HRP20211133T1 - Proizvod za suzbijanje obrastanja - Google Patents
Proizvod za suzbijanje obrastanja Download PDFInfo
- Publication number
- HRP20211133T1 HRP20211133T1 HRP20211133TT HRP20211133T HRP20211133T1 HR P20211133 T1 HRP20211133 T1 HR P20211133T1 HR P20211133T T HRP20211133T T HR P20211133TT HR P20211133 T HRP20211133 T HR P20211133T HR P20211133 T1 HRP20211133 T1 HR P20211133T1
- Authority
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- Croatia
- Prior art keywords
- medetomidine
- enantiomer
- salt
- antifouling
- solution
- Prior art date
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- 230000003373 anti-fouling effect Effects 0.000 title claims 36
- HRLIOXLXPOHXTA-UHFFFAOYSA-N medetomidine Chemical compound C=1C=CC(C)=C(C)C=1C(C)C1=CN=C[N]1 HRLIOXLXPOHXTA-UHFFFAOYSA-N 0.000 claims 44
- 229960002140 medetomidine Drugs 0.000 claims 44
- 150000003839 salts Chemical class 0.000 claims 24
- 229920005862 polyol Polymers 0.000 claims 13
- 150000003077 polyols Chemical class 0.000 claims 13
- 239000004814 polyurethane Substances 0.000 claims 11
- 229920002635 polyurethane Polymers 0.000 claims 11
- 239000002904 solvent Substances 0.000 claims 11
- 239000000203 mixture Substances 0.000 claims 10
- 239000012948 isocyanate Substances 0.000 claims 6
- 150000002513 isocyanates Chemical class 0.000 claims 6
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims 5
- 239000004721 Polyphenylene oxide Substances 0.000 claims 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims 4
- 150000004985 diamines Chemical class 0.000 claims 4
- 150000002009 diols Chemical class 0.000 claims 4
- 239000011159 matrix material Substances 0.000 claims 4
- 239000003973 paint Substances 0.000 claims 4
- 229920005906 polyester polyol Polymers 0.000 claims 4
- 229920000570 polyether Polymers 0.000 claims 4
- 229920000642 polymer Polymers 0.000 claims 4
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims 3
- 230000003115 biocidal effect Effects 0.000 claims 3
- 239000003139 biocide Substances 0.000 claims 3
- 239000003795 chemical substances by application Substances 0.000 claims 3
- 238000013270 controlled release Methods 0.000 claims 3
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims 3
- 238000000034 method Methods 0.000 claims 3
- 239000004970 Chain extender Substances 0.000 claims 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims 2
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(i) oxide Chemical compound [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- 239000000049 pigment Substances 0.000 claims 2
- 229920000768 polyamine Polymers 0.000 claims 2
- 239000004971 Cross linker Substances 0.000 claims 1
- 239000002519 antifouling agent Substances 0.000 claims 1
- 238000005266 casting Methods 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 239000002274 desiccant Substances 0.000 claims 1
- 229910044991 metal oxide Inorganic materials 0.000 claims 1
- 150000004706 metal oxides Chemical class 0.000 claims 1
- 238000000465 moulding Methods 0.000 claims 1
- 239000002105 nanoparticle Substances 0.000 claims 1
- 238000005507 spraying Methods 0.000 claims 1
- 239000003351 stiffener Substances 0.000 claims 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium(II) oxide Chemical compound [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims 1
- 239000011787 zinc oxide Substances 0.000 claims 1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1625—Non-macromolecular compounds organic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/10—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by other chemical means
- B05D3/107—Post-treatment of applied coatings
- B05D3/108—Curing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6603—Compounds of groups C08G18/42, C08G18/48, or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6607—Compounds of groups C08G18/42, C08G18/48, or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6633—Compounds of group C08G18/42
- C08G18/6637—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/664—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
- C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0058—Biocides
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
- C08K5/3445—Five-membered rings
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- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
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- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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Claims (15)
1. Proizvod za suzbijanje obrastanja koji sadrži:
poliuretan i
medetomidin ili enantiomer ili njegovu sol, od 0,1 % po težini navedenog proizvoda za suzbijanje obrastanja i prisutan u matrici polimera navedenog poliuretana, pri čemu se navedeni proizvod za suzbijanje obrastanja može dobiti:
miješanjem medetomidina ili navedenog enantiomera ili njegove soli i otapala da nastane otopina medetomidina;
reakcijom navedene otopine medetomidina s barem jednim izocijanatom koji sadrži barem dvije skupine izocijanata po molekuli i barem jedan poliol za stvaranje poliuretana, pri čemu je navedeni medetomidin ili navedeni enantiomer ili njegova sol prisutan u navedenoj matrici polimera; i
pretvaranjem navedenog poliuretana u navedeni proizvod za suzbijanje obrastanja, pri čemu je navedeni medetomidin ili enantiomer ili njegova sol, prisutan u barem 0,1 % po težini navedenog proizvoda za suzbijanje obrastanja.
