GB991797A - New polyvinyl chloride compositions and process for coating metal articles therewith - Google Patents

New polyvinyl chloride compositions and process for coating metal articles therewith

Info

Publication number
GB991797A
GB991797A GB13218/62A GB1321862A GB991797A GB 991797 A GB991797 A GB 991797A GB 13218/62 A GB13218/62 A GB 13218/62A GB 1321862 A GB1321862 A GB 1321862A GB 991797 A GB991797 A GB 991797A
Authority
GB
United Kingdom
Prior art keywords
weight per
per cent
compositions
phthalate
polyvinyl chloride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB13218/62A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wacker Chemie AG
Original Assignee
Wacker Chemie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE1961W0029757 external-priority patent/DE1290273C2/en
Application filed by Wacker Chemie AG filed Critical Wacker Chemie AG
Publication of GB991797A publication Critical patent/GB991797A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/18Processes for applying liquids or other fluent materials performed by dipping
    • B05D1/22Processes for applying liquids or other fluent materials performed by dipping using fluidised-bed technique
    • B05D1/24Applying particulate materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • C08K5/12Esters; Ether-esters of cyclic polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/56Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
    • C08K5/57Organo-tin compounds
    • C08K5/58Organo-tin compounds containing sulfur
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/04Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C09D127/06Homopolymers or copolymers of vinyl chloride
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2202/00Metallic substrate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2401/00Form of the coating product, e.g. solution, water dispersion, powders or the like
    • B05D2401/30Form of the coating product, e.g. solution, water dispersion, powders or the like the coating being applied in other forms than involving eliminable solvent, diluent or dispersant
    • B05D2401/32Form of the coating product, e.g. solution, water dispersion, powders or the like the coating being applied in other forms than involving eliminable solvent, diluent or dispersant applied as powders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2506/00Halogenated polymers
    • B05D2506/20Chlorinated polymers
    • B05D2506/25PVC
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0218Pretreatment, e.g. heating the substrate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Pulverulent compositions for coating metal articles and having a particle size distribution in the range 0.03 to 0.2 mm. comprises 85 to 55 weight per cent of polyvinyl chloride mass polymer having a K value of not more than 60, 12 to 44 weight per cent of a plasticizer and 1 to 3 weight per cent of a stabilizer. The compositions may also comprise up to 10 weight per cent of another vinyl chloride polymer or copolymer, e.g. with maleic acid or vinyl acetate and maleic acid, and up to 5 weight per cent of a liquid epoxide resin. Specified plasticizers are dioctyl phthalate, dicyclohexyl phthalate, dioctyl adipate, octyl tributyl citrate, tritolyl phosphate and polyesters. Specified stabilizers are basic lead carbonate, lead orthosilicate, dibasic lead phosphite, dibasic lead phosphate, cadmium and barium ricinoleates, stearates and naphthenates, alkali metal phosphates and particularly dibutyl tin dimercaptide. Pigments and fillers, e.g. zinc oxide, zinc sulphide, lithopone, barium sulphate, calcium carbonate, carbon black, silica and clay may also be present, and the compositions may be used for fluidized bed coating of metal articles. Examples describe compositions comprising polyvinyl chloride, dibutyl tin dimercaptide, titanium dioxide and (1 to 3) dioctyl phthalate, (4) dioctyl phthalate and dicyclohexyl phthalate, (5) dicyclohexyl phthalate and (6) a vinyl chloride/vinyl acetate/maleic acid copolymer, dioctyl phthalate and a liquid epoxy resin.ALSO:Metal articles are coated by immersing the heated articles in fluidized beds of pulverulent compositions having a particle size distribution in the range 0,03-0,2 mm. and comprising 85-55 weight per cent of a polyvinyl chloride mass polymer having a K value not exceeding 60, 12-44 weight per cent of a plasticizer and 1-3 weight per cent of a stabilizer. Preferred plasticizers are dioctyl and dicyclohexyl phthalates. The preferred stabilizer is dibutyl tin dimercaptide. The compositions may also comprise fillers and pigments, up to 10 weight per cent of other vinyl chloride polymers and copolymers, e.g. with maleic acid or vinyl acetate and maleic acid, and up to 5 weight per cent of a liquid epoxide resin. In examples sand blasted iron sheets are coated with compositions comprising polyvinyl chloride, dibutyl tin dimercaptide and titanium dioxide, with (1 to 3) dioctyl phthalate, (4) dioctyl phthalate and dicyclohexyl phthalate, and (5) dicyclohexyl phthalate.
GB13218/62A 1961-04-05 1962-04-05 New polyvinyl chloride compositions and process for coating metal articles therewith Expired GB991797A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE1961W0029757 DE1290273C2 (en) 1961-04-05 1961-04-05 Coating of objects according to the fluidized bed sintering process

Publications (1)

Publication Number Publication Date
GB991797A true GB991797A (en) 1965-05-12

Family

ID=7599314

Family Applications (1)

Application Number Title Priority Date Filing Date
GB13218/62A Expired GB991797A (en) 1961-04-05 1962-04-05 New polyvinyl chloride compositions and process for coating metal articles therewith

Country Status (2)

Country Link
GB (1) GB991797A (en)
NL (2) NL139919B (en)

Also Published As

Publication number Publication date
NL139919B (en) 1973-10-15
NL276516A (en) 1900-01-01

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