleneglycol-600-dimyristate.
Example 3 C1Q to C12-alkylpolyglycol ether (6 ethylene oxide radicals) (e.g. Marlipal KF of Chemische Werke Huels) polyethyleneglycol-800-dioleate di-C^^ to C^g-alkyl dimethylammonium bromide formalin (40%) opacifying agent (e.g. fatty acid polyglycol ester) perfume staining solution (0.1% L-red solution) % by weight 18.0 .0 3.5 0.2 0.6 0.3 water 71.8 Example 4 % by weight to C12-alkylpolyglycol ether (6 ethylene oxide radicals) (e.g. Marlipal KF of Chemische Werke Huels) 18.0 polyethyleneglycol-600-dioleate (e.g.
Marlipal FS of Chemische Werke Huels) 5.0 dilauryl dimethylammonium chloride 3.5 carboxylmethylhydroxyethyl cellulose (e.g.
Hercules (trade mark) CMHEC of Hercules Powder) 0.5 formalin (40%) 0.2 opacifying agent (e.g. fatty acid polyglycol ester) 0.6 perfume 0.6 staining solution (0.1% L-red solution) 0.3 water 71.3 Dilauryl dimethylammonium chloride may be replaced by a quaternized fatty amide, e.g. the product Consoft C or Consoft CPN sold by the company Consos, Inc.
Example 5 C1Q to C12~alkylpolyglycol ether (6 ethylene oxide radicals) (e.g. Marlipal KF of Chemische Werke Huels) polyethyleneglycol-1000-dioleate <3i-i2 to Cjg-alkyldirnethylammonium chloride Carboxymethyihydroxyethyl cellulose (e.g Hercules CMHEC of Hercules Powder) formalin (40%) opacifying agent perfume % by weight 18.0 .0 3.5 1.0 0.2 0.6 0.6 staining solution (0.1% L-red solution) 0.3 water 70.8 Example δ % by weight j C1Q to C-^-alkylpolyglycol ether (8 ethylene oxide radicals 16.0 polyethyleneglycol-600-dioleate (e.g.
Marlipal PS of Chemische Werke Huels) 5.0 nonylphenolpolyglycol ether (e.g. Arkopal .0 N-060 of Farbwerke Hoechst) 2.0 distearyldimethylammonium chloride 3.5 formalin (40%) 0,2 opacifying agent (e.g. fatty acid polyglycol ester) 0.6 perfume 0.6 staining solution (0.1% L-red solution) 0.3 water 71.8 distearyl dimethylammonium chloride may be replaced by ditallow dimethyl ammonium methyl sulfate (e.g.
Ammonyx 2194) or ditallowdimethyl ammonium chloride.
Example 7 % by weight C^q to C^-alkylpolyglycol ether (6 ethylene oxide radicals) (e.g.
Marlipal KF of Chemische Werke Huels) 16.0 polyethyleneglycol-400 distearate 3.0 nonylphenolpolyglycol ether (e.g. Arkopal N-060 of Farbwerke Hoechst) 4.0 4.0 distearyldimethylammonium chloride formalin (40%) 0.2 - 11 opacifying agent (e.g. fatty acid polyglycol ester) 0.6 perfume 0.6 staining solution (0.1% L-red solution) 0.3 water 71.3 Example 8 % by weight to Cg2_slkylpolyglyc°l ether (e.g. ethylene oxide radicals) (e.g. Marlipal KF of Chemische Werke Huels) 36.0 polyethyleneglycol-600-dioleate (e.g.
Marlipal. FS of Chemische Werke Huels) J0.0 distearylmethylbenzylammonium chloride 7.0 formalin (40%) 0.2 opacifying agent (e.g. fatty acid polyglycol ester) 0.6 perfume 0.6 staining solution (0.1% L-red solution) 0.3 water 45.3 Example 9 % by weight C1Q to C^2-alkylpolyglycol ether (6 ethylene oxide radicals) (e.g. Marlipal KF of Chemische Werke Huels) 27.0 polyethyleneglycol-600-dilinoleate 7.5 difatty alkyldimethylammonium chloride (e.g. Praepagen WKT of Farbwerke Hoechst) 5.3 formalin (40%) 0.2 0.6 opacifying agent perfume 0.6 316 4 - 12 staining solution (0.1% L-red solution) 0.3 water 58.5 Example 10 % by weight i polyoxyethylene polyoxypropylene block polymer e.g. Pluronic (trade mark) L62 of BASF-Wyandotte Co.) 25.0 polyethyleneglycol-600-distearate 6.5 distearyldimethylammonium chloride 2.5 lauryldimethylamine oxide 1,5 formalin (40%) 0.3 perfume 0.7 staining solution (0.1%) 0.5 Water 63.0 Example 11 % by weight fatty acid amiiiopolyglycol ether (Dionil W 100 of Chemische Huels) 26.0 polyethyleneglycol-800-dioleate 8.0 ) dlmyristyl diethylammonium chloride 2.0 formalin (40%) 0.3 perfume 0.7 staining solution (0.1%) 0.5 water 62.5 Example 12 % by weight alkylphenolpolglycol ether (9 ethylene oxide (units); Nonidet P80 of Shell Chem. U.K. Ltd.) 25.5 polyethyleneglycol-600-dilaurate 9·5 lauryldimethylamine oxide 1.5 Steinaquat M 5040 6.0 formalin (40%) 0.3 sodium tripolyphosphate 0.7 perfume 0.8 pearlesence agent 0.2 water 58.5 Steinaquat M 5040 (1-ethyl-l')alkylaminoethyl2-alkylimidazolinium-ethosulfate) may be replaced by dialkyl imidazolinium methosulfate, e.g. Ammonyx 4080, by Onyx Chem. Co.

