HRP20220087T1 - Prethodno sulfidiranje i prethodno kondicioniranje ostataka katalizatora hidrokonverzije za procese hidrokonverzije s vrijućim slojem - Google Patents
Prethodno sulfidiranje i prethodno kondicioniranje ostataka katalizatora hidrokonverzije za procese hidrokonverzije s vrijućim slojem Download PDFInfo
- Publication number
- HRP20220087T1 HRP20220087T1 HRP20220087TT HRP20220087T HRP20220087T1 HR P20220087 T1 HRP20220087 T1 HR P20220087T1 HR P20220087T T HRP20220087T T HR P20220087TT HR P20220087 T HRP20220087 T HR P20220087T HR P20220087 T1 HRP20220087 T1 HR P20220087T1
- Authority
- HR
- Croatia
- Prior art keywords
- hydroconversion
- reactor
- catalyst
- fluidized bed
- sulfur
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims 15
- 238000000034 method Methods 0.000 title claims 9
- 230000003750 conditioning effect Effects 0.000 title 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 13
- 229930195733 hydrocarbon Natural products 0.000 claims 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 7
- 229910052739 hydrogen Inorganic materials 0.000 claims 7
- 239000001257 hydrogen Substances 0.000 claims 7
- 239000011593 sulfur Substances 0.000 claims 7
- 229910052717 sulfur Inorganic materials 0.000 claims 7
- 239000003921 oil Substances 0.000 claims 6
- 229910044991 metal oxide Inorganic materials 0.000 claims 5
- 150000004706 metal oxides Chemical class 0.000 claims 5
- 150000001875 compounds Chemical class 0.000 claims 4
- 239000004215 Carbon black (E152) Substances 0.000 claims 3
- 239000007789 gas Substances 0.000 claims 3
- 229910052976 metal sulfide Inorganic materials 0.000 claims 2
- 150000003464 sulfur compounds Chemical class 0.000 claims 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 239000000571 coke Substances 0.000 claims 1
- 239000012530 fluid Substances 0.000 claims 1
- 229910052750 molybdenum Inorganic materials 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 230000000737 periodic effect Effects 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- 239000000725 suspension Substances 0.000 claims 1
- 229910052721 tungsten Inorganic materials 0.000 claims 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/12—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/06—Sulfides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/04—Sulfides
- B01J27/043—Sulfides with iron group metals or platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/04—Sulfides
- B01J27/047—Sulfides with chromium, molybdenum, tungsten or polonium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/20—Sulfiding
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1074—Vacuum distillates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1077—Vacuum residues
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/202—Heteroatoms content, i.e. S, N, O, P
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/70—Catalyst aspects
- C10G2300/703—Activation
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Claims (5)
1. Proces hidrokonverzije, naznačen time, da se sastoji od:
dovođenja vodika i ostatka ugljikovodika koji se sastoji od ugljikovodika koji sadržavaju sumpor u reaktor hidrokonverzije s vrijućim slojem (14);
dovođenje u kontakt, u hidrokonverzijskom reaktoru s vrijućim slojem (14), vodika i zaostalog ugljikovodika s barem djelomično sulfidiranim i prethodno kondicioniranim katalizatorom hidrokonverzije za pretvaranje barem dijela zaostalog ugljikovodika u barem jedan od hidrotretiranih proizvoda i ili jedan hidrokrekirani proizvod;
kontinuirano:
dovođenje svježeg ili regeneriranog katalizatora hidrokonverzije koji sadržava metalni oksid u predreaktor (22);
