GB996840A - Stabilization of chlorohydrocarbon solvents - Google Patents

Stabilization of chlorohydrocarbon solvents

Info

Publication number
GB996840A
GB996840A GB1366964A GB1366964A GB996840A GB 996840 A GB996840 A GB 996840A GB 1366964 A GB1366964 A GB 1366964A GB 1366964 A GB1366964 A GB 1366964A GB 996840 A GB996840 A GB 996840A
Authority
GB
United Kingdom
Prior art keywords
acid
chlorohydrocarbon
dinitrocumene
dinitrotoluene
methylene chloride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1366964A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US271864A external-priority patent/US3247027A/en
Priority claimed from US271861A external-priority patent/US3257326A/en
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of GB996840A publication Critical patent/GB996840A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G5/00Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
    • C23G5/02Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
    • C23G5/028Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing halogenated hydrocarbons
    • C23G5/02854Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing halogenated hydrocarbons characterised by the stabilising or corrosion inhibiting additives
    • C23G5/02883Nitrogen-containing compounds
    • C23G5/02887Nitro-compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00Preparation of halogenated hydrocarbons
    • C07C17/38Separation; Purification; Stabilisation; Use of additives
    • C07C17/42Use of additives, e.g. for stabilisation
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/02Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using non-aqueous solutions
    • C23C22/03Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using non-aqueous solutions containing phosphorus compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Detergent Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

C1- 3-chlorohydrocarbon solvents, especially methylene chloride, methyl chloroform, carbon tetrachloride and particularly tri- or perchlorethylene, are stabilised by the inclusion of 0.001-1%, preferably 0.005-1%, by weight of picric acid. The composition suitably also includes 0.01-5% of another nitro aromatic compound (e.g. those referred to in the main Specification), the preferred compounds being 2,4 - dinitrotoluene, 3,5 - dinitrobenzoic acid and 2,4-dinitrocumene.ALSO:Metal surfaces, e.g. of stainless steel, may be simultaneously degreased and phosphatized by employing a C1- 3-chlorohydrocarbon solvent, especially methylene chloride, methyl chloroform, carbon tetrachloride, and particularly tri- and per-chlorethylene which contains 1-10% of a C3- 8-aliphatic alcohol, preferably butyl or amyl alcohol, and/or an acid C3- 8-alkyl phosphate ester, 0.05-7.5%, preferably 0.2-0.8%, phosphoric acid, and, as a stabilizer, 0.001-1%, preferably 0.005-1%, by weight of picric acid. The composition suitably also includes 0.01-5% of another nitro aromatic compound (e.g. those referred to in the parent Specification), the preferred compounds being 2,4-dinitrotoluene, 3,5-dinitrobenzoic acid and 2,4-dinitrocumene, and generally contains at least 85% of the solvent.
GB1366964A 1963-04-10 1964-04-02 Stabilization of chlorohydrocarbon solvents Expired GB996840A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US271864A US3247027A (en) 1963-04-10 1963-04-10 Metal phosphatizing composition and process
US271861A US3257326A (en) 1963-04-10 1963-04-10 Stabilized chlorohydrocarbon solvent composition

Publications (1)

Publication Number Publication Date
GB996840A true GB996840A (en) 1965-06-30

Family

ID=26955153

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1366964A Expired GB996840A (en) 1963-04-10 1964-04-02 Stabilization of chlorohydrocarbon solvents

Country Status (1)

Country Link
GB (1) GB996840A (en)

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