HRP20180263T1 - Jednostupanjski ("one-pot") postupak za pripravu smjesa biodizela i glicerol-etera korisnih kao biogoriva - Google Patents
Jednostupanjski ("one-pot") postupak za pripravu smjesa biodizela i glicerol-etera korisnih kao biogoriva Download PDFInfo
- Publication number
- HRP20180263T1 HRP20180263T1 HRP20180263TT HRP20180263T HRP20180263T1 HR P20180263 T1 HRP20180263 T1 HR P20180263T1 HR P20180263T T HRP20180263T T HR P20180263TT HR P20180263 T HRP20180263 T HR P20180263T HR P20180263 T1 HRP20180263 T1 HR P20180263T1
- Authority
- HR
- Croatia
- Prior art keywords
- oil
- formula
- acids
- group
- methyl
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims 2
- 239000003225 biodiesel Substances 0.000 title 1
- 239000002551 biofuel Substances 0.000 title 1
- RBNPOMFGQQGHHO-UHFFFAOYSA-N glyceric acid Chemical compound OCC(O)C(O)=O RBNPOMFGQQGHHO-UHFFFAOYSA-N 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000005580 one pot reaction Methods 0.000 title 1
- 238000000034 method Methods 0.000 claims 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical class O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 7
- 239000003921 oil Substances 0.000 claims 7
- 235000019198 oils Nutrition 0.000 claims 7
- 239000002253 acid Substances 0.000 claims 5
- 239000003377 acid catalyst Substances 0.000 claims 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 4
- 150000007513 acids Chemical class 0.000 claims 3
- 125000000217 alkyl group Chemical group 0.000 claims 3
- 238000006243 chemical reaction Methods 0.000 claims 3
- -1 isobutenyl Chemical group 0.000 claims 3
- 239000002994 raw material Substances 0.000 claims 3
- 235000012239 silicon dioxide Nutrition 0.000 claims 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 2
- 125000003342 alkenyl group Chemical group 0.000 claims 2
- 125000000304 alkynyl group Chemical group 0.000 claims 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 150000001735 carboxylic acids Chemical class 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 2
- 239000003925 fat Substances 0.000 claims 2
- 235000019197 fats Nutrition 0.000 claims 2
- 239000000194 fatty acid Substances 0.000 claims 2
- 229930195729 fatty acid Natural products 0.000 claims 2
- 150000004665 fatty acids Chemical class 0.000 claims 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 2
- 235000014593 oils and fats Nutrition 0.000 claims 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims 2
- 235000005713 safflower oil Nutrition 0.000 claims 2
- 239000003813 safflower oil Substances 0.000 claims 2
- 239000000377 silicon dioxide Substances 0.000 claims 2
- 238000002604 ultrasonography Methods 0.000 claims 2
- 239000002699 waste material Substances 0.000 claims 2
- 235000019489 Almond oil Nutrition 0.000 claims 1
- 235000001274 Anacardium occidentale Nutrition 0.000 claims 1
- 244000226021 Anacardium occidentale Species 0.000 claims 1
- 235000014698 Brassica juncea var multisecta Nutrition 0.000 claims 1
- 235000006008 Brassica napus var napus Nutrition 0.000 claims 1
- 240000000385 Brassica napus var. napus Species 0.000 claims 1
- 235000006618 Brassica rapa subsp oleifera Nutrition 0.000 claims 1
- 235000004977 Brassica sinapistrum Nutrition 0.000 claims 1
- 235000004936 Bromus mango Nutrition 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 235000019499 Citrus oil Nutrition 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 235000010099 Fagus sylvatica Nutrition 0.000 claims 1
- 240000000731 Fagus sylvatica Species 0.000 claims 1
- 235000019500 Grapefruit seed oil Nutrition 0.000 claims 1
- 235000019487 Hazelnut oil Nutrition 0.000 claims 1
- 240000000950 Hippophae rhamnoides Species 0.000 claims 1
- 235000003145 Hippophae rhamnoides Nutrition 0.000 claims 1
- 241000221089 Jatropha Species 0.000 claims 1
