GB721154A - Improvements in and relating to epoxyalkoxy aryl resin polymeric compositions - Google Patents

Improvements in and relating to epoxyalkoxy aryl resin polymeric compositions

Info

Publication number
GB721154A
GB721154A GB11600/51A GB1160051A GB721154A GB 721154 A GB721154 A GB 721154A GB 11600/51 A GB11600/51 A GB 11600/51A GB 1160051 A GB1160051 A GB 1160051A GB 721154 A GB721154 A GB 721154A
Authority
GB
United Kingdom
Prior art keywords
acetate
cellulose
maleic
epoxy resin
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB11600/51A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beazer East Inc
Original Assignee
Koppers Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Koppers Co Inc filed Critical Koppers Co Inc
Publication of GB721154A publication Critical patent/GB721154A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/18—Homopolymers or copolymers of nitriles
    • C08L33/20—Homopolymers or copolymers of acrylonitrile
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C08G59/04—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
    • C08G59/06—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols
    • C08G59/08—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols from phenol-aldehyde condensates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/42—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
    • C08G59/4246—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof polymers with carboxylic terminal groups
    • C08G59/4261—Macromolecular compounds obtained by reactions involving only unsaturated carbon-to-carbon bindings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C08L63/04—Epoxynovolacs
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Epoxy Resins (AREA)
  • Artificial Filaments (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A composition of matter suitable for forming shaped articles consists of an epoxyalkoxyaryl resin as claimed in Specification 721,149 or Specification 721,151, and either an active hydrogen-containing fibre-forming polymer of an ethylenically unsaturated monomer, or regenerated cellulose or a cellulose ester or ether, e.g. cellulose nitrate, acetate, formate, propionate, butyrate, acetate-butyrate, methyl, ethyl or benzoyl cellulose, b -hydroxy ethyl cellulose or cellulose half esters of maleic, succinic or fumaric acid. Polymers mentioned are polyvinyl alcohol, polyvinyl acetals, partially hydrolysed polyvinyl acetate, polymers or copolymers of acrylic acid, maleic acid, fumeric acid, maleic or fumeric half esters, acrylamide, hydroxyamino- or carboxy-styrene, and copolymers of acrylonitrile, styrene, acyrlates, or vinyl esters with acids such as acrylic, maleic or itaconic. The epoxy resins may be incorporated into spinning compositions containing the polymers and cross-linking effected by heat or catalysts during or after the spinning operation, or fibres formed from the polymers may be impregnated with a solution of epoxy resin, the solvent evaporated and the product treated with heat or catalysts to effect reaction between the polymer and the epoxy resin. Preferably the proportion of epoxy resin in the mixture varies from 1-5 per cent in the case of fibre manufacture but for moulded products the proportion may be up to 50 per cent. Catalysts for the cross-linking reaction between the two resins are oxalic, maleic or phthalic acid, diethylamine, dibutylamine, diethylene triamine, piperidine, piperidine benzoate, trimethylamine, triethylamine, triethanolamine, methyl di-n-propylamine, guanidine, aluminium chloride or bromide, zinc chloride or bromide, boron trifluoride, silicon tetrachloride, stannic chloride or bromide, titanium tetrachloride, bismuthtrichloride, alkali hydroxides, calcium hydroxide or sodium amide. The catalysts may be added with the epoxy resin or, as a solution subsequently. The epoxy resin may be added as a solution, e.g. in acetone, methyl ethyl ketone, methyl, ethyl or n-butyl acetate, propylene oxide, dioxane, chloroform, ethylene, dichloride, dichloro ethyl ether, b -hydroxyethyl acetate, b - butoxyethanol, toluene-alcohol mixtures, or a mono-epoxy alkane such as phenyl glycidyl ether, isopropylphenyl glycidyl ether, o- or p-monobutylm-cresyl glycidyl ether, glycidyl acetate, or mono- or di-glycidyl phthalate. Mixed epoxy resins of different molecular weights may be used. In the examples: (1) copolymers of acrylonitrile with 1 and 5 per cent itaconic acid are prepared in emulsion in presence of ammonium benzene sulphonate. They are dissolved in N,N-dimethyl formamide and a glycidyl ether of a formaldehyde-p-cresol condensate is added. Fibres are spun by dry or wet methods, freed from solvent, dried, cold-drawn and then heated at 150 DEG C. for 1 hour; (2) cellulose acetate is dissolved in acetone and the glycidyl ether used in example 1 is added. Fibres were spun by dry-spinning and heat-treated at 75 DEG C. forabout 2 hours. Specification 721,153 also is referred to.
GB11600/51A 1950-05-27 1951-05-17 Improvements in and relating to epoxyalkoxy aryl resin polymeric compositions Expired GB721154A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US164841A US2683130A (en) 1950-05-27 1950-05-27 Polymeric compositions from phenolaldehyde-epoxy resins and resins reactive therewith

Publications (1)

Publication Number Publication Date
GB721154A true GB721154A (en) 1954-12-29

Family

ID=22596314

Family Applications (2)

