GB987788A - Method of preparing aromatic mono-and dinitriles - Google Patents

Method of preparing aromatic mono-and dinitriles

Info

Publication number
GB987788A
GB987788A GB32500/62A GB3250062A GB987788A GB 987788 A GB987788 A GB 987788A GB 32500/62 A GB32500/62 A GB 32500/62A GB 3250062 A GB3250062 A GB 3250062A GB 987788 A GB987788 A GB 987788A
Authority
GB
United Kingdom
Prior art keywords
al2o3
aromatic mono
ammonia
specifications
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB32500/62A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toray Industries Inc
Original Assignee
Toyo Rayon Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyo Rayon Co Ltd filed Critical Toyo Rayon Co Ltd
Publication of GB987788A publication Critical patent/GB987788A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Aromatic mono- and di-nitriles are prepared by reacting a saturated aliphatic hydrocarbon (at least C7) with ammonia and oxygen in the vapour phase at 250-800 DEG C. over a catalyst comprising at least one of Cu, Ag, Sn, U, Th, V, Cr, Mo, W or Group VIII metals or at least one compound thereof. In examples, benzonitrile, tolunitrile, phthalonitrile, isophthalonitrile and terephthalonitrile are produced. Specifications 796,765, 806,492, 867,348 and 874,493 are referred to.ALSO:Exemplified catalysts for the production of aromatic nitriles from hydrocarbons, ammonia and oxygen, wherein the indicated active metals appear to be present as oxides, are: Pt1V/Mo/Al2O3, V/Al2O3, V/Cr/Al2O3, V/SiC, V/Mo/Al2O3, V/Mo/Cr/Fe/Al2O3, V/Mo/Cr/Bi/Al2O3, V/Mo/Cr/Al2O3. The catalyst were prepared by simultaneous and/or consecutive absorption of aqueous solutions of compounds of the active metals on the carrier, followed by calcination. Specifications 796,765, 806,492, 867,348 and 874,493.
GB32500/62A 1961-08-24 1962-08-23 Method of preparing aromatic mono-and dinitriles Expired GB987788A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP3067461 1961-08-24
JP3251562 1962-08-06

Publications (1)

Publication Number Publication Date
GB987788A true GB987788A (en) 1965-03-31

Family

ID=26369072

Family Applications (1)

Application Number Title Priority Date Filing Date
GB32500/62A Expired GB987788A (en) 1961-08-24 1962-08-23 Method of preparing aromatic mono-and dinitriles

Country Status (3)

Country Link
DE (1) DE1277839B (en)
FR (1) FR1336453A (en)
GB (1) GB987788A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1181408A (en) * 1981-12-21 1985-01-22 Ernest C. Milberger Nitrogenation of hydrocarbons, including the production of maleimide

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2450636A (en) * 1946-01-31 1948-10-05 Socony Vacuum Oil Co Inc Production of nitriles
US2450638A (en) * 1946-02-01 1948-10-05 Socony Vacuum Oil Co Inc Production of nitriles
US2450640A (en) * 1946-03-09 1948-10-05 Socony Vacuum Oil Co Inc Production of nitriles
US2450641A (en) * 1946-05-24 1948-10-05 Socony Vacuum Oil Co Inc Production of nitriles
US2540787A (en) * 1948-12-01 1951-02-06 Socony Vacuum Oil Co Inc Production of benzonitrile
US2828325A (en) * 1956-06-26 1958-03-25 Allied Chem & Dye Corp Production of benzonitrile

Also Published As

Publication number Publication date
FR1336453A (en) 1963-08-30
DE1277839B (en) 1968-09-19

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