GB979243A - Process for the production of spinnable solutions of polymers of acrylonitrile in aqueous nitric acid - Google Patents
Process for the production of spinnable solutions of polymers of acrylonitrile in aqueous nitric acidInfo
- Publication number
- GB979243A GB979243A GB4711/63A GB471163A GB979243A GB 979243 A GB979243 A GB 979243A GB 4711/63 A GB4711/63 A GB 4711/63A GB 471163 A GB471163 A GB 471163A GB 979243 A GB979243 A GB 979243A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- nitric acid
- acrylonitrile
- polymerization
- vinyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 title abstract 5
- 229910017604 nitric acid Inorganic materials 0.000 title abstract 5
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 title abstract 3
- 229920000642 polymer Polymers 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 abstract 4
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 abstract 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 abstract 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- FCYVWWWTHPPJII-UHFFFAOYSA-N 2-methylidenepropanedinitrile Chemical compound N#CC(=C)C#N FCYVWWWTHPPJII-UHFFFAOYSA-N 0.000 abstract 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 abstract 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 abstract 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 229960005070 ascorbic acid Drugs 0.000 abstract 1
- 235000010323 ascorbic acid Nutrition 0.000 abstract 1
- 239000011668 ascorbic acid Substances 0.000 abstract 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 abstract 1
- 239000004202 carbamide Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000005112 continuous flow technique Methods 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 238000007872 degassing Methods 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 125000005395 methacrylic acid group Chemical class 0.000 abstract 1
- 125000005394 methallyl group Chemical group 0.000 abstract 1
- -1 methallyl sulphonic acid Chemical compound 0.000 abstract 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 239000004332 silver Substances 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/18—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/42—Nitriles
- C08F20/44—Acrylonitrile
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/28—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/38—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds comprising unsaturated nitriles as the major constituent
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Textile Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Toxicology (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Polyethers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH195262A CH418517A (de) | 1963-02-01 | 1962-02-16 | Spinnlösung eines Acrylnitril-homo- oder -copolymerisates |
| CH1239363A CH434555A (de) | 1963-10-09 | 1963-10-09 | Verfahren zur Herstellung von verspinnbaren Lösungen von Polymeren des Acrylnitrils |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB979243A true GB979243A (en) | 1965-01-01 |
Family
ID=25689084
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4711/63A Expired GB979243A (en) | 1962-02-16 | 1963-02-05 | Process for the production of spinnable solutions of polymers of acrylonitrile in aqueous nitric acid |
| GB40327/64A Expired GB1017046A (en) | 1962-02-16 | 1964-10-02 | A process for the production of spinnable solutions of acrylonitrile polymers |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB40327/64A Expired GB1017046A (en) | 1962-02-16 | 1964-10-02 | A process for the production of spinnable solutions of acrylonitrile polymers |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3410941A (en, 2012) |
| BE (2) | BE654144A (en, 2012) |
| GB (2) | GB979243A (en, 2012) |
| NL (2) | NL6411708A (en, 2012) |
| SE (1) | SE307240B (en, 2012) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE628520A (en, 2012) * | 1962-02-16 | |||
| US3516903A (en) * | 1966-10-17 | 1970-06-23 | Rohm & Haas | Novel modacrylic fiber |
| US3926930A (en) * | 1969-05-08 | 1975-12-16 | Asahi Chemical Ind | Hygroscopic acrylic synthetic fibers and method for preparing the same |
| US4172823A (en) * | 1970-03-26 | 1979-10-30 | Ceskoslovenska Akademie Ved | Method of preparing cross-linked hydrogels |
| US4123406A (en) * | 1970-03-26 | 1978-10-31 | Ceskoslovenska Akademie Ved | Method of preparing shaped articles from cross-linked hydrogels |
| CS153794B1 (en, 2012) * | 1970-07-02 | 1974-03-29 | ||
| US3948870A (en) * | 1973-09-17 | 1976-04-06 | Ceskoslovenska Akademie Ved | Method of preparing hydrophilic copolymers of acrylonitrile |
| US6277933B1 (en) * | 1998-04-03 | 2001-08-21 | Solutia Inc. | Polyacrylonitrile particles by surfmer polymerization and sodium removal by chemical exchange |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2612490A (en) * | 1948-12-24 | 1952-09-30 | Hercules Powder Co Ltd | Homogeneous polymerization of vinylidene compounds with an alpha, alpha-dialkylarylmethyl hydroperoxide and a heavy metal compound as catalyst |
| US3073669A (en) * | 1958-09-06 | 1963-01-15 | Asahi Chemical Ind | Method for producing shaped articles from polymers and copolymers of acrylonitrile |
| GB996513A (en) * | 1961-09-05 | 1965-06-30 | Japan Exlan Co Ltd | Improvements in preparation of acrylonitrile copolymers |
| US3080209A (en) * | 1961-10-12 | 1963-03-05 | Asahi Chemical Ind | Method for producing acrylonitrile polymer fibers and filaments by wet spinning process |
| BE628520A (en, 2012) * | 1962-02-16 | |||
| US3287304A (en) * | 1963-01-03 | 1966-11-22 | Asahi Chemical Ind | Acrylonitrile copolymers and compositions |
| US3147322A (en) * | 1963-01-23 | 1964-09-01 | Asahi Chemical Ind | Method for preparing acrylonitrile synthetic fiber |
-
0
- BE BE628520D patent/BE628520A/xx unknown
- NL NL288990D patent/NL288990A/xx unknown
-
1963
- 1963-02-05 GB GB4711/63A patent/GB979243A/en not_active Expired
- 1963-02-15 SE SE1700/63A patent/SE307240B/xx unknown
-
1964
- 1964-10-02 GB GB40327/64A patent/GB1017046A/en not_active Expired
- 1964-10-08 NL NL6411708A patent/NL6411708A/xx unknown
- 1964-10-08 BE BE654144A patent/BE654144A/xx unknown
-
1967
- 1967-03-30 US US626936A patent/US3410941A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| GB1017046A (en) | 1966-01-12 |
| NL6411708A (en, 2012) | 1965-04-12 |
| BE654144A (en, 2012) | 1965-04-08 |
| US3410941A (en) | 1968-11-12 |
| BE628520A (en, 2012) | |
| SE307240B (en, 2012) | 1968-12-23 |
| NL288990A (en, 2012) |
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