GB964231A - Process for the protection of light sensitive cellulose textile material which may be coloured or brightened and textile material protected thereby - Google Patents
Process for the protection of light sensitive cellulose textile material which may be coloured or brightened and textile material protected therebyInfo
- Publication number
- GB964231A GB964231A GB2889262A GB2889262A GB964231A GB 964231 A GB964231 A GB 964231A GB 2889262 A GB2889262 A GB 2889262A GB 2889262 A GB2889262 A GB 2889262A GB 964231 A GB964231 A GB 964231A
- Authority
- GB
- United Kingdom
- Prior art keywords
- brightened
- vinyl
- textile material
- polymers
- plasticized
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000463 material Substances 0.000 title abstract 3
- 239000004753 textile Substances 0.000 title abstract 3
- 229920002678 cellulose Polymers 0.000 title abstract 2
- 239000001913 cellulose Substances 0.000 title 1
- -1 hydrocarbon radicals Chemical class 0.000 abstract 5
- 229920000642 polymer Polymers 0.000 abstract 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 abstract 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 abstract 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- 244000198134 Agave sisalana Species 0.000 abstract 2
- 229920003043 Cellulose fiber Polymers 0.000 abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 abstract 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 2
- 125000001931 aliphatic group Chemical group 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 229920003086 cellulose ether Polymers 0.000 abstract 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 abstract 2
- 150000001993 dienes Chemical class 0.000 abstract 2
- 239000003960 organic solvent Substances 0.000 abstract 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 abstract 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 229920000742 Cotton Polymers 0.000 abstract 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 abstract 1
- 229920000877 Melamine resin Polymers 0.000 abstract 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- 239000004952 Polyamide Substances 0.000 abstract 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 abstract 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- 125000003368 amide group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 abstract 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 abstract 1
- 239000004202 carbamide Substances 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 239000012975 dibutyltin dilaurate Substances 0.000 abstract 1
- 150000004816 dichlorobenzenes Chemical class 0.000 abstract 1
- AFSIMBWBBOJPJG-UHFFFAOYSA-N ethenyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC=C AFSIMBWBBOJPJG-UHFFFAOYSA-N 0.000 abstract 1
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 abstract 1
- 229920001519 homopolymer Polymers 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 125000004464 hydroxyphenyl group Chemical group 0.000 abstract 1
- 230000000266 injurious effect Effects 0.000 abstract 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 1
- 239000004800 polyvinyl chloride Substances 0.000 abstract 1
- 239000004627 regenerated cellulose Substances 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
Abstract
Cellulosic textile materials, e.g. cotton, sisal and regenerated cellulose fibres, which may have been coloured or brightened, are protected from the injurious effects of light by treating them with an organic solvent solution of a polymer which contains at least one 2-(21 hydroxyphenyl)-benztriazole compound of the formula <FORM:0964231/D1-D2/1> in which A and B may be substituted in the 5, 31, 41 and 51 positions by new colour producing substituents, e.g. hydrocarbon radicals, halogen atoms, ether or diether groups, carboxylic acid or sulphonic acid ester or amide groups or alkyl sulphenyl or aryl sulphenyl groups. Suitable polymers are addition polymers of at least one ethylenically unsaturated vinyl or vinylidene monomer, e.g. vinyl chloride, vinyl acetate, vinylidene chloride, styrene, methyl acrylate, butylacrylate and methyl methacrylate, homopolymers of aliphatic conjugated dienes having 4-6 carbonatoms, copolymers of aliphatic conjugated dienes having 4-6 carbon atoms with styrene or acrylonitrile, polyesters, polyamides, precondensates of urea and/or melamine with aldehydes, e.g. formaldehyde or fruthural, cellulose ethers and cellulose ethers and cellulose esters. Polymers plasticized internally or externally, e.g. polyvinyl chloride externally plasticized with dioctyl phthalate and vinyl chloride polymers internally plasticized by copolymerisation with vinyl stearate, may be used. The organic solvent may be tetrachloroethane, cyclohexame, benzene, toluene, chlorobenzene, dichlorobenzenes, acetone, methyl ethyl betane, ethyl acetate or butyl acetate. The treating solution may also contain as stabilizer dibutyl tin dilaurate. The cellulose fibres may have been brightened with <FORM:0964231/D1-D2/2> <FORM:0964231/D1-D2/3> <FORM:0964231/D1-D2/4> <FORM:0964231/D1-D2/5> <FORM:0964231/D1-D2/6> The treatment of sisal carpets is described.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH891161 | 1961-07-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB964231A true GB964231A (en) | 1964-07-22 |
Family
ID=4346173
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2889262A Expired GB964231A (en) | 1961-07-28 | 1962-07-27 | Process for the protection of light sensitive cellulose textile material which may be coloured or brightened and textile material protected thereby |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB964231A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3441361A (en) * | 1965-01-05 | 1969-04-29 | Monsanto Co | Dyed polyvinyl acetal sheet containing an alkylated hydroxy phenyl benzotriazole stabilizer |
| GB2174731A (en) * | 1985-05-08 | 1986-11-12 | Sandoz Ltd | Extinguishing or preventing optical brightening |
-
1962
- 1962-07-27 GB GB2889262A patent/GB964231A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3441361A (en) * | 1965-01-05 | 1969-04-29 | Monsanto Co | Dyed polyvinyl acetal sheet containing an alkylated hydroxy phenyl benzotriazole stabilizer |
| GB2174731A (en) * | 1985-05-08 | 1986-11-12 | Sandoz Ltd | Extinguishing or preventing optical brightening |
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