- 235000019501 Lemon oil Nutrition 0.000 claims 1
- 235000019493 Macadamia oil Nutrition 0.000 claims 1
- 235000014826 Mangifera indica Nutrition 0.000 claims 1
- 240000007228 Mangifera indica Species 0.000 claims 1
- 241001465754 Metazoa Species 0.000 claims 1
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 claims 1
- 235000019502 Orange oil Nutrition 0.000 claims 1
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- 235000019482 Palm oil Nutrition 0.000 claims 1
- 235000019483 Peanut oil Nutrition 0.000 claims 1
- 235000019496 Pine nut oil Nutrition 0.000 claims 1
- 235000019497 Pistachio oil Nutrition 0.000 claims 1
- 244000088415 Raphanus sativus Species 0.000 claims 1
- 235000006140 Raphanus sativus var sativus Nutrition 0.000 claims 1
- 235000019485 Safflower oil Nutrition 0.000 claims 1
- 244000057114 Sapium sebiferum Species 0.000 claims 1
- 235000005128 Sapium sebiferum Nutrition 0.000 claims 1
- 235000009184 Spondias indica Nutrition 0.000 claims 1
- 235000019486 Sunflower oil Nutrition 0.000 claims 1
- 235000019498 Walnut oil Nutrition 0.000 claims 1
- 125000005907 alkyl ester group Chemical group 0.000 claims 1
- ZOJBYZNEUISWFT-UHFFFAOYSA-N allyl isothiocyanate Chemical compound C=CCN=C=S ZOJBYZNEUISWFT-UHFFFAOYSA-N 0.000 claims 1
- 239000008168 almond oil Substances 0.000 claims 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims 1
- 229910021486 amorphous silicon dioxide Inorganic materials 0.000 claims 1
- 239000010479 artichoke oil Substances 0.000 claims 1
- 235000015278 beef Nutrition 0.000 claims 1
- 125000004369 butenyl group Chemical group C(=CCC)* 0.000 claims 1
- 125000000480 butynyl group Chemical group [*]C#CC([H])([H])C([H])([H])[H] 0.000 claims 1
- 235000019519 canola oil Nutrition 0.000 claims 1
- 239000000828 canola oil Substances 0.000 claims 1
- 239000002041 carbon nanotube Substances 0.000 claims 1
- 229910021393 carbon nanotube Inorganic materials 0.000 claims 1
- 239000004359 castor oil Substances 0.000 claims 1
- 235000019438 castor oil Nutrition 0.000 claims 1
- 235000013339 cereals Nutrition 0.000 claims 1
- 239000010500 citrus oil Substances 0.000 claims 1
- 235000019864 coconut oil Nutrition 0.000 claims 1
- 239000003240 coconut oil Substances 0.000 claims 1
- 235000005687 corn oil Nutrition 0.000 claims 1
- 239000002285 corn oil Substances 0.000 claims 1
- 235000012343 cottonseed oil Nutrition 0.000 claims 1
- 239000002385 cottonseed oil Substances 0.000 claims 1
- 239000001224 daucus carota l. seed absolute Substances 0.000 claims 1
- 235000013399 edible fruits Nutrition 0.000 claims 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 claims 1
- 229940013317 fish oils Drugs 0.000 claims 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims 1
- 239000010468 hazelnut oil Substances 0.000 claims 1
- 239000010460 hemp oil Substances 0.000 claims 1
- 125000006038 hexenyl group Chemical group 0.000 claims 1
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 1
- 239000003456 ion exchange resin Substances 0.000 claims 1
- 229920003303 ion-exchange polymer Polymers 0.000 claims 1
- 239000002608 ionic liquid Substances 0.000 claims 1
- 125000000555 isopropenyl group Chemical group [H]\C([H])=C(\*)C([H])([H])[H] 0.000 claims 1
- 229940119170 jojoba wax Drugs 0.000 claims 1
- 239000010501 lemon oil Substances 0.000 claims 1
- 235000021388 linseed oil Nutrition 0.000 claims 1
- 239000000944 linseed oil Substances 0.000 claims 1
- 239000010469 macadamia oil Substances 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 229910044991 metal oxide Inorganic materials 0.000 claims 1
- 150000004706 metal oxides Chemical group 0.000 claims 1
- 239000011707 mineral Substances 0.000 claims 1
- 239000002808 molecular sieve Substances 0.000 claims 1
- 229910052901 montmorillonite Inorganic materials 0.000 claims 1
