GB976566A - Amphoteric ion exchange resins - Google Patents

Amphoteric ion exchange resins

Info

Publication number
GB976566A
GB976566A GB402261A GB402261A GB976566A GB 976566 A GB976566 A GB 976566A GB 402261 A GB402261 A GB 402261A GB 402261 A GB402261 A GB 402261A GB 976566 A GB976566 A GB 976566A
Authority
GB
United Kingdom
Prior art keywords
formula
ion exchange
exchange resins
amphoteric ion
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB402261A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DEF30457A external-priority patent/DE1153022B/en
Application filed by Bayer AG filed Critical Bayer AG
Publication of GB976566A publication Critical patent/GB976566A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D203/00Heterocyclic compounds containing three-membered rings with one nitrogen atom as the only ring hetero atom
    • C07D203/04Heterocyclic compounds containing three-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D203/06Heterocyclic compounds containing three-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D203/08Heterocyclic compounds containing three-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring nitrogen atom
    • C07D203/12Radicals substituted by nitrogen atoms not forming part of a nitro radical
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J43/00Amphoteric ion-exchange, i.e. using ion-exchangers having cationic and anionic groups; Use of material as amphoteric ion-exchangers; Treatment of material for improving their amphoteric ion-exchange properties
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/38Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/547Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/564Three-membered rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G14/00Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00
    • C08G14/02Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes
    • C08G14/04Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols
    • C08G14/06Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols and monomers containing hydrogen attached to nitrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02Polyamines
    • C08G73/0206Polyalkylene(poly)amines
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02Polyamines
    • C08G73/0206Polyalkylene(poly)amines
    • C08G73/0213Preparatory process

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Epoxy Resins (AREA)

Abstract

The invention comprises amphoteric ion exchange resins which are polymers having units of the formula <FORM:0976566/C3/1> where A is a -P(O)(OH)2 radical or salt or monoester thereof and, optionally, units of the formula <FORM:0976566/C3/2> They are prepared by polymerizing ethylene imine -N- ethyl phosphoric acid esters of the formula <FORM:0976566/C3/3> where R is C1- 4 alkyl or a salt-forming ion in the presence of a sulphonic acid ester or dialkyl sulphate as catalyst, and when R is alkyl, saponifying or hydrolysing the product. For the copolymers, b ,b 1-(diethylene-imino) -pdiethyl benzene is added to the polymerization mixture. Solvents and emulsifiers may be present and the products may be in the form of beads. Specifications 976,567, 976,568, 976,569 and 976,570 are referred to.
GB402261A 1960-02-04 1961-02-02 Amphoteric ion exchange resins Expired GB976566A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DEF30460A DE1160183B (en) 1960-02-04 1960-02-04 Process for the production of copolymers of ethyleneimine compounds serving as amphoteric ion exchangers
DEF30457A DE1153022B (en) 1960-02-04 1960-02-04 Process for the preparation of AEthylenimin-N-ethylphosphonic acid dialkyl esters
FR851318A FR1278553A (en) 1960-02-04 1961-02-01 Amphoteric ion exchange resins

Publications (1)

Publication Number Publication Date
GB976566A true GB976566A (en) 1964-11-25

Family

ID=27210163

Family Applications (5)

Application Number Title Priority Date Filing Date
GB402261A Expired GB976566A (en) 1960-02-04 1961-02-02 Amphoteric ion exchange resins
GB54263A Expired GB976567A (en) 1960-02-04 1961-02-02 A process for the production of amphoteric ion exchange resins
GB54363A Expired GB976568A (en) 1960-02-04 1961-02-02 A process for the production of amphoteric ion exchange resins
GB54463A Expired GB976569A (en) 1960-02-04 1961-02-02 A process for the preparation of diesters of n-dihydroxy-phosphinylethyl ethylene imine
GB3602163A Expired GB976570A (en) 1960-02-04 1961-02-02 Amphoteric ion exchange resins

Family Applications After (4)

Application Number Title Priority Date Filing Date
GB54263A Expired GB976567A (en) 1960-02-04 1961-02-02 A process for the production of amphoteric ion exchange resins
GB54363A Expired GB976568A (en) 1960-02-04 1961-02-02 A process for the production of amphoteric ion exchange resins
GB54463A Expired GB976569A (en) 1960-02-04 1961-02-02 A process for the preparation of diesters of n-dihydroxy-phosphinylethyl ethylene imine
GB3602163A Expired GB976570A (en) 1960-02-04 1961-02-02 Amphoteric ion exchange resins

Country Status (4)

Country Link
DE (1) DE1160183B (en)
FR (1) FR1278553A (en)
GB (5) GB976566A (en)
NL (1) NL260849A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3018862A1 (en) * 1975-01-27 1982-01-21 A.T. Ramot Plastics Ltd., Tel Aviv AROMATIC ARALIPHATIC POLYMERS AND COPOLYMERS AND PRODUCTS MADE THEREOF
EP0490231A2 (en) * 1990-12-14 1992-06-17 BASF Aktiengesellschaft Polyethyleneimine- and polyvinylamine-derivates, aluminum based carriers coated with them and their use in making offsetprinting plates

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1270287B (en) * 1965-09-27 1968-06-12 Max Planck Gesellschaft Process for the production of copolymers of ethyleneimine compounds serving as amphoteric ion exchangers
US3459686A (en) * 1966-06-06 1969-08-05 Dow Chemical Co Aziridine copolymers
US3468818A (en) * 1966-08-01 1969-09-23 Nalco Chemical Co Polymers and process of preparation
US4020019A (en) 1975-01-29 1977-04-26 Gianluigi Soldati Anticaries agents
JPS5443292A (en) * 1977-09-12 1979-04-05 Unitika Ltd Etherified phenolic chelate resin* its production* and adsorption treatment
CN108479713A (en) * 2018-04-10 2018-09-04 浙江农林大学 A kind of aminocarboxylic acid type hydro-thermal bamboo charcoal synthetic method

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL110743C (en) * 1954-05-17 1900-01-01
DE1056825B (en) * 1956-03-07 1959-05-06 Wolfen Filmfab Veb Process for the preparation of insoluble nitrogen-containing cation exchange resins
DE1056371B (en) * 1956-05-23 1959-04-30 Wolfen Filmfab Veb Process for the production of synthetic resins used as anion exchangers or adsorbents

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3018862A1 (en) * 1975-01-27 1982-01-21 A.T. Ramot Plastics Ltd., Tel Aviv AROMATIC ARALIPHATIC POLYMERS AND COPOLYMERS AND PRODUCTS MADE THEREOF
EP0490231A2 (en) * 1990-12-14 1992-06-17 BASF Aktiengesellschaft Polyethyleneimine- and polyvinylamine-derivates, aluminum based carriers coated with them and their use in making offsetprinting plates
EP0490231A3 (en) * 1990-12-14 1994-01-19 Basf Ag
EP0687700A2 (en) * 1990-12-14 1995-12-20 Basf Aktiengesellschaft Polyvinylamine derivatives aluminium-based carriers coated with them and their use in making off-set printing plates
EP0687700A3 (en) * 1990-12-14 1996-01-03 Basf Ag

Also Published As

Publication number Publication date
DE1160183B (en) 1963-12-27
GB976570A (en) 1964-11-25
GB976569A (en) 1964-11-25
GB976568A (en) 1964-11-25
NL260849A (en)
FR1278553A (en) 1961-12-08
GB976567A (en) 1964-11-25

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