Claims (27)

1. A liquid fine washing agent comprising an aqueous base and, calculated on the agent, (a) 7 to 40% by weight of at least one non-ionic surface active agent; (b) 3 to 15% by weight of at least one Cg-C 2Q fatty acid polyglycol diesters; and (c) 1 to 7.5% by weight of at least one cationic component with textile softening properties.
2. A washing agent as claimed in claim 1, wherein 3 component (a) is a C^ 0 _C 2g) -alkylpolyglycol ether and/or a C g to C 20 ~alkylphenol-polyglycol ether.
3. A washing agent as claimed in claim 1, wherein component (a) comprises a to C lg -alkylpolyglycol ether which is alkoxylated with 3 to 10 ethylene oxide i and/or propylene oxide groups per mol.
4. A washing agent as claimed in claim 3, wherein component (a) comprises a C 1Q _C .^-alkylpolyglycol ether which is alkoxylated with 5 to 7 moles of ethylene oxide and/or propylene oxide.
5. A washing agent as claimed in claim 1, wherein component (a) comprises an alkylphenolpolyglycol ether of the general formula 0-(CH 2 CH 2 O) n H wherein R is a C g to C 20 alkyl group and n is a whole number from 3 to 15, or a corresponding compound in which some or all of the ethoxylate groups are replaced by propoxylate groups. 4 316 4 - 15
6. A washing agent as claimed in claim 5, wherein R in the general formula is a C g to C lg alkyl group.
7. A washing agent as claimed in claim 5, wherein n in the general formula is a whole number from 5 to 10. 5
8. A washing agent as claimed in claim 1, wherein component (a) comprises polyether glycol.
9. A washing agent as claimed in claim 8, wherein component (a) comprises a polyether glycol block polymer of the general formula io ho(c 2 h 4 o) x —(c 3 h 6 o) 4 —(c 2 h 4 o) 2 h or ΗΟ(Ο 3 Η 6 Ο) η -(Ο 2 Η 4 Ο)— (C 3 H 6 O) n wherein x is a number from 10 to 40, y and z, are each numbers from 10 to 60, m is a number from 10 to 50 and 15 n is a number from 10 to 40.
10. A washing agent as claimed in claim 9, wherein, in the general formulae, x is a number from 26 to 30, y and z_ are each numbers from 30 to 40, m is a number from 36 to 40 and n is a number from 20 to 30. 20
11. A washing agent as claimed in claim 1, wherein component (a) comprises a fatty acid amide polyglycol ether.
12. A washing agent as claimed in claim 11, wherein component (a) comprises a fatty acid amide polyglycol ether of the general formula R— C— N—CH, —CIi 2 — O(CH 2 CH 2 O) n H 0 H 3164 - 16 or ch 2 _ ch 2 — o (ch 2 ch 2 o) n H R— C-N II \ 0 CH 2 —CH 2 —O(CH 2 CH 2 O) m H wherein R is an alkyl radical and n and m are each a number from 1 to 20, or the corresponding compounds in ί which some or all of the ethoxylate groups are replaced by propoxylate groups.
13. A washing agent as claimed in claim 12, wherein R in the general formulae is a C g to C 2Q alkyl radical. 0
14. A washing agent as claimed in claim 12 or claim 13, wherein n and m in the general formulae are each a number from 5 to 15.
15. A washing agent as claimed in any one of claims 1 to 14, wherein the polyglyeol residue of com5 ponent (b) has a molecular weight of from 200 to 800.
16. A washing agent as claimed in any one of claims 1 to 15, wherein component (b) comprises an ester of an unsaturated fatty acid.
17. A washing agent as claimed in claim 16, wherein component (b) comprises an ester of oleic acids.
18. component A washing agent as claimed in claim 17, wherein (b) is polyethylene glycol-600-dioleate.
19. A washing agent as claimed in any one of claims 1 to 18, wherein component (c) comprises a di-Cto C 22 -alkyl dimethyl- or di ethyl-ammonium halide. - 17 20. A washing agent as claimed in claim 19, wherein component (c) comprises a di-C 32 to C 2Q -alkyl dimethyl ammonium chloride. 21. A washing agent as claimed in any one of 5 claims 1 to 19, wherein component (c) comprises a quatcrnizei imidazoline derivative of the general formula: r 2 c-cr 2 N R'S'' \/\ c I R* wherein R is H or an optionally substituted, alkyl group with 1 to 18 carbon atoms, R' is an alkyl group 10 with 8 to 22 carbon atoms, R'' is an alkyl group with 1 to 6 carbon atoms and X is a monovalent anion. 22. A washing agent as claimed in any one of claims 1 to 18, wherein component (c) comprises a long chain alkyl pyridinium halide. 15 23. A washing agent as claimed in any one of claims 1 to 22, wherein component (a) comprises from 13 to 20% by weight of the agent. 24. A washing agent as claimed in any one of claims 1 to 23, wherein component (b) comprises from 5
20. To 10% by weight of the agent.
21. 25. A washing agent as claimed in any one of claims 1 to 24, wherein component (c) comprises from 1 to 5.5% by weight of the agent. 164 - 18
22. 26. A washing agent as claimed in claim 25, wherein component (c) comprises from 2 to 4% by weight of the agent.
23. 27. A washing agent as claimed in any one of i claims 1 to 26, having a pH of from 2 and 7.
24. 28. A washing agent as claimed in claim 27 having a pH of from 3 to 6.
25. 29. A washing agent as claimed in any one of claims 1 to 28 having a turbidity point of from 10°C to 0 65°C.
26. 30. A washing agent as claimed in claim 29, having a turbidity point of from 30°C to 55°C.
27. 31. A washing agent substantially as described in any one of the Examples herein.
IE1414/76A 1975-07-02 1976-06-29 Liquid fine washing agent IE43164B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2529444A DE2529444C3 (en) 1975-07-02 1975-07-02 Liquid mild detergent