- 230000000877 morphologic effect Effects 0.000 claims 1
- 239000008164 mustard oil Substances 0.000 claims 1
- 229910052758 niobium Inorganic materials 0.000 claims 1
- 239000010955 niobium Substances 0.000 claims 1
- 229910000484 niobium oxide Inorganic materials 0.000 claims 1
- URLJKFSTXLNXLG-UHFFFAOYSA-N niobium(5+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[O-2].[O-2].[Nb+5].[Nb+5] URLJKFSTXLNXLG-UHFFFAOYSA-N 0.000 claims 1
- 235000008390 olive oil Nutrition 0.000 claims 1
- 239000004006 olive oil Substances 0.000 claims 1
- 239000010502 orange oil Substances 0.000 claims 1
- 150000007524 organic acids Chemical class 0.000 claims 1
- 235000005985 organic acids Nutrition 0.000 claims 1
- 239000002540 palm oil Substances 0.000 claims 1
- 239000000312 peanut oil Substances 0.000 claims 1
- 235000021317 phosphate Nutrition 0.000 claims 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims 1
- 239000010490 pine nut oil Substances 0.000 claims 1
- 239000010471 pistachio oil Substances 0.000 claims 1
- 229940082415 pistachio oil Drugs 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 239000010491 poppyseed oil Substances 0.000 claims 1
- 244000144977 poultry Species 0.000 claims 1
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 claims 1
- 125000002568 propynyl group Chemical group [*]C#CC([H])([H])[H] 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 235000011803 sesame oil Nutrition 0.000 claims 1
- 239000008159 sesame oil Substances 0.000 claims 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims 1
- 239000011973 solid acid Substances 0.000 claims 1
- 235000012424 soybean oil Nutrition 0.000 claims 1
- 239000003549 soybean oil Substances 0.000 claims 1
- 150000003460 sulfonic acids Chemical class 0.000 claims 1
- 239000002600 sunflower oil Substances 0.000 claims 1
- 239000003760 tallow Substances 0.000 claims 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 239000004408 titanium dioxide Substances 0.000 claims 1
- 238000005809 transesterification reaction Methods 0.000 claims 1
- 150000003626 triacylglycerols Chemical class 0.000 claims 1
- 239000008158 vegetable oil Substances 0.000 claims 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 1
- 239000008170 walnut oil Substances 0.000 claims 1
- 239000010457 zeolite Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
- C10L1/026—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/10—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing sonic or ultrasonic vibrations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
- B01J19/122—Incoherent waves
- B01J19/126—Microwaves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
- B01J19/122—Incoherent waves
- B01J19/129—Radiofrequency
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/09—Preparation of ethers by dehydration of compounds containing hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/14—Preparation of ethers by exchange of organic parts on the ether-oxygen for other organic parts, e.g. by trans-etherification
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/24—Preparation of carboxylic acid esters by reacting carboxylic acids or derivatives thereof with a carbon-to-oxygen ether bond, e.g. acetal, tetrahydrofuran
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
- C07C67/297—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
- C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/003—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with alcohols
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2200/00—Components of fuel compositions
- C10L2200/02—Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
- C10L2200/0254—Oxygen containing compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2200/00—Components of fuel compositions
- C10L2200/04—Organic compounds
