EA201591271A1 - Однореакторный способ производства биодизельного топлива и смесей эфиров глицерина, которые могут быть использованы в качестве биодизельного топлива - Google Patents

Однореакторный способ производства биодизельного топлива и смесей эфиров глицерина, которые могут быть использованы в качестве биодизельного топлива

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Publication number
EA201591271A1
EA201591271A1 EA201591271A EA201591271A EA201591271A1 EA 201591271 A1 EA201591271 A1 EA 201591271A1 EA 201591271 A EA201591271 A EA 201591271A EA 201591271 A EA201591271 A EA 201591271A EA 201591271 A1 EA201591271 A1 EA 201591271A1
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EA
Eurasian Patent Office
Prior art keywords
biodiesel fuel
mixtures
production
reactor method
fatty acids
Prior art date
Application number
EA201591271A
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English (en)
Other versions
EA027246B1 (ru
Inventor
Джованни Николози
Кармело Драго
Леонарда Франческа Лиотта
Валерия Ла Парола
Мария Луиза Теста
Original Assignee
Консильо Национале Делле Ричерке
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Application filed by Консильо Национале Делле Ричерке filed Critical Консильо Национале Делле Ричерке
Publication of EA201591271A1 publication Critical patent/EA201591271A1/ru
Publication of EA027246B1 publication Critical patent/EA027246B1/ru

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/026—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/10—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing sonic or ultrasonic vibrations
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
    • B01J19/122—Incoherent waves
    • B01J19/126—Microwaves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
    • B01J19/122—Incoherent waves
    • B01J19/129—Radiofrequency
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/09—Preparation of ethers by dehydration of compounds containing hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/14—Preparation of ethers by exchange of organic parts on the ether-oxygen for other organic parts, e.g. by trans-etherification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/24—Preparation of carboxylic acid esters by reacting carboxylic acids or derivatives thereof with a carbon-to-oxygen ether bond, e.g. acetal, tetrahydrofuran
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/297—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/003—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with alcohols
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/02—Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
    • C10L2200/0254—Oxygen containing compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/04—Organic compounds
    • C10L2200/0461—Fractions defined by their origin
    • C10L2200/0469—Renewables or materials of biological origin
    • C10L2200/0476—Biodiesel, i.e. defined lower alkyl esters of fatty acids first generation biodiesel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2270/00—Specifically adapted fuels
    • C10L2270/02—Specifically adapted fuels for internal combustion engines
    • C10L2270/026—Specifically adapted fuels for internal combustion engines for diesel engines, e.g. automobiles, stationary, marine
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/34—Applying ultrasonic energy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/36—Applying radiation such as microwave, IR, UV
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Emergency Medicine (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Fats And Perfumes (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

Изобретение относится к способу превращения исходного материала, содержащего один или более триглицеридов жирных кислот в смесь, содержащую один или более алкильных эфиров жирных кислот и t-алкильные эфиры глицерина, включающий взаимодействие указанного сырья с соединением формулы (I): R-O-R(I), в которой Rпредставляет собой алкил, алкенил или алкинил, содержащий 1-18 атомов углерода; R представляет собой Н или третичную алкильную группу, в котором взаимодействие происходит в присутствии кислотного катализатора переэтерификации при облучении микроволновым излучением, и/или ультразвуком, и/или радиоволнами.
EA201591271A 2013-02-05 2014-02-04 Однореакторный способ производства биодизельного топлива и смесей эфиров глицерина, которые могут быть использованы в качестве биодизельного топлива EA027246B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT000156A ITMI20130156A1 (it) 2013-02-05 2013-02-05 Procedimento "one-pot" per la produzione di miscele di biodiesel e eteri del glicerolo utili come biocarburanti
PCT/IB2014/058783 WO2014122579A1 (en) 2013-02-05 2014-02-04 One-pot process for the production of biodiesel and glycerol ether mixtures useful as biofuels

Publications (2)

Publication Number Publication Date
EA201591271A1 true EA201591271A1 (ru) 2015-12-30
EA027246B1 EA027246B1 (ru) 2017-07-31

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EA201591271A EA027246B1 (ru) 2013-02-05 2014-02-04 Однореакторный способ производства биодизельного топлива и смесей эфиров глицерина, которые могут быть использованы в качестве биодизельного топлива

