HUE037793T2 - Ezüst ionokkal adszorbeált szílícium-dioxid szemcsék biocid hatású, kolloid diszperziói - Google Patents
Ezüst ionokkal adszorbeált szílícium-dioxid szemcsék biocid hatású, kolloid diszperzióiInfo
- Publication number
- HUE037793T2 HUE037793T2 HUE10819117A HUE10819117A HUE037793T2 HU E037793 T2 HUE037793 T2 HU E037793T2 HU E10819117 A HUE10819117 A HU E10819117A HU E10819117 A HUE10819117 A HU E10819117A HU E037793 T2 HUE037793 T2 HU E037793T2
- Authority
- HU
- Hungary
- Prior art keywords
- biocidal
- silica particles
- silver ions
- colloidal dispersions
- ions adsorbed
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
- C01B33/141—Preparation of hydrosols or aqueous dispersions
- C01B33/1415—Preparation of hydrosols or aqueous dispersions by suspending finely divided silica in water
- C01B33/1417—Preparation of hydrosols or aqueous dispersions by suspending finely divided silica in water an aqueous dispersion being obtained
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
- C01B33/146—After-treatment of sols
- C01B33/149—Coating
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/18—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G5/00—Compounds of silver
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G5/00—Compounds of silver
- C01G5/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G5/00—Compounds of silver
- C01G5/006—Compounds containing, besides silver, two or more other elements, with the exception of oxygen or hydrogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/28—Compounds of silicon
- C09C1/30—Silicic acid
- C09C1/3045—Treatment with inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/67—Particle size smaller than 100 nm
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/68—Particle size between 100-1000 nm
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/02—Ingredients treated with inorganic substances
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Nanotechnology (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Plant Pathology (AREA)
- Dispersion Chemistry (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Composite Materials (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Silicon Compounds (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE0901216A SE533902C2 (sv) | 2009-09-22 | 2009-09-22 | Nanopartiklar av silver |
Publications (1)
Publication Number | Publication Date |
---|---|
HUE037793T2 true HUE037793T2 (hu) | 2018-09-28 |
Family
ID=43535814
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
HUE10819117A HUE037793T2 (hu) | 2009-09-22 | 2010-09-20 | Ezüst ionokkal adszorbeált szílícium-dioxid szemcsék biocid hatású, kolloid diszperziói |
Country Status (9)
Country | Link |
---|---|
US (1) | US9108854B2 (hu) |
EP (1) | EP2480499B1 (hu) |
CN (1) | CN102548901B (hu) |
DK (1) | DK2480499T3 (hu) |
ES (1) | ES2671518T3 (hu) |
HU (1) | HUE037793T2 (hu) |
NO (1) | NO2480499T3 (hu) |
SE (1) | SE533902C2 (hu) |
WO (1) | WO2011037523A1 (hu) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2414282B1 (es) * | 2012-01-18 | 2014-05-13 | Endeka Ceramics, S.A. | Nanocomposite de plata para tinta de piezas cerámicas, tintas bactericidas multifuncionales obtenidas a partir de los mismos, y método de preparacion |
US9392794B2 (en) * | 2012-01-19 | 2016-07-19 | Wizard Labs, Llc | Odor eliminating solution |