- C10L2200/0461—Fractions defined by their origin
- C10L2200/0469—Renewables or materials of biological origin
- C10L2200/0476—Biodiesel, i.e. defined lower alkyl esters of fatty acids first generation biodiesel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2270/00—Specifically adapted fuels
- C10L2270/02—Specifically adapted fuels for internal combustion engines
- C10L2270/026—Specifically adapted fuels for internal combustion engines for diesel engines, e.g. automobiles, stationary, marine
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/34—Applying ultrasonic energy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/36—Applying radiation such as microwave, IR, UV
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Emergency Medicine (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Fats And Perfumes (AREA)
- Liquid Carbonaceous Fuels (AREA)
Claims (11)
1. Postupak za pretvorbu sirovine koja sadrži jedan ili više triglicerida masnih kiselina u smjesu koja sadrži jedan ili više alkil-estera masnih kiselina i t-alkilglicerola, koji obuhvaća reakciju rečene sirovine sa spojem formule (I):
R–O–R' (I)
u kojoj:
R' je alkil, alkenil ili alkinil koji ima 1-18 ugljikovih atoma; R je H ili tercijarna alkilna skupina formule (II):
[image]
u kojoj RIII, RIV i RV neovisno jesu ravni ili razgranati alkil, alkenil ili alkinilna skupina koja ima 1 do 6 ugljikovih atoma;
u kojoj je rečena reakcija provedena u prisutnosti kiselog katalizatora za transesterifikaciju ozračavanjem s mikrovalovima i/ili ultrazvukom i/ili radiovalovima, s tim da kada R jest H, dodaje se alkohol formule R-OH, u kojoj R jest kao što je gore definirano, u ekvimolarnoj količini prema RI-OH.
2. Postupak prema patentnom zahtjevu 1, naznačeno time da su RIII, RIV i RV u formuli (II) odabrani iz skupine koju čine metil, etil, propil, izopropil, butil, t-butil, etenil, propenil, izopropenil, butenil, izobutenil, heksenil, etinil, propinil i butinil.
3. Postupak prema patentnom zahtjevu 2, naznačeno time da RIII, RIV i RV u formuli (II) jesu metil.
4. Postupak prema bilo kojem od patentnih zahtjeva 1 do 3, naznačeno time da je RI u formuli (I) odabran iz skupine koju čine metil, etil, propil, izopropil i butil.
5. Postupak prema patentnom zahtjevu 4, naznačeno time da RI u formuli (I) jest metil.
6. Postupak prema bilo kojem od patentnih zahtjeva 1 do 5, naznačeno time da spoj formule (I) jest tert-butil-metil-eter.
7. Postupak prema bilo kojem od patentnih zahtjeva 1 do 6, naznačeno time da je sirovina odabrana iz skupine koju čine:
‒ biljna ulja kao što je kokosovo ulje, kukuruzno ulje, ulje sjemenki pamuka, maslinovo ulje, palmino ulje, ulje kikirikija, ulje sjemenki uljane repice, ulje uljane repice, ulje šafranike, ulje sezama, sojino ulje, suncokretovo ulje, bademovo ulje, ulje sjemenki bukve, ulje Anacardium occidentale, ulje lješnjaka, ulje makadamije, ulje pinjola, ulje pistacija, ulje oraha, ulja citrusa, ulje sjemenki grejpa, ulje limuna, ulje naranče, ricinusovo ulje, ulje konoplje, ulje gorušice, ulje rotkvice, ulje zrna riže, ulje caklenjače, ulje jatrofine, ulje jojobe, ulje sjemenki lana, ulje maka, ulje Sapium sebirefum, ulje voćke, ulje artičoke, ulje sjemenki mrkve, ulje manga te ulje morske pasjakovine;
– životinjske masti kao što je goveđi loj, mast, mast peradi te riblja ulja;
– otpadna ulja i masti iz raznih izvora, kao što su ulja i masti korištene u restoranima i u ugostiteljstvu općenito, a prisutni su u otpadu od industrija poljoprivrednih i morskih proizvoda.
8. Metoda prema bilo kojem od patentnih zahtjeva 1 do 7, naznačeno time da se ozračavanje odvija samo s jednom vrstom elektromagnetske frekvencije odabranom od mikrovalova, ultrazvuka ili radiovalova ili s različitim vrstama rečenih elektromagnetskih frekvencija, istodobno ili jedan iza drugog.