Publications (2)

Publication Number Publication Date
IE43164L IE43164L (en) 1977-01-02
IE43164B1 true IE43164B1 (en) 1980-12-31

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ID=5950449

Family Applications (1)

Application Number Title Priority Date Filing Date
IE1414/76A IE43164B1 (en) 1975-07-02 1976-06-29 Liquid fine washing agent

Country Status (20)

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US (1) US4268401A (en)
JP (1) JPS593518B2 (en)
AT (2) AT343777B (en)
AU (1) AU1407676A (en)
BE (1) BE843687A (en)
BR (1) BR7604054A (en)
CA (1) CA1053111A (en)
CH (1) CH606406A5 (en)
DD (1) DD124657A1 (en)
DE (1) DE2529444C3 (en)
FR (1) FR2316326A1 (en)
GB (1) GB1546829A (en)
GR (1) GR60565B (en)
IE (1) IE43164B1 (en)
IL (1) IL49394A (en)
MX (1) MX146192A (en)
NL (1) NL180850C (en)
PL (1) PL103561B1 (en)
RO (1) RO69082A (en)
ZA (1) ZA762982B (en)

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MX146192A (en) 1982-05-24
RO69082A (en) 1982-09-09
IL49394A (en) 1979-01-31
GB1546829A (en) 1979-05-31
AT353925B (en) 1979-12-10
FR2316326B1 (en) 1980-04-18
CA1053111A (en) 1979-04-24
ATA98876A (en) 1979-05-15
DD124657A1 (en) 1977-03-09
GR60565B (en) 1978-06-22
FR2316326A1 (en) 1977-01-28
NL7604327A (en) 1977-01-04
DE2529444C3 (en) 1982-04-15
NL180850C (en) 1987-05-04
AT343777B (en) 1978-06-12
BE843687A (en) 1977-01-03
DE2529444B2 (en) 1981-05-14
AU1407676A (en) 1977-11-24
ZA762982B (en) 1977-04-27
BR7604054A (en) 1977-07-05
JPS526707A (en) 1977-01-19
NL180850B (en) 1986-12-01
ATA512075A (en) 1977-10-15
US4268401A (en) 1981-05-19
CH606406A5 (en) 1978-10-31
IE43164L (en) 1977-01-02
JPS593518B2 (en) 1984-01-24
IL49394A0 (en) 1976-06-30
DE2529444A1 (en) 1977-01-27
PL103561B1 (en) 1979-06-30

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