2. Proizvod za suzbijanje obrastanja prema zahtjevu 1, pri čemu miješanje medetomidina ili navedenog enantiomera ili njegove soli i navedenog otapala obuhvaća miješanje medetomidina ili enantiomera ili njegove soli i otapala odabranog iz skupine koja sadrži diol, poliol, diamin, poliamin i njihovu mješavinu, po mogućnosti skupinu koja sadrži diol, diamin ili njihovu mješavinu i još više po mogućnosti 1,4-butandiol.
3. Proizvod za suzbijanje obrastanja prema zahtjevima 1 i 2, pri čemu miješanje medetomidina ili navedenog enantiomera ili njegove soli i navedenog otapala obuhvaća miješanje medetomidina ili navedenog enantiomera ili njegove soli i otapala upotrijebljenog kao produljivač lanca i/ili poprečna spona u reakciji navedene otopine medetomidina s navedenim barem jednim izocijanatom i navedenim barem jednim poliolom.
4. Proizvod za suzbijanje obrastanja prema zahtjevima od 1 do 3, pri čemu miješanje medetomidina ili navedenog enantiomera ili njegove soli i navedenog otapala obuhvaća otapanje medetomidina ili navedenog enantiomera ili njegove soli u navedenom otapalu da nastane navedena otopina medetomidina koja sadrži medetomidin ili navedeni enantiomer ili njegovu sol, od 0,1 pa do 20 % po težini navedene otopine medetomidina, po mogućnosti od 5 pa do 20 % po težini navedene otopine medetomidina i još više po mogućnosti od 10 pa do 20 % po težini navedene otopine medetomidina.
5. Proizvod protiv obrastanja prema bilo kojem od zahtjeva od 1 do 4, pri čemu reakcija navedene otopine medetomidina obuhvaća reakciju navedene otopine medetomidina s metilen difenil diizocijanatom (MDI) i najmanje jednim poliolom da nastane poliuretan.
6. Proizvod za suzbijanje obrastanja prema zahtjevu 5, pri čemu reakcija navedene otopine medetomidina obuhvaća reakciju navedene mješavine medetomidina s MDI-jem i barem jednim polieterskim poliolom, barem jednim poliesterskim poliolom ili mješavinom barem jednog polieterskog poliola i barem jednoga poliesterskog poliola.
7. Proizvod za suzbijanje obrastanja prema bilo kojem od zahtjeva od 1 do 6, koji sadrži medetomidin ili navedeni enantiomer ili njegovu sol, od 0,1 do 2 % po težini navedenog proizvoda za suzbijanje obrastanja, po mogućnosti od 0,1 do 1,5 % po težini navedenog proizvoda za suzbijanje obrastanja i još više po mogućnosti od 0,1 pa do 1 % po težini navedenog proizvoda za suzbijanje obrastanja.
8. Proizvod za suzbijanje obrastanja prema bilo kojem od zahtjeva od 1 do 7, pri čemu navedeni proizvod za suzbijanje obrastanja sadrži:
poliuretan;
medetomidin ili enantiomer ili njegovu sol, od 0,1 % po težini navedenog proizvoda za suzbijanje obrastanja i prisutan u navedenoj matrici polimera;
opcionalno barem jedan pigment;
opcionalno barem jedan biocid koji nije medetomidin ili enantiomer ili njegova sol; i
opcionalno barem jedno sredstvo s kontroliranim otpuštanjem, pri čemu je medetomidin ili navedeni enantiomer ili njegova sol i/ili navedeni barem jedan opcionalni biocid koji nije medetomidin ili navedeni enantiomer ili njegova sol opcionalno barem djelomično vezan s navedenim barem jednim sredstvom s kontroliranim otpuštanjem.
9. Proizvod za suzbijanje obrastanja prema bilo kojem od zahtjeva od 1 do 8, pri čemu se navedeni proizvod za suzbijanje obrastanja odabire iz skupine koja se sastoji od sloja protiv obrastanja, filma protiv obrastanja i boje protiv obrastanja, po mogućnosti sloj protiv obrastanja, film protiv obrastanja i boja protiv obrastanja podvodnog ili uronjivog uređaja ili strukture odabrane iz skupine koja se sastoji od tunela propelera, lopatice vodilice, branika, brodskog trupa, opreme za vez, podvodnog užeta, podvodne žice i podvodne mreže.
