GB993794A - Wax compositions - Google Patents

Wax compositions

Info

Publication number
GB993794A
GB993794A GB5263/62A GB526362A GB993794A GB 993794 A GB993794 A GB 993794A GB 5263/62 A GB5263/62 A GB 5263/62A GB 526362 A GB526362 A GB 526362A GB 993794 A GB993794 A GB 993794A
Authority
GB
United Kingdom
Prior art keywords
ethyl acrylate
wax
polymer
maleic anhydride
hydrocarbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5263/62A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rohm and Haas Co
Original Assignee
Rohm and Haas Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm and Haas Co filed Critical Rohm and Haas Co
Publication of GB993794A publication Critical patent/GB993794A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09G—POLISHING COMPOSITIONS; SKI WAXES
    • C09G1/00—Polishing compositions
    • C09G1/06—Other polishing compositions
    • C09G1/08—Other polishing compositions based on wax
    • C09G1/10—Other polishing compositions based on wax based on mixtures of wax and natural or synthetic resin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/06—Organic solvent
    • C08F2/08—Organic solvent with the aid of dispersing agents for the polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0016—Plasticisers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • C08L91/06—Waxes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Wax/polymer compositions are made by polymerizing an addition polymerizable monomer charge in a substantially anhydrous liquid hydrocarbon medium in which the resulting polymer is insoluble, the polymerization being carried out in the presence of a polymeric dispersing agent which has in its molecule two distinct polymeric components, one of which has a preference for the hydrocarbon liquid and the other has a preferential affinity for the addition polymer, and dissolving a wax in the hydrocarbon liquid of the dispersion thus formed. Preferred waxes are carnauba, paraffin, scale, bees, Japan and montan waxes, waxy polyethylene, oxidized hydrocarbon wax, a vinyl acetate/stearate copolymer, butyl stearate, chlorinated diphenyl and naphthalene, and N,N-dibutyl stearamide. The methods of polymerization are of the type involving the formation of a polymeric dispersing agent by grafting a part of the monomer charge on to a preformed polymer, which may be pretreated with an organic peroxide to develop active sites thereon. Suitable preformed polymers are an isobutylene-isoprene copolymer, a butadiene-styrene copolymer, crepe rubber, and a copolymer of vinylpyrrolidone, butyl acrylate, lauryl methacrylate and stearyl methacrylate. The examples describe the addition of waxes to dispersions of copolymers of: (a) ethyl acrylate, methyl methacrylate and, optionally, maleic anhydride, and (b) ethyl acrylate and methacrylic acid, (c) acrylonitrile butyl acrylate and maleic anhydride, (d) acrylonitrile and 2-ethylhexyl acrylate, (e) maleic anhydride and vinyl toluene, (f) methyl methacrylate, ethyl acrylate and methacrylamide, (g) ethyl acrylate, methyl methacrylate, vinyl toluene and methacrylic acid, and (h) vinylidene chloride, ethyl acrylate and itaconic acid, and also to homopolymers of (i) vinyl chloride and (j) vinyl acetate. The resulting dispersions are used for coating various substrates and sizing cellulosic yarns. Specifications 893,429 and 992,635 are referred to.ALSO:Surfaces of steel, aluminium, wood, leather, polystyrene and regenerated cellulose films are coated by applying thereto wax/polymer dispersions made by polymerizing monomer in a liquid hydrocarbon in which the resulting polymer is insoluble and which contains a dispersing agent formed by grafting a part of the monomer charge on to a preformed polymer, e.g. rubber, dissolved in the liquid hydrocarbon, and thereafter dissolving a wax in the hydrocarbon medium of the dispersion (see Division C3). The examples describe the coating of surfaces of the abovementioned types with dispersions in hydrocarbons of methyl methacrylate/ethyl acrylate, methyl methacrylate/ethyl acrylate/maleic anhydride, acrylonitrile/butylacrylate/maleic anhydride, acrylonitrile/2-ethylhexyl acrylate, ethyl acrylate/methacrylic acid, maleic anhydride/vinyl toluene, methyl methacrylate/ethyl acrylate, methacrylamide, ethyl acrylate/methyl methacrylate/vinyl toluene/methacrylic acid, and vinylidene chloride/ethyl acrylate/itaconic acid copolymers, polyvinyl chloride and polyvinyl acetate, the dispersions having added thereto carnauba, paraffin, scale, bees, Japan and montan waxes. waxy polyethylene, oxidized hydrocarbon wax, a vinyl acetate/stearate copolymer, butyl stearate, chlorinated diphenyl and naphthalene and N,N-dibutylstearamide. Specifications 983,429 and 992,635 are referred to.ALSO:Cellulosic yarns are sized and cotton fabric is rendered water-repellant by applying thereto wax/polymer dispersions consisting of particles of an addition polymer suspended in a liquid hydrocarbon, the dispersion being stabilized by a dispersing agent formed by grafting monomer on to a preformed polymer, e.g. rubber, dissolved in the liquid hydrocarbon, and containing a wax dissolved in the hydrocarbon medium (see Division C3). The examples describe: (14) sizing cellulose yarns with a toluene dispersion of an ethyl acrylate/methacrylic acid copolymer containing dissolved butyl stearate, (15) sizing cellulose acetate yarns with a dispersion of a maleic anhydride/vinyl toluene copolymer containing dissolved montan wax, and (19) rendering cotton fabric water-repellant by applying thereto a dispersion in mineral spirits of a vinylidene chloride/ethyl acrylate/itaconic acid copolymer containing dissolved chlorinated diphenyl. Specifications 893,429 and 992,635 are referred to.
GB5263/62A 1961-02-13 1962-02-12 Wax compositions Expired GB993794A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US8863261A 1961-02-13 1961-02-13