9. Metoda prema bilo kojem od patentnih zahtjeva 1 do 8, naznačeno time da kiseli katalizator korišten u reakciji može biti katalizator sa slobodnom kiselinom ili nanesen na nosač.
10. Postupak prema patentnom zahtjevu 9, naznačeno time da je kiseli katalizator odabran iz skupine koju čine:
– jake mineralne kiseline i organske kiseline;
– zeoliti, molekulska sita, fosfati, cirkonati, kaoliniti, montmoriloniti, porozne gline, hidrotalciti i smole za kiselu ionsku izmjenu;
– čvrsta kiselina ili pogodni materijali funkcionalizirani u kiseline kao što su perfluorirani oksidi i/ili polimeri; silicijevi dioksidi i silicijevi dioksidi s dodanim Al, Ti ili Zr u različitim morfološkim oblicima, heteropolikiseline, kiseline adsorbirane i/ili kovaletno vezane na metalne okside; organske sulfonske i/ili organske karboksilne kiseline nanešene na amorfni silicijev dioksid i/ili mezo i mikrostrukturirani silicijev dioksid; polioksimetalati stabilizirani na silicijevom dioksidu i/ili titanijevom dioksidu; Kegginove strukture koje sadrže niobijeve ione; niobijeve okside; ionske tekućine i/ili ugljikove nanocijevi funkcionalizirane s organskim sulfonskim kiselinama i/ili organskim karboksilnim kiselinama.
11. Postupak prema patentnom zahtjevu 10, naznačeno time kiseli katalizator jest alkilsulfonska kiselina vezana na amorfni silicijev dioksid.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT000156A ITMI20130156A1 (it) | 2013-02-05 | 2013-02-05 | Procedimento "one-pot" per la produzione di miscele di biodiesel e eteri del glicerolo utili come biocarburanti |
| PCT/IB2014/058783 WO2014122579A1 (en) | 2013-02-05 | 2014-02-04 | One-pot process for the production of biodiesel and glycerol ether mixtures useful as biofuels |
| EP14707234.2A EP2953921B1 (en) | 2013-02-05 | 2014-02-04 | One-pot process for the production of biodiesel and glycerol ether mixtures useful as biofuels |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| HRP20180263T1 true HRP20180263T1 (hr) | 2018-03-23 |
Family
ID=48050086
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HRP20180263TT HRP20180263T1 (hr) | 2013-02-05 | 2018-02-13 | Jednostupanjski ("one-pot") postupak za pripravu smjesa biodizela i glicerol-etera korisnih kao biogoriva |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US9873843B2 (hr) |
| EP (1) | EP2953921B1 (hr) |
| CN (1) | CN105073706B (hr) |
| BR (1) | BR112015018657B1 (hr) |
| CY (1) | CY1119997T1 (hr) |
| DK (1) | DK2953921T3 (hr) |
| EA (1) | EA027246B1 (hr) |
| ES (1) | ES2658176T3 (hr) |
| HR (1) | HRP20180263T1 (hr) |
| HU (1) | HUE035628T2 (hr) |
| IT (1) | ITMI20130156A1 (hr) |
| LT (1) | LT2953921T (hr) |
| MY (1) | MY172168A (hr) |
| NO (1) | NO2953921T3 (hr) |
| PL (1) | PL2953921T3 (hr) |
| PT (1) | PT2953921T (hr) |
| RS (1) | RS56847B1 (hr) |
| SI (1) | SI2953921T1 (hr) |
| WO (1) | WO2014122579A1 (hr) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108250053B (zh) * | 2016-12-29 | 2024-01-09 | 中国石油化工股份有限公司 | 制备甘油烷基醚的方法和系统 |
| RU2661872C1 (ru) * | 2017-12-26 | 2018-07-20 | Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский Нижегородский государственный университет им. Н.И. Лобачевского" | Способ непрерывного получения пластификаторов поливинилхлорида и аппарат для его осуществления |
| US10633318B2 (en) | 2018-03-26 | 2020-04-28 | International Flora Technologies, Ltd. | Wax ethers and related methods |
