HRP20200365T1 - Postupak povećavanja brzine nastajanja produkta reakcije karboksilne kiseline s ureom dodavanjem kiseline - Google Patents

Postupak povećavanja brzine nastajanja produkta reakcije karboksilne kiseline s ureom dodavanjem kiseline Download PDF

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Publication number
HRP20200365T1
HRP20200365T1 HRP20200365TT HRP20200365T HRP20200365T1 HR P20200365 T1 HRP20200365 T1 HR P20200365T1 HR P20200365T T HRP20200365T T HR P20200365TT HR P20200365 T HRP20200365 T HR P20200365T HR P20200365 T1 HRP20200365 T1 HR P20200365T1
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HR
Croatia
Prior art keywords
acid
substituted
reaction product
formulation
group
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Application number
HRP20200365TT
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English (en)
Inventor
Jerry Stoller
Ritesh Sheth
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Stoller Enterprises, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Stoller Enterprises, Inc. filed Critical Stoller Enterprises, Inc.
Publication of HRP20200365T1 publication Critical patent/HRP20200365T1/hr

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C273/00Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C273/18Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas
    • C07C273/1854Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas by reactions not involving the formation of the N-C(O)-N- moiety
    • C07C273/1863Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas by reactions not involving the formation of the N-C(O)-N- moiety from urea
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C275/00Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C275/46Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups containing any of the groups, X being a hetero atom, Y being any atom, e.g. acylureas
    • C07C275/48Y being a hydrogen or a carbon atom
    • C07C275/50Y being a hydrogen or an acyclic carbon atom

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Claims (12)

1. Postupak dobivanja produkta reakcije povećanom brzinom nastajanja, naznačen time što se sastoji u osiguravanju otopine koja sadrži karboksilnu kiselinu i ureu; dodavanju najmanje jedne kiseline u navedenu otopinu kako bi se dobilo produkt reakcije koji ima formulu [image] , gdje su R1 i R2 isti ili različiti i bira ih se iz skupine koju čine vodik ili supstituirani i nesupstituirani alkil, a R3 i R4 su isti ili različiti i bira ih se iz skupine koju čine vodik, supstituirane i nesupstituirane alkilne, alilne, vinilne i alkoksilne skupine s od 1-6 atoma ugljika, supstituirane i nesupstituirane fenilne skupine i halogenidi.
2. Postupak u skladu s patentnim zahtjevom 1, naznačen time što je navedena karboksilna kiselina mravlja kiselina.
3. Postupak u skladu s patentnim zahtjevom 1, naznačen time što navedena karboksilna kiselina ima formulu RCOOH, gdje se R bira iz skupine koju čine vodik, supstituirane i nesupstituirane alkilne, alilne, vinilne i alkoksilne skupine s od 1 do 6 atoma ugljika, supstituirane i nesupstituirane fenilne skupine i halogenidi.
4. Postupak u skladu s bilo kojim od patentnih zahtjeva 1-3, naznačen time što navedena urea ima formulu (NHR′)2CO, gdje je svaki R′ isti ili različiti i bira se iz skupine koju čine vodik, supstituirane i nesupstituirane alkilne skupine s od 1 do 6 atoma ugljika, supstituirane i nesupstituirane alkoksilne skupine s od 1 do 6 atoma ugljika, supstituirane i nesupstituirane fenilne skupine i halogenidi.
5. Postupak u skladu s bilo kojim od patentnih zahtjeva 1-4, naznačen time što navedena otopina sadrži 0,1-20%, težinski, navedene najmanje jedne kiseline; ili što navedena otopina sadrži 0,1-10%, težinski, navedene najmanje jedne kiseline.
6. Postupak u skladu s bilo kojim od patentnih zahtjeva 1-5, naznačen time što se N,N′-diformilureu kao produkt reakcije dobiva osiguravanjem otopine koja sadrži mravlju kiselinu kao navedenu karboksilnu kiselinu i ureu kao navedenu ureu.
7. Formulacija za poboljšavanje rasta biljaka naznačena time što sadrži najmanje jedno otapalo i navedeni produkt reakcije u skladu s bilo kojim od patentnih zahtjeva 1-6, gdje navedena formulacija ne sadrži ikakve modifikatore pH koji su spojevi koji sadrže hidroksid.
8. Formulacija u skladu s patentnim zahtjevom 7, naznačena time što je navedeni modifikator pH kalijev hidroksid.
9. Formulacija u skladu s bilo kojim od patentnih zahtjeva 7 ili 8, naznačena time što je navedeno najmanje jedno otapalo N-metilpirolidon (NMP).
10. Formulacija u skladu s bilo kojim od patentnih zahtjeva 7-9, naznačena time što navedena formulacija sadrži 0,001-1,0 M produkta reakcije; ili što navedena formulacija sadrži 0,001-0,050 M produkta reakcije.
11. Formulacija u skladu s bilo kojim od patentnih zahtjeva 7-10, naznačena time što se navedenu najmanje jednu kiselinu bira iz skupine koju čine sumporna kiselina, sulfaminska kiselina, klorovodična kiselina, bromovodična kiselina, fluorovodična kiselina, dušična kiselina, fosforna kiselina, polifosforna kiselina, metalni halogenidi, alkil- i arilsulfonske kiseline, aminokiseline, trihalogenalkil kiseline, te organotitanati.
12. Formulacija u skladu s bilo kojim od patentnih zahtjeva 7-10, naznačena time što je navedena najmanje jedna kiselina sumporna kiselina.
HRP20200365TT 2014-12-30 2020-03-04 Postupak povećavanja brzine nastajanja produkta reakcije karboksilne kiseline s ureom dodavanjem kiseline HRP20200365T1 (hr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201462098180P 2014-12-30 2014-12-30
PCT/US2015/067992 WO2016109622A1 (en) 2014-12-30 2015-12-30 Method for enhancing the rate of the formation of the reaction product of a carboylic acid and a urea via acid addition
EP15876223.7A EP3240774B1 (en) 2014-12-30 2015-12-30 Method for enhancing the rate of the formation of the reaction product of a carboylic acid and a urea via acid addition