Country Status (19)

Country Link
US (1) US9873843B2 (ru)
EP (1) EP2953921B1 (ru)
CN (1) CN105073706B (ru)
BR (1) BR112015018657B1 (ru)
CY (1) CY1119997T1 (ru)
DK (1) DK2953921T3 (ru)
EA (1) EA027246B1 (ru)
ES (1) ES2658176T3 (ru)
HR (1) HRP20180263T1 (ru)
HU (1) HUE035628T2 (ru)
IT (1) ITMI20130156A1 (ru)
LT (1) LT2953921T (ru)
MY (1) MY172168A (ru)
NO (1) NO2953921T3 (ru)
PL (1) PL2953921T3 (ru)
PT (1) PT2953921T (ru)
RS (1) RS56847B1 (ru)
SI (1) SI2953921T1 (ru)
WO (1) WO2014122579A1 (ru)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108250053B (zh) * 2016-12-29 2024-01-09 中国石油化工股份有限公司 制备甘油烷基醚的方法和系统
RU2661872C1 (ru) * 2017-12-26 2018-07-20 Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский Нижегородский государственный университет им. Н.И. Лобачевского" Способ непрерывного получения пластификаторов поливинилхлорида и аппарат для его осуществления
US10633318B2 (en) 2018-03-26 2020-04-28 International Flora Technologies, Ltd. Wax ethers and related methods
EP3874012A4 (en) * 2018-11-01 2022-07-20 Ariel Scientific Innovations Ltd. PRODUCTION OF BIODIESEL
LV15515A (lv) 2018-12-28 2020-07-20 Rīgas Tehniskā Universitāte Biodīzeļdegviela un tās izgatavošanas paņēmiens

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0112557D0 (en) * 2001-05-23 2001-07-11 Infineum Int Ltd A process for manufacturing monoesters of polyhydroxyalcohols
US20050274065A1 (en) * 2004-06-15 2005-12-15 Carnegie Mellon University Methods for producing biodiesel
US20100130763A1 (en) * 2006-12-06 2010-05-27 Southern Illinois University Carbondale Processes for the production of fatty acid alkyl esters
WO2009003109A1 (en) * 2007-06-26 2008-12-31 The Penn State Research Foundation Ultrasonic and microwave methods for enhancing the rate of a chemical reaction and apparatus for such methods
US8591605B2 (en) * 2007-07-26 2013-11-26 Board Of Regents Of The Nevada System Of Higher Education, On Behalf Of The University Of Nevada, Reno Methods, systems, and apparatus for obtaining biofuel from coffee and fuels produced therefrom
US20090148920A1 (en) * 2007-12-05 2009-06-11 Best Energies, Inc. Integrated glyceride extraction and biodiesel production processes
US8598378B2 (en) * 2008-03-14 2013-12-03 University Of Hawaii Methods and compositions for extraction and transesterification of biomass components
ITMI20080459A1 (it) * 2008-03-18 2009-09-19 Eni Spa Processo per la produzione di una composizione utile come carburante
US8858657B1 (en) * 2010-12-22 2014-10-14 Arrowhead Center, Inc. Direct conversion of algal biomass to biofuel

Also Published As

Publication number Publication date
ES2658176T3 (es) 2018-03-08
CY1119997T1 (el) 2018-12-12
ITMI20130156A1 (it) 2014-08-06
EA027246B1 (ru) 2017-07-31
US20160024408A1 (en) 2016-01-28
BR112015018657A2 (pt) 2017-07-18
PT2953921T (pt) 2018-02-07
CN105073706A (zh) 2015-11-18
RS56847B1 (sr) 2018-04-30
NO2953921T3 (ru) 2018-04-14
HUE035628T2 (en) 2018-05-28
DK2953921T3 (en) 2018-02-12
EP2953921A1 (en) 2015-12-16
US9873843B2 (en) 2018-01-23
BR112015018657B1 (pt) 2021-01-12
MY172168A (en) 2019-11-15
HRP20180263T1 (hr) 2018-03-23
LT2953921T (lt) 2018-02-26
SI2953921T1 (en) 2018-03-30
PL2953921T3 (pl) 2018-04-30
CN105073706B (zh) 2018-06-12
EP2953921B1 (en) 2017-11-15
WO2014122579A1 (en) 2014-08-14

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