| EP3874012A4 (en) * | 2018-11-01 | 2022-07-20 | Ariel Scientific Innovations Ltd. | PRODUCTION OF BIODIESEL |
| LV15515A (lv) | 2018-12-28 | 2020-07-20 | Rīgas Tehniskā Universitāte | Biodīzeļdegviela un tās izgatavošanas paņēmiens |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0112557D0 (en) * | 2001-05-23 | 2001-07-11 | Infineum Int Ltd | A process for manufacturing monoesters of polyhydroxyalcohols |
| US20050274065A1 (en) * | 2004-06-15 | 2005-12-15 | Carnegie Mellon University | Methods for producing biodiesel |
| EP2089347A2 (en) * | 2006-12-06 | 2009-08-19 | Southern Illinois University Carbondale | Processes for the production of fatty acid alkyl esters |
| US8052848B2 (en) * | 2007-06-26 | 2011-11-08 | The Penn State Research Foundation | Ultrasonic and microwave methods for enhancing the rate of a chemical reaction and apparatus for such methods |
| US8591605B2 (en) * | 2007-07-26 | 2013-11-26 | Board Of Regents Of The Nevada System Of Higher Education, On Behalf Of The University Of Nevada, Reno | Methods, systems, and apparatus for obtaining biofuel from coffee and fuels produced therefrom |
| US20090148920A1 (en) * | 2007-12-05 | 2009-06-11 | Best Energies, Inc. | Integrated glyceride extraction and biodiesel production processes |
| US8598378B2 (en) * | 2008-03-14 | 2013-12-03 | University Of Hawaii | Methods and compositions for extraction and transesterification of biomass components |
| ITMI20080459A1 (it) * | 2008-03-18 | 2009-09-19 | Eni Spa | Processo per la produzione di una composizione utile come carburante |
| US8858657B1 (en) * | 2010-12-22 | 2014-10-14 | Arrowhead Center, Inc. | Direct conversion of algal biomass to biofuel |
-
2013
- 2013-02-05 IT IT000156A patent/ITMI20130156A1/it unknown
-
2014
- 2014-02-04 US US14/765,745 patent/US9873843B2/en active Active
- 2014-02-04 HU HUE14707234A patent/HUE035628T2/en unknown
- 2014-02-04 ES ES14707234.2T patent/ES2658176T3/es active Active
- 2014-02-04 EA EA201591271A patent/EA027246B1/ru unknown
- 2014-02-04 LT LTEP14707234.2T patent/LT2953921T/lt unknown
- 2014-02-04 PL PL14707234T patent/PL2953921T3/pl unknown
- 2014-02-04 SI SI201430595T patent/SI2953921T1/en unknown
- 2014-02-04 DK DK14707234.2T patent/DK2953921T3/en active
- 2014-02-04 EP EP14707234.2A patent/EP2953921B1/en active Active
- 2014-02-04 MY MYPI2015001949A patent/MY172168A/en unknown
- 2014-02-04 NO NO14707234A patent/NO2953921T3/no unknown
- 2014-02-04 WO PCT/IB2014/058783 patent/WO2014122579A1/en active Application Filing
- 2014-02-04 BR BR112015018657-2A patent/BR112015018657B1/pt active IP Right Grant
- 2014-02-04 CN CN201480007373.XA patent/CN105073706B/zh active Active
- 2014-02-04 RS RS20180137A patent/RS56847B1/sr unknown
- 2014-02-04 PT PT147072342T patent/PT2953921T/pt unknown
-
2018
- 2018-02-05 CY CY20181100136T patent/CY1119997T1/el unknown
- 2018-02-13 HR HRP20180263TT patent/HRP20180263T1/hr unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ES2658176T3 (es) | 2018-03-08 |
| BR112015018657B1 (pt) | 2021-01-12 |
| US9873843B2 (en) | 2018-01-23 |
| WO2014122579A1 (en) | 2014-08-14 |
| EP2953921A1 (en) | 2015-12-16 |
| BR112015018657A2 (pt) | 2017-07-18 |
| NO2953921T3 (hr) | 2018-04-14 |
| LT2953921T (lt) | 2018-02-26 |
| ITMI20130156A1 (it) | 2014-08-06 |
| EA027246B1 (ru) | 2017-07-31 |
| CY1119997T1 (el) | 2018-12-12 |