Publications (1)

Publication Number Publication Date
GB993794A true GB993794A (en) 1965-06-02

Family

ID=22212489

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5263/62A Expired GB993794A (en) 1961-02-13 1962-02-12 Wax compositions

Country Status (3)

Country Link
BE (1) BE613856A (en)
GB (1) GB993794A (en)
NL (1) NL274754A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0965680A1 (en) * 1998-06-18 1999-12-22 Clariant International Ltd. Aqueous dispersions, their preparation and use thereof
WO2004005354A1 (en) * 2002-07-03 2004-01-15 Basf Aktiengesellschaft Method for producing an aqueous polymer dispersion
WO2004020543A1 (en) * 2002-09-02 2004-03-11 3M Innovative Properties Company Finishing method and finishing agent
EP1426425A1 (en) * 2002-12-04 2004-06-09 Basf Ag Wax formulations and use thereof for polishing and preservation of surfaces
US20140336308A1 (en) * 2010-04-07 2014-11-13 Jeen International Corporation Low Energy, Cold Process Formulation Aid

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0965680A1 (en) * 1998-06-18 1999-12-22 Clariant International Ltd. Aqueous dispersions, their preparation and use thereof
WO1999066118A1 (en) * 1998-06-18 1999-12-23 Clariant Finance (Bvi) Limited Aqueous dispersions, their production and use
US6736865B1 (en) * 1998-06-18 2004-05-18 Clariant Finance (Bvi) Limited Aqueous dispersions, their production and use
WO2004005354A1 (en) * 2002-07-03 2004-01-15 Basf Aktiengesellschaft Method for producing an aqueous polymer dispersion
WO2004020543A1 (en) * 2002-09-02 2004-03-11 3M Innovative Properties Company Finishing method and finishing agent
EP1426425A1 (en) * 2002-12-04 2004-06-09 Basf Ag Wax formulations and use thereof for polishing and preservation of surfaces
US6992125B2 (en) 2002-12-04 2006-01-31 Basf Aktiengesellschaft Wax formulations and their use for maintaining and preserving surfaces
US20140336308A1 (en) * 2010-04-07 2014-11-13 Jeen International Corporation Low Energy, Cold Process Formulation Aid
US10138374B2 (en) * 2010-04-07 2018-11-27 Jeen International Corp. Low energy, cold process formulation aid

Also Published As

Publication number Publication date
NL274754A (en) 1900-01-01
BE613856A (en) 1900-01-01

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