dovođenje vodika i ostatka ugljikovodika koji sadržava spojeve sa sumporom identične ostatku ugljikovodika koji je u kontaktu s vodikom u reaktoru za hidrokonverziju (14) u predreaktor (22);
dovođenje u kontakt katalizatora hidrokonverzije s vodikom i ostatkom ugljikovodika koji sadržava sumporne spojeve u predreaktoru (22) pri jačini rada nižoj od one koja se koristi u reaktoru hidrokonverzije pri temperaturi u rasponu od 230 do 450 °C i tlaku u rasponu od 0,1 do 20 MPa (1 do 200 bara), za istodobno:
i) pretvaranje najmanje 30 molarnih postotaka metalnog oksida u metalni sulfid; i
ii) predkondicioniranje katalizatora, čime se proizvodi niža razina naslaga ugljičnog koksa na česticama katalizatora hidrokonverzije; i izdvajanje zaostalog ugljikovodika sa smanjenim sadržajem sumpora iz
predreaktora (22); i
transport barem djelomično sulfidiranog i prethodno kondicioniranog katalizatora hidrokonverzije iz predreaktora (22) do reaktora za hidrokonverziju s vrijućim slojem (14) bilo kontinuirano ili povremeno, bez izazivanja bilo kakvih prekida procesa za reaktor hidrokonverzije s vrijućim slojem (14), pri čemu se dovođenje u kontakt katalizatora hidrokonverzije s vodikom i ostatkom ugljikovodika koji sadržava sumporne spojeve u predreaktoru (22) provodi tako da se ne koristi dodani spoj koji sadržava sumpor osim ostatka ugljikovodika koji sadržava ugljikovodike koji sadržavaju sumpor,
pri čemu postupak dalje uključuje :
kontinuirano ili povremeno uklanjanje istrošenog katalizatora iz hidrokonverzijskog reaktora s vrijućim slojem (14) i kontinuirana ili povremena zamjena istrošenog katalizatora svježim ili regeneriranim katalizatorom koji je prethodno sulfidiran i prethodno kondicioniran kako je definirano pod i) i ii), čime se izbjegava izravno uvođenje svježeg ili regeneriranog katalizatora u reaktor hidrokonverzije s vrijućim slojem (14) i pri čemu se provodi transport barem djelomično sulfidiranog i prethodno kondicioniranog katalizatora hidrokonverzije iz predreaktora (22) u reaktor za hidrokonverziju s vrijućim slojem (14) korištenjem ostataka ugljikovodika koji sadržavaju spojeve sa sumporom koji se koriste za dobivanje barem djelomično sulfidiranog i prethodno kondicioniranog katalizatora hidrokonverzije iz predreaktora (22).
2. Postupak u skladu s patentnim zahtjevom 1, naznačen time, da ostatak ugljikovodika sadržava najmanje jedno od sljedećeg: atmosferski ili vakuumski ostatak nafte, deasfaltirano ulje, deasfaltiranu smolu, hidrokrekirano dno atmosferskog ili vakuumskog tornja, primarno vakuumsko plinsko ulje, hidrokrekirano vakumsko plinsko ulje, fluidno katalitički krekirana suspenzijska ulja, vakuumsko plinsko ulje iz procesa s vrijućim slojem i najmanje jedan od hidrotretiranih proizvoda i hidrokrekiranih proizvoda.
3. Postupak u skladu s patentnim zahtjevom 1, naznačen time, da metalni oksid sadržava najmanje jedan element odabran iz skupina 4 do 12 periodnog sustava elemenata.
4. Postupak u skladu s patentnim zahtjevom 3, naznačen time, da metalni oksid sadržava najmanje jedan od Co, Ni, W i Mo.
5. Postupak u skladu s patentnim zahtjevom 1, naznačen time, da dovođenje u kontakt svježeg ili regeneriranog katalizatora hidrokonverzije s vodikom i spojevima koji sadržavaju sumpor uključuje pretvaranje najmanje 50 posto metalnog oksida u metalni sulfid.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/509,252 US9523048B2 (en) | 2009-07-24 | 2009-07-24 | Pre-sulfiding and pre-conditioning of residuum hydroconversion catalysts for ebullated-bed hydroconversion processes |
| PCT/US2010/041272 WO2011011200A2 (en) | 2009-07-24 | 2010-07-08 | Pre-sulfiding and pre-conditioning of residuum hydroconversion catalysts for ebullated-bed hydroconversion processes |