| HUE035628T2 (en) | 2018-05-28 |
| SI2953921T1 (en) | 2018-03-30 |
| EA201591271A1 (ru) | 2015-12-30 |
| CN105073706A (zh) | 2015-11-18 |
| US20160024408A1 (en) | 2016-01-28 |
| PT2953921T (pt) | 2018-02-07 |
| PL2953921T3 (pl) | 2018-04-30 |
| EP2953921B1 (en) | 2017-11-15 |
| CN105073706B (zh) | 2018-06-12 |
| MY172168A (en) | 2019-11-15 |
| DK2953921T3 (en) | 2018-02-12 |
| RS56847B1 (sr) | 2018-04-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| HRP20180263T1 (hr) | Jednostupanjski ("one-pot") postupak za pripravu smjesa biodizela i glicerol-etera korisnih kao biogoriva | |
| Munir et al. | Sustainable production of bioenergy from novel non-edible seed oil (Prunus cerasoides) using bimetallic impregnated montmorillonite clay catalyst | |
| Munir et al. | A practical approach for synthesis of biodiesel via non-edible seeds oils using trimetallic based montmorillonite nano-catalyst | |
| Galadima et al. | Biodiesel production from algae by using heterogeneous catalysts: A critical review | |
| Niju et al. | Modification of egg shell and its application in biodiesel production | |
| Mutreja et al. | Potassium impregnated nanocrystalline mixed oxides of La and Mg as heterogeneous catalysts for transesterification | |
| Yan et al. | Supported CaO catalysts used in the transesterification of rapeseed oil for the purpose of biodiesel production | |
| Supamathanon et al. | Properties of Jatropha seed oil from Northeastern Thailand and its transesterification catalyzed by potassium supported on NaY zeolite | |
| Srilatha et al. | Biodiesel production from used cooking oil by two-step heterogeneous catalyzed process | |
| Earle et al. | Green synthesis of biodiesel using ionic liquids | |
| CA2767280C (en) | A process for the production of bio-naphtha from complex mixtures of natural occurring fats & oils | |
| Chen et al. | From ethyl biodiesel to biolubricants: Options for an Indian mustard integrated biorefinery toward a green and circular economy | |
| US20130019520A1 (en) | Methods of Making Fatty Acids and Fatty Acid Alkyl Esters | |
| CN104711126A (zh) | 一种废弃油脂高质化利用的方法 | |
| Basumatary et al. | Composition of biodiesel from Gmelina arborea seed oil | |
| Ilgen | Adsorption of oleic acid from sunflower oil on Amberlyst A26 (OH) | |
| CN103275812B (zh) | 一种利用废弃动植物油制备润滑油基础油的方法 | |
| Basumatary et al. | Identification of chemical composition of biodiesel from Tabernaemontana divaricata seed oil | |
| Wang et al. | Biodiesel produced from catalyzed transesterification of triglycerides using ion-exchanged zeolite Beta and MCM-22 | |
| Pandiangan et al. | The effect of calcination temperatures on the activity of CaO and CaO/SiO2 heterogeneous catalyst for transesterification of rubber seed oil in the presence of coconut oil as a co-reactant | |
| D’Oca et al. | Base/acid-catalyzed FAEE production from hydroxylated vegetable oils | |
| CN102154064B (zh) | 生物柴油的制备方法 | |
| Dibenedetto et al. | Tunable mixed oxides: efficient agents for the simultaneous trans-esterification of lipids and esterification of free fatty acids from bio-oils for the effective production of FAMEs | |
| Lemoine et al. | A preliminary study of acid catalyzed transesterification of a Jatropha-like bio-oil | |
| AMINU | Biodiesel production from oleic acid and palm fatty acid distillate/oleic acid using sulfonated carbon |