GB975768A - Producing lead-potassium-sodium alloys electrolytically - Google Patents
Producing lead-potassium-sodium alloys electrolyticallyInfo
- Publication number
- GB975768A GB975768A GB33069/62A GB3306962A GB975768A GB 975768 A GB975768 A GB 975768A GB 33069/62 A GB33069/62 A GB 33069/62A GB 3306962 A GB3306962 A GB 3306962A GB 975768 A GB975768 A GB 975768A
- Authority
- GB
- United Kingdom
- Prior art keywords
- potassium
- koh
- electrolyte
- lead
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/36—Alloys obtained by cathodic reduction of all their ions
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
Lead-potassium-sodium alloys are obtained by electrolysing a fused electrolyte of potassium and sodium hydroxides using a molten lead cathode and an anode of a different metal such as iron which does not melt at the operating temperature. Preferably the sodium hydroxide is not less than 20%, e.g. between 30 and 50%, by weight of the electrolyte, and a part of the potassium hydroxide may be replaced by potassium carbonate or chloride, preferably not exceeding 10% by weight of the electrolyte. The anode may be a perforated circular metal plate. For example, using an electrolyte of 46 kg. KOH and 24 kg. NaOH at 400 DEG C., an alloy containing 2.8% K, 0.5% Na and balance Pb is obtained. The Na content of the alloy obtained may be reduced by melting it along with KOH or KOH mixed with a smaller amount of NaOH than in the original eletrolyte, K2CO3 or KCl again optionally replacing part of the KOH. The final alloy may contain 3.3% K and 0.1% Na. The above alloys may be used to debismuthize lead. Specification 491,827 is referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR873972A FR1311228A (en) | 1961-09-22 | 1961-09-22 | Manufacturing process of lead, potassium and sodium alloys |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB975768A true GB975768A (en) | 1964-11-18 |
Family
ID=8763354
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB33069/62A Expired GB975768A (en) | 1961-09-22 | 1962-08-28 | Producing lead-potassium-sodium alloys electrolytically |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE1176376B (en) |
| FR (1) | FR1311228A (en) |
| GB (1) | GB975768A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111850322A (en) * | 2020-07-31 | 2020-10-30 | 淄博泰坦电子科技有限公司 | Process and device for producing potassium metal |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR737785A (en) * | 1931-06-01 | 1932-12-16 | Process for manufacturing an alkaline-lead or alkaline-earth metal alloy, in particular for accumulator plates |
-
1961
- 1961-09-22 FR FR873972A patent/FR1311228A/en not_active Expired
-
1962
- 1962-08-28 GB GB33069/62A patent/GB975768A/en not_active Expired
- 1962-09-01 DE DES81240A patent/DE1176376B/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| DE1176376B (en) | 1964-08-20 |
| FR1311228A (en) | 1962-12-07 |
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