| EP10802652.7A EP2456843B1 (en) | 2009-07-24 | 2010-07-08 | Pre-sulfiding and pre-conditioning of residuum hydroconversion catalysts for ebullated-bed hydroconversion processes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| HRP20220087T1 true HRP20220087T1 (hr) | 2022-04-15 |
Family
ID=43496368
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HRP20220087TT HRP20220087T1 (hr) | 2009-07-24 | 2010-07-08 | Prethodno sulfidiranje i prethodno kondicioniranje ostataka katalizatora hidrokonverzije za procese hidrokonverzije s vrijućim slojem |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US9523048B2 (hr) |
| EP (1) | EP2456843B1 (hr) |
| JP (1) | JP5452719B2 (hr) |
| KR (1) | KR101429830B1 (hr) |
| AU (1) | AU2010274166B2 (hr) |
| CA (1) | CA2750334C (hr) |
| EA (1) | EA023527B1 (hr) |
| EG (1) | EG26809A (hr) |
| HR (1) | HRP20220087T1 (hr) |
| HU (1) | HUE056967T2 (hr) |
| MX (1) | MX2011008743A (hr) |
| MY (1) | MY156957A (hr) |
| PL (1) | PL2456843T3 (hr) |
| PT (1) | PT2456843T (hr) |
| SG (1) | SG174297A1 (hr) |
| WO (1) | WO2011011200A2 (hr) |
| ZA (1) | ZA201106467B (hr) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10941353B2 (en) * | 2004-04-28 | 2021-03-09 | Hydrocarbon Technology & Innovation, Llc | Methods and mixing systems for introducing catalyst precursor into heavy oil feedstock |
| JP5318410B2 (ja) | 2004-04-28 | 2013-10-16 | ヘッドウォーターズ ヘビー オイル リミテッド ライアビリティ カンパニー | 沸騰床水素化処理方法およびシステムならびに既存の沸騰床システムをアップグレードする方法 |
| US9790440B2 (en) | 2011-09-23 | 2017-10-17 | Headwaters Technology Innovation Group, Inc. | Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker |
| US9644157B2 (en) | 2012-07-30 | 2017-05-09 | Headwaters Heavy Oil, Llc | Methods and systems for upgrading heavy oil using catalytic hydrocracking and thermal coking |
| US20140034549A1 (en) * | 2012-08-03 | 2014-02-06 | Lummus Technology Inc. | Residue hydrocracking |
| US20140221709A1 (en) * | 2013-02-04 | 2014-08-07 | Lummus Technology Inc. | Integration of residue hydrocracking and solvent deasphalting |
| US9650312B2 (en) | 2013-03-14 | 2017-05-16 | Lummus Technology Inc. | Integration of residue hydrocracking and hydrotreating |
| US10208261B2 (en) | 2014-02-12 | 2019-02-19 | Lummus Technology Inc. | Processing vacuum residuum and vacuum gas oil in ebullated bed reactor systems |
| US11414608B2 (en) | 2015-09-22 | 2022-08-16 | Hydrocarbon Technology & Innovation, Llc | Upgraded ebullated bed reactor used with opportunity feedstocks |
| US11414607B2 (en) | 2015-09-22 | 2022-08-16 | Hydrocarbon Technology & Innovation, Llc | Upgraded ebullated bed reactor with increased production rate of converted products |
| KR102088494B1 (ko) | 2015-11-06 | 2020-03-13 | 유오피 엘엘씨 | 부타디엔 제조 목적으로 알데히드를 스트리핑하기 위한 c4 흡수기 오버헤드의 사용 |
| US11421164B2 (en) | 2016-06-08 | 2022-08-23 | Hydrocarbon Technology & Innovation, Llc | Dual catalyst system for ebullated bed upgrading to produce improved quality vacuum residue product |
| US11118119B2 (en) | 2017-03-02 | 2021-09-14 | Hydrocarbon Technology & Innovation, Llc | Upgraded ebullated bed reactor with less fouling sediment |
| US11732203B2 (en) | 2017-03-02 | 2023-08-22 | Hydrocarbon Technology & Innovation, Llc | Ebullated bed reactor upgraded to produce sediment that causes less equipment fouling |
| CA3057131C (en) | 2018-10-17 | 2024-04-23 | Hydrocarbon Technology And Innovation, Llc | Upgraded ebullated bed reactor with no recycle buildup of asphaltenes in vacuum bottoms |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4089930A (en) | 1976-02-12 | 1978-05-16 | New England Power Service Company | Process for the catalytic reduction of nitric oxide |