10. Proizvod za suzbijanje obrastanja prema bilo kojem od zahtjeva od 1 to 8, pri čemu se navedeni proizvod za suzbijanje obrastanja odabire iz skupine koja sadrži učvršćivač savijenih dijelova, ograničivač savijanja, obalni odbojnik, branik i opremu za vez.
11. Metoda za proizvodnju proizvoda za suzbijanje obrastanja koja obuhvaća:
miješanje medetomidina ili enantiomera ili njegove soli i otapala da nastane otopina medetomidina;
reakciju navedene otopine medetomidina s barem jednim izocijanatom koji sadrži barem dvije skupine izocijanata po molekuli i barem jedan poliol za nastanak poliuretana, pri čemu je navedeni medetomidin ili navedeni enantiomer ili njegova sol prisutan u matrici polimera navedenog poliuretana; i
pretvaranjem navedenog poliuretana u navedeni proizvod za suzbijanje obrastanja, pri čemu je navedeni medetomidin ili enantiomer ili njegova sol, prisutan u barem 0,1 % po težini navedenog proizvoda za suzbijanje obrastanja.
12. Metoda prema zahtjevu 11, pri čemu pretvaranje navedenog poliuretana u navedeni proizvod protiv obrastanja obuhvaća:
prskanje mješavine navedene otopine medetomidina, navedenog barem jednog izocijanata i navedenog barem jednog poliola na površinu da nastane sloj, film ili boja; i
stvrdnjavanje navedenog sloja, navedenog filma ili navedene boje na navedenoj površini da se stvori navedeni proizvod protiv obrastanja.
13. Metoda prema zahtjevu 11, pri čemu pretvaranje navedenog poliuretana u navedeni proizvod protiv obrastanja obuhvaća:
oblikovanje ili lijevanje mješavine navedene otopine medetomidina, navedenog barem jednog izocijanata ili navedenog barem jednog poliola u kalup; i
stvrdnjavanje navedene mješavine u navedenom kalupu da nastane navedeni proizvod za suzbijanje obrastanja.
14. Komplet za proizvodnju proizvoda protiv obrastanja, navedeni komplet sadrži:
barem jedan poliol, po mogućnosti barem jedan polieterski poliol, barem jedan poliesterski poliol ili mješavinu barem jednoga polieterskog poliola i barem jednoga poliesterskog poliola;
barem jedan izocijanat koji sadrži barem dvije skupine izocijanata po molekuli, po mogućnosti metilen difenil diizocijanat (MDI);
otapalo, po mogućnosti odabrano iz skupine koja sadrži diol, poliol, diamin, poliamin i njihovu mješavinu, po mogućnosti skupinu koja sadrži diol, diamin ili njihovu mješavinu i još više po mogućnosti 1,4-butandiol;
medetomidin ili enantiomer ili njegovu sol u količini dovoljnoj da se postigne koncentracija medetomidina od najmanje 0,1 % po težini navedenog sredstva protiv obrastanja;
opcionalno katalizator;
opcionalno barem jedan produljivač lanca i/ili poprečna spona;
opcionalno barem jedno sredstvo za sušenje;
opcionalno barem jedan pigment;
opcionalno barem jedan biocid koji nije medetomidin ili enantiomer ili njegova sol; i
po mogućnosti barem sredstvo s kontroliranim ispuštanjem, po mogućnosti nanočestice od oksida metala po mogućnosti titanijeva(II) oksida, bakrenog(II) oksida, bakrenog(I) oksida ili cinkova oksida.
15. Komplet prema zahtjevu 14, sadrži medetomidin ili enantiomer ili njegovu sol i navedeno otapalo u količinama dovoljnim da nastane otopina medetomidina koja sadrži medetomidin ili enantiomer ili njegovu sol i navedeno otapalo s medetomidinom ili enantiomerom ili njegovom solju od 0,1 pa do 20 % po težini navedene otopine medetomidina, po mogućnosti od 5 pa do 20 % po težini navedene otopine medetomidina i još više po mogućnosti od 10 pa do 20 % po težini otopine medetomidina.