CL2013002101A1 (es) * | 2013-07-23 | 2014-08-29 | Univ Chile | Aditivo que confiere propiedades biocidas a distintos materiales que comprende un material de soporte o portador modificado con un agente bacteriano que forma estructuras nanometricas sobre la superficie externa de dicho material de soporte; y metodo para preparacion de dicho aditivo. |
US10400109B2 (en) | 2013-10-04 | 2019-09-03 | 3M Innovative Properties Company | Coatable composition, antistatic composition, antistatic articles, and methods of making the same |
CN103639423B (zh) * | 2013-12-27 | 2016-06-08 | 哈尔滨理工大学 | 硅酸铝包覆银纳米核壳粒子及制备方法和用途 |
US10093885B2 (en) * | 2014-01-29 | 2018-10-09 | Conopco, Inc. | Aqueous composition containing oligodynamic metal |
ITUB20150539A1 (it) * | 2015-04-23 | 2016-10-23 | Maria Vittoria Favini | Formulazione di un preparato a base di argento e sue applicazioni come biocida |
WO2017029482A1 (en) | 2015-08-14 | 2017-02-23 | Imerys Minerals Limited | Inorganic particulate containing antimicrobial metal |
CN107343505B (zh) * | 2016-05-06 | 2020-09-25 | 识骅科技股份有限公司 | 具二氧化硅纳米粒子及银纳米粒子的纳米碳管复合结构 |
WO2017216285A1 (en) | 2016-06-15 | 2017-12-21 | Prebona Ab | Composite sols |
ITUA20164486A1 (it) * | 2016-06-17 | 2017-12-17 | Maria Vittoria Favini | Formulazione di un preparato a base di argento e sue applicazioni come biocida |
EP3658502A1 (en) * | 2017-07-24 | 2020-06-03 | Prebona Ab | Metal containing formulations |
CN107670080B (zh) * | 2017-11-03 | 2018-12-11 | 济南芯乐智能设备有限公司 | 一种冰箱去异味杀菌消毒的方法和装置 |
WO2019122429A1 (en) | 2017-12-21 | 2019-06-27 | Prebona Ab | Pharmaceutical composition comprising a colloidal dispersion and a therapeutic agent and methods and uses thereof |
CA3084893A1 (en) | 2017-12-21 | 2019-06-27 | Prebona Ab | Compositions and methods for reducing odor |
WO2019122366A1 (en) * | 2017-12-22 | 2019-06-27 | Eckart Gmbh | Electrically conductive particles, composition, article and method of manufacturing electrically conductive particles |
CN114025804A (zh) * | 2019-06-26 | 2022-02-08 | 普瑞伯纳公司 | 包含胶体分散体的药物组合物及其方法和用途 |
EP4081031A1 (en) * | 2019-12-27 | 2022-11-02 | Aerogel ApS | Use of biocidal aerogel compositions in on-shore paints, coatings and sealants |
CN114101656B (zh) * | 2021-12-07 | 2022-09-27 | 浙江大学 | 一种具有万能分散特性银纳米颗粒的制备方法及应用 |
Family Cites Families (26)
Publication number | Priority date | Publication date | Assignee | Title |
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US4284580A (en) * | 1980-01-02 | 1981-08-18 | The Procter & Gamble Company | Fractionation of triglyceride mixture |
JP2590653B2 (ja) | 1990-11-28 | 1997-03-12 | 松下電器産業株式会社 | 抗菌性複合体、その製造法、それを用いた樹脂およびコ−キング材 |
JPH0699258B2 (ja) * | 1991-03-22 | 1994-12-07 | 株式会社萩原技研 | 耐熱・耐候性抗菌性組成物 |
US5651978A (en) | 1993-05-18 | 1997-07-29 | Matsushita Electric Industrial Co., Ltd. | Silver thiosulfate silica gel antibacterial compositions |
JP3095960B2 (ja) * | 1994-10-05 | 2000-10-10 | 触媒化成工業株式会社 | 抗菌剤 |
US8753691B2 (en) | 1999-06-01 | 2014-06-17 | American Silver, Llc | Antiviral colloidal silver composition |
CN1308866A (zh) * | 2000-12-29 | 2001-08-22 | 天津大学 | 一种无机广谱抗菌添加剂的制备方法 |
WO2004073400A2 (de) * | 2003-02-19 | 2004-09-02 | Fraunhofer Gesellschaft zur Förderung der angewandten Forschung e.V. | Mit einer silberhaltigen schicht überzogenes anorganisches trägermaterial |
WO2005019096A1 (en) * | 2003-08-23 | 2005-03-03 | Chul-Sang Jeong | Nanocomposite solution with complex function and method for preparation thereof |
