GB998804A - Production of carbon tetrachloride - Google Patents
Production of carbon tetrachlorideInfo
- Publication number
- GB998804A GB998804A GB25586/61A GB2558661A GB998804A GB 998804 A GB998804 A GB 998804A GB 25586/61 A GB25586/61 A GB 25586/61A GB 2558661 A GB2558661 A GB 2558661A GB 998804 A GB998804 A GB 998804A
- Authority
- GB
- United Kingdom
- Prior art keywords
- carbon
- phosgene
- chloride
- chlorine
- treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/18—Preparation of halogenated hydrocarbons by replacement by halogens of oxygen atoms of carbonyl groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
Carbon tetrachloride is made by passing phosgene over a volatile chloride of molybdenum or tungsten supported on active carbon, or a mixture of such chlorides supported on active carbon, at 300 DEG to 600 DEG C., the carbon having been treated to remove substantially all oxygen prior to use in the disproportionation of the phosgene. Preferably the chloride is added to the phosgene being fed over the catalyst, the partial pressure of the chloride vapour being sufficient to load the carbon at a rate comparable with the slow desorption of metal chloride from it. Metal chloride is removed from the product gases and recycled. Preferred are catalysts made from charcoal, e.g. coconut charcoal. Preferably the carbon catalyst is treated in situ. Desirably the carbon is purged with argon to remove water before treatment for the removal of oxygen. Oxygen may be removed by saturating the carbon with hydrogen at above 200 DEG C., preferably 300 DEG to 500 DEG C., and then treated with chlorine at similar temperatures. The hydrogen treatment may be omitted and after about 4 hours treatment with chlorine a volatile metal chloride e.g. aluminium chloride, is added to the feed gases. The chlorine in the above treatments may be substituted by phosgene. In a modification in which the volatile chloride is recycled, the carbon may be deoxygenated by passing tungsten hexachloride in argon, and tungsten oxychlorides, condensed from the product gases, on recycling through the reactor with phosgene, are converted back to hexachloride. Pressures of 25 to 50 atmospheres may be used. Reaction temperatures of 350 DEG to 450 DEG C. are appropriate. The feed may be diluted with chlorine, to avoid the production of catalyst poisons, but preferably contains at least 70% of phosgene. The phosgene may be formed in situ from carbon monoxide and chlorine. The residence time, when working under pressure, is conveniently 30 seconds to 5 minutes. Examples are provided of the use of molybdenum pentachloride and tungsten hexachloride. Specification 847,552 is referred to.ALSO:Catalysts consisting of a volatile chloride of molybdenum and/or tungsten supported on active carbon are, before use in the production of carbon tetrachloride from phosgene at 300-600 DEG C., treated substantially to remove all of the oxygen from the carbon. Preferably the volatile chlorides are added with the phosgene feed so that a high concentration of catalyst on the carrier is maintained. Preferred active carbons are charcoals, e.g. coconut charcoal. Before removal of oxygen the carbon is preferably purged with argon to remove water. Oxygen may be removed by saturation with hydrogen at above 200 DEG C., preferably 300-500 DEG C., followed by chlorine-treatment at similar temperatures. The treatment with hydrogen may be omitted and phosgene used instead of chlorine. When hydrogen treatment is omitted the chlorine treatment is followed by the addition of a volatile metal chloride, e.g. aluminium chloride, and molybdenum or tungsten chlorides. Where provision is made for recycling metal chloride vapour separated from product gases deoxygenation may be effected by passing a stream of tungsten hexachloride vapour in argon through the catalyst. Preferably the carbon is treated in situ. Examples illustrate the preparation of catalysts from charcoal and molybdenum pentachloride or tungsten hexachloride by methods outlined above.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB25586/61A GB998804A (en) | 1961-07-14 | 1961-07-14 | Production of carbon tetrachloride |
FR904030A FR1335178A (en) | 1961-07-14 | 1962-07-13 | Process for manufacturing carbon tetrachloride |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB25586/61A GB998804A (en) | 1961-07-14 | 1961-07-14 | Production of carbon tetrachloride |
Publications (1)
Publication Number | Publication Date |
---|---|
GB998804A true GB998804A (en) | 1965-07-21 |
Family
ID=10230078
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB25586/61A Expired GB998804A (en) | 1961-07-14 | 1961-07-14 | Production of carbon tetrachloride |
Country Status (2)
Country | Link |
---|---|
FR (1) | FR1335178A (en) |
GB (1) | GB998804A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7386919B2 (en) | 2006-11-20 | 2008-06-17 | Akiva Pinto | Textile recycling apparatus |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1029262A (en) * | 1963-01-28 | 1966-05-11 | Ici Ltd | Manufacture of carbon tetrachloride |
US3406216A (en) * | 1965-11-15 | 1968-10-15 | Fmc Corp | Preparation of carbon tetrachloride from phosgene |
-
1961
- 1961-07-14 GB GB25586/61A patent/GB998804A/en not_active Expired
-
1962
- 1962-07-13 FR FR904030A patent/FR1335178A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7386919B2 (en) | 2006-11-20 | 2008-06-17 | Akiva Pinto | Textile recycling apparatus |
Also Published As
Publication number | Publication date |
---|---|
FR1335178A (en) | 1963-08-16 |
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