| US4177136B1 (en) | 1978-01-03 | 1994-05-03 | Standard Oil Co Ohio | Hydrotreating process utilizing elemental sulfur for presulfiding the catalyst |
| US4443330A (en) | 1981-06-01 | 1984-04-17 | Hri, Inc. | Catalyst activity in coal liquid upgrading |
| FR2542754A1 (fr) | 1983-03-15 | 1984-09-21 | Raffinage Cie Francaise | Procede d'hydrodemetallisation de charges d'hydrocarbures et catalyseur pour la mise en oeuvre de ce procede |
| FR2548205B1 (fr) | 1983-06-30 | 1985-11-29 | Eurecat Europ Retrait Catalys | Procede de presulfuration de catalyseur de traitement d'hydrocarbures |
| US4943547A (en) | 1988-09-13 | 1990-07-24 | Seamans James D | Method of presulfiding a hydrotreating catalyst |
| US6291391B1 (en) | 1998-11-12 | 2001-09-18 | Ifp North America, Inc. | Method for presulfiding and preconditioning of residuum hydroconversion catalyst |
| EP1299192A1 (en) | 2000-06-19 | 2003-04-09 | Institut Francais Du Petrole | Method for presulfiding and preconditioning of residuum hydroconversion catalyst |
| JP4612229B2 (ja) | 2001-06-08 | 2011-01-12 | 日本ケッチェン株式会社 | 重質炭化水素油の水素化処理用触媒並びに水素化処理方法 |
| JP4426858B2 (ja) | 2004-01-30 | 2010-03-03 | 日本ケッチェン株式会社 | 炭化水素油の水素化処理装置のスタートアップ方法 |
| FR2874838B1 (fr) | 2004-09-08 | 2006-11-24 | Inst Francais Du Petrole | Procede de sulfuration de catalyseurs d'hydrotraitement |
| US8077626B2 (en) * | 2006-07-14 | 2011-12-13 | Qualcomm Incorporated | Quality of service (QoS) aware establishment of communication sessions |
| US20080087578A1 (en) * | 2006-10-06 | 2008-04-17 | Bhan Opinder K | Methods for producing a crude product and compositions thereof |
-
2009
- 2009-07-24 US US12/509,252 patent/US9523048B2/en active Active
-
2010
- 2010-07-08 HU HUE10802652A patent/HUE056967T2/hu unknown
- 2010-07-08 WO PCT/US2010/041272 patent/WO2011011200A2/en active Application Filing
- 2010-07-08 PL PL10802652T patent/PL2456843T3/pl unknown
- 2010-07-08 PT PT108026527T patent/PT2456843T/pt unknown
- 2010-07-08 AU AU2010274166A patent/AU2010274166B2/en not_active Ceased
- 2010-07-08 EP EP10802652.7A patent/EP2456843B1/en active Active
- 2010-07-08 EA EA201171058A patent/EA023527B1/ru not_active IP Right Cessation
- 2010-07-08 SG SG2011064813A patent/SG174297A1/en unknown
- 2010-07-08 KR KR1020127001366A patent/KR101429830B1/ko active IP Right Grant
- 2010-07-08 MX MX2011008743A patent/MX2011008743A/es active IP Right Grant
- 2010-07-08 MY MYPI2011003916A patent/MY156957A/en unknown
- 2010-07-08 HR HRP20220087TT patent/HRP20220087T1/hr unknown
- 2010-07-08 CA CA2750334A patent/CA2750334C/en active Active
- 2010-07-08 JP JP2012521666A patent/JP5452719B2/ja not_active Expired - Fee Related
-
2011
- 2011-09-05 ZA ZA2011/06467A patent/ZA201106467B/en unknown
-
2012
- 2012-01-19 EG EG2012010110A patent/EG26809A/en active
Also Published As
| Publication number | Publication date |
|---|---|
| US20110017641A1 (en) | 2011-01-27 |
| EP2456843A4 (en) | 2013-03-06 |
| JP2013500353A (ja) | 2013-01-07 |
| KR101429830B1 (ko) | 2014-09-23 |
| HUE056967T2 (hu) | 2022-04-28 |
| JP5452719B2 (ja) | 2014-03-26 |
| MY156957A (en) | 2016-04-15 |
| EP2456843B1 (en) | 2021-11-03 |
| WO2011011200A3 (en) | 2011-04-21 |
| PL2456843T3 (pl) | 2022-04-04 |
| MX2011008743A (es) | 2011-09-06 |
| WO2011011200A2 (en) | 2011-01-27 |
| EA023527B1 (ru) | 2016-06-30 |
| AU2010274166B2 (en) | 2013-09-19 |
| EP2456843A2 (en) | 2012-05-30 |
| CA2750334A1 (en) | 2011-01-27 |
| PT2456843T (pt) | 2021-12-23 |
| KR20120035189A (ko) | 2012-04-13 |
| EG26809A (en) | 2014-09-24 |
| EA201171058A1 (ru) | 2012-06-29 |
| SG174297A1 (en) | 2011-10-28 |
| US9523048B2 (en) | 2016-12-20 |
| CA2750334C (en) | 2014-09-30 |
| AU2010274166A1 (en) | 2011-09-15 |
| ZA201106467B (en) | 2012-05-30 |
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