US7488520B2 (en) * | 2003-10-16 | 2009-02-10 | Kimberly-Clark Worldwide, Inc. | High surface area material blends for odor reduction, articles utilizing such blends and methods of using same |
KR100606253B1 (ko) * | 2004-06-18 | 2006-07-31 | 주식회사 옥시 레킷벤키저 | 나노실버를 함유하는 살균/항균 및 소취 기능의섬유탈취제용 수성 조성물 |
CN1274595C (zh) * | 2004-12-07 | 2006-09-13 | 中国乐凯胶片集团公司 | 一种载银离子硅凝胶制备方法 |
US7511007B2 (en) | 2005-02-25 | 2009-03-31 | Solutions Biomed, Llc | Aqueous sanitizers, disinfectants, and/or sterilants with low peroxygen content |
SE529440C2 (sv) | 2005-06-01 | 2007-08-14 | Small Particles Technology Gbg | Dispergerbart pulver av kiselsyra |
WO2007117087A1 (en) | 2006-04-12 | 2007-10-18 | Industry-University Cooperation Foundation Hanyang University | Facilitated olefin transporting polymer membrane containing metal nanoparticle |
JP4970851B2 (ja) | 2006-06-05 | 2012-07-11 | 田中貴金属工業株式会社 | 金コロイドの製造方法及び金コロイド |
WO2008024422A2 (en) | 2006-08-24 | 2008-02-28 | Solutions Biomed, Llc | Methods and compositions for decontamination and treatment of disease or injury |
WO2008024426A2 (en) | 2006-08-24 | 2008-02-28 | Neuwirth Robert S | Nanosilver-containing absorbent articles |
WO2008147395A2 (en) | 2006-11-10 | 2008-12-04 | Grune Guerry L | Anti-microbial compounds used in garments for water based activities |
WO2008079149A1 (en) | 2006-12-22 | 2008-07-03 | Marianna Cooley | Dental antimicrobial formulations and methods of using the same |
DE102007012696A1 (de) | 2007-03-13 | 2008-09-18 | Bundesdruckerei Gmbh | Sicherheits- und/oder Wertdokument mit zumindest zwei verschiedenen registergenau positionierten Sicherheitsmerkmalen |
WO2008122131A1 (en) | 2007-04-04 | 2008-10-16 | Perlen Converting Ag | Antimicrobial material |
US7892317B2 (en) | 2007-07-11 | 2011-02-22 | Jafar Rahman Nia | Preparation of colloidal nanosilver |
ITPD20070242A1 (it) | 2007-07-17 | 2009-01-18 | Farmogal S P A | Composizione conservante con argento elettrolitico per prodotti cosmetici |
DE102007044582A1 (de) | 2007-09-19 | 2009-04-09 | Deckner, Peter G., Dr. med. | Zusammensetzung für Wundbehandlungen im Humanbereich |
RU2437715C1 (ru) | 2007-10-26 | 2011-12-27 | Асахи Касеи Кемикалз Корпорейшн | Материал с композитными частицами на подложке, способ его получения и способ получения соединений с использованием материала с композитными частицами на подложке в качестве катализатора для химического синтеза |
-
2009
- 2009-09-22 SE SE0901216A patent/SE533902C2/sv unknown
-
2010
- 2010-09-20 WO PCT/SE2010/051007 patent/WO2011037523A1/en active Application Filing
- 2010-09-20 ES ES10819117.2T patent/ES2671518T3/es active Active
- 2010-09-20 CN CN201080042069.0A patent/CN102548901B/zh active Active
- 2010-09-20 DK DK10819117.2T patent/DK2480499T3/en active
- 2010-09-20 EP EP10819117.2A patent/EP2480499B1/en active Active
- 2010-09-20 NO NO10819117A patent/NO2480499T3/no unknown
- 2010-09-20 US US13/497,503 patent/US9108854B2/en active Active
- 2010-09-20 HU HUE10819117A patent/HUE037793T2/hu unknown
Also Published As
Publication number | Publication date |
---|---|
EP2480499A4 (en) | 2014-02-19 |
CN102548901B (zh) | 2016-06-29 |
DK2480499T3 (en) | 2018-06-14 |
SE0901216A1 (sv) | 2011-02-22 |
ES2671518T3 (es) | 2018-06-06 |
WO2011037523A1 (en) | 2011-03-31 |
NO2480499T3 (hu) | 2018-08-04 |
US9108854B2 (en) | 2015-08-18 |
EP2480499B1 (en) | 2018-03-07 |
SE533902C2 (sv) | 2011-02-22 |
US20120301553A1 (en) | 2012-11-29 |
CN102548901A (zh) | 2012-07-04 |
EP2480499A1 (en) | 2012-08-01 |
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