Publications (1)

Publication Number Publication Date
HRP20200365T1 true HRP20200365T1 (hr) 2020-08-21

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Family Applications (1)

Application Number Title Priority Date Filing Date
HRP20200365TT HRP20200365T1 (hr) 2014-12-30 2020-03-04 Postupak povećavanja brzine nastajanja produkta reakcije karboksilne kiseline s ureom dodavanjem kiseline

Country Status (24)

Country Link
US (1) US9920001B2 (hr)
EP (1) EP3240774B1 (hr)
KR (1) KR102654043B1 (hr)
CN (1) CN107108484B (hr)
AR (1) AR103335A1 (hr)
AU (1) AU2015374094B2 (hr)
CA (1) CA2962148C (hr)
CL (1) CL2017000861A1 (hr)
CO (1) CO2017004933A2 (hr)
CR (1) CR20170295A (hr)
EC (1) ECSP17035769A (hr)
ES (1) ES2776426T3 (hr)
HR (1) HRP20200365T1 (hr)
HU (1) HUE047943T2 (hr)
LT (1) LT3240774T (hr)
MX (1) MX2017008810A (hr)
NI (1) NI201700084A (hr)
PE (1) PE20171065A1 (hr)
PH (1) PH12017501227A1 (hr)
PL (1) PL3240774T3 (hr)
PT (1) PT3240774T (hr)
RS (1) RS60620B1 (hr)
WO (1) WO2016109622A1 (hr)
ZA (1) ZA201704904B (hr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110372541A (zh) * 2019-07-26 2019-10-25 南通市争妍新材料科技有限公司 一种羧酸和尿素高效固相合成酰胺衍生物的方法
CN115024389A (zh) * 2022-07-06 2022-09-09 青岛元农生物科技有限公司 一种缓释非蛋白氮添加剂及其制备和使用方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DD87780A (hr) 1971-11-17 1972-11-12
US773251A (en) * 1903-03-09 1904-10-25 Firm Of E Merck Ureide of dialkyl-acetic and process of making same.
ES2243993T3 (es) * 1996-04-10 2005-12-01 Stoller Enterprises, Inc. Diformilurea y productos de reaccion de urea y acidos carboxilicos.
US6040273A (en) * 1997-04-09 2000-03-21 Stoller Enterprises, Inc. Diformylurea and reaction products of urea and carboxylic acids
EP2185505A2 (en) 2007-06-25 2010-05-19 Yissum Research Development Company of the Hebrew University of Jerusalem Ltd Acyl-urea derivatives and uses thereof
JP6117226B2 (ja) * 2011-11-03 2017-04-19 バイエル クロップサイエンス エルピーBayer Cropscience Lp 植物の質を向上させるための組成物及び方法

Also Published As

Publication number Publication date
HUE047943T2 (hu) 2020-05-28
EP3240774A1 (en) 2017-11-08
US9920001B2 (en) 2018-03-20
US20160185715A1 (en) 2016-06-30
PE20171065A1 (es) 2017-07-21
CO2017004933A2 (es) 2017-07-28
WO2016109622A1 (en) 2016-07-07
CL2017000861A1 (es) 2017-11-10
KR102654043B1 (ko) 2024-04-02
PT3240774T (pt) 2020-03-10
AU2015374094A1 (en) 2017-04-27
RS60620B1 (sr) 2020-09-30
AU2015374094B2 (en) 2020-07-16
CN107108484B (zh) 2021-04-13
ECSP17035769A (es) 2017-06-30
CA2962148C (en) 2023-04-25
ZA201704904B (en) 2018-12-19
PH12017501227B1 (en) 2018-01-15
CN107108484A (zh) 2017-08-29
LT3240774T (lt) 2020-03-25
CR20170295A (es) 2017-11-24
PL3240774T3 (pl) 2020-06-29
MX2017008810A (es) 2017-10-19
KR20170104143A (ko) 2017-09-14
AR103335A1 (es) 2017-05-03
ES2776426T3 (es) 2020-07-30
EP3240774A4 (en) 2018-08-15
NI201700084A (es) 2017-07-18
CA2962148A1 (en) 2016-07-07
PH12017501227A1 (en) 2018-01-15
EP3240774B1 (en) 2019-12-11

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