GB997495A - Oxidation products of 1-benzyl-tetrahydroisoquinolines - Google Patents
Oxidation products of 1-benzyl-tetrahydroisoquinolinesInfo
- Publication number
- GB997495A GB997495A GB910863A GB910863A GB997495A GB 997495 A GB997495 A GB 997495A GB 910863 A GB910863 A GB 910863A GB 910863 A GB910863 A GB 910863A GB 997495 A GB997495 A GB 997495A
- Authority
- GB
- United Kingdom
- Prior art keywords
- carbon atoms
- benzyl
- oxidation products
- tetrahydroisoquinolines
- aqueous solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D217/00—Heterocyclic compounds containing isoquinoline or hydrogenated isoquinoline ring systems
- C07D217/12—Heterocyclic compounds containing isoquinoline or hydrogenated isoquinoline ring systems with radicals, substituted by hetero atoms, attached to carbon atoms of the nitrogen-containing ring
- C07D217/18—Aralkyl radicals
- C07D217/20—Aralkyl radicals with oxygen atoms directly attached to the aromatic ring of said aralkyl radical, e.g. papaverine
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Other In-Based Heterocyclic Compounds (AREA)
Abstract
Alkaloid-like oxidation products are obtained when a quaternary N-alkyl-1-benzyl-1,2,3,4-tetrahydroisoquinolinium salt of the formula <FORM:0997495/C2/1> where R represents an alkyl radical of up to 4 carbon atoms, R1, R2 and R4, the same or different, represent hydroxy groups or alkoxy groups of up to 4 carbon atoms, R3 represents a hydrogen atom, a hydroxy group or an alkoxy group of up to 4 carbon atoms and X represents a univalent anion, is subjected to mild oxidation in aqueous solution at a pH of from 4 to 10, said solution being 0.001 to 0.01 molar. The process is preferably carried out at 20 DEG to 90 DEG C. Oxidizing agents which may be used are all such agents which can be applied to an aqueous solution or suspension.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF36207A DE1203784B (en) | 1962-03-07 | 1962-03-07 | Process for the preparation of bisisoquinolinium ethers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB997495A true GB997495A (en) | 1965-07-07 |
Family
ID=7096357
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB910863A Expired GB997495A (en) | 1962-03-07 | 1963-03-07 | Oxidation products of 1-benzyl-tetrahydroisoquinolines |
Country Status (3)
| Country | Link |
|---|---|
| CH (1) | CH427798A (en) |
| DE (1) | DE1203784B (en) |
| GB (1) | GB997495A (en) |
-
1962
- 1962-03-07 DE DEF36207A patent/DE1203784B/en active Pending
-
1963
- 1963-02-28 CH CH257763A patent/CH427798A/en unknown
- 1963-03-07 GB GB910863A patent/GB997495A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| CH427798A (en) | 1967-01-15 |
| DE1203784B (en) | 1965-10-28 |
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