GB988171A - Improvements in or relating to thermosetting resin compositions - Google Patents

Improvements in or relating to thermosetting resin compositions

Info

Publication number
GB988171A
GB988171A GB1337760A GB1337760A GB988171A GB 988171 A GB988171 A GB 988171A GB 1337760 A GB1337760 A GB 1337760A GB 1337760 A GB1337760 A GB 1337760A GB 988171 A GB988171 A GB 988171A
Authority
GB
United Kingdom
Prior art keywords
poly
methacrylate
copolymer
films
ester
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1337760A
Inventor
John Edwin Oakley Mayne
Henry Warson
Geoffrey Ernest John Reynolds
Ralph Manuel Levine
Arthur Frederick Moyles
Edward Vahe Gulbekian
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Celanese Emulsions Ltd
Original Assignee
Vinyl Products Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vinyl Products Ltd filed Critical Vinyl Products Ltd
Priority to GB1337760A priority Critical patent/GB988171A/en
Publication of GB988171A publication Critical patent/GB988171A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062—Copolymers with monomers not covered by C09D133/06
    • C09D133/068—Copolymers with monomers not covered by C09D133/06 containing glycidyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L35/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/062—Copolymers with monomers not covered by C08L33/06
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/062—Copolymers with monomers not covered by C08L33/06
    • C08L33/068—Copolymers with monomers not covered by C08L33/06 containing glycidyl groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Paints Or Removers (AREA)

Abstract

Ethylene glycol bis-(b ,b -dimethyl glycidate) is prepared by condensing 2 mols. of acetone with 1 mol. of ethylene glycol di-(monochloro-acetate) in presence of sodium methoxide at a low temperature.ALSO:Thermoset resins are prepared by heating in absence of a cross-linking catalyst and in presence of molecular oxygen at above 100 DEG C., a mixture of a non-ionizable polyepoxide with a polymer or copolymer of an ester of a mono- or di-hydric ether alcohol with an a ,b -ethylenically-unsaturated mono- or poly-carboxylic acid. In a modification, the mixture is replaced by a copolymer of a glycidyl ester of an a , b -ethylenically-unsaturated mono- or poly-carboxylic acid with the unsaturated ester. a ,b -ethylenically unsaturated acids mentioned are acrylic, methacrylic, fumaric, maleic, itaconic, aconitic, and mesaconic. Polyepoxides mentioned are condensates of di-p-phenylol-2,2-propane and epichlorhydrin, e.g. "Epikote" or "Araldite" (Registered Trade Marks); and a polymer of a glycidyl ester of an a ,b -ethylenically-unsaturated mono- or poly-carboxylic acid. When a copolymer of the unsaturated ester is used, the co-monomer is preferably non-acidic, e.g. styrene, and at least 10% of the ester is used, based on the weight of copolymer. The compositions may be applied to wood, stone, concrete, plaster, paper, textile materials or metals, if desired from solution or emulsion, before thermosetting. In Examples, (1) a solution of poly-(b -ethoxy-ethyl methacrylate) in toluene was mixed with various quantities of "Epikote" and "Araldite" resins, films were deposited from the, mixtures and heated at temperatures of 120 DEG 150 DEG and 180 DEG C. (2) Copolymers were produced from mixtures of b -ethoxyethyl methacrylate and glycidyl methacrylate using benzoyl peroxide as catalyst, and dissolved in toluene. One mixture also included methyl methacrylate and ethyl acrylate, and this copolymer was dissolved in xylene and methyl ethyl ketone. Heated at 150 DEG C. the solution yielded films. (3) Films were cast from solutions of poly-(b -ethoxyethyl acrylate) in xylene-methyl ethyl ketone mixture, dried and baked at 150 DEG C. Poly-)methoxybutyl methacrylate) and poly-(diethylene glycol monobutyl ether methacrylate) are also referred to as suitable polyesters. (4) Films deposited from a toluene solution of a copolymer of b -ethoxyethylmethacrylate, glycidyl methacrylate, styrene and ethyl acrylate were baked at 150 DEG C. (5) Mixtures of varying proportions of b -ethoxyethyl methacrylate and glycidyl methacrylate were copolymerized in emulsion with potassium persulphate. The emulsifiers are specified. One of the mixtures also contained methyl methacylate. Films deposited from the copolymer emulsions were dried and insolubilized at 150 DEG C. (6) An emulsion of poly-(b -ethoxyethyl methacrylate) was mixed with an emulsion of a copolymer of glycidyl methacrylate and styrene, and used for making films which were stored at 150 DEG C. The emulsifiers used are specified. (7) A film of mixed ethylene glycol bis-(b -b -dimethyl glycidate) and poly-(b -ethoxyethyl methacrylate) was stored at 150 DEG C.
GB1337760A 1960-04-14 1960-04-14 Improvements in or relating to thermosetting resin compositions Expired GB988171A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1337760A GB988171A (en) 1960-04-14 1960-04-14 Improvements in or relating to thermosetting resin compositions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1337760A GB988171A (en) 1960-04-14 1960-04-14 Improvements in or relating to thermosetting resin compositions

Publications (1)

Publication Number Publication Date
GB988171A true GB988171A (en) 1965-04-07

Family

ID=10021864

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1337760A Expired GB988171A (en) 1960-04-14 1960-04-14 Improvements in or relating to thermosetting resin compositions

Country Status (1)

Country Link
GB (1) GB988171A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1984004099A1 (en) * 1983-04-09 1984-10-25 Basf Farben & Fasern Thermosetting binder mixture
GB2152947A (en) * 1984-01-02 1985-08-14 Jotun As Marine coating and certain new terpolymers for use therein

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1984004099A1 (en) * 1983-04-09 1984-10-25 Basf Farben & Fasern Thermosetting binder mixture
GB2152947A (en) * 1984-01-02 1985-08-14 Jotun As Marine coating and certain new terpolymers for use therein
AU570530B2 (en) * 1984-01-02 1988-03-17 Jotun A/S Acrylic anti-fouling marine coatings

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