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SE1750367 | 2017-03-29 | ||
EP18717750.6A EP3601446B1 (en) | 2017-03-29 | 2018-03-29 | Antifouling article |
PCT/SE2018/050347 WO2018182499A1 (en) | 2017-03-29 | 2018-03-29 | Antifouling article |
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US (1) | US11603475B2 (hr) |
EP (1) | EP3601446B1 (hr) |
JP (2) | JP7201611B2 (hr) |
KR (1) | KR102540792B1 (hr) |
CN (1) | CN110662808B (hr) |
DK (1) | DK3601446T3 (hr) |
ES (1) | ES2882193T3 (hr) |
HR (1) | HRP20211133T1 (hr) |
PL (1) | PL3601446T3 (hr) |
PT (1) | PT3601446T (hr) |
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TWI692563B (zh) * | 2019-08-06 | 2020-05-01 | 健豐全球貿易股份有限公司 | 防污結構及其製備方法 |
CN114621577B (zh) * | 2022-03-22 | 2023-09-01 | 浙江伟星实业发展股份有限公司 | 一种抗吸色树脂材料及其制备方法和应用 |
WO2024047144A1 (en) * | 2022-09-01 | 2024-03-07 | I-Tech Ab | Composition protecting wood against marine woodborers |
WO2024075529A1 (ja) * | 2022-10-06 | 2024-04-11 | Dic株式会社 | 積層体、包装材 |
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GB1307001A (en) | 1970-01-12 | 1973-02-14 | Kroyer K K K | Marine structure having a surface coating for the prevention of accumulation of marine organisms |
US3702778A (en) | 1970-03-23 | 1972-11-14 | Battelle Memorial Institute | Ship's hull coated with antifouling silicone rubber |
GB2101114B (en) | 1981-07-10 | 1985-05-22 | Farmos Group Ltd | Substituted imidazole derivatives and their preparation and use |
US6054504A (en) * | 1997-12-31 | 2000-04-25 | Hydromer, Inc. | Biostatic coatings for the reduction and prevention of bacterial adhesion |
SE513474C2 (sv) * | 1999-01-25 | 2000-09-18 | Hans Elwing Instutionen Foer C | Metod för att förhindra kräftdjurs, särskilt havstulpaners, etablering på fasta ytor med hjälp av en substans som stör nervsignaler, varvid substansen är medetomidin, dvs (+)-4-/1- (2,3-dimetylfenyl)-etyl/-IH-imidazol |
US7311766B2 (en) | 2005-03-11 | 2007-12-25 | I-Tech Ab | Method and use of nanoparticles to bind biocides in paints |
US7531581B2 (en) * | 2005-03-11 | 2009-05-12 | I-Tech Ab | Method and use of acidified modified polymers to bind biocides in paints |
DE102005011990A1 (de) * | 2005-03-14 | 2006-09-21 | Basf Ag | Foulingresistente Polyurethane, insbesondere für maritime Anwendungen |
WO2007007901A1 (ja) | 2005-07-12 | 2007-01-18 | Kabushiki Kaisya Advance | 電源及び簡易電気泳動装置 |
WO2009100908A1 (en) | 2008-02-13 | 2009-08-20 | Jotun A/S | Antifouling composition |
US20110274763A1 (en) * | 2009-05-19 | 2011-11-10 | Nyden Bo Magnus | Slow releasing microcapsules and microspheres containing an active substance |
US20120015017A1 (en) * | 2009-05-19 | 2012-01-19 | Nyden Bo Magnus | Slow releasing microcapsules containing an active substance |
WO2011070069A1 (en) | 2009-12-09 | 2011-06-16 | I-Tech Ab | Process for preparation of medetomidine |
AU2012271948B2 (en) | 2011-06-21 | 2015-10-15 | Akzo Nobel Coatings International B.V. | Biocidal foul release coating systems |
BR112013032393B1 (pt) | 2011-06-21 | 2021-01-26 | Basell Polyolefine Gmbh | processo para descarregar partículas de poliolefina a partir de reator de polimerização em fase gasosa e processo para polimerizar olefinas |
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WO2013190121A1 (en) * | 2012-06-22 | 2013-12-27 | Ppg Coatings Europe B.V. | Antifouling coating composition |
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DK3601446T3 (da) | 2021-08-09 |
JP2020515691A (ja) | 2020-05-28 |
WO2018182499A1 (en) | 2018-10-04 |
US20200048477A1 (en) | 2020-02-13 |
EP3601446B1 (en) | 2021-05-05 |
EP3601446A1 (en) | 2020-02-05 |
US11603475B2 (en) | 2023-03-14 |
SG11201908605XA (en) | 2019-10-30 |
PL3601446T3 (pl) | 2021-11-02 |
KR20190130617A (ko) | 2019-11-22 |
PT3601446T (pt) | 2021-07-20 |
CN110662808A (zh) | 2020-01-07 |
CN110662808B (zh) | 2022-05-24 |
JP2023014073A (ja) | 2023-01-26 |
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