GB959376A - Copolymers containing phosphorus and a process for their manufacture - Google Patents

Copolymers containing phosphorus and a process for their manufacture

Info

Publication number
GB959376A
GB959376A GB3060660A GB3060660A GB959376A GB 959376 A GB959376 A GB 959376A GB 3060660 A GB3060660 A GB 3060660A GB 3060660 A GB3060660 A GB 3060660A GB 959376 A GB959376 A GB 959376A
Authority
GB
United Kingdom
Prior art keywords
vinyl
ester
monomer
styrene
sodium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3060660A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Farbwerke Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG, Farbwerke Hoechst AG filed Critical Hoechst AG
Publication of GB959376A publication Critical patent/GB959376A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C08F218/08—Vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F30/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F30/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing phosphorus

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Copolymers are produced of at least one vinyl phosphonic acid of formula: <FORM:0959376/C3/1> where R1 and R2 each represent an alkyl group containing more than two carbon atoms, or a cycloalkyl, aralkyl, or aryl group and at least one monomer of formula: <FORM:0959376/C3/2> where R1 is hydrogen, halogen, alkyl or nitrile and R2 is R1 or carbonyl, carbalkoxy, acyl or carbonamide. It is preferred that the phosphonic acid component is present within the range of 5 to 70%. Specified phosphonic esters are vinyl phosphonic acid bis-(2-ethyl-hexyl ester), dioctylester, diethyl ester and dibutyl ester. Specified comonomers are styrene, methyl styrene, acrylic acid, methacrylic acid, their esters, amides and nitriles, vinyl methyl ketone, vinyl chloride, vinylidene chloride, vinyl acetate, propionate, stearate or benzoate, ethylene and propylene. The third monomer may also be present; thus the ester may be copolymerized with vinyl chloride or acetate and an acrylic acid ester, acrylonitrile, styrene, a vinyl ether, butadiene, vinylidene chloride or trichloroethylene. The polymerization may take place in aqueous media in suspension or emulsion preferably with a portion of the monomer present initially, the remainder being added during polymerization, and using emulsifiers, suspension stabilizers and catalysts such as per-compounds and particularly redox systems e.g. sodium or potassium persulphate and sodium or potassium bisulphite or consisting of hydrogen peroxide and sodium formaldehyde sulphoxylate. Specification 855,669 is referred to.
GB3060660A 1959-09-04 1960-09-05 Copolymers containing phosphorus and a process for their manufacture Expired GB959376A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEF29303A DE1125658B (en) 1959-09-04 1959-09-04 Process for the production of phosphorus-containing copolymers

Publications (1)

Publication Number Publication Date
GB959376A true GB959376A (en) 1964-06-03

Family

ID=7093247

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3060660A Expired GB959376A (en) 1959-09-04 1960-09-05 Copolymers containing phosphorus and a process for their manufacture

Country Status (5)

Country Link
BE (1) BE594750A (en)
CH (1) CH418645A (en)
DE (1) DE1125658B (en)
GB (1) GB959376A (en)
NL (3) NL6801605A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4147853A (en) 1977-05-31 1979-04-03 Stauffer Chemical Company Internally plasticized vinyl chloride copolymer
EP3666872A1 (en) * 2018-12-12 2020-06-17 Henkel AG & Co. KGaA Phosphonated acrylic copolymers for surface hydrophilization

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3318855A (en) * 1962-06-22 1967-05-09 Union Carbide Corp Phosphorus containing copolymers
DE1215374B (en) * 1963-07-27 1966-04-28 Hoechst Ag Process for the production of phosphorus-containing copolymers
CA1116790A (en) * 1977-01-27 1982-01-19 Stauffer Chemical Company Internally plasticized vinyl chloride copolymer
DE3418496A1 (en) * 1984-05-18 1985-11-21 Hoechst Ag, 6230 Frankfurt METHOD FOR PRODUCING MIXED POLYMERISATES FROM VINYLPHOSPHONIC ACID AND (METH-) ACRYLIC ACID IN AQUEOUS SOLUTION AND THE USE THEREOF
JPS63112675A (en) * 1986-10-30 1988-05-17 Denki Kagaku Kogyo Kk Adhesive

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2671077A (en) * 1951-08-07 1954-03-02 Du Pont Phosphorus-containing polymers

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4147853A (en) 1977-05-31 1979-04-03 Stauffer Chemical Company Internally plasticized vinyl chloride copolymer
EP3666872A1 (en) * 2018-12-12 2020-06-17 Henkel AG & Co. KGaA Phosphonated acrylic copolymers for surface hydrophilization

Also Published As

Publication number Publication date
NL125864C (en)
CH418645A (en) 1966-08-15
NL255391A (en)
NL6801605A (en) 1968-04-25
DE1125658B (en) 1962-03-15
BE594750A (en) 1961-03-06

Similar Documents

Publication Publication Date Title
GB1433908A (en) Perfluoroalkyl groups containing polymerisation products
GB1309513A (en) Copolymer compositions
GB959376A (en) Copolymers containing phosphorus and a process for their manufacture
GB694253A (en) Manufacture of polymers containing plasticizers
GB859717A (en) Method of polymerizing compounds
GB1009303A (en) Process for the polymerisation of ethylenically unsaturated compounds
GB1105798A (en) Process for the manufacture of copolymers of vinyl chloride
GB975381A (en) Process for the polymerisation of vinyl chloride
GB852611A (en) Process for polymerizing vinyl compounds
GB1050625A (en)
GB1092884A (en) Copolymers
GB919324A (en) New synthetic resins
US3846390A (en) Process for producing polyvinyl chloride in the presence of alkyl thioglycolate as a chain transfer agent
GB1004055A (en) Water-soluble copolymers and process for preparing them
GB1017457A (en) Inhibition of polymerisation
GB1017895A (en) Polymerization of unsaturated monomers
US3403123A (en) Polyvinyl halide latices stabilized with diammonium phosphate and ammonium hydroxide
GB996737A (en) Polymerization process and catalyst therefor
GB948975A (en) A process for the production of acrylonitrile polymers
GB1414393A (en) Process for making chloroprene-sulphur copolymers
GB1415060A (en) Method for polymerizing n-alkyl-n-arylaminoethyl esters of acrylic acid and acrylic acid derivatives
US3637632A (en) Shortstopping free radical polymerization of vinylidene monomers
GB1272584A (en) Process for deodorising polymers of unsaturated esters
GB852019A (en) Improvements in and relating to polymerization
GB1127995A (en) Process for the production of vinyl chloride polymers