GB991817A - A process for the preparation of a protective surface layer on aluminium or aluminium alloys - Google Patents

A process for the preparation of a protective surface layer on aluminium or aluminium alloys

Info

Publication number
GB991817A
GB991817A GB44197/62A GB4419762A GB991817A GB 991817 A GB991817 A GB 991817A GB 44197/62 A GB44197/62 A GB 44197/62A GB 4419762 A GB4419762 A GB 4419762A GB 991817 A GB991817 A GB 991817A
Authority
GB
United Kingdom
Prior art keywords
aluminium
coating
alloy
surface layer
nial3
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB44197/62A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Institutt for Atomenergi
Original Assignee
Institutt for Atomenergi
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Institutt for Atomenergi filed Critical Institutt for Atomenergi
Publication of GB991817A publication Critical patent/GB991817A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/31Coating with metals
    • C23C18/32Coating with nickel, cobalt or mixtures thereof with phosphorus or boron
    • C23C18/34Coating with nickel, cobalt or mixtures thereof with phosphorus or boron using reducing agents
    • C23C18/36Coating with nickel, cobalt or mixtures thereof with phosphorus or boron using reducing agents using hypophosphites
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/02Alloys based on aluminium with silicon as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C10/00Solid state diffusion of only metal elements or silicon into metallic material surfaces
    • C23C10/28Solid state diffusion of only metal elements or silicon into metallic material surfaces using solids, e.g. powders, pastes
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/12Light metals
    • C23G1/125Light metals aluminium
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/14Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
    • C23G1/22Light metals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Chemically Coating (AREA)

Abstract

Aluminium or aluminium alloys for use in nuclear reactors are protected against corrosion with a surface layer containing Ni and Al, e.g. of NiAl3 covered by Ni2Al3 or Ni but particularly entirely of NiAl3, by coating an aluminium or aluminium alloy body with a phosphorus containing nickel alloy by chemical deposition, e.g. by reduction of Ni ions with sodium hypophosphite to obtain a coating containing up to 12% P, and extracting phosphorus from the coating by the action of an appropriate salt bath which also effects alloying of the Al and Ni by diffusion annealing. The salt bath may consist of NaNO3 or KNO, mixed with KNO2 or NaNO2 respectively in ratios of 0.9.1.1 to 1.1:0.9, the temperature thereof being 450 - 600 DEG C. A preferred basic material may be an aluminium alloy of composition: - Si 8 - 15%, Ni 0.5 - 2%, Fe 0.2 - 1%, Mg 0 - 1.5% Ti 0 - 0.5%, Zr 0 - 0.5%, Al balance. A comparison alloy is disclosed consisting of 1% Ni, 0.5% Fe, 0.3% Si, balance Al. Prior to coating, an aluminium body may be pickled in aqueous NaOH or concentrated HNO3 and HF.
GB44197/62A 1961-11-22 1962-11-22 A process for the preparation of a protective surface layer on aluminium or aluminium alloys Expired GB991817A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NO14225561 1961-11-22

Publications (1)

Publication Number Publication Date
GB991817A true GB991817A (en) 1965-05-12

Family

ID=19908623

Family Applications (1)

Application Number Title Priority Date Filing Date
GB44197/62A Expired GB991817A (en) 1961-11-22 1962-11-22 A process for the preparation of a protective surface layer on aluminium or aluminium alloys

Country Status (3)

Country Link
BE (1) BE625077A (en)
CH (1) CH405869A (en)
GB (1) GB991817A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2909697A1 (en) * 1978-03-14 1979-09-20 Centre Rech Metallurgique METAL STRIP SURFACE TREATMENT METHOD

Also Published As

Publication number Publication date
BE625077A (en) 1900-01-01
CH405869A (en) 1966-01-15

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