Application Number Title Priority Date Filing Date
GB11340/51A Expired GB721153A (en) 1950-05-27 1951-05-15 Hardenable epoxyalkoxy aryl resin compositions
GB11600/51A Expired GB721154A (en) 1950-05-27 1951-05-17 Improvements in and relating to epoxyalkoxy aryl resin polymeric compositions

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB11340/51A Expired GB721153A (en) 1950-05-27 1951-05-15 Hardenable epoxyalkoxy aryl resin compositions

Country Status (4)

Country Link
US (1) US2683130A (en)
BE (1) BE503546A (en)
FR (2) FR1061644A (en)
GB (2) GB721153A (en)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2732368A (en) * 1956-01-24 Type hi phenolic resins and their
US2716099A (en) * 1952-01-19 1955-08-23 Shell Dev Epoxy resins from alkyl phenol novolac resins
NL108217C (en) * 1952-06-06
US2790010A (en) * 1952-12-18 1957-04-23 Hooker Electrochemical Co Synthesis of meta-substituted phenols
US2844553A (en) * 1953-04-24 1958-07-22 Sherwin Williams Co Polyhydric phenol-aldehyde-epihalo-hydrin resins
US2885385A (en) * 1953-07-16 1959-05-05 Union Carbide Corp Polyphenylol derivatives of olefinic aldehydes
US2920058A (en) * 1955-01-14 1960-01-05 Dow Corning Compositicn consisting essentially of the resinous reaction product of an esterified phenol-aldehyde resin and a silicone resin
US2938880A (en) * 1955-05-09 1960-05-31 Bailey William Russell Cured epoxy resin composition containing boron trifluoride complex of a monoethylamine and piperidine, method of curing said composition and glass fibers impregnated therewith
US3030247A (en) * 1955-07-28 1962-04-17 Minnesota Mining & Mfg Stable heat-curing epoxy resin compositions
NL210722A (en) * 1955-09-20
US2983131A (en) * 1955-10-12 1961-05-09 Clifford A Stephens Manufacture of coated leather shaft seals
US2829124A (en) * 1955-12-23 1958-04-01 Borden Co Epoxide resin
US3039981A (en) * 1955-12-27 1962-06-19 Owens Corning Fiberglass Corp Aqueous binder composition of phenolformaldehyde condensate, aluminum sulfate and mineral oil, and glass fiber coated therewith
US2890204A (en) * 1956-02-13 1959-06-09 Furane Plastics Epoxy resin compositions
NL221118A (en) * 1956-09-27 1900-01-01
US2938884A (en) * 1956-11-20 1960-05-31 Dow Chemical Co Oxypropylation of phenolic resins
DE1124240B (en) * 1959-05-15 1962-02-22 Basf Ag Use of diureas as hardening agents for epoxy resins
US3048920A (en) * 1959-07-09 1962-08-14 Charles J Wheeler Tool for parting elongated fracturable members
US3242120A (en) * 1960-03-22 1966-03-22 Du Pont Self-supporting gel shaped structures
US3444246A (en) * 1961-06-01 1969-05-13 Hooker Chemical Corp 3,5-dicyclohexyl phenol
GB1032979A (en) * 1962-12-26 1966-06-15 Tokyo Shibaura Electric Co Process for preparing filmy adhesive
US3379561A (en) * 1964-03-18 1968-04-23 Tokyo Shibaura Electric Co Process of preparing filmy adhesive
JPS5010408B2 (en) * 1971-11-06 1975-04-21
US4021410A (en) * 1971-11-13 1977-05-03 Nippon Kynol Inc. Melt-spun drawn or undrawn flame-resistant and antifusing cured epoxy-modified novolak filaments and process for production thereof
JPS5021568B2 (en) * 1972-06-03 1975-07-24
DE2813000C2 (en) * 1977-03-24 1982-04-08 Andreas Milano Pavel Electroacoustic system for high quality reproduction of audio events
CN104087222B (en) * 2014-04-28 2016-01-20 湖北大学 A kind of preparation method of soybean oil based two-component keel tackiness agent
EP3569629B1 (en) * 2018-05-17 2022-07-06 Evonik Operations GmbH Fast curing epoxy systems

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2040212A (en) * 1936-05-12 Water-soluble condensation
DE576177C (en) * 1930-11-11 1933-05-08 Louis Blumer Fa Process for the production of resinous products from phenol condensation products and polyhydric alcohols
GB455849A (en) * 1934-09-20 1936-10-26 Aceta Gmbh Improvements in the manufacture of artificial silk, films and like products
BE466573A (en) * 1945-07-13 1900-01-01
US2615008A (en) * 1945-09-18 1952-10-21 Devoe & Raynolds Co Epoxide resin compositions
US2506486A (en) * 1948-04-21 1950-05-02 Union Carbide & Carbon Corp Thermosetting resin from a diphenol and a diglycidyl ether of a diphenol
US2615007A (en) * 1950-12-08 1952-10-21 Devoe & Raynolds Co Epoxide resins

Also Published As

Publication number Publication date
BE503546A (en)
FR1061644A (en) 1954-04-14
FR1057836A (en) 1954-03-11
US2683130A (en) 1954-07-06
GB721153A (en) 1954-12-29

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